Air Pollution Variables Research Articles

Investigating the spatiotemporal associations between meteorological conditions and air pollution in the federal state Baden-Württemberg (Germany)

When analyzing health data in relation to environmental stressors, it is crucial to identify which variables to include in the statistical model to exclude dependencies among the variables. Four meteorological parameters: temperature, ultraviolet radiation, precipitation, and vapor pressure and four outdoor air pollution parameters: ozone (O3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ ext{O}_3$$\\end{document}), nitrogen dioxide (NO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ ext{NO}_2$$\\end{document}), particulate matter (PM2.5\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$PM_{2.5}$$\\end{document}, PM10\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$PM_{10}$$\\end{document}) were studied on a daily basis for Baden-Württemberg (Germany). This federal state covers urban and rural compartments including mountainous and river areas. A temporal and spatial analysis of the internal relationships was performed among the variables using (a) cross-correlations, both on the grand ensemble of data as well as within subsets, and (b) the Local Indications of Spatial Association (LISA) method. Meteorological and air pollution variables were strongly correlated within and among themselves in time and space. We found a strong interaction between nitrogen dioxide and ozone, with correlation coefficients varying over time. The coefficients ranged from negative correlations in January (−0.84), April (−0.47), and October (−0.54) to a positive correlation in July (0.45). The cross-correlation plot showed a noticeable change in the correlation direction for O3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ ext{O}_3$$\\end{document} and NO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ ext{NO}_2$$\\end{document}. Spatially, NO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ ext{NO}_2$$\\end{document}, PM2.5\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$PM_{2.5}$$\\end{document}, and PM10\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$PM_{10}$$\\end{document} concentrations were significantly higher in urban than rural regions. For O3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ ext{O}_3$$\\end{document}, this effect was reversed. A LISA analysis confirmed distinct hot and cold spots of environmental stressors. This work examined and quantified the spatio-temporal relationship between air pollution and meteorological conditions and recommended which variables to prioritize for future health impact analyses. The results found are in line with the underlying physico-chemical atmospheric processes. It also identified postal code areas with dominant environmental stressors for further studies.

The value of adding black carbon to community monitoring of particulate matter

Low-cost particulate matter (PM) sensors are increasingly used by researchers, public health agencies, and the public to measure spatial and temporal variations in air pollution, which can inform strategies for community air pollution reduction. While low-cost PM sensors provide a valuable measure of harmful fine particulate matter (PM2.5), a significant portion of ambient PM2.5 is typically the secondary product of air pollution emitted by varied sources outside of community boundaries. In contrast, concentrations of black carbon (BC), a component of PM2.5, are directly emitted by a few specific sources, such as diesel engines within communities. Motivated by community organizations seeking to understand persistent sources of local pollution, this study deployed a suite of custom-built BC sensors alongside a network of low-cost PM sensors for four weeks in two seasons at 50 stationary locations in the adjacent cities of Richmond, North Richmond, and San Pablo, California, east of the San Francisco Bay. Concentrations of BC varied more than PM2.5 both temporally and spatially. Monthly network-average BC was 3 × higher in winter than late spring, while PM2.5 was only 10% lower. In both seasons, average PM2.5 concentrations at two-thirds of sites were within ±10% of the network average, whereas two-thirds of sites had BC levels outside of ±10% of the network-average concentration. The most and least polluted locations were more persistent across seasons for BC than PM2.5, and the temporal dynamics of BC at these sites were similar, signifying that they are impacted by the same emission sources. Together, these spatiotemporal trends show that BC is a better indicator of the proximity and activity of local pollution sources than PM2.5. Thus, including BC in addition to PM2.5 in community monitoring networks can provide additional insights about local sources of air pollution.

The Role of Neighborhood Air Pollution in Disparate Racial and Ethnic Asthma Acute Care Use.

Rationale: The share of Black or Latinx residents in a census tract remains associated with asthma-related emergency department (ED) visit rates after controlling for socioeconomic factors. The extent to which evident disparities relate to the within-city heterogeneity of long-term air pollution exposure remains unclear. Objectives: To investigate the role of intraurban spatial variability of air pollution in asthma acute care use disparity. Methods: An administrative database was used to define census tract population-based incidence rates of asthma-related ED visits. We estimate the associations between census tract incidence rates and 1) average fine and coarse particulate matter, nitrogen dioxide (NO2), and sulfur dioxide (SO2), and 2) racial and ethnic composition using generalized linear models controlling for socioeconomic and housing covariates. We also examine for the attenuation of incidence risk ratios (IRRs) associated with race/ethnicity when controlling for air pollution exposure. Measurements and Main Results: Fine and coarse particulate matter and SO2 are all associated with census tract-level incidence rates of asthma-related ED visits, and multipollutant models show evidence of independent risk associated with coarse particulate matter and SO2. The association between census tract incidence rate and Black resident share (IRR, 1.51 [credible interval (CI), 1.48-1.54]) is attenuated by 24% when accounting for air pollution (IRR, 1.39 [CI, 1.35-1.42]), and the association with Latinx resident share (IRR, 1.11 [CI, 1.09-1.13]) is attenuated by 32% (IRR, 1.08 [CI, 1.06-1.10]). Conclusions: Neighborhood-level rates of asthma acute care use are associated with local air pollution. Controlling for air pollution attenuates associations with census tract racial/ethnic composition, suggesting that intracity variability in air pollution could contribute to neighborhood-to-neighborhood asthma morbidity disparities.

Short-term exposure to air pollution and hospital admission after COVID-19 in Catalonia: the COVAIR-CAT study.

A growing body of evidence has reported positive associations between long-term exposure to air pollution and poor COVID-19 outcomes. Inconsistent findings have been reported for short-term air pollution, mostly from ecological study designs. Using individual-level data, we studied the association between short-term variation in air pollutants [nitrogen dioxide (NO2), particulate matter with a diameter of <2.5 µm (PM2.5) and a diameter of <10 µm (PM10) and ozone (O3)] and hospital admission among individuals diagnosed with COVID-19. The COVAIR-CAT (Air pollution in relation to COVID-19 morbidity and mortality: a large population-based cohort study in Catalonia, Spain) cohort is a large population-based cohort in Catalonia, Spain including 240902 individuals diagnosed with COVID-19 in the primary care system from 1 March until 31 December 2020. Our outcome was hospitalization within 30 days of COVID-19 diagnosis. We used individual residential address to assign daily air-pollution exposure, estimated using machine-learning methods for spatiotemporal prediction. For each pandemic wave, we fitted Cox proportional-hazards models accounting for non-linear-distributed lagged exposure over the previous 7days. Results differed considerably by pandemic wave. During the second wave, an interquartile-range increase in cumulative weekly exposure to air pollution (lag0_7) was associated with a 12% increase (95% CI: 4% to 20%) in COVID-19 hospitalizations for NO2, 8% (95% CI: 1% to 16%) for PM2.5 and 9% (95% CI: 3% to 15%) for PM10. We observed consistent positive associations for same-day (lag0) exposure, whereas lag-specific associations beyond lag0 were generally not statistically significant. Our study suggests positive associations between NO2, PM2.5 and PM10 and hospitalization risk among individuals diagnosed with COVID-19 during the second wave. Cumulative hazard ratios were largely driven by exposure on the same day as hospitalization.

Development and application of a multi-task oriented deep learning model for quantifying drivers of air pollutant variations: A case study in Taiyuan, China

Quantitative assessment of the drivers behind the variation of six criteria pollutants, namely fine particulate matter (PM2.5), ozone (O3), nitrogen dioxide (NO2), sulfur dioxide (SO2), particulate matter (PM10), and carbon monoxide (CO), in the warming climate will be critical for subsequent decision-making. Here, a novel hybrid model of multi-task oriented CNN-BiLSTM-Attention was proposed and performed in Taiyuan during 2015–2020 to synchronously and quickly quantify the impact of anthropogenic and meteorological factors on the six criteria pollutants variations. Empirical results revealed the residential and transportation sectors distinctly decreased SO2 by 25 % and 22 % and CO by 12 % and 10 %. Gradual downward trends for PM2.5, PM10, and NO2 were mainly ascribed to the stringent measures implemented in transportation and power sectors as part of the Blue Sky Defense War, which were further reinforced by the COVID-19 pandemic. Nevertheless, temperature-dependent adverse meteorological effects (27 %) and anthropogenic intervention (12 %) jointly increased O3 by 39 %. The O3-driven pollution events may be inevitable or even become more prominent under climate warming. The industrial (5 %) and transportation sectors (6 %) were mainly responsible for the anthropogenic-driven increase of O3 and precursor NO2, respectively. Synergistic reduction of precursors (VOCs and NOx) from industrial and transportation sectors requires coordination with climate actions to mitigate the temperature-dependent O3-driven pollution, thereby improving regional air quality. Meanwhile, the proposed model is expected to be applied flexibly in various regions to quantify the drivers of the pollutant variations in a warming climate, with the potential to offer valuable insights for improving regional air quality in near future.

Decoding seasonal variability of air pollutants with climate factors: A geostatistical approach using multimodal regression models for informed climate change mitigation

In response to changes in climatic patterns, a profound comprehension of air pollutants (AP) variability is vital for enhancing climate models and facilitating informed decision-making in nations susceptible to climate change. Earlier research primarily depended on limited models, potentially neglecting intricate relationships and not fully encapsulating associations. This study, in contrast, probed the spatiotemporal variability of airborne particles (CO, CH4, SO2, and NO2) under varying climatic conditions within a climate-sensitive nation, utilizing multiple regression models. Spatial and seasonal AP data were acquired via the Google Earth Engine platform, which indicated elevated AP concentrations in primarily urban areas. Remarkably, the average airborne particle levels were lower in 2020 than in 2019, though they escalated during winter. The study employed linear regression, Pearson's correlation (PC), Spearman rank correlation models, and Geographically Weighted Regression (GWR) models to probe the relationship between pollutant variability and climatic elements such as rainfall, temperature, and humidity. Across all seasons, APs showed a negative correlation with rainfall while displaying positive correlations with temperature and humidity. The GWR and PC models produced the most reliable results from all the models employed, with the GWR model superseding the rest. Moreover, heightened aerosol levels were detected within a rainfall range of 600 mm/season, a temperature range of 25–30 °C, and humidity levels of 75 %–85 %. Overall, this study emphasizes the growing levels of APs in correlation with meteorological changes. By adopting a comprehensive approach and considering multiple factors, this research provides a more sophisticated understanding of the relationship between AP variability and climatic shifts.

Underappreciated Emission Spikes From Power Plants During Heatwaves Observed From Space: Case Studies in India and China

AbstractThe frequency, intensity, and duration of extreme heatwaves are projected to increase in the global context of climate change. However, evidence of how anthropogenic emissions respond to heatwaves and further impact air quality remains elusive. Here, we use satellite remote sensing measurements alongside chemical transport model simulations to reveal abrupt variations in primary and secondary air pollutants introduced by extreme heatwaves. We highlight evidence from China and India, where satellite sulfur dioxide (SO2) and nitrogen dioxide (NO2) columns over thermal power plants enhance consistently responding to heatwaves. We attribute such spiked emissions to soaring electricity use and demonstrate that bottom‐up inventories underestimate the emissions from the power sector by 34.9% for the selected case. Elevated emissions facilitate fine particulate matter (PM2.5) and ozone (O3) formation over thermal power plants in an inhomogeneous manner, due to the combined effect of atmospheric oxidizing capacity, thermal decomposition of peroxyacetyl nitrate, planetary boundary layer rise, and air stagnation. Our results underscore the emerging challenge of pollution control attributable to the increasing climate penalty and the necessity of targeted control strategies and alternative energy sources during heatwaves.

The price of clean air – quantifying air pollution exposure in real estate decisions

PurposeThe purpose of this paper is to explore the significance impact of air quality as a contributing factor on residential property rents by applying geo-informatics to economic issues. Since air pollution poses a severe health threat, city residents should have a right to know about the (invisible) hazards they are exposed to.Design/methodology/approachWithin spatial-temporal modeling of air pollutants in Berlin, Germany, three interpolation techniques are tested. The most suitable one is selected to create seasonal maps for 2018 and 2021 with pollution concentrations for particulate matter values and nitrogen dioxide for each 1,000 m2 cell within the administrative boundaries. Based on the evaluated pollution particulate matter values, which are used as additional variables for semi-parametric regressions the impact of the air quality on rents is estimated.FindingsThe findings reveal a compelling association between air quality and the economic aspect of the residential real estate market, with noteworthy implications for both tenants and property investors. The relationship between air pollution variables and rents is statistically significant. However, there is only a “willingness-to- pay” for low particulate matter values, but not for nitrogen dioxide concentrations. With good air quality, residents in Berlin are willing to pay a higher rent (3%).Practical implicationsThese results suggest that a “marginal willingness-to-pay” occurs in a German city. The research underscores the multifaceted impact of air quality on the residential rental market in Berlin. The evidence supports the notion that a cleaner environment not only benefits human health and the planet but also contributes significantly to the economic bottom line of property investors.Originality/valueThe paper has a unique data engineering approach. It collects spatiotemporal data from network of state-certified measuring sites to create an index of air pollution. This spatial information is merged with residential listings. Afterward non-linear regression models are estimated.

Revisiting the importance of temperature, weather and air pollution variables in heat-mortality relationships with machine learning.

Extreme heat events have significant health impacts that need to be adequately quantified in the context of climate change. Traditionally, heat-health association methods have relied on statistical models using a single air temperature index, without considering other heat-related variables that may influence the relationship and their potentially complex interactions. This study aims to introduce and compare different machine learning (ML) models, which naturally consider interactions between predictors and non-linearities, to re-examine the importance of temperature, weather and air pollution predictors in modeling the heat-mortality relationship. ML approaches based on tree ensembles and neural networks, as well as non-linear statistical models, were used to model the heat-mortality relationship in the two most populated metropolitan areas of the province of Quebec, Canada. The models were calibrated using a comprehensive database of heat-related predictors including various lagged temperature indices, temperature variations, meteorological and air pollution variables. Performance was evaluated based on out-of-sample summer mortality predictions. For the two studied regions, models relying only on lagged temperature indices performed better, or equally well, than models considering more heat-related predictors such as temperature variations, weather and air pollution variables. The temperature index with the best performance differed by region, but both mean temperature and humidex were among the best indices. In terms of modeling approaches, non-linear statistical models were as competent as more advanced ML models for predicting out-of-sample summer mortality. This research validated the current use of non-linear statistical models with the appropriate lagged temperature index to model the heat-mortality relationship. Although ML models have not improved the performance of all-cause mortality modeling, these approaches should continue to be explored, particularly for other health effects that may be more directly linked to heat exposure and, in the future, when more data become available.

Neighborhood-Level Air Pollution Monitoring and Analysis in Massachusetts

Air pollution is a significant environmental issue with far-reaching consequences for both human health and the planet. It arises from the emission of harmful pollutants, such as particulate matter, ozone, and nitrogen dioxide, into the atmosphere. These pollutants originate from various sources, including vehicles, industrial facilities, and power plants. The impacts of air pollution are wide-ranging, encompassing respiratory infections, cardiovascular disease, cancer, harm to ecosystems, and contributions to climate change. The study of air pollution is a multidisciplinary field that draws upon knowledge from physics, chemistry, biology, and engineering. Understanding the causes and effects of air pollution is crucial for developing effective strategies to mitigate its harmful effects. Physics, in particular, plays a vital role in this field by providing the tools and techniques required to measure and comprehend the behavior of pollutants. By examining air pollution, we gain insights into the factors driving this problem and can devise measures to reduce pollution levels. Moreover, this knowledge empowers individuals and societies to make informed decisions about minimizing exposure to pollutants and formulating policies and regulations that safeguard both human well-being and the environment. In our study conducted in the central Massachusetts region, we investigated the status of air pollution using a combination of Environmental Protection Agency (EPA) monitoring sites and hand-held sensors. While the EPA sites offer longterm monitoring data, hand-held devices’ flexible and affordable nature allowed us to explore air quality at the local neighborhood and street levels. By utilizing these tools, we assessed the spatial and temporal variations in air pollution within the city, aiding in the identification of localized hotspots. Such information is valuable for targeting specific areas requiring interventions and further understanding the dynamics of pollution distribution.

How urban air quality affects land values: Exploring non-linear and threshold mechanism using explainable artificial intelligence

Air pollution has a significant impact on human health and influences housing choices. Existing studies on determinant factors affecting property prices, including air pollution, mainly employed hedonic and spatial regression models that have limitations in capturing non-linear relationships and local interactions. Neglecting the non-linear relationships can lead to incomplete estimation impacts between explainable features and prices. To fill these gaps, this study used machine learning algorithms and SHAP (SHapley Additive exPlanations) to identify the relative importance of air pollutant variables on land values and their non-linear mechanism. The results showed that the Extreme Gradient Boosting (XGBoost) outperformed Ordinary Least Squares (OLS), Gradient Boosting Decision Tree (GBDT), Random Forest (RF), K-Nearest Neighbors (K-NN), and Extra Tree Regression (ETR) models in price prediction and capturing the non-linear relationship between air pollution and land values. Notably, Ozone (O3) and Nitric Oxide (NO) concentrations contribute 1.64% and 1.47% to land value variation, respectively. The results confirmed the non-linear relationship and identified that the threshold effect between air pollution and land values is at mean concentration values. Furthermore, we observed that the negative influence of O3 and NO on land values appears as their concentration level is higher than 29.3 and 13 ppb, respectively. This paper contributes valuable insights by advancing our understanding of the non-linear mechanism impact of air pollution on house and land values, informing environmental policymaking, and shedding light on housing decisions.

Spatial variation of air pollutants by using GIS modelling

&lt;p&gt;Air pollution in Tamil Nadu has become a pressing issue, as various pollutants have surpassed the limits established by the pollution control board. The major air pollutants in the region, namely sulphur dioxide, nitrogen dioxide, and suspended particulate matter, have been identified. This study aims to monitor and analyse the levels of air pollution in Tamil Nadu, with a specific focus on key parameters such as SO2, NO2, PM2.5, PM10, and ozone. By examining the atmospheric levels of these pollutants and their correlation with temperature fluctuations, the impact on human health and respiratory problems can be evaluated. Moreover, the study will assess the contribution of traffic emissions and vehicular pollution to the concentration of PM10 in different areas. Additionally, GIS technology will be utilized to spatially and temporally investigate pollution concentrations and evaluate their effect on the air quality index. By comparing the pollution concentration from thermal power stations and vehicular pollution, the study will identify the sources of pollutants, with a particular emphasis on SO2 and NOx emissions from vehicles and higher levels of suspended particulate matter from thermal stations. The analysis of these pollutants and their sources will provide valuable insights for the implementation of effective pollution control measures and the management of environmental pollution in Tamil Nadu. Given the concerns regarding pollutants exceeding the prescribed limits set by the pollution control board, monitoring air pollution in Tamil Nadu is of utmost importance.&lt;/p&gt;&#x0D;

Proposal of policies based on temporal-spatial dynamic characteristics and co-benefits of CO2 and air pollutants from vehicles in Shanghai, China

In megacities, vehicle emissions face urgent challenges related to air pollution and CO2 control. To achieve the refinement of vehicle control policies for the co-control of air pollutants and CO2, this study established a vehicle emission inventory with high spatial and temporal resolution based on the hourly traffic flow in Shanghai and analyzed the spatial and temporal distribution characteristics of the real-time vehicle emissions. Meanwhile, a policy evaluation framework was constructed by combining pollutant emission predictions with quantitative co-control effect assessments. The results indicated that spatio-temporal variations in different air pollutants and CO2 could mainly be attributed to primary contributing vehicle types. The pollutants (CO2, CO and VOCs) primarily contributed by private cars exhibited a bimodal pattern in 24-h time series and their spatial distribution was concentrated in the urban city center. The spatial distribution of NOx and PM primarily contributed by heavy trucks was still obvious on non-urban center areas. Furthermore, the results of synergistic effect analysis revealed that the alternative energy replacement scenario demonstrated the most significant potential for the co-control. Based on temporal-spatial and co-benefit analysis, the precise control policy of vehicle emissions can be established through time-, region-, and model-control. This study provides references and research methods for the formulation of the vehicle refinement control policies in worldwide megacities.

Characteristics of air pollution variation and potential source contributions of typical megacities in the Sichuan Basin, Southwest China

Characteristics of air pollution variation and potential source contributions of typical megacities in the Sichuan Basin, Southwest China

Variability of Air Pollutants in the Indoor Air of a General Store

This research investigates different facets of indoor air quality and the corresponding health symptoms within a retail environment. Formaldehyde, classified as a Group B carcinogenic substance, was found within safe limits indoors, primarily originating from surface coatings, flooring products, textiles, and furniture. Monoterpenes, lactic acid, and particulate matter levels were also assessed, with varying indoor–outdoor ratios. Notably, we identified a relatively low concentration of PM2.5, possibly influenced by enhanced cleaning practices during the COVID-19 pandemic. Symptom assessment revealed that many young workers experienced work-related symptoms, notably fatigue, nose-, throat-, and skin-related issues, aligning with previous findings. Although we could not conclusively link these symptoms to sick building syndrome (SBS) or formaldehyde exposure, it underscores the importance of further investigation. Notably, we observed no gender-based differences in symptom prevalence, but this study’s limited size requires caution in generalization. This study contributes to understanding indoor air quality and associated symptoms in an economically significant sector, emphasizing the need for continued research, especially considering the potential impact on workforce health in the broader context.

Distribution of COVID-19 Cases According to Environmental Pollutants and Meteorological Factors in Districts of Maharashtra

Abstract Introduction: Environmental factors such as temperature, precipitation, and various other pollutants in the air like nitrogen dioxide (NO2), CO2, etc., have been studied for sustenance and transmission of Coronavirus disease-19 (COVID-19). Studies from India are lacking about the distribution of COVID-19 cases according to air pollutants and meteorological factors. Hence, the present study was conducted to study the relationship between COVID-19 and environmental factors with the objectives of Cluster mapping of the COVID-19 cases district-wise for the state of Maharashtra. Methodology: The air pollution variables NO2 column density (mol/m2), sulfur dioxide column density (mol/m2), Aerosol absorbing index (Ai), Carbon monoxide (CO) column density (mol/m2), and Ozone column density (mol/m2) were extracted from Sentinel-5P datasets available in Google Earth Engine (GEE) (https://code.earthengine.google.com/). The meteorological variables precipitation (m), temperature (t), and humidity (k) were extracted from the European Environmental Agency 5-Land reanalysis dataset in GEE, which provides data at a resolution of 1113.2 m. The preprocessing and retrieval of data were carried out in GEE. These values were correlated with daily cases, density, and other demographic factors. Results: The study identified a cluster of cases in few districts of Maharashtra. These districts were Pune, Ahmednagar, Mumbai, Nashik, and Nagpur. Population density and NO2 were important factors in most of the monthly data. Conclusion: The present study used data available on public platforms to assess the association between COVID-19 and environmental factors. The study found that various environmental factors such as NO2, CO, and Ai may be associated with increase cases of COVID-19 in the district. However, ecological bias may be kept in mind.

Modeling NO2 air pollution variation during and after COVID-19-regulation using principal component analysis of satellite imagery

By implementing Principal Component Analysis (PCA) of multitemporal satellite data, this paper presents modeling solutions for air pollutant variation in three scenarios related to COVID-19 lockdown: pre, during, and after lockdown. Tropospheric NO2 satellite data from Sentinel-5P was used. Two novel PCA-models were developed: Weighted Principal Component Analysis (WPCA) and Rescaled Principal Component Analysis (RPCA). Model results were tested for goodness-of-fit to empirical NO2 data. The models were used to predict actual near-surface NO2 concentrations. Model-predicted NO2 concentrations were validated with NO2 data acquired at ground monitoring stations. Besides, meteorological bias affecting NO2 was assessed. It was found that the weather component had substantial impact on NO2 built-ups, propitiating air pollutant decrease during lockdown and increase after. WPCA and RPCA models well fitted to observed NO2. Both models accurately estimated near-surface NO2 concentrations. Modeled NO2 variation results evidenced the prolongated effect of the total lockdown (up to half a year). Model-predicted NO2 concentrations were found to highly correlate with monitoring station NO2 data collected on the ground. It is concluded that PCA is reliable in identifying and predicting air pollution variation patterns. The implementation of PCA is recommended when analyzing other pollutant gases.

Evaluation of total ozone measurements from Geostationary Environmental Monitoring Spectrometer (GEMS)

Abstract. The continued interest in air pollution and stratospheric ozone variability has motivated the development of a Geostationary Environmental Monitoring Spectrometer (GEMS) for hourly ozone monitoring. This paper provides the atmospheric science community with the world's first assessment of GEMS total column ozone (TCO) retrieval performance and diurnal ozone variation. The algorithm used for GEMS is a more advanced version of its predecessor, the Total Ozone Mapping Spectrometer (TOMS) V8, that incorporates several improvements, including a new lookup table, a simple Lambertian-equivalent reflectivity model, and a spectral dependence correction. The GEMS algorithm also uses the optimal estimation method (OEM) to make error analysis more accessible and robust. The estimated retrieval errors range from 1.5 to 2 DU in September and 2 DU in December, with a constant degree of freedom of the signal (DFS) of 1 in September and a variable DFS of 1.25 to 1.4 in December throughout the day, depending on solar zenith angle (SZA). To assess the performance of the GEMS algorithm, the hourly GEMS total ozone was compared with ground-based measurements from Pandora instruments and other satellite platforms from TROPOMI (TROPOspheric Monitoring Instrument) and OMPS (Ozone Mapping and Profiler Suite Nadir Mapper). GEMS has a high correlation of 0.97 and small RMSE values compared to Pandora TCO at Busan and Seoul in South Korea. It is notable that despite exhibiting seasonal dependence in the mean bias of GEMS with Pandora, GEMS is capable of observing daily variations in ozone that are highly consistent with Pandora measurements, with a bias of approximately 1 %. The comparison of GEMS TCO data with TROPOMI and OMPS TCO data shows a high correlation of 0.99 and low RMSE compared to TROPOMI and OMPS TCO data, but the data have a negative bias of −2.38 % and −2.17 %, with standard deviations of 1.33 % and 1.57 %, respectively. Similar to OMPS, the influence of SO2 from volcanic eruptions is not properly removed in some regions, leading to GEMS overestimating TCO in those areas. The mean biases of GEMS TCO data with TROPOMI and OMPS TCO are within ±1 % at low latitudes but become negative at midlatitudes, with an increasingly negative dependence on latitude. Furthermore, this dependence becomes more prominent from summer to winter. The empirical correction applied to the GEMS irradiance data improves the dependence of the mean bias on season and latitude, but a consistent bias still remains, and a marginal positive trend was observed in December. Therefore, further investigation into correction methods is needed. The results are a meaningful scientific advance by providing the first validated, hourly UV ozone retrievals from a satellite in geostationary orbit. This experience can be used to advance research with future geostationary environmental satellite missions, including the incoming TEMPO (Tropospheric Emissions: Monitoring of Pollution) and Sentinel-4.

Ultrafine particulate matter exposure during second year of life, but not before, associated with increased risk of autism spectrum disorder in BKMR mixtures model of multiple air pollutants

Prenatal and early postnatal air pollution exposures have been shown to be associated with autism spectrum disorder (ASD) risk but results regarding specific air pollutants and exposure timing are mixed and no study has investigated the effects of combined exposure to multiple air pollutants using a mixtures approach. We aimed to evaluate prenatal and early life multipollutant mixtures for the drivers of associations of air pollution with ASD. This study examined 484 typically developing (TD) and 660 ASD children from the CHARGE case-control study. Daily air concentrations for NO2, O3, ultrafine (PM0.1), fine (PM0.1-2.5), and coarse (PM2.5-10) particles were predicted from chemical transport models with statistical bias adjustment based on ground-based monitors. Daily averages were calculated for each exposure period (pre-pregnancy, each trimester of pregnancy, first and second year of life) between 2000 and 2016. Air pollution variables were natural log-transformed and then standardized. Individual and joint effects of pollutant exposure with ASD, and potential interactions, were evaluated for each period using hierarchical Bayesian Kernel Machine Regression (BKMR) models, with three groups: PM size fractions (PM0.1, PM0.1-2.5, PM2.5-10), NO2, and O3. In BKMR models, the PM group was associated with ASD in year 2 (group posterior inclusion probability (gPIP) = 0.75), and marginally associated in year 1 (gPIP = 0.497). PM2.5-10 appeared to drive the association (conditional PIP (cPIP) = 0.64) in year 1, while PM0.1 appeared to drive the association in year 2 (cPIP = 0.76), with both showing a moderately strong increased risk. Pre-pregnancy O3 showed a slight J-shaped risk of ASD (gPIP = 0.55). No associations were observed for exposures during pregnancy. Pre-pregnancy O3 and year 2 p.m.0.1 exposures appear to be associated with an increased risk of ASD. Future research should examine ultrafine particulate matter in relation to ASD.

Variation of air pollutants during COVID-19 lockdown phases in the mega-city of Lahore (Pakistan); Insights into meteorological parameters and atmospheric chemistry

Variation of air pollutants during COVID-19 lockdown phases in the mega-city of Lahore (Pakistan); Insights into meteorological parameters and atmospheric chemistry