Variation Of Layer Thickness Research Articles

Heterogeneity of nanoparticle deposition micro-structure and modeling deposition layer thickness variation underneath periodically growing single boiling bubbles in nanofluids

Nanoparticle deposition in nanofluid boiling can significantly impact heat transfer efficiency. However, there is still much to be uncovered regarding the heterogeneity of micro-structures in nanoparticle deposition and how to quantitatively model variations in deposition layer thickness. To gain a deeper understanding, we conducted experiments where single boiling bubbles were grown from an artificial micro-cavity in SiO2 nanofluids with varying concentrations and durations under a constant heat flux. Our results reveal that the nanoparticle deposition region increases with concentration and boiling duration. Notably, while the deposition morphology is irregular near the bubble nucleation site, it becomes more uniform further away from the bubble nucleation site. We believe that the heterogeneity in the micro-structure of the deposition layer is due to differences in the evaporation time of the liquid microlayer at different positions, variations in its thickness beneath a single boiling bubble, and dependency of nanoparticles Brownian motion on temperature. Additionally, the thickness of the deposition layer decreases as the distance from the nucleation site increases. To accurately describe this variation in thickness, we have proposed a semi-empirical correlation based on the liquid microlayer evaporation theory and the conservation of mass of nanoparticles beneath a single boiling bubble. The thickness of the nanoparticle deposition layer is determined by the number of growing bubbles, liquid density, initial thickness of the liquid microlayer, local nanoparticle concentration, and local nanoparticle stacking density. This study provides valuable insights into optimizing micro-structures or thickness of the deposition layer, leading to improved nanofluid boiling heat transfer.

Wafer-Scale Emission Energy Modulation of Indium Flushed Quantum Dots

Semiconductor self-assembled quantum dots (QDs) have garnered immense attention for their potential in various quantum technologies and photonics applications. Here, we explore a novel approach for fine-tuning the emission wavelength of QDs by building upon the indium flush growth method: Submonolayer variations in the capping thickness reveal a non-monotonic progression, where the emission energy can decrease even though the capping thickness decreases. indium flush, a well-known technique for inducing blue shifts in quantum dot emissions, involves the partial capping of QDs with GaAs followed by a temperature ramp-up. However, our findings reveal that the capping layer roughness, stemming from fractional monolayers during overgrowth, plays a pivotal role in modulating the emission energy of these QDs. We propose increased indium interdiffusion between the QDs and the surrounding GaAs capping layer for a rough surface surrounding the QD as the driving mechanism. This interdiffusion alters the indium content within the QDs, resulting in an additional emission energy shift, counterintuitive to the capping layer’s thickness increase. We utilize photoluminescence spectroscopy to generate wafer maps depicting the emission spectrum of the QDs. Using thickness gradients, we produce systematic variations in the capping layer thickness on 3″ wafers, resulting in modulations of the emission energy of up to 26 meV.

InGaAs-Based MSM Photodetector: Researching Absorption Layer, Barrier Layer, and Digital Graded Superlattice Layer with 3D Simulation

The effects of absorption, barrier, and digital graded layer thickness on dark current and photocurrent in Metal Semiconductor Metal (MSM) photodetectors by using 3D Silvaco TCAD are reported. The photo-dark current ratio (Iphoto/Idark) is calculated using the photocurrent and dark current values obtained by simulation. In study A (absorption layer thickness variation) the photocurrent, dark current and photo-dark current ratio are increased with increased absorption layer thickness, and the dark current is 1.138x10-7 A levels. In Study B (barrier layer thickness variation), when the barrier layer is added to the absorption layer, the dark current is decreased to 1.56x10-11 A levels. It is reported that the photo-dark current ratio with increasing barrier layer thickness increases. In study C (digital graded superlattice layer thickness variation), the dark current increases, and photocurrent decreases with the increase of the digital graded superlattice layer thickness. However, the photo-dark current ratio with increasing digital graded superlattice layer thickness decreases. Furthermore, a similar trend of development is observed on photo-dark current with adding of the barrier layer and digital graded superlattice layer on the absorption layer. These findings demonstrate the importance of optimizing layer thickness in MSM photodetectors for improved device performance.

Three-dimensional instrument polarization analysis and optimization of liquid-crystal-based Stokes polarimeter.

The Stokes polarimeter based on liquid crystal variable retarders (LCVRs) is a space polarization measurement technology widely used. However, due to the tilt of the optic axis of the LCVR with the driving voltage in the direction of light propagation and the interference in LCVR, the LCVRs-based Stokes polarimeter produces a large instrument polarization, which affects the accurate polarization measurement. In this paper, we combine polarization ray tracing with multi-beam interference, and establish a general three-dimensional polarization analysis model of the LCVRs-based Stokes polarimeter. The simulation results of adjusting the LCVR voltage to reduce the instrument polarization are analyzed, and the variation of polarization measurement accuracy with the field of view before and after optimization of the LCVRs-based Stokes polarimeter is simulated and analyzed. A LCVR structure with additional films for matching the refractive index is proposed. According to the simulation results, this structure can significantly reduce the interference effects and reduce the impact of variations in liquid crystal layer thickness on the interference effects.

Thickness-variation-insensitive near-infrared quantum dot LEDs

In terms of tunable luminescence and high quantum efficiency, colloidal quantum dots (CQDs) are promising semiconductors for constructing near-infrared light-emitting diodes (NIR-LEDs). However, currently available NIR-LEDs are susceptible to variations in the emission layer thickness (EMLT), the highest external quantum efficiency (EQE) decreases to below 50% (relative to peak EQE) when the EMLT varies out of a narrow range of (±30 nm). This is due to the thickness-dependent carrier recombination rate and current density variation, resulting in batch-to-batch EQE fluctuations that limit LED reproducibility. Here we report efficient NIR-LEDs that exhibit EQE variations of less than 15% (relative to the champion EQE) over an EMLT range of 40–220 nm; the highest achievable EQE of ∼11.5% was obtained by encapsulating a 212 nm-thick CQD within a type-I inorganic shell to enhance the radiative recombination in the dots, resulting in a high photoluminescence quantum yield of 80%, and by post-treating the films with a bifunctional linking agent to improve and balance the hole and electron mobilities in the entire film (electron mobility: 8.23 × 10−3 cm2 V−1 s−1; hole mobility: 7.0 × 10−3 cm2 V−1 s−1). This work presents the first NIR-LEDs that exhibit EMLT-invariant EQE over an EMLT range of 40–220 nm, which represents the highest EQE among reported CQD NIR-LEDs with a QD thickness exceeding 100 nm.

Performance optimization of high-K GAA-PZT negative capacitance FET MFIS silicon nanowire for low power RFIC and analog applications

In this article, Gate-All-Around Lead Zirconate Titanate Negative Capacitance (GAA PZT- NCFET) based Silicon Nanowire (SiNW) device architecture is investigated for the RF/Analog applications using Sentauras TCAD simulations. In this study the variation of ferroelectric layer thicknesses (tfe) has been systematically investigated. The proposed device yields higher values of on current, transconductance, cut off frequency, TFP, and Ion/Ioff ratio and lower values of off current, SS and threshold voltage, compared to baseline device. The proposed device delivers Ion, gm, fT, and TFP as 3.38 mA, 9.6 mS, 7.625 THz, and 74.85 THz V−1, respectively which are 220%, 219%, 95% and 259% respectively, higher than the baseline device. Moreover, the Ion/Ioff ratio for the proposed work is 8 × 1013 which is 7.1 × 103 times that of baseline device showing a monumental increment in this ratio. Furthermore, the effect of FE thicknesses on various linearity parameters, higher order harmonics, voltage intercept points (VIP2, VIP3), third order power intercept (IIP3) and third order intermodulation distortion (IMD3) have been investigated thoroughly. The proposed device structure offers lower values of higher order harmonics and higher values of voltage intercept points. Also, the IIP3 and IMD3 have been improved. Therefore, the linearity parameters of the device have been significantly improved when compared to the baseline device. The alluring results have been utilized to optimize the bias point of the presented device. Owing to the improved RF/Analog and linearity performance, the presented device could be utilized for imminent next generation low power RFIC applications.

Dynamic Mapping of Electrochemiluminescence Reactivity in Space: Application to Bead-Based Assays.

As an electrochemical technique offering an optical readout, electrochemiluminescence (ECL) evolved recently into a powerful microscopy technique with the visualization of a wide range of microscopic entities. However, the dynamic imaging of transient ECL events did not receive intensive attention due to the limited number of electrogenerated photons. Here, the reaction kinetics of the model ECL bioassay system was revealed by dynamic imaging of single [Ru(bpy)3]2+-functionalized beads in the presence of the efficient tripropylamine coreactant. The time profile behavior of ECL emission, the variations of the ECL layer thickness, and the position of maximum ECL intensity over time were investigated, which were not achieved by static imaging in previous studies. Moreover, the dynamics of the ECL emission were confronted with the simulation. The reported dynamic ECL imaging allows the investigation of the ECL kinetics and mechanisms operating in bioassays and cell microscopy.

Performance Signature of the Best Candidate-Graded Bandgap Materials for Solar Cells with Steady-State Conversion Efficiency

This is a comprehensive research endeavor focused on enhancing the efficiency of the proposed solar cell design. The integration of the simulation techniques, judicious material selection, and meticulous performance metrics showcase a methodical approach toward creating a solar cell capable of achieving high efficiency across a wide spectrum of light in the AM 1.5 G1 sun solar cell illumination spectrum. Having said this, many researchers are still working on the efficiency potential—based on external radiative efficiency (ERE), open-circuit voltage loss, and fill factor loss—of high-efficiency solar cells. The solar cell is built on aluminum-doped zinc oxide (ZnO) as a transparent conductive oxide layer; aluminum nitride (AlN) as the window layer (emitter); an SWCNT layer as the absorber layer; gallium phosphide (GaP) as the contact layer; and silicon as the substrate. The proposed solar cell transmission, reflection, and absorption relative to the variations in wavelength band spectrum are studied. The conduction and valence band energy diagrams of the solar cell design structure are simulated against the layer thickness variations for the suggested solar cell structure. Short-circuit current density and maximum power variations are clarified versus the bias voltage. Light current density is simulated versus the bias voltage (J/V characteristics curve) of the suggested solar cell design structure. The carrier generation–recombination rate is also simulated by the COMSOL simulation program versus the layer thickness of the suggested solar cell structure. The solar cell circuit design has a fill factor (FF) value of 74.31% and a power conversion efficiency value of 29.91%.

Exploring the impact of strain on the electronic and optical properties of inorganic novel cubic perovskite Sr3PI3

Inorganic perovskite materials have drawn great attention in the realm of solar technology because of their remarkable structural, electronic, and optical properties. Herein, we investigated strain-modulated electronic and optical properties of Sr3PI3, utilizing first-principles density-functional theory (FP-DFT) in detail. The SOC effect has been included in the computation to provide an accurate estimation of the band structure. At its Г(gamma)-point, the planar Sr3PI3 molecule exhibits a direct bandgap of 1.258 eV (PBE). The application of the spin-orbit coupling (SOC) relativistic effect causes the bandgap of Sr3PI3 to decrease to 1.242 eV. Under compressive strain, the bandgap of the structure tends to decrease, whereas, under tensile strain, it tends to increase. Due to its band properties, this material exhibits strong absorption capabilities in the visible area, as evidenced by optical parameters including dielectric function, absorption coefficient, and electron loss function. The increase in compressive or tensile strain also causes a red-shift or blue-shift behavior in the photon energy spectrum of the dielectric function and absorption coefficient. Finally, the photovoltaic (PV) performance of novel Sr3PI3 absorber-based cell structures with SnS2 as an Electron Transport Layer (ETL) was systematically investigated at varying layer thicknesses using the SCAPS-1D simulator. The maximum power conversion efficiency (PCE) of 28.15% with JSC of 34.65 mA cm−2, FF of 87.30%, and VOC of 0.92 V was found for the proposed structure. Therefore, the strain-dependent electronic and optical properties of Sr3PI3 studied here would facilitate its future use in the design of photovoltaic cells and optoelectronics.

The influence of bone model geometries on the determination of skull acoustic properties.

In this study, we investigated the impact of various simulated skull bone geometries on the determination of skull speed of sound and acoustic attenuation values via optimization using transmitted pressure amplitudes beyond the bone. Using the hybrid angular spectrum method (HAS), we simulated ultrasound transmission through four model sets of different geometries involving sandwiched layers of diploë and cortical bone in addition to three models generated from CT images of ex-vivo human skull-bones. We characterized cost-function solution spaces for each model and, using optimization, found that when a model possessed appreciable variations in resolvable layer thickness, the predefined attenuation coefficients could be found with low error (RMSE < 0.01 Np/cm). However, we identified a spatial frequency cutoff in the models' geometry beyond which the accuracy of the property determination begins to fail, depending on the frequency of the ultrasound source. There was a large increase in error of the attenuation coefficients determined by the optimization when the variations in layer thickness were above the identified spatial frequency cutoffs, or when the lateral variations across the model were relatively low in amplitude. For our limited sample of three CT-image derived bone models, the attenuation coefficients were determined successfully. The speed of sound values were determined with low error for all models (including the CT-image derived models) that were tested (RMSE < 0.4 m/s). These results illustrate that it is possible to determine the acoustic properties of two-component models when the internal bone structure is taken into account and the structure satisfies the spatial frequency constraints discussed.

TiO2 coatings on titanium obtained by anodising in a 2% Na2SiO3 solution at various voltages

Commercially pure titanium is recognised as one of the most biocompatible materials used in everyday medicine, particularly in prosthodontics. However, its high reactivity with oxygen and low thermal expansion makes titanium difficult to process, making it less popular as a material for porcelain fused to metal substructures. Analysing the available literature studies, both positive and negative effects of the oxide layer on the titanium-ceramic bond have been found. The given work attempted to anodically create oxide coatings in a 2% Na2SiO3 solution on commercially pure titanium, which could serve as substructures for crowns and dental bridges.Grade 2 titanium discs (diameter 20 mm, height 5 mm) were ground and polished. The alloy composition was determined by X-ray fluorescence analysis. The samples were divided into six groups and subjected to anodic oxidation in a 2% Na2SiO3 solution at constant voltages: 230 V, 270 V, 300 V, 350 V, 400 V, and a time of t = 1 min. The obtained oxide layers were examined by X-ray diffraction, chemical composition analysis, and SEM observation.Coating thicknesses ranging from 0.65 μm to 13.2 μm were obtained. Besides titanium oxide, an amorphous phase is present in the anodised layer.It is crucial to provide the ideal voltage directly related to the employed solution to maintain the useable thickness of the oxide layers. Variations in oxide layer thickness beyond optimal value may lead to exfoliating if it exceeds 1 μm or present fractures if it subceeds 1 μm.Titanium oxide layers obtained by anodic oxidation are mainly tested on their biocompatibility and tissue integration so important in implantology. However, the given paper focuses on creating oxide layers that may strengthen the bond between titanium and dental ceramics.

Propagation of ship noise in shallow water over a high shear-speed seabed

Assessing the acoustic impact of shipping close to the coast and within ports and harbours requires an understanding of the propagation of underwater sound in these environments. In the Australian context, this often means propagation over seabeds with shear speeds approaching the in-water sound speed, a situation that results in very different propagation conditions to the low shear speed sediments more commonly encountered in other parts of the world. Acoustic propagation modelling approaches were explored using a dataset of continuous underwater recordings featuring a mix of shipping, industrial, and recreational activities, acquired from 23 Jul to 16 Sep 2022 in Cockburn Sound, off the west coast of Australia. Cockburn Sound is a sheltered marine embayment with a relatively uniform water depth of 17–20 m in the 5 km × 11 km central portion of the basin, with a thin, variable thickness (0.5 m–5 m) layer of silty sediments overlying a calcarenite basement. The results of modelling the calcarenite basement as an equivalent fluid were compared to those obtained by modelling it as an elastic solid, and with measurements. Subsequent implications of the choice of geoacoustic model will be discussed

Diversity and evolution of cerebellar folding in mammals.

The process of brain folding is thought to play an important role in the development and organisation of the cerebrum and the cerebellum. The study of cerebellar folding is challenging due to the small size and abundance of its folia. In consequence, little is known about its anatomical diversity and evolution. We constituted an open collection of histological data from 56 mammalian species and manually segmented the cerebrum and the cerebellum. We developed methods to measure the geometry of cerebellar folia and to estimate the thickness of the molecular layer. We used phylogenetic comparative methods to study the diversity and evolution of cerebellar folding and its relationship with the anatomy of the cerebrum. Our results show that the evolution of cerebellar and cerebral anatomy follows a stabilising selection process. We observed two groups of phenotypes changing concertedly through evolution: a group of 'diverse' phenotypes - varying over several orders of magnitude together with body size, and a group of 'stable' phenotypes varying over less than 1 order of magnitude across species. Our analyses confirmed the strong correlation between cerebral and cerebellar volumes across species, and showed in addition that large cerebella are disproportionately more folded than smaller ones. Compared with the extreme variations in cerebellar surface area, folial anatomy and molecular layer thickness varied only slightly, showing a much smaller increase in the larger cerebella. We discuss how these findings could provide new insights into the diversity and evolution of cerebellar folding, the mechanisms of cerebellar and cerebral folding, and their potential influence on the organisation of the brain across species.

Suppression of epitaxial grain growth in laser powder bed fusion fabricated Inconel 625 through intermittent variation of the build layer thickness

Microstructural anisotropy, which often leads to anisotropy in the mechanical performance, induced by the epitaxial grain growth during solidification is a major concern in a number of metal and alloy components that are manufactured using the additive manufacturing technique of laser powder bed fusion (LPBF). In this work, we demonstrate that a periodic variation in the layer thickness during LPBF results in the alteration of the grain growth direction and can effectively suppress the formation of columnar grains. Such a build strategy simultaneously decreases the grain size and the texture intensity, resulting in a reduced anisotropy in the mechanical properties. The variation of grain growth direction can be rationalized by thermal gradient variation near the transition area that occurs after the layer thickness is altered. This simple strategy provides an additional and new tool for grain structure tailoring during LPBF.

A novel narrow-band red-emitting multi-layer phosphor for white – Light emitting devices

SrZr2La2O7: Eu+3 (0.5–2.5 mol %) phosphors have been synthesized through the standard solid-state reaction technique. The photoluminescent and other structural properties such as PXRD (Powder X-ray Diffraction), SEM (Scanning Electron Microscopy) and Energy Dispersive X-ray spectroscopy (EDX), FTIR (Fourier transform infrared spectroscopy), PSD (Particle Size Distribution) of the phosphors were learned. The photoluminescence spectra show that the phosphor exhibited intense and dominant red emissions at 627 nm belonging to the 5D0 → 7F2 electric dipole transition. The FWHM of the red emissions at 627 nm is only 8.0 nm increasing in luminous efficacy. Hereby we propose a novel RED phosphor for RED emitting LEDs with phosphor-embedded polymer matrix layers of variable thickness and stacking up to 400 µm. The intensity of the red color was enhanced by self-excitation of photon absorption and emission. As a result, Eu3+doped SrZr2La2O7 phosphors can be widely used as red phosphors in UV chip-based WLEDs and displays. The phosphor exhibits high color purity up to 99% when excited at 590 nm. X-ray powder diffraction analysis confirms that the phosphor is highly crystalline and has a cubic phase.

Processing condition dependency of increased layer thickness on surface quality during electron beam powder bed fusion

The energy beam and powder layer interaction influences the dynamic melt behavior and determines the surface quality in electron beam powder bed fusion (PBF-EB). It is generally believed that increasing the powder layer thickness favors production efficiency but is contradictory to improving the forming quality. How variations in the powder layer thickness affect the interaction between the electron beam and the powder bed, which influences the melt behavior and resultant surface quality, has not been well understood. In this study, cylindrical specimens with increased nominal layer thicknesses from 80 to 140 μm were prepared using PBF-EB. The study verified the processing feasibility of ensuring the forming quality under a high layer thickness. Within the processing regime of this study, a relatively large powder layer thickness expanded the processing window. According to the thermophysical-property analysis of the powder bed, the emissivity and thermal conductivity exhibited upward and downward trends, respectively, with increased powder layer thickness. The increased thickness reduced the fusion efficiency, restricting the height difference within the overall sample surface caused by overheating. The numerical simulation clarified the dependence of the layer thickness-effect on the processing conditions. The proportion of incomplete melted powder in the electron beam irradiating area increased at a high scan speed. Subsequently, the hindering effect on heat absorption and transfer caused by the powder layer and its increased thickness was fully manifested. That is, the evolution trend of melt behavior and surface morphology resulting from increased layer thickness is remarkable at high scan speeds.

Microstructures and nanomechanical properties of nanolaminated Ta/Co composites and their strengthening mechanisms

In this study, nanolaminated tantalum (Ta)/cobalt (Co) composites (NTCCs) with an individual layer thickness (h) ranging from 5 nm to 100 nm were fabricated via magnetron sputtering. The microstructures and nanomechanical properties of the NTCCs were affected by variation in h. The NTCCs showed nanograin structures in Ta and Co layers, with Ta and Co textures that were randomly oriented. Nanohardness (H) and corresponding yield strength, σys=H/2.7, of the NTCCs gradually increased from 5.75 ± 0.15 GPa to 7.20 ± 0.13 GPa and from 2.12 ± 0.06 GPa to 2.67 ± 0.05 GPa, respectively, with reducing h from 100 nm to 5 nm. NTCC showed an extraordinarily high yield strength (∼ 2.67 GPa) at h = 5 nm due to its reduced individual layer thickness and non-defective microstructures, which is well above the maximum yield strength of studied nanolaminated materials (comprised of at least one hcp constituent), to date. The creep depth of 5 nm NTCC was lower than that of the 100 nm NTCC, and the creep deformation of 5 nm NTCC is related to the bending, breaking, and intermixing of Ta and Co layers, whereas the 100 nm NTCC exhibited bending and thinning of Ta and Co layers with more deformation. Strain rate sensitivity (m) of NTCC increased from 0.0666 to 0.2076 with increasing h from 5 nm to 100 nm. The Hall–Petch and Confined Layer Slip strengthening mechanisms governed the strength of the NTCCs for h = 25–100 nm and h = 10 nm, respectively. It is worth noting that the 5 nm NTCC did not follow any of the strengthening mechanisms and became independent of h; rather, the strength at this length scale was greatly influenced by grains, layer thickness, and microstructural variations at the interfaces. The increased σys and E at h = 5 nm may facilitate tailoring the mechanical properties of NTCCs with high strength and ductility.

Performance based assessment of a small-scale artificially nourished beach

In coastal engineering studies, coastal protection procedures can be provided by hard and soft methods. Soft methods applied using the right techniques and methods are not only long-lasting but also adapt to the natural structure of the coast. This study aims to present monitoring the development of a small-scale artificial nourished beach between the groins for 15 months and analyze its performance. For this purpose, field studies were carried out with land and sea observations taken once before nourishment and at 8 different times after nourishment. The seabed and profile variations observed at different sections were analyzed after processing field data. For determining the characteristics of the natural beach and borrow area before nourishment a sieve analysis was done for sediment samples taken from the shoreline, beach face, and 1-m depth on the nourished area. Sediment transportation of nourished material was observed by monitoring the amount of material remaining in 3 sub-regions (a nearshore region between the groins - A, a region representing the seaward end of the groins - B, and a region offshore of the groins - C) in the nourished region over time. The relationship between this behavior and waves was examined by considering the wave roses and time series of wave parameters produced as a result of wave simulations performed with the third-generation wave hindcast model SWAN. Lastly, as well as the variation of the mean layer thickness, the retreat of coastline, and mean beach width on the nourished area by the time were extracted for 8 different surveys. The results show that artificial beach nourishment materials were eroded in less than five months and the beach width returned to its initial position. The nourished material transported out groin-protected area moved eastward due to north-west dominated waves and the eastward longshore transport.

Numerical study of MoSe2-based dual-heterojunction with In2Te3 BSF layer toward high-efficiency photovoltaics

In this study, molybdenum diselenide (MoSe2)-based dual-heterojunction with Indium Telluride (In2Te3) as an absorber and a back surface field (BSF) layers with Al/ITO/CdS/MoSe2/In2Te3/Ni heterostructure has been studied by SCAPS-1D simulator. To explore the potentiality of layered materials in photovoltaic devices, a detailed investigation has been executed on the CdS window, MoSe2 absorber, and In2Te3 BSF layers at varied layer thicknesses, carrier concentrations, interface and defect densities, resistances, and operating temperatures. The photoconversion efficiency (PCE) of 24.78% with short circuit current J sc of 30.55 mA cm−2, open circuit voltage V oc of 0.95 V, and fill factor FF of 85.5% were obtained in the reference cell (without the In2Te3 BSF layer), while a notably improved PCE of 29.94% (5.16% higher) with J sc of 31.06 mA cm−2, V oc of 1.10 V, and FF of 87.28% was achieved by inserting the In2Te3 BSF layer. With a favorable band alignment and almost similar chemical and physical properties as transitional metal dichalcogenides (TMDCs) materials, the proposed dual heterostructure with CdS, MoSe2, and In2Te3 exhibits huge potential as a photoactive material and paves a pathway for the fabrication of uniquely layered material-based thin, flexible high-efficiency solar cells.

Chlorine‐doped perovskite materials for highly efficient perovskite solar cell design offering an efficiency of nearly 29%

AbstractThe new form of renewable energy attracts enormous attention from researchers for its immense importance and impact on our daily life. A fossil energy is a non‐renewable source that will end shortly because of its immense use in houses and industries. Among the renewable sources, solar cells based on perovskite (PVK) materials exponentially increase their efficiency from 3.8% to 25.8% rapidly in a diminutive period of time. In the present study, doped and undoped PVK layers (MAPbI3, MAPb[I1‐xClx]3) are considered and optimized for solar cell application by using the SCAPS‐1D device simulator. A detailed investigation is done in terms of PVK absorber layer (PAL) thickness variation with different electron and hole transport layers, temperature, and bulk defect density to optimize the device performance. The MAPb(I1‐xClx)3‐based device delivered the highest conversion efficiency of ~29% with JSC of 25.59 mA/cm2, VOC of 1.348 Volt, and an FF of about 83.68%. Results reported in this work may pave the way for the development of advanced high‐efficiency PVK solar cells.