Vapor Deposition Research Articles

Moisture Transformation in Warm Air Intrusions Into the Arctic: Process Attribution With Stable Water Isotopes

AbstractWarm Airmass Intrusions (WAIs) from the mid‐latitudes significantly impact the Arctic water budget. Here, we combine water vapor isotope measurements from the MOSAiC expedition, with a Lagrangian‐based process attribution diagnostic to track moisture transformation in the central Arctic Ocean during two WAIs, under contrasting sea‐ice concentrations (SIC). During winter with high SIC, two moisture supplies are identified. The first is Arctic moisture, locally‐sourced over the sea ice, with isotopic composition influenced by kinetic fractionation during ice‐cloud formation and vapor deposition. This moisture is rapidly overprinted by low‐latitude moisture advected poleward during WAI. In summer under low SIC, moisture is supplied through evaporation from land and ocean, with moisture removal via liquid‐cloud and dew formation. The isotopic composition reflects the influence of higher relative humidity at the evaporation sites. Given the projected increase of frequency and duration of WAIs, our study contributes to assessing process changes in the Arctic water cycle.

Influence of NiCrAlY coating on anti-corrosion of M951 alloy

M951 alloy is a cast nickel-based super-alloy widely used in gas turbines and aircraft engines, thus a suitable high temperature protective coating must be applied on its surface to enhance the corrosion resistance. In this research, NiCrAlY coating was deposited on M951 by arc ion plating. TGA at 1100 °C, cyclic oxidation at 1000 °C and hot corrosion in molten Na2SO4+25 wt% K2SO4 salt at 850 °C of M951 bare alloy and NiCrAlY coating specimens were investigated respectively. After TGA and cyclic oxidation, mixed oxides of NiO, NiAl2O4, Nb2O5 and Al2O3 formed on M951 surface, which spalled seriously during cyclic oxidation process. Thin, continuous and adhesive α- Al2O3 formed on the surface of NiCrAlY coating after both oxidation process. In molten Na2SO4+25 wt%K2SO4 salt at 850 °C, catastrophic corrosion occurred for the M951 alloy only after 10 hours, while thin and continuous θ- Al2O3 film formed on the surface of the NiCrAlY coating. In a word, NiCrAlY coating greatly improved the high temperature oxidation and hot corrosion resistance of the M951 superalloy. This study will further refine the oxidation and corrosion behaviors of M951 superalloy under different high temperature protective coatings and provides theoretical and experimental basis for the application of M951 superalloy in corrosive environments.

Correlation of Seebeck coefficient and selenization temperature in CuSe thin films grown on glass substrate

Copper selenide is emerging as a promising thermoelectric material that has the ability to harvest electricity from heat. In the present research work, copper selenide thin films were grown on glass substrate using thermal evaporation deposition technique. The phase transition from cubic to hexagonal structure was achieved by the selenization of grown samples at different temperatures (250, 300 and 350 °C) for 2 h. The phase, morphology and thermoelectric properties of the selenized CuSe thin films were studied using different characterization techniques. It was observed that the structural, morphological, and thermoelectric properties of the samples were modulated by varying the selenization temperature. XRD results suggested that as grown sample possessed a cubic phase but it transformed into hexagonal phase by selenization process. It was observed that Seebeck coefficient, electrical conductivity and power factor were modulated with the selenization temperature with maximum value of power factor (3.0 × 10−5±0.5 W m−1C−2) was obtained at optimal selinization temperature.

Integral LOCA experiments to study FFRD behavior of high burnup nuclear fuels

This paper introduces the Integral Loss Of Coolant (LOCA) facility (i-LOCA) established at Seoul National University. The facility was designed to investigate the integral fuel behavior of Light Water Reactors during LOCA, encompassing aspects such as cladding oxidation, ballooning and burst, reflood quenching, secondary hydriding, and fuel pellet dispersal. Integral LOCA experiments were carried out using three types of surrogate ZrO2 pellets, representing various segment burnups: cylindrical pellets with no fuel fragmentation (<55 GWd/MTU), mixed fragments of different sizes simulating ∼68 GWd/MTU (D = 0.3, 0.5, 1.0, 2.0, 3.0, and 5.0 mm with the same mass fraction), and small single powdered fragments simulating ultra-high burnup fuel (D = 0.5 mm, ∼94 GWd/MTU). Zr-Nb-Sn, Zr-1.1Nb, and Cr-coated (15 μm, Arc Ion Plating) Zr-1.1Nb ATF cladding were employed, with rod internal pressures ranging from 1 MPa to 7 MPa. The burst size and hoop strain exhibited significant variations depending on the type of surrogate pellets used, with larger burst sizes and hoop strains observed for smaller average diameters of surrogate pellets due to the effect of azimuthal and axial temperature distribution. Fuel dispersal was influenced by rod internal pressure, burst size, and the size of pellet fragments. Only pellet fragments smaller than the burst hole width underwent dispersal upon fuel burst, while larger fragments blocked the dispersal of smaller fragments. The rapidly escalating average dispersal fraction of single powder compared to mixed powder indicated a threshold burnup for fuel dispersal between 69–94 GWd/MTU. Cladding inner oxidation length was influenced by burst hole size and remaining fuel pellets. The results of inner oxidation confirmed the validity of the U.S. NRC’s assumption regarding the length of inner wall oxidation. The tested 15 μm Cr-coated cladding tubes, produced using the arc ion plating method, exhibited no significant differences in burst geometry, fuel dispersal, inner oxidation, and secondary hydriding when compared to the uncoated reference cladding.

Microstructure and stress evolution of W nanofilms prepared by arc ion plating under different deposition time and substrate bias

Microstructure and stress evolution of W nanofilms prepared by arc ion plating under different deposition time and substrate bias

Nitrogen doping of cuprous oxide films: A surface science perspective

Nitrogen doping of Cu2O films grown on Au(111) and Pt(111) supports was explored by a variety of surface-science techniques, including electron-diffraction, X-ray photoelectron-spectroscopy (XPS), scanning tunneling microscopy and photoluminescence spectroscopy (PL). The films were prepared by Cu vapor deposition and high-pressure oxidation at 50 mbar O2. Nitrogen was inserted by adding N2 to the reactive gas or via sputter doping. Only the latter resulted in a clear N1s signal in XPS, compatible with the insertion of N-atoms at O substitutional sites. The N-doping caused an overall degradation of the oxide lattice and suppressed the formation of the (√3×√3)R30° surface reconstruction observed on pristine Cu2O(111). Moreover, the oxide Fermi level shifted from the valence-band top into the band gap, indicative for a reduced p-type conductivity of the sample upon doping. The N-dopants featured low thermal stability and largely desorbed at around 500 K, leaving behind a pronounced 850 nm PL peak due to O vacancy emission. Our findings indicate that the N-atoms initially occupy O substitutional sites but get removed easily at moderate temperature, casting doubts whether N-doping is a suitable pathway to improve the conductance and luminescence behavior of Cu2O.

Simulated particle evolution within a winter storm: contributions of riming to radar moments and precipitation fallout

Abstract. Remote sensing radars from airborne and spaceborne platforms provide critical observations of clouds to estimate precipitation rates across the globe. The ability of these radars to detect changes in precipitation properties is advanced by Doppler measurements of particle fall speed. Within mixed-phase clouds, precipitation mass and its fall characteristics are especially sensitive to the effects of riming. In this study, we quantified these effects and investigated the distinction of riming from aggregation in Doppler radar vertical profiles using quasi-idealized particle-based model simulations. Observational constraints of a control simulation were determined from airborne in situ and remote sensing measurements collected during the Investigation of Microphysics and Precipitation for Atlantic Coast-Threatening Snowstorms (IMPACTS) for a wintry–mixed precipitation event over the northeastern United States on 4 February 2022. From the upper boundary of a one-dimensional column, particle evolution was simulated through vapor deposition, aggregation, and riming processes, producing realistic Doppler radar profiles. Despite a modest observed amount of supercooled liquid water (0.05 g m−3), riming accounted for 55 % of the ice-phase precipitation mass, cumulatively increasing reflectivity by 44 % and Doppler velocity by 68 %. Independent evaluation of process-based sensitivities showed that, while radar reflectivity is comparably sensitive to either riming- or aggregation-based particle morphology, the Doppler velocity profile is uniquely sensitive to particle density changes during riming. Thus, Doppler velocity profiles advance the diagnosis of riming as a dominant microphysical process in stratiform clouds from single-wavelength radars, which has implications for quantitative constraints of particle properties in remote sensing applications.

Surface modification and patterning of polymer thin films by plasma and adsorption behavior of proteins

The surface wettability property of hydrophobic polystyrene (PS) and hydrophilic polyethylene glycol (PEG) thin films subjected to modification by direct current plasma glow discharge is studied. The polymer films exhibited change of surface wettability on exposure to air, nitrogen, oxygen or argon plasmas. In PS films a swift modification to hydrophilic surface and subsequent steady recovery following first order kinetics are observed. The rate of modification and recovery are adjustable by adjusting the plasma ambient and parameters and additional wet-chemical treatment using ionic solutions. In PEG films the hydrophobic wettability evolve with ageing following the first order kinetics, and is stable for long period on exposure to air ambient. Moreover, a vapor deposition like process is possible using the PEG films as source to deposit self-assembled molecular layers with hydrophobic wettability on other surfaces. Using these surface modification or molecular deposition processes, the fabrication of wettability patterns in the surface of PS and PEG films and on other surfaces by vapor transport using PEG films, and also the possibility to produce gradient wettability patterns are demonstrated. Moreover, the adsorption behavior of immuno-specific system of proteins on surface modified hydrophilic PS films is studied.

A Review on Preparation of Palladium Oxide Films

Fabrication aspects of PdO thin films and coatings are reviewed here. The work provides and organizes the up-to-date information on the methods to obtain the films. In recent years, the interest in Pd oxide for different applications has increased. Since Pd can be converted into PdO, it is instructive to pay attention to the preparation of the pure and the alloyed Pd films, heterostructures, and nanoparticles synthesized on different substrates. The development of PdO films is presented from the early reports on coatings’ formation by oxidation of Pd foils and wires to present technologies. Modern synthesis/growth routes are gathered into chemical and physical categories. Chemical methods include hydrothermal, electrochemical, electroless deposition, and coating methods, such as impregnation, precipitation, screen printing, ink jet printing, spin or dip coating, chemical vapor deposition (CVD), and atomic layer deposition (ALD), while the physical ones include sputtering and cathodic arc deposition, laser ablation, ion or electron beam-induced deposition, evaporation, and supersonic cluster beam deposition. Analysis of publications indicates that many as-deposited Pd or Pd-oxide films are granular, with a high variety of morphologies and properties targeting very different applications, and they are grown on different substrates. We note that a comparative assessment of the challenges and quality among different films for a specific application is generally missing and, in some cases, it is difficult to make a distinction between a film and a randomly oriented, powder-like (granular), thin compact material. Textured or epitaxial films of Pd or PdO are rare and, if orientation is observed, in most cases, it is obtained accidentally. Some practical details and challenges of Pd oxidation toward PdO and some specific issues concerning application of films are also presented.

Effect of Zr/Dy on thermal corrosion resistant properties of NiCrAlY coatings

Dy or Zr doped NiCrAlY coatings were fabricated via arc ion plating technology on nickel-based single crystal superalloy. Thermal corrosion tests of NiCrAlY, NiCrAlYZr, and NiCrAlYDy coatings with 75 wt% Na2SO4 + 25 wt% NaCl mixed salt were conducted at 900 °C. The weight gain of the NiCrAlY, NiCrAlYZr, and NiCrAlYDy coating samples after 100 h of thermal corrosion was as follows: −11.32, 1.06 and −6.56 mg∙cm−2. The results indicated that the NiCrAlYZr coating exhibits superior thermal corrosion resistance compared to both NiCrAlY and Dy-doped NiCrAlY coatings due to the beneficial effects of Zr interacting with S and Cl, making it more effectively protect the hot components of aircraft engine from thermal corrosion.

Vertical multilayer structure of MoS2 flakes prepared by thermal evaporative deposition

In this investigation, we explore the synthesis of MoS2 through thermal evaporative deposition, seeking to uncover the growth dynamics and structural evolution of MoS2 under varied experimental conditions. By adjusting the temperature and the carrier gas, this study targets the fabrication of vertical multilayer MoS2 and its growth mode. Our analysis demonstrates that thermal conditions markedly influence flake morphology and dimensions, leading to a notable shift from AA to AB stacking configurations as temperatures rise in the vacuum. Additionally, the application of carrier distinctly modifies growth behaviors, enhancing the uniformity of nucleation sites and the propensity for lateral flake expansion. The insights gained from this research highlight the adaptability and effectiveness of thermal evaporative deposition in producing MoS2, thereby enriching our understanding of the fundamental mechanisms guiding MoS2 synthesis.

Structural and Optical Characterization of Cu2Se0.8S0.2 Thin Films Deposited by Thermal Evaporation

Abstract A simple cost thermal evaporation deposition technique was used to prepare of Cu2SeS thin films on the substrates made of glass at RT with thickness ( 500 + − 20 ) nm . Structural, and optical properties of these films were investigated. The films were structurally characterized using X-ray diffraction XRD analyses, the film samples were morphologically characterized using atomic force microscopy (AFM), and optical UV-Vis spectroscopy was also to characterize the samples. The films have been treated at deferent temperatures (403, 453 &amp;503) K for 1 hour, X-ray diffraction (XRD-with wavelength 1.54 A) study the structure properties of this films suggest a cubic structure and have prominent (111) orientation. AFM analysis, it is evident that Cu2SeS film is polycrystalline in nature, and that crystallite size and average grain size for films after annealing were increasing. The optical absorption coefficient (α) of the film was evaluated using absorbance spectra in the wavelength range (400-1100) nm. The direct band gap of about 2.2 eV, decrease by increasing annealing temperature, The structure and the optical characteristics of these films may have practical applications in renewable energy.

Growth of anthracene microcrystals by the micro-space sublimation method and their photophysical properties

Anthracene and its derivatives are widely utilized in optoelectronic devices due to their unique properties. Generally, single-crystal structures can avoid non-radiative recombination, enhance carrier mobility, and ultimately improve device performance. In this work, anthracene microcrystals were prepared using the micro-space sublimation method. Through real-time in-situ observation, the crystallization dynamics of anthracene molecules were revealed. Unlike traditional vacuum evaporation deposition technique, the close proximity of the substrate to the source facilitates the self-assembly of anthracene molecules into an ordered crystal structure. Six peaks can be observed in the photoluminescence spectrum, corresponding to various lowest excited state decay processes. The fluorescence intensity at the peak of 423 nm decreases significantly with increasing temperature. The reason for this is the relatively high exciton binding energy, which makes excitons more stable and easier to form. The lattice vibrations induced by increased temperature were found to affect the transport and separation of excitons. Time-resolved fluorescence spectroscopy imaging revealed that a relatively uniform distribution of fluorescence lifetimes in the anthracene microcrystals, indicating high crystallization quality. This work provides valuable insights for controlling the morphology and investigating the photophysical properties of organic semiconductors.

Quantitative characterization on influence of surface particles on corrosion behavior of multiarc ion plated CrAlN coatings

Surface particles on multiarc ion plated coatings are common defects, and their influence on the service performance of coatings is rarely defined. The CrAlN coatings were deposited on the tungsten steel (YG8) substrates using multiarc ion plating. The effects of the substrate bias voltages and nitrogen flow rates on the quantity of the surface particles were investigated, and the influence of the surface particles on the corrosion resistance of the coatings is quantitatively characterized. The morphology of surface particles was characterized using a scanning electron microscope. The quantity of the surface particles was counted by image software. The corrosion resistance of the coatings was evaluated through an electrochemical workstation. The results show that the quantity of surface particles decreased with the increase in the substrate bias voltage and nitrogen flow rate. The corrosion resistance of the coatings showed a positive correlation with the quantity of the surface particles, and it decreased dramatically when the quantity of the surface particles exceeded 111/10 000 μm2. The corrosion mechanism of the coatings was attributed to the defect-induced pitting corrosion.

Image Sensors and Photodetectors Based on Low‐Carbon Footprint Solution‐Processed Semiconductors

AbstractThis mini‐review explores the evolution of image sensors, essential electronic components increasingly integrated into daily life. Traditional manufacturing methods for image sensors and photodetectors, employing high carbon footprint techniques like thermal evaporation and chemical vapor deposition, are being replaced by environmentally conscious solution processing. Organic and Colloidal Quantum Dot‐based image sensors emerge as promising candidates, aligning with the shift toward solution‐based device integration. This review provides insights into the working principles of photodetectors and image sensors, summarizing relevant materials and fabrication approaches. Additionally, it delves into the detailed exploration of pixelated patterning techniques and their potential applications in the realm of solution‐processed image sensor fabrication.

Enhancing Efficiency and Stability of Inverted Perovskite Solar Cells through Solution-Processed and Structurally Ordered Fullerene.

The electron transporting layer (ETL) used in high performance inverted perovskite solar cells (PSCs) is typically composed of C60, which requires time-consuming and costly thermal evaporation deposition, posing a significant challenge for large-scale production. To address this challenge, herein, we present a novel design of solution-processible electron transporting material (ETM) by grafting a non-fullerene acceptor fragment onto C60. The synthesized BTPC60 exhibits an exceptional solution processability and well-organized molecular stacking pattern, enabling the formation of uniform and structurally ordered film with high electron mobility. When applied as ETL in inverted PSCs, BTPC60 not only exhibits excellent interfacial contact with the perovskite layer, resulting in enhanced electron extraction and transfer efficiency, but also effectively passivates the interfacial defects to suppress non-radiative recombination. Resultant BTPC60-based inverted PSCs deliver an impressive power conversion efficiency (PCE) of 25.3% and retain almost 90% of the initial values after aging at 85°C for 1500 hours in N2. More encouragingly, the solution-processed BTPC60 ETL demonstrates remarkable film thickness tolerance, and enables a high PCE up to 24.8% with the ETL thickness of 200 nm. Our results highlight BTPC60 as a promising solution-processed fullerene-based ETM, opening an avenue for improving the scalability of efficient and stable inverted PSCs.

Thermal Corrosion Properties of Composite Ceramic Coating Prepared by Multi-Arc Ion Plating

In this study, a NiCr/YSZ coating was applied to a γ-TiAl surface using multi-arc ion plating technology to enhance its high-temperature performance and explore the mechanisms of high-temperature oxidation and thermal corrosion. The thermal corrosion properties of the γ-TiAl matrix and NiCr/YSZ coating were investigated at 850 °C and 950 °C using a constant-temperature corrosion test in a 75% Na2SO4 + 25% NaCl mixture. The results indicate that after 100 h, the thermal corrosion weight gain of the coating samples was 70.1 mg/cm2 at 850 °C and 118.2 mg/cm2 at 950 °C. At these temperatures, sulfide formation on the surface increases, leading to a loose and porous surface. After 100 h of high-temperature corrosion at 850 °C, the primary oxidation product on the surface of the coating was tetragonal-ZrO2. At 950 °C, Y2O3, which mainly acts as a stabilizer in YSZ, reacted with Na2SO4, resulting in the continuous consumption of Y2O3. This reaction caused a substantial amount of tetragonal-ZrO2 to transform into monoclinic-ZrO2, altering the volume of the ceramic layer, which induced internal stress, crack propagation, and minor spallation. A continuous and dense internal thermally grown oxide (TGO) layer effectively impeded the diffusion of molten salt substances and oxygen, thereby significantly improving the thermal corrosion resistance of the thermal barrier coating.

Hot corrosion of sputtered nanocrystalline coating with and without preoxidation and arc ion plating coating on a Ni-based single-crystal superalloy

Hot corrosion of the N5 nanocrystalline coating with 0.5 wt% Y addition with and without preoxidation under 75 wt% Na2SO4 + 25 wt% NaCl molten salts at 900 °C was investigated, in comparison with that of the NiCrAlY coating under the same condition. The results showed that the nanocrystalline coating with nano-columnar structure suffered more severe corrosion than NiCrAlY coating. The high density of grain boundaries in the nanocrystalline coating facilitated inward penetration of the corrosive medium and accelerated the destruction of the scale. Preoxidation significantly enhanced the corrosion resistance of the nanocrystalline coating by forming an exclusive Al2O3 scale on the surface that could prevent molten salt from accessing the coating surface. The coating preoxidized at 1000 °C exhibited the highest corrosion resistance with the least internal corrosion. Y stabilized Ta and/or S during preoxidation and subsequent corrosion process, improving the purity and stability of the scale. The coating preoxidized at 1100 °C performed worse than that at 1000 °C. The inferior corrosion resistance was attributed to the more Ta oxides segregation and faster consumption of Al at the higher preoxidation temperature, accelerating scale destruction during hot corrosion.

Evaluation of wear resistance of CrN, CrAlN, and TiAlN coatings deposited by multi-arc ion plating on spinning die of Cr12MoV

Abstract This study successfully deposited CrN, CrAlN, and TiAlN coatings on the surface of Cr12MoV substrate using multi-arc ion plating (MAIP). The influence of phase composition and surface morphology on the hardness, adhesion strength, friction performance, and wear mechanisms of these coatings was investigated, with a comparative analysis of their wear resistance. Nanoindentation results revealed that the hardness (H) of CrN, CrAlN, and TiAlN coatings increased by 70.37%, 74.97%, and 75.64%, respectively, compared to the substrate. The hardness (H) and elastic modulus (E) were found to be positively correlated. CrAlN demonstrated superior resistance to deformation, reflected in its higher H/E and H 3 /E 2 radios compared to the CrN and TiAlN. Adhesion tests showed that CrAlN had the strongest adhesion strength to the substrate, with an adhesion force of 81.55 N, representing a 14.78% and 8.46% improvement over CrN and TiAlN, respectively. Friction and wear tests identified CrAlN as having the lowest friction coefficient (0.389), attributed to its high hardness and strong adhesion. The wear mechanisms of CrAlN observed were primarily mild abrasive wear, oxidative wear, and adhesive wear. In comparison, CrN and TiAlN coatings exhibited higher friction coefficients of 0.424 and 0.391, respectively, due to their lower hardness and adhesion, which led to more severe oxidative and abrasive wear. Additionally, the TiAlN coating showed signs of brittle failure in wear scars, likely due to the formation of Al2O3 oxides during wear.

Degradation behavior of chromium-coated zirconium cladding under 1200 oC steam oxidation according to the coating microstructure

In 2011, the Great East Japan Earthquake and tsunami caused a hydrogen explosion at the Fukushima Daiichi nuclear power plant, which exposed radioactive materials to the atmosphere and had a very negative impact on the nuclear power industry. Since then, efforts have intensified around the world to make nuclear power safer. Accident-tolerant fuel (ATF) is being developed to prevent the rapid oxidation of zirconium cladding, which directly causes hydrogen explosions. ATF research can be divided into two main approaches: changing the cladding material, or coating the surface of the cladding. Coatings are easier to commercialize and apply to existing nuclear power plants, so most vendors have focused on this approach. Chromium is a popular coating medium because of its superior properties such as a low oxidation rate and excellent adhesion. Therefore, research has been focused on suppressing the rapid oxidation of zirconium cladding in the event of an accident by adding a chromium coating with an appropriate thickness in terms of both economy and effectiveness. Even if the thickness of the coating is fixed, the penetration of oxidizing substances can be further delayed by improving the microstructure of the chromium coating, such as by reducing the grain boundary area. In this study, chromium-coated zirconium cladding tubes were fabricated by the arc ion plating process. The microstructure of the chromium coating was adjusted by varying the negative voltage (0–125 V), which in turn controlled the incident energy at which the chromium ionic particles hit the surface of the cladding tube. Experiments were then performed in 1200 °C steam environment to determine the optimal microstructure for high-temperature oxidation resistance. The development of various material degradation phenomena that occurred during 1200 °C steam oxidation was observed to identify the oxidation mechanism and the main factors of the microstructure that affect the zirconium oxidation rate.