Alkali-activated materials (AAM) have garnered significant attention for the treatment of Pb-contaminated solid waste, attributed to their low carbon footprint and superior stabilization/solidification (S/S) capabilities. However, recent concerns arise regarding their long-term S/S performance, especially when exposed to rainwater environments and considering the inherent shrinkage and potential cracking of AAM. This research delves into the feasibility of enhancing the S/S efficacy of alkali-activated slag (AAS) through the integration of super absorbent polymers (SAP). Findings reveal a marked improvement in the S/S performance of Pb-laden AAS upon SAP addition. Specifically, incorporating 0.5 wt% and 1 wt% SAP curtailed Pb leaching in AAS samples (cured for 90 days) by 47 % and 75 %, respectively. Comprehensive analyses using XRD, TGA, MIP, BSEM, EDX, XPS and MAS NMR suggest that the bolstered S/S performance of SAP-augmented AAS is not rooted in alterations to the reaction degree, pore structure, or reaction products of AAS. Instead, it hinges on the innate capacity of SAP to absorb and retain Pb. Leaching tests reveal that, in AAS cured for 90 days, approximately 1.72 mg of Pb ions were retained per gram of SAP. This investigation furnishes a novel vantage point for refining and deploying alkali-activated materials (or other cementitious materials) as effective S/S agents.
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