Variation Of Electrical Conductivity Research Articles

Assessing an Abandoned Pyrite Cinder Deposit in Southeast Spain with Electrical Resistivity Tomography: A Case Study

Industrial activities have historically generated significant quantities of by-products, including pyrite cinders, a residue produced during the synthesis of sulphuric acid. This study presents a multidisciplinary approach to characterise an abandoned pyrite cinder deposit. Combining geophysical (electrical resistivity tomography—ERT), geochemical, and statistical methods, we assess the physicochemical properties of the deposit and its environmental implications. Our findings reveal the presence of heavy metals, with lead (7017.5 mg.kg−1) being the most concentrated element on the surface of the deposit, exceeding local legal thresholds by more than 163 times, posing environmental risks and inhibiting vegetation growth. Subsurface characterisation indicates a decreasing concentration trend of metals with depth, alongside variations in pH and electrical conductivity. Clustering analysis identifies groups of similar behaviours between resistivity, the most abundant heavy metals, and other variables, providing valuable insights into the complex interplay within the deposit. Our study underscores the importance of integrated approaches in assessing and managing hazardous waste sites, with implications for environmental remediation strategies.

Role of sodium sulfate in electrical conductivity and structure of lignin-derived carbons

Lignin is a promising renewable alternative to fossil fuels for producing carbon materials such as carbon fibers, activated carbons, or carbon black. Despite extensive research, lignin-derived carbon materials show limited graphitization relative to comparable petroleum-derived carbons. Further, lignin-derived carbons show high variation in graphitization and electrical conductivity depending on the source of the lignin. Herein, nine lignins, derived from various feedstocks and isolation procedures, are pyrolyzed to produce biochar at 1100∘C. These lignins have a range of chemical compositions, carbon structures, and particle sizes. As a result, the pyrolysis behavior of these lignins varies, with powdered, clumped powder, and “foam” biochar morphologies resulting from finely powdered lignin. The produced biochars vary widely in both electrical conductivity, from 0.19 to 19 S/cm, and in-plane graphitic crystallite size, from 3.4 to 41.2Å. A significant decrease in electrical conductivity is identified when Na2SO4 is removed from lignin, accompanied by an increase in graphitic crystallite size. Based on this finding, a quadratic relationship between biochar graphitic crystallite aspect ratio and electrical conductivity is proposed that builds on established quasi-percolation models for biochar electrical conductivity.

Impact of variable electrical conductivity, viscosity on convective heat and mass transfer flow of CuO- and Al2O3-water nanofluids in cylindrical annulus

In the food industry, electrical conductivity is essential for heating processes. The dependence on temperature conductivity of electricity on the outermost layers flow of the nanofluid is the main topic of this paper. Variable electrical conductivity, viscosity, thermo diffusion, thermal radiation and radiation absorption on convective heat and mass transfer flow Cuo and Al2O3-water nano-fluids confined in cylindrical annulus. The non-linear governing equations have been solved by finite element technique with quadratic approximation functions. For various parametric adjustments, the temperature, speed, and nanoconcentration have all been examined. Similar to the cylindrical wall, quantitative evaluations have been made of the surface resistance, temperature rate and mass transport. It is discovered that for both types of nanofluids, a higher thermo-diffusion effect leads to a lower concentration and Sherwood digits on the cylinders. An augment in Q1 enriches the rapidity in CuO-water nanofluidic system as well as decreases in Al2O3-water nanofluidic. Increased Q1 lowers the real temperature and nanoconcentration in both types of nanofluids.

Quenching of zonal winds in Jupiter’s interior

Gravity and magnetic field data obtained by the Juno mission show that Jupiter's strong zonal winds extend a few thousand kilometers into the interior, but are quenched above the level where the electrical conductivity becomes significant. Here, we extend a simple linearized model [Christensen et al., Astrophys. J. 890, 61 (2020)] that explains the braking of the jets by the combination of stable stratification and electromagnetic effects. We show that in the inviscid limit, the process is essentially governed by a single parameter, which we call the MAC-number (for the forces acting on the flow-Magnetic, Archimedian, and Coriolis). The predictions for the drop-off of the zonal winds agree well with results from 3D-convection models. We run calculations that take the full range of density and electrical conductivity variations in the top 5,600 km of Jupiter into account. In order to satisfy constraints on the power driving the jets and on their effect on Jupiter's magnetic field, the top of the stable layer and the region where the jet velocity drops sharply must be near 2,000 km depth. The dissipation associated with quenching of the jets increases toward the poles, which can partly explain why the jets near [Formula: see text]20[Formula: see text] are faster than those at higher latitude.

Numerical assessment of viscoelastic tetra hybrid nanofluid flow across a stretchable rotatory disk under the Soret and Dufour aspects

PurposeFluid flows through rotatory disks are encountered in industrial and practical engineering processes, such as computer storage devices, gas turbine rotators, rotating machinery, air cleaning machines, etc. The primary purpose of this research is to examine the combined aspects of variable electrical conductivity, thermal radiation, Soret and Dufour effects on a magnetohydrodynamic Maxwell single-walled carbon nanotubes–graphene oxide–multi-walled carbon nanotubes–copper (SWCNT–GO–MWCNT–Cu)/sodium alginate tetra-hybrid nanofluid flow through a stretchable rotatory disk.Design/methodology/approachThe modeled administrative equations of the present flow problem are converted to a non-dimensional system of ordinary differential equations by applying suitable similarity conversion and then solved numerically by implementing the bvp4c method. The impressions of noteworthy dimensionless parameters on velocity, temperature, concentration distributions, Nusselt number, skin friction and Sherwood number are reported via graphs and tables.FindingsThe authors figured out that the developed values of the rotation parameter diminish the temperature but enhance both the radial and angular velocities. Further, the mass and heat transmission rates are better for tetra-hybrid nanofluids than for ternary and hybrid nanofluids.Originality/valueThe present study emphasizes a special type of fluid called the tetra-hybrid nanofluid. The existing literature has not discussed the Maxwell tetra hybrid nanofluid flow through a stretchable rotatory disk with variable electrical conductivity. Besides, the novel aspects of magnetohydrodynamics, thermal radiation, Soret and Dufour effects are also incorporated into the present flow problem.

Cryosphere and land cover influence on stream water quality in Central Asia's glacierized catchments

This work helps address recent calls for systematic water quality assessment in Central Asia and considers how nutrient and salinity sources, and transport, affect water quality along the continuum from the cryosphere to the lowland plains. Spatial and, for the first time, temporal variations in stream water pH, temperature, electrical conductivity, and nitrate and phosphate concentrations are presented for four catchments (485–13,500 km2), all with glaciers and major urban areas. The catchments studied were: Kaskelen (Kazakhstan), Ala-Archa (Kyrgyzstan), Chirchik (Uzbekistan) and the Kofarnihon (Tajikistan). Measurements were made in cryosphere, stream water, groundwater, reservoir and lake samples over a 22-month period at fortnightly intervals from 35 sites. The results highlight that glacier, permafrost and rock glacier outflows were primary and secondary nitrate sources (>1 mg N L−1) to the headwaters, and there were major increases in salinity and nitrate concentrations where rivers receive inputs from agriculture and settlements. Overall, the water quality complied with national and World Health Organization standards, however there were pollution hot-spots with shallow urban groundwaters contaminated with nitrate (>11 mg N L−1) and stream electrical conductivity above 800 μS cm−1 in some agricultural areas indicative of high salinity. Phosphate concentrations were generally low (<0.06 mg P L−1) throughout the catchments, though elevated (>0.2 mg P L−1) in urban areas due to effluent contamination. A melt water dilution effect along the main river channels was discernible, in the electrical conductivity and nitrate concentration seasonal dynamics, 100 s of km from the headwaters. Thus, the input of relatively clean water from the cryosphere is an important regulator of main channel water quality in the urban and farmed lowland plains adjacent to the Tien Shan and Pamir. Improved sewage treatment is needed in urban areas.

Lateral electrical conductivity variations along the Main Himalayan thrust in the northwestern Himalayas: Insights from 3D Magnetotelluric forward modeling

Understanding the arc parallel variation on the geometry of the Main Himalayan Thrust (MHT) is as important as understanding the arc perpendicular variation in the Himalayas. The geometric variability of the MHT holds significant implications for the occurrence of major and great earthquakes. Three-dimensional magnetotelluric (MT) forward modeling enables the investigation of potential crustal models along the MHT in northwest Himalayas. MT impedance tensors were computed utilizing the 3D forward modeling code MTD3FWD. Previously established MT resistivity and seismic velocity models from various sectors of the northwestern Himalayas were employed as inputs for generating the resistivity mesh necessary for 3D forward modeling. The computed impedance tensors by 3D forward computation were cross-referenced with the original published MT data to validate their accuracy. A lateral resistivity cross section is also derived from the 3D forward model along the sub-Himalaya and lesser-Himalaya region to study the lateral heterogeneity. The lateral resistivity cross-section reveals significant heterogeneity within the crust, marked by both high and low-resistive structures and a possible lateral ramp along the MHT. The geometry of the lateral MHT showcases a gradual incline within the Himachal sector and a steep ramp within the Garhwal and Kumaun sectors in the northwestern Himalayas. The crustal architecture exhibits distinct nearly-vertical resistive and conductive features beneath the study area. Consequently, the crust within this region is characterized by considerable heterogeneity, influenced by a network of subsurface faults and ridges. The Delhi Haridwar Ridge, which exhibits high resistivity, plays a significant role in dictating the lateral dip of the MHT and exerting control over seismic activity patterns in the region.

Mapping of Groundwater Recharge Zones in Hard Rock Aquifer through Analytic Hierarchy Process in Geospatial Platform

Extensive use of groundwater is a result of the growing population; in relation to this, studies have focused on groundwater conservation measures. This study identified groundwater artificial recharge zones (GWARZs) in the upper Manimuktha sub-basin through the application of remote sensing and GIS. A spatial analysis using the analytical hierarchical process (AHP) and weighted overlay analysis (WOA) was employed by integrating several spatial thematic layers such as geology, geomorphology, aquifer thickness, lineament density (LD), drainage density (DD), soil, slope, rainfall, and land use/land cover (LULC) in order to classify the GWARZs. The geomorphology along with lithology, higher aquifer thickness, low lineament densities, higher drainage densities, and gentle slope regions, were identified as suitable areas for artificial recharge zones. The study area was divided up into five classifications based on the integration analysis: excellent (41.1 km2), good (150.6 km2), moderate (123.9 km2), bad (125.5 km2), and very poor (57.7 km2). Excellent and good GWARZs were identified in the eastern and central regions of the study area. The final outcomes of this research were evaluated with seasonal electrical conductivity (EC) variations. The majority of samples with minor seasonal EC variations were observed in the excellent and good GWARZ categories. The results showed that the spatial analysis tool is useful for GWARZ delineation and sustainably managing groundwater resources.

Synergistic corrosion inhibition of rubber seed extract with KI on cold rolled steel in sulfuric acid solution

BackgroundPlant-based inhibitor has emerged an important topic owing to the combing merits of eco-friendly, low cost, rich natural resources as well as easy preparation. Rubber seed is the agricultural waste, and is mainly composed of oil and fatty acids those contain many polar oxygen atoms, and so it can be extracted to prepare the potential corrosion inhibitor. MethodsRubber seed extract (RSE) is prepared using reflux extraction method with the extracting solvent of ethanol aqueous solution. The synergistic inhibition effect of RSE and potassium iodide (KI) on the corrosion of cold rolled steel (CRS) in 0.50 M H2SO4 solution is firstly studied by weight loss, potentiodynamic polarization (PDP) curves and electrochemical impedance spectroscopy (EIS) methods. CRS surface was thoroughly characterized using metallographic microscope, scanning electron microscope (SEM), atomic force microscope (AFM), X-ray photoelectron spectroscopy (XPS) and contact angle measurements. FTIR, UV–vis and liquid chromatography mass spectrometry (LC-MS) compositional analysis of RSE were used to analyze the efficient components in RSE. Significant findingsThe results indicate that individual RSE or KI cannot function as a successful inhibitor to prevent CRS corrosion, but the mixture of RSE/KI performs better at inhibiting, with a maximal inhibition efficacy of up to 96.4% of 200 mg L−1 RSE/100 mg L−1 KI. The synergistic coefficient of the mixture is larger than 1, indicating that a true synergism. RSE/KI can drastically retard both cathodic and anodic processes, and interfacial capacitance falls as the charge transfer resistance of CRS/solution rises. It exhibits remarkable inhibition properties when the capacitor arc grows. There is only a small corrosion response in the inhibited media, as evidenced by the variations in electrical conductivity and ultraviolet spectrum before and after immersion. The hydrophilicity and surface roughness of CRS surface is dropped as a result of the introduction of RSE/KI. A series of metallurgical microscopy, AFM, SEM or contact angle tests indicate a synergistic inhibition effect is more pronounced for RSE/KI. XPS results clearly demonstrate that elements including Fe, S, N, and I are bonded to the surface of CRS. The primary ingredients of oleic acid, polyphenols, phenylpropanoids can also produce a strong synergism with KI.

Viscous dissipation and Joule heating in case of variable electrical conductivity Carreau–Yasuda nanofluid flow in a complex wavy asymmetric channel through porous media

This paper focuses on flow structures and thermal fields of the Carreau–Yasuda (CY) nanofluid model through a two-dimensional, wavy, complicated vertical asymmetrical conduit filled with porous elements. Formulations of the viscous dissipation in the case of CY nanofluids are derived and nonlinear radiation flux as well as joule heating are examined. Buongiorno’s nanofluid approach, which involves Brownian motion and thermophoresis aspects is considered. The electrical conductivity of the suspension is considered as a variable where it depends upon the ambient temperature and concentration distributions and the Joule heating impacts are not neglected. The approach of solving the problem is contingent upon converting the system to dimensionless form then the lubrication approach with low magnetic Reynold numbers is applied. Numerical solutions are found for the resultant system, and wide ranges are considered for Weissenberg number We, non-Newtonian parameter n and Darcy number [Formula: see text], namely, [Formula: see text], [Formula: see text] and [Formula: see text], respectively. The major results indicated that gradients of the pressure are higher in case of shear thickening [Formula: see text] comparing to in the instance of shear thinning [Formula: see text]. Also, the velocity is enhanced, close to the channel’s lowest portion, as the Weissenberg number is growing. The variable electrical conductivity gives a higher mass transfer rate compared to the constant property.

Multivariate statistical analysis of bioavailability of heavy metals and mineral characterization in selected species of coastal flora

This study presents a thorough investigation into the concentration of heavy metals and mineral composition within four distinct coastal flora species: Cyperus conglomeratus, Halopyrum mucronatum, Sericostem pauciflorum, and Salvadora persica. Employing rigorous statistical methodologies such as Pearson coefficient correlation, principal component analysis (PCA), analysis of variance (ANOVA), and interclass correlation (ICC), we aimed to elucidate the bioavailability of heavy metals, minerals, and relevant physical characteristics. The analysis focused on essential elements including copper (Cu), iron (Fe), manganese (Mn), zinc (Zn), magnesium (Mg2+), calcium (Ca2+), sodium (Na+), potassium (K+), and chloride (Cl–), all of which are known to play pivotal roles in the ecological dynamics of coastal ecosystems. Through PCA, we discerned distinctive patterns within PC1 to PC4, collectively explaining an impressive 99.65% of the variance observed in heavy metal composition across the studied flora species. These results underscore the profound influence of environmental factors on the mineral composition of coastal flora, offering critical insights into the ecological processes shaping these vital ecosystems. Furthermore, significant correlations among mineral contents in H. mucronatum; K+ with content of Na+ (r = 0.989) and Mg2+ (r = 0.984); as revealed by ICC analyses, contributed to a nuanced understanding of variations in electrical conductivity (EC), pH levels, and ash content among the diverse coastal flora species. By shedding light on heavy metal and mineral dynamics in coastal flora, this study not only advances our scientific understanding but also provides a foundation for the development of targeted environmental monitoring and management strategies aimed at promoting the ecological sustainability and resilience of coastal ecosystems in the face of ongoing environmental challenges.

Electrical properties and conduction mechanisms of Ba0.75Sr0.25Ti1-xZrxO3 ceramics synthesized by sol-gel route

A series of Ba0.75Sr0.25Ti1-xZrxO3 (x = 0, 0.01, 0.03, 0.05, and 0.1) ceramics were synthesized via a facile sol-gel route. The confirmation of a tetragonal structure was achieved through Rietveld refinement of the powder X-ray diffraction (XRD), and the finding was subsequently corroborated by Raman spectroscopy. The Scanning electron microscopy (SEM) confirmed the roughly cubical-shaped grains and average grain size is 0.31 μm for x = 0 and 0.70 μm for x = 0.05. The electrical properties such as dielectric constant, dielectric loss and ac/dc conductivity were investigated as a function of temperature and frequency. The Jonscher's universal power law (JPL) and Arrhenius equation have been used for the analysis of conductivity. The electrical conductivity variation at intermediate frequencies was explained using JPL. The Super-linear power law (SPL) explains the electrical response at higher frequencies. The temperature-dependent frequency exponents ‘s1’ and ‘s2’ were employed to predict the quantum mechanical tunneling (QMT), non-overlapping small polarons hopping (NSPT), and correlated barrier hopping (CBH) conduction mechanisms.

Investigation of spectroscopic and electrical properties of doped poly(pyrrole-3-carboxylic acid)

The spectroscopic and electrical properties of poly(pyrrole-3-carboxylic acid) doped with p-TSA- (p-toluenesulfonate) and AQS- (anthraquinone sulfonate) were investigated. The variation in electrical conductivity as a function of temperature shows that the systems have semiconductor-like electrical characteristics. The investigated polymers exhibit 3D conductivity and less than 0.6 eV energy gaps. The IR and Raman spectra show that the charge carriers are polarons and bipolarons. Doping the poly(pyrrole-3-carboxylic acid) increases the number of charge carriers. Electron paramagnetic resonance has shown that localized polarons and bipolarons are formed within these polymers.

Global well-posedness for the inhomogeneous incompressible MHD equations with variable viscosity coefficient and electrical conductivity

In this paper, we study the Cauchy problem for the inhomogeneous incompressible MHD system with variable viscosity coefficient and electrical conductivity. It is shown that the 3-D inhomogeneous incompressible MHD system has unique global solutions with small initial data conditions. Furthermore, we establish the global well-posedness of the two-dimensional MHD equations in critical spaces, given certain conditions on the density.

Electrical Conductivity, Basic Cations and Organic Matter content of Soils under different Land use Practices in AkwaIbom State

Variation in electrical conductivity, basic cations and organic matter content of soils can be influenced by land use practices, and these parameters may be affected by another. The study was conducted to ascertain the electrical conductivity (EC), basic cations and organic matter content of soils under varying land use types and to assess the relationship between electrical conductivity and the other parameters. The land use types were intensively cultivated farmland (ICF), natural forest (NF), oil palm plantation (OPP) and gmelina plantation (GP). Stratified random sampling technic was used in the collection of soil samples from the land use types. Three (3) replicates of bulk soil were collected for each land use giving a total of twelve (12) observational units. Soil samples were prepared and analyzed in a laboratory and data generated were subjected to analysis of variance, regression analysis and descriptive statistics. There was significant (P≤0.05) variation in the measured parameter among soils of the land use types. Soils under ICF, OPP, and GP had similar electrical conductivity of 0.08 (dS/m), while NF had 0.10 (dS/m). Organic matter (OM) content of 13.3 g/kg, 19.0 g/kg, 15.3 g/kg and 18.7 g/kg were observed under ICF, NF, OPP and GP, respectively. Exchangeable calcium at ICL was 2.33 cmol/kg; at NF it was 2.50 cmol/kg; at OPP, it was 2.40cmol/kg, and 1.93cmol/kg at GP. Exchangeable magnesium (Mg) was highest (1.07 cmol/kg) at ICL but lowest (0.93cmol/kg) at GP. Similarly, ICF had highest (1.73cmol/kg) and NF had lowest (0.04 cmol/kg) for exchangeable sodium. Calcium and magnesium had significant (P≤0.05) positive relationships with electrical conductivity, while organic matter and sodium had negative but non-significant relationship with electrical conductivity. The soils do not have salt problem and may not be prone to salinity in the future, meanwhile, organic matter input should be increased at the soil under intensively cultivated farmland.

Variation of electrical properties with temperature for polyethylene oxide doped with 0.1 wt. % iodine

The electrical properties of thin films made of polyethylene oxide (PEO) dispersed with dopants fixed amount of iodine (0.1 wt. %) were studied using the AC impedance technique. The films were prepared by electrically casting method. In this present work, the variation of AC electrical conductivity with temperatures ranging from 30 oC to 55 oC at a frequency of 200 kHz for (PEO) film doped with 0.1wt. % iodine and undoped (PEO) film were studied. Physical quantities and parameters such as AC conductivity, impedance, dielectric constant, and dielectric loss, were determined. The observed values of the impedance (Z), dielectric constant ('), dielectric loss ("), and AC-conductivity (σAC) showed temperature dependence. It was found that the dielectric constant and the dielectric loss of the prepared thin films increased with doped (0.1wt. %) iodine complexes and also increased with the increase of temperature according to the polarization processes.

Response of the TEROS 12 Soil Moisture Sensor under Different Soils and Variable Electrical Conductivity.

In this work, the performance of the TEROS 12 electromagnetic sensor, which measures volumetric soil water content (θ), bulk soil electrical conductivity (σb), and temperature, is examined for a number of different soils, different θ and different levels of the electrical conductivity of the soil solution (ECW) under laboratory conditions. For the above reason, a prototype device was developed including a low-cost microcontroller and suitable adaptation circuits for the aforementioned sensor. Six characteristic porous media were examined in a θ range from air drying to saturation, while four different solutions of increasing Electrical Conductivity (ECw) from 0.28 dS/m to approximately 10 dS/m were used in four of these porous media. It was found that TEROS 12 apparent dielectric permittivity (εa) readings were lower than that of Topp's permittivity-water content relationship, especially at higher soil water content values in the coarse porous bodies. The differences are observed in sand (S), sandy loam (SL) and loam (L), at this order. The results suggested that the relationship between experimentally measured soil water content (θm) and εa0.5 was strongly linear (0.869 < R2 < 0.989), but the linearity of the relation θm-εa0.5 decreases with the increase in bulk EC (σb) of the soil. The most accurate results were provided by the multipoint calibration method (CAL), as evaluated with the root mean square error (RMSE). Also, it was found that εa degrades substantially at values of σb less than 2.5 dS/m while εa returns to near 80 at higher values. Regarding the relation εa-σb, it seems that it is strongly linear and that its slope depends on the pore water electrical conductivity (σp) and the soil type.

Effects of Variable Electrical Conductivity Levels in Hydroponic Nutrient Solutions on Morphological and Physiochemical Characteristics of Cucumber Plants in Advanced Greenhouse Cultivation

Cucumber (Cucumus sativus L.) is a fruit of the Cucurbitaceae family that is refreshing, low in calories, and offers various health benefits due to its rich nutritional profile. However, high-tech hydroponic greenhouse production of cucumber is nutrient-intensive and requires efficient management of electrical conductivity (EC) in the growing medium. In this study, three different EC levels (1.3, 2.6, and 3.6 dS/m) were applied to the nutrient medium of hydroponically grown Lebanese and Continental varieties of cucumber. The experiment did not have a significant impact on the number of fruits (p=0.744, p=0.163) or leaves per plant (p=0.252, p=0.377) at varying EC levels. However, in the Continental variety, pH (0.001***) and osmolality (0.005**) were significantly different among the three varied EC levels. High EC levels in the nutrient medium resulted in reduced TSS, pH, and osmolality of the fruit juice. Although the plants grown in low EC conditions produced almost the same number of fruits and leaves per plant as those grown in optimal EC conditions (2.6 dS/m), the physio-chemical attributes of the cucumbers were of inferior quality.

Irreversibility Analysis for Magnetized and Nonlinear Convection Flow of Carreau Fluid Past a Nonlinear Surface with Higher-Order Adherence Factor

Studying entropy generation allows scientists and engineers to optimize processes, design more efficient systems, and develop sustainable technologies. These studies aim towards minimizing energy losses, reducing environmental impacts, and advancing the frontiers of thermodynamics and energy science. As such, the current investigation expunges the dynamics of heat, flow, entropy and irreversibility analysis for a magnetized and dissipative Carreau fluid flow over a nonlinearly stretching sheet. The model is subject to thermal and electrical conductivity variations, higher-order adherence factors and nonlinear convective motion over an inclined nonlinear surface. Herein, the heat source in the flow system is considered space and temperature-dependent. The mathematical model presented in PDE systems is transformed to ODEs via similarity transformation. Numerically, the solutions to the distribution profiles are approximated via Chebyshev Collocation Method (CCM) with the pseudospectra (differentiation matrix) technique. In the limited case, the results here benchmark existing literature. Our findings identified that thermal irreversibility dominated the entire flow system, further entropy generation and irreversibility enhancement requires more thermal energy. We as well elucidate that alteration of both heat source modulation affects the heat transfer coefficient while Joule heating effect generates inner energy which induces the Carreau fluid energy. Carreau fluid, Entropy generation Momentum slip, Nonlinear Convection, Pseudo spectral method

Natural responses of Neoproterozoic dynamic karst springs to rainfall events, São Miguel Watershed, Minas Gerais, Brazil

AbstractKarst aquifers consist of complex networks of conduits in which groundwater flows and recharge/discharge processes are generally more dynamic than in other types of aquifers. Due to their intrinsic heterogeneity and anisotropy, monitoring, quantifying, and analysing natural responses of karst springs is an efficient tool. Unlike Cenozoic and Mesozoic rocks, in Neoproterozoic karst systems, groundwater circulates and stores generally in dissolution features known as tertiary porosity, as the rock's primary porosity is recrystallized, considered negligible. This article studies the hydrodynamics of a karst portion of the São Miguel River basin, southwest of the state of Minas Gerais, Brazil. The region is predominantly composed of Neoproterozoic carbonate rocks, dating from about 570 to 540 million years ago. During a hydrological year (2019–2020), three karst springs (S1, S2, and S3) were daily monitored through their natural responses (variations of electrical conductivity, EC, temperature, T, and discharge, Q) to rainfall episodes. The data were interpreted based on the analysis of spring hydrographs, time series, recession curves (seasonal and intra‐annual), and statistics of EC, T, and Q variations. The results show the three springs generally exhibit quick flow, typically karstic, in the case of hydrosystems with a well‐structured and functional underground drainage network. The time series indicate the hydrosystem drained by S1 presents slower circulation and a lower degree of linearity, resulting from the higher sinuosity of the system, while the hydrosystems of S2 and S3 have similar behaviours, of quick water circulations immediately after a rainy episode. The degrees of karstification classify S1 and S2 as complex and extensive karst systems consisting of several subsystems, and S3 as a system in which the conduit network is more developed at the upper epiphreatic zone than near the outlet.