Kems4Bats, a new research group initiated under the BMBF's NanoMatFutur framework at Hochschule Mannheim, employs both established and innovative experimental methods to analyze thermal and gaseous emissions in lithium-ion batteries. Operating from a state-of-the-art laboratory equipped with advanced instrumentation, the group examines how variations in electrode materials and particle dimensions influence diffusion and gas generation. Key research focuses include studying diffusion processes, the formation of solid electrolyte interfaces, and the impacts of fast charging on battery aging. Significant achievements of Kems4Bats include the development of a new instrument based on the KEMS (Knudsen effusion mass spectrometry) method, which enables precise, real-time in-situ measurements of gas evolution in lithium-ion batteries. Moreover, this device allows for highly accurate measurements of vapor pressures, particularly for organic substances with high vapor pressures, such as electrolyte solvents. Additionally, the group has established a battery production line, enhancing the safety and effectiveness of these energy storage systems.The improvement and detailed study of lithium-ion batteries are essential for advancing energy storage technologies. Understanding how gases evolve within these batteries during their formation, operational cycles, and aging is crucial for enhancing their performance and safety. Historically, Knudsen Effusion Mass Spectrometry (KEMS) has been an effective method for measuring the temperature-dependent vapor pressures of various materials, both organic and inorganic. This technique aids in calculating important thermodynamic properties. This study expands the application of KEMS to investigate gas evolution in lithium-ion batteries, marking a significant development in battery diagnostics.A unique prototype was developed to modify the KEMS approach, allowing for accurate monitoring of gas species evolution in lithium-ion batteries. This innovation not only provides detailed insights into the types and quantities of gases produced at different stages of the battery lifecycle but also broadens the traditional boundaries of KEMS measurements. Our modified system allows for the analysis of substances with high vapor pressures, such as electrolyte components, which were previously challenging to study due to methodological limitations.The results of this research shows the complex patterns of gas formation in lithium-ion batteries, providing essential insights for improving battery design and establishing higher safety standards. This research not only advances the field of battery technology but also highlights the adaptability of KEMS as a powerful tool in materials science.
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