Vapor Density Research Articles

On the thermodynamic properties of hydrolysed urine: Experimental data, predictive and correlative models for the design of concentrative urine treatment technologies

Source-separated urine contains the potential for water, nutrient and energy recovery. During the recovery of such resources, urine treatment technologies undergo temporal changes in the thermodynamic properties of urine. To inform the design of thermal, membrane and electrochemical urine treatment processes, this study experimentally measured and modelled the thermophysical properties of synthetic hydrolysed urine (vapour pressure, osmotic pressure, density, and electrical conductivity) across temperature and concentration profiles using two approaches: predictive thermodynamic equations based on an ionic speciation model and correlative modelling. The vapour pressure and osmotic pressure were accurately predicted to 14 wt% for the predictive model, within an error of 0.30% and 0.46%, respectively, while the correlative model based on the experimental data from this study demonstrated an error of <1% for both parameters across the whole range of salt concentrations and temperatures (4.5 to 32.2 wt%; 333 to 373 K). The predictive and correlative models for density and electrical conductivity showed adequate agreement with the experimental data, where error did not exceed 2.12% and 1.2%, respectively, across the entire range of concentrations and temperatures.The value of the models for the development of sustainable urine treatment technologies was demonstrated by their application to determine the optimum heating surface area of a urine evaporator and the energy requirements of a reverse osmosis process.

Atmospheric HDO Abundance Measurements in the Tibetan Plateau Based on Laser Heterodyne Radiometer

The Tibet Plateau is known as the “third pole” of the world, and its environmental change profoundly impacts East Asia and even the global climate. HDO is the stable isotope of water vapor, which acts as an ideal tracer for studying the water cycle, and which is commonly used for atmospheric circulation and climatic studies. To monitor the water vapor isotopic abundance in the Tibetan Plateau, a portable laser heterodyne radiometer was operated in Golmud in August 2019. The radiometer utilizes a narrow-linewidth 3.66 μm distributed feedback interband cascade laser as the local oscillator, the heterodyne module is been optimized and the radiometer performs with high resolution and stability in obtaining spectral data. Furthermore, the absorption spectra of atmospheric HDO and H2O are obtained, and the retrieval method for water vapor isotopic abundance is discussed. The optimal estimation method is adopted to retrieve the density of HDO and H2O. The average column density of H2O was 1.22 g/cm2, and the HDO/H2O ratio in Golmud was 178 ± 15 × 10−6 during the observation. For a better understanding of the retrieval, the retrieval errors are analyzed and compared. The results indicate that the smoothing error is significantly higher than the measurement error in this work. The backward trajectory analysis of atmospheric transport is used to investigate the relationship between water vapor density and atmospheric motion. The results indicate that the variation of H2O column density and HDO/H2O ratio have a relationship with atmospheric movements.

Measuring Turbulent Water Vapor Fluxes Using a Tunable Diode Laser-Based Open-Path Gas Analyzer

The reliable observation and accurate estimates of land–atmosphere water vapor (H2O) flux is essential for ecosystem management and the development of Earth system models. Currently, the most direct measurement method for H2O flux is eddy covariance (EC), which depends on the development of fast-response H2O sensors. In this study, we presented a cost-efficient open-path H2O analyzer (model: HT1800) based on the tunable diode laser absorption spectroscopy (TDLAS) technique, and investigated its applicability for measuring atmospheric turbulent flux of H2O using the EC method. We prepared two HT1800 analyzers with lasers that operate at wavelengths of 1392 nm and 1877 nm, respectively. The field performance of the two analyzers was evaluated through inter-comparative experiments with LI-7500RS and IRGASON, two of the most commonly used H2O analyzers in the EC community. Water vapor densities measured by the three types of analyzers had high overall agreement with the reference sensor; however, they all experienced drift. The mean density drifts of HT1800, LI-7500 and IRGASON were 3.7–5.2%, 4.0% and 3.8%, respectively. Even so, the half-hourly H2O fluxes measured by HT1800 were highly consistent with those by LI-7500RS and IRGASON (with a difference of less than 2%), suggesting that HT1800 can obtain H2O fluxes with high confidence. The HT1800 was also proved to be suitable for EC application in terms of data availability, flux detection limit and response to the high-frequency turbulent variation. Furthermore, we investigated how the spectroscopic effect influences the measurements of H2O density and flux. Despite the fact that the 1392 nm laser was much more susceptible to the spectroscopic effect, the fluxes after correcting for this bias showed excellent agreement with the IRGASON fluxes. Considering the cost advantage in laser and photodetector, the HT1800 analyzer using a 1392 nm infrared laser is a promising and economical solution for EC measurement studies of water vapor.

Selective reflection study of excitation-dependent dipole-dipole interaction in dense rubidium vapour

We conducted a comprehensive study of excitation dependent dipole-dipole interaction in dense rubidium gas using the resonant selective reflection of weak probe radiation from the dielectric-rubidium vapor interface. The excitation was created by the pump laser beam. The study involved exploring a diverse range of pumping radiation intensity and detuning for the number density of the rubidium vapour 2.8 × 1016 cm-3. We have measured experimental selective reflection spectra in both linear and nonlinear pumping modes.

TWO-PHASE FLOW METERING OF MALDISTRIBUTION INSIDE A HEADER BY MEANS OF VENTURI FLOWMETER SOLELY

In evaporators, the distribution of the liquid and vapor phases among the channels is a convoluted problem, depending on a wide range of parameters. However, maldistribution causes important losses of performance. Due to their complexity, the accurate modeling of such two-phase flows is difficult to handle. Hence, experimental studies are still of great importance to help the understanding of maldistribution behaviors inside evaporators. Most of the experimental investigations of two-phase flow distribution are measuring the liquid and vapor quantities in the channels through a phase separation process, increasing the test duration and complexity. As a consequence, the number of parameters investigated is usually limited. Therefore, a new inline instrumentation method would allow for a more complete study by simplifying the measurement process. In the present work, an isothermal air/water mixture was used as fluid. The distribution of the two phases in eight channels of 10-mm I.D. connected to a simplified header was investigated. The inlet mass flow rates considered ranged from 0 to 0.025 kg/s for the water, and from 0 to 0.022 kg/s for the air. Consequently, qualities x up to 0.7 and void fractions &amp;alpha; up to 0.9 were reached. All the tests were carried at a pressure condition of 7 bar to reach a liquid to vapor density ratio similar to what is encountered for traditional refrigerant. Finally, to allow a continuous measurement process, the mass flow rates in each of the 10-mm I.D. channel were measured using a flowmeter calibrated on a separate line. Since no void fraction meter was coupled, a new iterative methodology, based on the Venturi pressure drops measurement solely, was developed and is proposed here. It proved to successfully predict the vapor and liquid phase flow rates in each channel.

MAVEN/IUVS Observations of OH Prompt Emission: Daytime Water Vapor in the Thermosphere of Mars

AbstractWe report the highest altitude detection of water vapor on Mars to date. The daytime limb observations by the Imaging Ultraviolet Spectrograph (IUVS) on the Mars Atmosphere and Volatile EvolutioN (MAVEN) spacecraft are of hydroxyl (OH) prompt emission near 308 nm, which is excited directly from the photodissociation of water vapor by the solar Lyman‐α flux. Average IUVS daytime water vapor densities near 130 km are 3 × 107 cm−3 around perihelion. The water vapor densities diurnally vary with a peak near midday and no detection at sunrise and sunset. To evaluate the large daytime water vapor densities for self‐consistency, we also report the simultaneous observation of OH solar fluorescence emission near 308 nm in the thermosphere, which enables the retrieval of OH densities. Using a one‐dimensional photochemical model initialized with the daytime IUVS water vapor densities, modeled peak OH densities are in good agreement with the observed IUVS peak OH densities. Because the observed thermospheric temperatures are controlled by solar insolation and cross the water frost point during the day, we suggest that the IUVS observed water vapor is created by the daily sublimation of water ice particles supplied from below. We discuss the implications of the IUVS observations on the present day loss of water vapor from Mars in the form of atomic hydrogen.

Investigation of non-ideal effects in compressible boundary layers of dense vapors through direct numerical simulations

In this work, we present an investigation about the sources of dissipation in adiabatic boundary layers of non-ideal compressible fluid flows. Direct numerical simulations (DNS) of transitional, zero-pressure gradient boundary layer flows are performed for two fluids characterized by different complexity of the fluid molecules, namely, “air” and siloxane MM. Different sets of thermodynamic free-stream boundary conditions are selected to evaluate the influence of the fluid state on both the frictional loss and the dissipation mechanisms. The thermophysical properties of siloxane MM are calculated with a state-of-the-art equation of state. Results show that the dissipation due to both time-mean strain field, irreversible heat transfer, and turbulent dissipation differs significantly depending on both the molecular complexity of the fluid and its thermodynamic state. The dissipation coefficient calculated from the DNS results is then compared against the one obtained using a reduced-order model (ROM), which solves the two-dimensional boundary layer flow equations for an arbitrary fluid [M. Pini and C. De Servi, “Entropy generation in laminar boundary layers of non-ideal fluid flows,” in 2nd International Seminar on Non-Ideal Compressible Fluid Dynamics for Propulsion and Power (Springer, 2020), pp. 104–117]. Results from both the DNS and the ROM show that low values of the overall dissipation are observed in the case of fluids made of simple molecules, e.g., air, and if the fluid is at a thermodynamic state in the proximity of that of the vapor–liquid critical point.

Flow Condensation of Low-GWP Zeotropic Mixtures Inside 5 mm OD Micro-Finned Tube

In response to stringent rules inhibiting the implementation of refrigerants with high global warming impact, alternative candidates should undergo assessments to prove their viability. The mixtures R450A and R454B, being the center of the current focus, underwent experimentation for flow condensation inside a mini-scale micro-finned tube of 5 mm outer diameter. The operating conditions were set to be in the range of 0.1 to 0.95 for vapor quality, 75 to 400 kg m−2 s−1 for mass flux, and recorded at saturation temperatures of 30 and 40 °C. Having concluded the evaluations of thermal and hydraulic properties of heat transfer coefficient (HTC) and frictional pressure drop (FPD), a comparison was drawn between the two candidates, where R450A possessed superior HTC and higher FPD per unit length at higher vapor qualities due to lower vapor density. Ultimately, empirical models pertinent to flow condensation were compared with the acquired experimental results.

Force Field for Calculation of the Vapor-Liquid Phase Equilibrium of trans-Decalin

Based on the TraPPE force field, previously unknown values of the parameters of the intermolecular interaction potential of trans-decalin were determined. Parametrization was carried out using experimental data on saturated vapor pressure and density at atmospheric pressure. The found parameters make it possible to adequately describe the boiling and condensation lines of trans-decalin and also predict the critical values of pressure, density, and temperature with satisfactory accuracy. Calculations of vapor-liquid phase equilibrium conditions for a binary CO2—trans-decalin mixture in supercritical conditions for CO2 were carried out. When quantitatively comparing the calculated values with experimental data, an underestimation of pressure at a temperature of 345.4 K by 30% is observed, which decreases to 5% for temperatures up to 525 K.

Evaporation of Small Sessile Drop Deposited on a Horizontal Solid Surface: New Exact Solutions and Approximations

Evaporating a liquid sessile drop deposited on a horizontal surface is an important object of applications (printing technologies, electronics, sensorics, medical diagnostics, hydrophobic coatings, etc.) and theoretical investigations (microfluidics, self-assembly of nanoparticles, crystallization of solutes, etc.). The arsenal of formulas for calculating the slow evaporation of an axisymmetric drop of capillary dimensions deposited on a flat solid surface is reviewed. Characteristics such as vapor density, evaporation flux density, and total evaporation rate are considered. Exact solutions obtained in the framework of the Maxwellian model, in which the evaporation process of the drop is limited by vapor diffusion from the drop surface to the surrounding air, are presented. The summary covers both well-known results obtained during the last decades and new results published by us in the last few years, but practically unknown to the wider scientific community. The newest formulas, not yet published in refereed publications, concerning exact solutions for a number of specific contact angles are also presented. In addition, new approximate solutions are presented (total evaporation rate and mass loss per unit surface area per unit time in the whole range of contact angles θ∈[0, π), drop lifetime in constant contact radius evaporation regime and constant contact angle mode), which can be used in modeling without requiring significant computational resources.

A discontinuous Galerkin approach for atmospheric flows with implicit condensation

We present a discontinuous Galerkin method for moist atmospheric dynamics, with and without warm rain. By considering a combined density for water vapour and cloud water, we avoid the need to model and compute a source term for condensation. We recover the vapour and cloud densities by solving a pointwise non-linear problem each time step. Consequently, we enforce the requirement for the water vapour not to be supersaturated implicitly. Together with an explicit time-stepping scheme, the method is highly parallelisable and can utilise high-performance computing hardware. Furthermore, the discretisation works on structured and unstructured meshes in two and three spatial dimensions. We illustrate the performance of our approach using several test cases in two and three spatial dimensions. In the case of a smooth, exact solution, we illustrate the optimal higher-order convergence rates of the method.

Soy protein isolate film activated by black seed oil nanoemulsion as a novel packaging for shelf-life extension of bulk bread.

This paper investigates the addition of lecithin-emulsified black seed oil (BSO) nanoemulsions (LNEO) and whey protein isolate-stabilized Pickering emulsions (WPEO) to soy protein isolate (SPI)-based films and their effect on improving the shelf life of bread slices. The half-life of antioxidant activity, water vapor permeability, biodegradability, density, color difference, and film thickness significantly increased (p < .05) when BSO was added. However, the incorporation of BSO significantly reduced the solubility, tensile strength, strain to break (except for WPEO), and transparency (p < .05) of the samples. The interaction between SPI film and BSO-loaded nanocarriers, as well as the morphological properties of films, was evaluated using FT-IR and FE-SEM. SPI-based films containing LNEO-5% and WPEO-5% were selected based on their mechanical and barrier properties. The effect of films on the shelf life of bread slices was investigated for 17 days of storage. LNEO samples obtained the most acceptable results in the bread in terms of sensory evaluation and color properties. According to the results, bread slices packed in SPI film containing LNEO-5% showed no signs of mold growth until the 17th day of storage, whereas the sample packed in a low-density polyethylene bag began to corrupt on the 6th day. This study highlights the potential of BSO-loaded SPI films as a novel active packaging for the bakery industry.

Influence of gas density on void fraction and pressure drop in upward vapor–liquid flow

The influence of gas density on the void fraction, flow map, and pressure drop was examined for an upward vapor–liquid flow. The knowledge of the flow map is necessary to ensure a safe operational condition in a nuclear zone at high pressure. Moreover, the pressure gradient and its volumetric flow rate are related to the profitability of petroleum wells. Considering these scenarios, a modified cascade refrigeration cycle was constructed to generate and measure single-phase streams with different liquid and vapor density ratios. These single-phase liquid and vapor streams were mixed and injected into an upward vertical test section with an inner diameter of 26.64 mm and length of 5.8 m. The pressure ranged from 1.7 to 2.3 MPa, liquid–vapor density ratio ranged from 10.2 to 15.2, and total mass flux ranged from 733.1 to 882.9 kg.s−1.m−2. The void fraction, pressure gradient, and frictional pressure component were measured using quick-closing valves, temperature probes, and absolute and differential pressure sensors. The experimental data and transition line behavior of the flow map at high pressures in an upward two-phase flow as well as the proposed correction factors for the pressure gradient and its frictional component reflect the novelty of this study. Most existing studies have focused only on the influence of the gas density on the horizontal flow. A key observation of our study is that the liquid–vapor density ratio significantly changes the churn and annular transition lines. According to a vertical flow map found in the literature, the disappearance of the churn region can be foreseen and an annular transition occurs at lower gas velocities. The liquid–vapor density ratio does not influence the void fraction or slip velocity ratio; both increase with the superficial vapor velocity. Correction factors for the pressure gradient and its frictional component were proposed. The mean deviation for the pressure gradient was reduced from 27 % to 16 % after application of the correction factor. Half of the experimental points presented absolute relative errors lower than 30 % for the frictional pressure gradient. A cross-validation between the experimental data reported by other authors and the proposed correction factors was conducted to assess their response. In this cross-validation, 126 additional experimental points were used for the pressure gradient whereas 1270 points were used for its frictional component. Overall, the mean deviation of the pressure gradient was reduced from 92.7 % to 31.9 % after the application of the correction factor. Similarly, the mean deviation of the frictional gradient was reduced from 70.7 % to 31.3 % after the application of the correction factor. There was no evident influence of the liquid–vapor density ratio on the total pressure gradient and drift relationships for Froude numbers spanning from 2.6 to 7.4.

Assessing biases in atmospheric parameters for radiative effects estimation in tropical regions

Many studies highlight the importance of water vapor in tropical atmospheric radiative transfer calculations. However, limited research focuses on understanding the effects of biases in different atmospheric factors, such as pressure, temperature, water vapor, and ozone densities. These biases stem from various sources, including satellites, reanalysis data, and the standard TROPICAL atmosphere. This study explores how these biases influence estimates of two key things: atmospheric radiative forcing (ARF) and heating rate (HR) profiles over the tropical region. The study is undertaken at Gadanki, a rural background site in the tropics. It considers different situations - clear skies and those with aerosols - across different parts of the electromagnetic spectrum and throughout the seasons. Additionally, this study investigates how sensitive ARF and HR profiles are to biases in each of these atmospheric factors within specific spectral ranges. The study results show that the standard TROPICAL atmosphere often differs significantly from real-time measurements, leading to varied effects on radiation. Among the various factors, biases in water vapor density have the most substantial impact on ARF and HR, followed by biases in temperature. Moreover, longwave radiation is more sensitive to water vapor and temperature changes. This study emphasizes the importance of considering the exact state of the atmosphere, especially in tropical regions, when estimating ARF and HR. To improve estimates when real-time data isn't available, the study suggests combining data from the Microwave Limb Sounder (MLS) and the Atmospheric Infrared Sounder (AIRS), and using reanalysis data for broader assessments. It's also important to be cautious when using the TROPICAL atmosphere to analyze the radiative effects of aerosols.

A new separation method of hydrogen isotope by dynamically created nonequilibrium state

ABSTRACT Composition of deuterium (heavy) water in light water was drastically reduced to one-half by one stage of a newly invented device that can create a nonequilibrium vapor state driven by a dynamic system. Vapor density of heavy and light water is arbitrarily controlled. This system works at 20–60°C, even under atmospheric pressure. The mechanism should equally work even for tritium water, as tritium-contaminated water is a problem in the treatment of nuclear reactors as well as fusion reactors.

Seasonal and Diurnal Changes of Air Temperature and Water Vapor Observed with a Microwave Radiometer in Wuhan, China

Based on Microwave Radiometer (MWR) observations in Wuhan over the course of 21 months, we compared the temperature and water vapor levels with those from radiosonde (RS) sounding data at 00:00 and 12:00 UTC, and then analyzed the seasonal and diurnal changes of temperature and water vapor levels from the MWR data. The MWR and RS mean temperatures and dew points are roughly consistent with each other below 2 km, whereas above 2 km, the MWR temperature is slightly lower than the RS temperature. The difference in their water vapor densities decreases quickly with height, and the bias of their relative humidities is generally in the range of −15% to 20%. The MWR observations show that in autumn, the surface temperature is 6.8 K lower during precipitation events than during non-precipitation events, indicating that precipitation in autumn is mainly caused by cold air from the north. The relative humidity during precipitation events exceeds 90% from the ground to 5 km, which is obviously larger than during non-precipitation events. During non-precipitation events, the seasonal mean water vapor density at 0–1.0 km shows an approximately linear increase with the mean temperature; however, their diurnal changes are opposite due to the effect of the boundary layer. At 4.5–5.5 km and 8.5–9.5 km, the mean temperature shows a synchronized diurnal evolution, with the maximum value prior to that at 0–1.0 km, indicating the strong influence of the air–land interaction on the temperature near the ground. Hence, this study is helpful for deepening our understanding of temperature and humidity variabilities over Wuhan.

Correction to: Vapor Pressures, Densities, and PC-SAFT Parameters for 11 Bio-compounds

Correction to: Vapor Pressures, Densities, and PC-SAFT Parameters for 11 Bio-compounds

Effect of film thickness and temperature on condensation and momentum accommodation at the liquid–vapor methane interphase in contact with a quartz substrate

In this paper, we used the Molecular Dynamics method to simulate the equilibrium vapor–liquid methane in contact with a solid quartz substrate and study the condensation process and momentum exchange at the atomic level. A large potential cutoff radius is used to determine the vapor and liquid densities at good accuracy. By tracking the motions of fluid molecules exchanged between the vapor and liquid phases and carrying out statistical analysis of residence time, penetration depth and especially velocity correlation, the mass and the velocity accommodation coefficients can be determined at the same time. The latter is based on the assumption that the reflected events take place over a short time, near the interface and thus atoms velocities are correlated while the condensation/evaporation events are not. The calculated coefficients are sensitive to the film thickness due to the presence of the quartz substrate and the layering effects. As temperature increases, atoms condense less and reflect more and the reflection is more diffusive due to increasing collision rate. Near the critical temperature, both the condensation and momentum accommodation coefficients vary significantly.

Experimental study on axial self-propagation of heat transfer deterioration of near-critical carbon dioxide at low mass fluxes

Near-critical CO2 exhibits unique boiling heat transfer behavior due to its high saturated vapor density, low latent heat, and extremely low surface tension. In this study, an experimental investigation was conducted to study the heat transfer deterioration of near-critical CO2 inside a vertical circular channel at low mass fluxes. The experimental results show a rapid rise in wall temperature at the outlet side with minimal power increase (∆ power = 33 W), and the wall temperature rise continuously self-propagates toward the inlet side. The heat transfer deterioration mechanism responsible for the wall temperature rise was considered to be a departure from nucleate boiling type boiling crisis based on the low vapor quality of the bulk fluid. In addition, the evolution of the axial heat transfer deterioration was analyzed in detail. And a phenomenological model was developed to explain the axial self-propagation of heat transfer deterioration based on the low mass fluxes and unique bubble behavior resulting from the low surface tension, high vapor density and low latent heat of the near-critical CO2. The model was validated using different dry/wet interface movement speeds.

Case Analysis of Heavy Air Pollution Process in Xi'an Using Multi-source Data

Air pollution continues to be a serious problem in Xi'an. A heavy pollution process and formation mechanism were investigated in Xi'an in January 2019 using multi-source methods (such as material balance and sulfur/nitrogen oxidation rate (SOR/NOR)). The multi-source data included the concentrations of PM2.5, PM10, SO2, NO2, CO, and O3; the chemical components of PM2.5; the meteorological records of ground and vertical observations; the atmospheric reanalysis data. Three phases were obtained including the accumulation phase (P1), maintenance phase (P2), and dispersion phase (P3) during the pollution period. The pollution event was primarily attributed to the superposition of adverse weather conditions and feedback effects. During the periods of P1 and P2, the area of Xi'an was affected by blocking and zonal westerly airflow at 500 hPa (with flat westerly airflow) and uniform-distribution pressure at sea level with a limited pressure gradient and stable weather conditions, and the easterly wind was dominant at 925 hPa; not all of these factors were conducive to the pollutant diffusion. An interaction feedback mechanism between meteorological conditions and heavy pollution could be studied using the ground-based microwave radiometer. The correlations between PM2.5 and inversions of water vapor density, relative humidity, air temperature, and temperature inversion were significant with coefficients of 0.86, 0.62, 0.53, and 0.38, respectively. The feedback mechanism was primarily manifested as follows:with the pollutant accumulation, the radiative cooling effect could lead to or strengthen the occurrence and intensity of temperature inversion, decrease the mixed layer height, and cause moisture accumulation. High humidity could further maintain the pollution by accelerating the secondary formation and promoting the hygroscopic growth of aerosol particles. Therefore, the dominant chemical components to PM2.5were secondary inorganic ions (SO42-+NO3-+NH4+, SNA) and "other" components during the period of P2, with contributions of 43.2% and 23.1%, respectively. In addition, the peak values of PM2.5, SOR, NOR, and the light extinction coefficients all occurred on the same days (January 3 and 6), indicating that the effect of secondary formation was important for both heavy pollution events and visibility. The total contribution of NH4NO3, organic matter (OM), (NH4)2SO4, and EC to the light extinction coefficient was more than 85%. Limited variations in the proportion for components were observed in three phases. During the period of P3, the strong cold air in the mid-lower atmosphere was conducive to the dry and clean air sinking and the pressure gradient at sea level increasing. These were beneficial to the diffusion of air pollutants and water vapor.