A set of simple methodologies is presented so that optical parameters relevant to 10.6 μm CO 2 laser radiation processing of thermoplastics films are obtained. These methodologies are applied to transparent and white polyethylene and transparent polypropylene samples, with thicknesses between 10 and 800 μm. Optical parameters like transmittance, reflectance and absorptance are measured directly with two simple experimental apparatus. With these values, two methodologies are developed in order to obtain the attenuation coefficients. One of the methods relies on curve fitting and shows low uncertainty. The other, based on calculations derived from the Beer–Lambert law, presents dependency on experimental errors for samples with lower thickness, needing further calculation in order to minimize it. The attenuation length and the complex refractive index values are also determined. The resulting data demonstrate the high transparency of thermoplastic samples to 10.6 μm radiation for thicknesses lower than 200 μm, which is significant information for modelling thermoplastics laser processing.