Strength Values Research Articles

How to restore ecological impacts from wind energy? An assessment of Zhongying Wind Farm through MSPA-MCR model and circuit theory

The wind energy industry is developing rapidly in China with a maximum capacity worldwide. Meanwhile, the stability of the ecological network is challenged by extensive renewable energy expansion. There are still research deficiencies in wind farm ecological impacts at project scale from an ecological restoration perspective. It is of great necessity to monitor the ecological impacts with time going and explore ecological restoration strategies for wind power development. The research case of Zhongying Wind Farm is selected based on investigation and interviews regarding its ecological impact in the prior study. It employs a comparative methodology by comparing the ecological quality before and after the construction of Zhongying Wind Farm. Raw data from Landsat 8, the Digital Elevation Model (DEM), the Normalized Difference Vegetation Index (NDVI), and wind turbine statistics originating from open data platforms are analyzed and visually represented with ArcGIS. This paper establishes an ecological network based on morphological spatial pattern analysis (MSPA) and the Minimum Cumulative Resistance (MCR) model to quantify wind farms’ impacts on ecological corridors. The circuit theory and Pajek software are used to identify and categorize the ecological nodes into weak and obstacle points. The results reveal that ecological impacts on ecological corridors decay with distance, reflecting changes in length, connection strength and cumulative values of corridors. While the impacts on ecological nodes depend on nodes’ attributes: the number of weak points increased by 18.5 %, and obstacle points increased by 350 %, with their locations shifting from the edges of urban construction sites to the edges of wind farm. Differentiated strategies are proposed according to the impact magnitude of each ecological corridor and node: such as dynamic inspection mechanism, construction prohibition for protection; corridor structure and function recovering, stepping stones addition for restoration; buffer belts, warning radar, and monetary schemes for compensation. This research fills the gap of ecological impact assessment under the challenges of wind energy expansion. It helps to balance wind energy development and ecological restoration at the regional level.

Synthesis and characterization of TiNbZrMo medium-entropy bio-composites: Microstructure, mechanical properties, and in vitro degradation.

This study reports the synthesis and characterization of hydroxyapatite (HA)-based bio-composites reinforced with varying amounts (by weight, 1-15 wt.%) of bio-medium entropy alloy (BioMEA) for load-bearing implant applications. BioMEA powders consisting of Ti, Nb, Zr, and Mo were mechanically alloyed for 100 h and subsequently added to HA using powder metallurgy techniques. To show the effect of BioMEA, the microstructure, density, and mechanical tests have been conducted and the synthesized BioMEA was characterized by scanning electron microscope (SEM), x-ray diffractometer (XRD), and Fourier-transform infrared spectroscopy (FTIR) analysis. In addition, in vitro degradation behavior and bioactivity analyses of bio-composites have been conducted. XRD analysis revealed the formation of BioMEA after 20 h of mechanical alloying. The highest density value of 2.47 g/cm3 was found in 15 wt.% BioMEA-reinforced bio-composite. The addition of BioMEA reinforcement led to a significant increase in hardness and tensile strength values, with the highest values observed at 15 wt.% reinforcement. Compression tests demonstrated a significant increase in compressive strength and deformation capability of the bio-composites with the highest values observed at 15 wt.% BioMEA addition. The highest toughness of 7.68 kJ/m2 was measured in 10 wt.% MEA-reinforced bio-composites. The produced bio-composite materials have an elastic modulus between 3.5-5.5 GPa, which may provide a solution to the stress shielding problems caused by the high elastic modulus of metallic implant materials. The most severe degradation occurred in 15 wt.% MEA-reinforced bio-composites, and the effect of degradation caused a decrease in Ca and an increase in Ti-Ni-Zr-Mo in all bio-composites. These findings suggest that HA/BioMEA bio-composites have the potential to be developed as advanced biomaterials with moderate mechanical and biological properties for load-bearing implant applications.

Https://epg.science.cmu.ac.th/ejournal/journal-detail.php?id=11813

In this study, waste magnesite (WM) particles with different weight fractions (2.5%, 5%, and 7.5%) were used as particulate material in 6061 aluminium alloy to produce composites with improved properties. The composite material was manufactured using a stir-casting method. A surface morphology investigation confirms the uniform distribution and good interfacial bonding of the WM particles within the alloy base. The addition of 5% WM particles was found to improve the values of tensile strength of 146.68 MPa, hardness of 131.6 HV and coefficient of friction of 0.565. Incorporating 7.5% WM was found to give a low wear of 161 μm and a corrosion current of 8.5 x 10-6 A. The results obtained confirm that such a proportion of WM particles in Al 6061 alloy provides excellent anticorrosion protection, wear properties, and good mechanical properties. Adding 5% WM to Al 6061 improves overall performance characteristics among other ratios.

Механизм влияния электрического поля на процесс модифицирования серого чугуна

A diagram of an experimental installation for measuring the electrical resistance of a gray cast iron melt is presented, where a gauge based on a Kelvin double bridge is used. It is shown that the value of the specific electrical resistance of gray cast iron varies depending on the type of conditioning agent. Experimental data on the difference in specific resistivity values for various gray cast iron nucleating agents are presented. Changes in the values of electrical resistance under the influence of electric field treatment of inoculated cast iron melt are also given. Comparison of the strength values of gray cast iron with its values of the electrical resistivity of the cast iron melt after the electrical field exposure showed their simultaneous change. The decrease in the values of the electrical resistance of hot iron due to the electric field exposure is shown and it corresponds to an increment in the strength of inoculated cast iron. The effectiveness of the electric field exposure on the process of inoculation is determined by thermal ionization of the chemical elements included in the conditioning agent. The maximum increase of these parameters after electric field exposure when using FS75 nucleating agent is shown. The mechanism of the influence of an electric field on the cast iron solidification for the inoculation process of FS75, containing 75 % silicon in its composition, is described. The dependence of the efficiency of electric field exposure on the composition of the nucleating agent for gray cast iron is shown. A physical model of the effect of an electric field exposure on the process of cast iron inoculation is found. The possibility of influencing the hydrodynamic situation in the melt of gray cast iron and changing the rate of dissolution of nucleating agent particles by means of electric field exposure is given

Study on the Performance Optimization of Plant-Growing Ecological Concrete

The response surface regression model of plant-growing ecological concrete is established based on the factors of the water–binder ratio, fly ash content, and design porosity, with 28-day compressive strength, connectivity porosity, and pH value as response variables. Based on optimizing the mix proportion with the regression model, different dosages of acetic acid are used as excitation agents to increase the compressive strength and reduce the alkalinity of plant-growing ecological concrete to enhance its service life and vegetation performance. The results show that the compressive strength of plant-growing ecological concrete with a water–binder ratio of 0.3, a fly ash content of 26%, and a design porosity of 22% was 10.32 MPa, the connectivity porosity was 20.00%, and the pH value was 11. After the addition of acetic acid at 0.4% of the mass of the cementitious material, the compressive strength increased by 40.29%, and the pH value decreased by 6.33%. This study proposes a cost-effective means and provides data support for the engineering application of plant-growing ecological concrete.

Neodymium (III)-containing poly(lactide-co-glycolide)-coated robocast bioactive glass scaffolds for photothermal therapy and bone regeneration

In this study, trivalent neodymium-doped silicate-based 13–93 bioactive glass scaffolds were prepared by the robocasting method using sol-gel-derived bioactive glass powders for tissue engineering applications. Sintered scaffolds were coated by borate-based 13-93B3 bioactive glass-containing polylactide-co-glycolide solution. The produced composite scaffolds’ mechanical, morphological, and structural characteristics were thoroughly examined, as their in vitro bioactivity in cell culture media and simulated body fluid. Furthermore, the scaffolds’ amoxicillin adsorption and release behavior was examined over time. The outcomes demonstrated that it was feasible to effectively create periodic, mesh-like-patterned robocast glass scaffolds utilizing Nd3+-doped sol-gel-derived bioactive glass powders. The scaffolds’ compressive strengths ranged from 10.02 MPa to 18.6 MPa, with the PLGA-coated scaffolds exhibiting the highest strength values. All of the scaffolds that were submerged in simulated body fluid for 28 days showed hydroxyapatite formation. The presence of borate glass on the surface of the silicate-based glass scaffolds improved the hydroxyapatite formation ability. The quantity of drug adsorption for all types of scaffolds was measured to be between 4 and 9% whereas the cumulative drug release was in the range of 58 to 96%. Borate glass particle-containing PLGA coating enhanced the drug delivery behavior.

Prospects for detection of the pair-echo emission from TeV gamma-ray bursts

The intergalactic magnetic field (IGMF) present in the voids of large-scale structures is considered to be the weakest magnetic field in the Universe. Gamma-ray observations of blazars in the GeV-TeV domain have led to lower limits on the IGMF strength based on the search for delayed or extended emission. Nevertheless, these results have been obtained with strong assumptions placed on the unknown source properties. The recent discovery of TeV radiation from gamma-ray bursts (GRBs) has paved the way for IGMF studies with these bright transients. Among the current TeV-detected GRBs, GRB\,190114C, located at a redshift of $z = 0.42$, is the best sampled. Therefore, it can be considered to be representative of the properties of GRBs in the VHE domain. In addition GRB\,221009A ($z = 0.151$) is the brightest event ever detected. We present a phenomenological model based on the intrinsic properties of GRB\,190114C and GRB\,221009A to predict the delayed emission component (pair-echo) in the GeV-TeV band. We investigate the detectability of this component from low-redshift ($z 1$) GRBs for three values of IGMF strength ($10^ $ G, $10^ $ G and $10^ $ G) different observational times ($3$ hrs, $6$ hrs, and $9$ hrs) and source intrinsic properties. We find that for current and future generation gamma -ray instruments extending the observation for at least 3 hours after the GRB detection is a viable strategy for probing the IGMF. We also confirm that GeV-TeV observations of GRBs can probe IGMF strengths on the order of $10^ $ G, representing a competitive alternative to the current studies performed with active galactic nuclei (AGNs)

Comparative Assessment of the Shear Bond Strength of Ceramic Brackets Bonded to the Enamel Surface with a Self-adhesive System

Objectives: This study aimed to evaluate the shear bond strength of ceramic brackets bonded to the enamel surface using Vertise Flow, with or without the application of phosphoric acid. Materials and Methods: Forty-five extracted human premolar teeth were randomly assigned to three groups (N=15) based on the adhesive used for bonding: 1) Transbond XT, etch, and bond; 2) Vertise Flow; 3) Etch and Vertise Flow. After a 500-round thermocycling procedure, the shear bond strength was measured using a universal testing machine. The samples were then evaluated under a stereomicroscope to determine failure modes, and the Adhesive Remnant Index (ARI) was measured for each group. The data were analyzed with one-way ANOVA and post-hoc Tamhane at a significance level of P<0.05. Results: The highest shear bond strength values were observed in the Transbond XT (13.5±5.38MPa), acid etch and Vertise Flow (11.2±2.89MPa), and Vertise Flow (6.2±3.16MPa) groups, respectively, in descending order. The Vertise Flow group exhibited a significantly lower shear bond strength value compared to the other two groups, with no significant difference between the latter two. Conclusion: While all three study groups demonstrated clinically acceptable shear bond strength values, Vertise Flow showed lower values compared to the other two adhesives. The Vertise Flow composite resin system, whether used alone or with acid etching, remains a suitable choice for bonding ceramic brackets, offering the advantage of a simplified bonding procedure.

Two approaches to prepare cationic lignin‐based adsorbents for efficient removal of phosphate ion from wastewater

AbstractIn this work, two types of cationic lignin‐based adsorbents (AL‐METAC and AL‐GTA) were prepared through free radical polymerization or etherification reaction of alkali lignin with 2,3‐epoxypropyl‐3‐trimethylammonium chloride or methylacrylloxyethyl trimethyl ammonium chloride (METAC). The contents of quaternary ammonium groups in the adsorbents were adjusted by changing the dosages of 2,3‐epoxypropyl‐3‐trimethylammonium chloride and METAC to fabricate the adsorbents with excellent adsorption capacity. The structures, aqueous solubility, and physical properties of adsorbents were analyzed. Meanwhile, the effects of adsorbents dosage, pH value of solution, temperature, and ionic strength on the adsorption capacity of adsorbents were also analyzed. These two types of adsorbents exhibited outstanding affinity for phosphate, with a maximum removal efficiency of 51.8 and 73.2 mg/g, respectively. The adsorption processes followed pseudo‐second‐order and Langmuir models well. In addition, the AL‐GTA exhibited higher removal efficiency than AL‐METAC. Moreover, the AL‐METAC and AL‐GTA still retained 69.7% and 69.0% adsorption capacity after four times regeneration. The fabricated lignin‐based adsorbents have potential applications in the removal of phosphate from wastewater, which would promote the high‐value application of lignin.

Influence of tool velocity ratio on force-torque and mechanical properties of friction stir welded 2050-T84 Al-Li alloy plates

Abstract Aluminium-lithium (Al-Li) alloy is the most prominent alloy used in the aerospace industry's internal structure and wings due to its improved physical and mechanical properties. The present study introduces a novel investigation into the joining of Al-Li alloy 2050-T84 using friction stir welding (FSW) at different tool velocity ratios (TVR) of 0.6, 0.8, and 1, respectively (i.e., the amalgamation of various process parameters like tool rotational speed (TRS of 600, 1000, and 1400 rpm and traverse speed of 60, 120, and 240 mm/min) and constant tool tilt angle (1.50). A threaded taper tool was used for joining the Al-Li alloy 2050-T84. This work aims to ascertain the effects of varying tool velocity ratios (TVR; rotational speed/traverse speed) on macrostructure, grain size distribution in the nugget zone, and mechanical strength of the welded specimens. The experimental results reveal that increasing the tool velocity ratio increases the grain size and decreases the welded specimen's ultimate strength and hardness values. Higher tensile strength (403.2 MPa), micro-hardness values (122.15 HV0.1), and joint efficiency (75.49) of welded specimens are achieved at low TVR (0.6), and ductile failure is observed in all welded samples. Additionally, it is noticed that the stirred zone size increased with increasing the velocity ratio.

Healing of Undisturbed Slide Zone Soil: Experimental Study on the Huaipa Landslide in Sanmenxia City

The occurrence and development of a landslide is a gradual process of destruction, causing huge losses to people’s lives and property. The shear strength of the shear zone gradually decreases to the residual state during the sliding process but it can recover to a certain extent during a relatively stable period. In a landslide, more than one slide usually occurs; however, after the first slide stops, it can enter a dormant period. The sliding surface can then experience a self-healing strength recovery phenomenon; this self-healing phenomenon has a significant impact on the reactivation of the landslide. Relevant studies have shown that the strength of the sliding surface is slightly greater than the residual strength when a landslide is reactivated; however, the explanations provided by these studies have not been sufficiently systematic. In this study, focusing on the undisturbed slide zone soil of the Huaipa landslide in Sanmenxia City, the “shear–pause–shear–pause–shear” test scheme is adopted. The soil is subjected to 3 h, 6 h, 12 h, 24 h, and 72 h healing shear tests, and combined with the SEM microstructure characteristics of the shear surface, to explore the internal mechanism of self-healing. The results show that the landslide soil exhibits strong self-healing strength recovery characteristics; however, these strength recovery characteristics decrease rapidly after experiencing a very small displacement. The strength recovery was strongly correlated with the vertical stress and healing time. With increasing vertical stress, the strength recovery value of the soil increases. Under low pressure, the strength recovery is small, and under high pressure, the strength recovery is obvious. With increasing healing time, the strength recovery increases; however, the increase in the amplitude diminishes and ultimately approaches zero with increasing healing time. A “healing phenomenon” occurs in the shear surface of slide zone soil after a short period of time. A shear strength value greater than the residual strength can be used to check the landslide design, which can effectively reduce costs.

"Things That You Thought Mattered, None of That Matters": A Qualitative Exploration of Family Caregiver Values following Left Ventricular Assist Device Implantation.

Intentional exploration, or elicitation, of patient and family values-who/what matters most-is critical to the delivery of person-centered care, yet the values elicitation experiences of family caregivers have been understudied. Understanding caregiver experiences discussing, reflecting upon, and acting on their values is critical to optimizing health decisions after left ventricular assist device (LVAD) implantation. The aim of this study was to explore the values elicitation experiences of family caregivers of individuals with an LVAD in the postimplantation period. This was a qualitative descriptive study of LVAD caregivers recruited from an outpatient clinic in the southeast United States. After completing one-on-one semistructured interviews, participants' transcripts were analyzed using thematic analysis. Interviewed caregivers (n = 21) were 27 to 76 years old, with 67% African American, 76% female, 76% urban-dwelling, and 62% a spouse/partner. LVAD implantation was an impactful experience prompting caregiver reevaluation of their values; these values became instrumental to navigating decisions and managing stressors from their caregiving role. Three broad themes of caregiver values elicitation experiences emerged: (1) caregivers leverage their values for strength and guidance in navigating their caregiving role, (2) LVAD implantation prompts (re)evaluation of relationships and priorities, and (3) caregivers convey their goals and priorities when deemed relevant to patient care. Having a care recipient undergo LVAD implantation prompted caregivers to reevaluate their values, which were used to navigate caregiving decisions and stressors. Findings highlight the need for healthcare professionals to engage and support caregivers after LVAD implantation.

Momentum-Resolved Electronic Structures and Strong Electronic Correlations in Graphene-like Nitride Superconductors.

Although transition-metal nitrides have been widely applied for several decades, experimental investigations of their high-resolution electronic band structures are rare due to the lack of high-quality single-crystalline samples. Here, we report on the first momentum-resolved electronic band structures of titanium nitride (TiN) films, which are remarkable nitride superconductors. The measurements of the crystal structures and electrical transport properties confirmed the high quality of these films. More importantly, from a combination of high-resolution angle-resolved photoelectron spectroscopy and first-principles calculations, the extracted Coulomb interaction strength of TiN films can be as large as 8.5 eV, whereas resonant photoemission spectroscopy yields a value of 6.26 eV. These large values of Coulomb interaction strength indicate that superconducting TiN is a strongly correlated system. Our results uncover the unexpected electronic correlations in transition-metal nitrides, potentially providing a perspective not only to understand their emergent quantum states but also to develop their applications in quantum devices.

Facile Preparation of High-Performance Reduced Graphene Oxide (RGO)/Copper (Cu) Composites Based on Pyrolysis of Copper Formate

Graphene has attracted much interest in many scientific fields because of its high specific surface area, Young’s modulus, fracture strength, carrier mobility and thermal conductivity. In particular, the graphene oxide (GO) prepared by chemical exfoliation of graphite has achieved low-cost and large-scale production and is one of the most promising for Cu matrix composites. Here, we prepared a high strength, high electrical conductivity and high thermal conductivity reduced graphene oxide (RGO)/Cu composite by directly heating the GO/copper formate. The oxygen-containing functional groups and defects of RGO are significantly reduced compared with those of GO. The tensile yield strength and thermal conductivity of RGO/Cu composite with RGO volume fraction of 0.49 vol.% are as high as 553 MPa and 364 W/(m·K) at room temperature, respectively. The theoretical value of the tensile yield strength of the composite is calculated according to the strengthening mechanism, and the result shows that it agrees with the experimental value. After hot-rolling treatment, the ductility and conductivity of the composite materials have been greatly improved, and the ductility of the RGO/Cu composite with RGO volume fraction of 0.49 vol.% has been increased to four times the original. This work provides a highly efficient way to fabricate a high-performance RGO-reinforced Cu composite for commercial application.

#3109 Sarcopenia in peritoneal dialysis patients

Abstract Background and Aims Sarcopenia is considered a frequent cause of morbidity and mortality among patients with chronic kidney disease (CKD). In clinical practice, tools such as handgrip strength and bioelectrical impedance analysis (BIA) can help us diagnose sarcopenia and possibly predict clinical outcomes. However, the outcomes associated with this diagnosis in the population of patients under peritoneal dialysis (PD) and the consequent importance of the implementation of these tools is not clear. Method Single-centre retrospective study with patients who started peritoneal dialysis (PD) between January 1st 2017 and December 31st 2023, with a follow-up of 18 months or until technique dropout. Demographic, clinical data and outcomes were collected. Muscle strength (measured by handgrip strength with a dynamometer) and muscle mass (estimated through BIA-derived lean tissue index (LTI)) were also evaluated. Sarcopenia was considered when low strength (handgrip strength values <27 kg and <16 kg for men and women, respectively) and loss of muscle mass (LTI <10th percentile, relative to an age and gender-matched healthy population) were present. Results Fifty-three patients were included, with 66% male and a mean age of 58 ± 15 years. Comorbidities included hypertension in 88.7%, diabetes mellitus (DM) in 26.4% and coronary artery disease (CAD) in 17.0%. PD vintage was 23 months (IQR 21) and most were on continuous ambulatory peritoneal dialysis (75.5%). Median Clinical Frailty Score (CFS) was 2 (IQR 1). Mean LTI was 13.2 ± 2.7 kg/m2 and average handgrip strength was 28.4 ± 8.8 kg in the right arm and 26 kg (IQR 13) in the left. Reported outcomes of number of peritonitis, outer peritoneal catheter infection, hospitalizations and MACE (Major Adverse Cardiovascular Events) episodes were low. There were 3 reported deaths during follow-up. Six patients were considered sarcopenic, with 66% male and a mean age of 58.1 ± 14.9 years, with DM in 50%, hypertension in 100% and CAD in 33.3%. Median LTI was 9.4 (IQR 1.2), with left and right median hand grip of 24 (IQR 10) and 26 (13), respectfully. Outcomes were also low, with no statistically significant difference between sarcopenic and non-sarcopenic patients. Conclusion Despite being considered an indication of higher morbidity and mortality, the diagnosis of sarcopenia was not associated with worse outcomes in patients under peritoneal dialysis.

"When I do have some time, rather than spend it polishing silver, I want to spend it with my grandkids": a qualitative exploration of patient values following left ventricular assist device implantation.

Values are broadly understood to have implications for how individuals make decisions and cope with serious illness stressors, yet it remains uncertain how patients and their family and friend caregivers discuss, reflect upon, and act on their values in the post-left ventricular assist device (LVAD) implantation context. This study aimed to explore the values elicitation experiences of patients with an LVAD in the post-implantation period. Qualitative descriptive study of LVAD recipients. Socio-demographics and patient resource use were analyzed using descriptive statistics and semi-structured interview data using thematic analysis. Adult (> 18 years) patients with an LVAD receiving care at an outpatient clinic in the Southeastern United States. Interviewed patients (n = 27) were 30-76 years, 59% male, 67% non-Hispanic Black, 70% married/living with a partner, and 70% urban-dwelling. Three broad themes of patient values elicitation experiences emerged: 1) LVAD implantation prompts deep reflection about life and what is important, 2) patient values are communicated in various circumstances to convey personal goals and priorities to caregivers and clinicians, and 3) patients leverage their values for strength and guidance in navigating life post-LVAD implantation. LVAD implantation was an impactful experience often leading to reevaluation of patients' values; these values became instrumental to making health decisions and coping with stressors during the post-LVAD implantation period. Patient values arose within broad, informal exchanges and focused, decision-making conversations with their caregiver and the healthcare team. Clinicians should consider assessing the values of patients post-implantation to facilitate shared understanding of their goals/priorities and identify potential changes in their coping.

Optimization of the FDM Processing Parameters on the Compressive Properties of ABS Objects for the Production of High-Heeled Shoes

The influence of 3D printing parameters on compressive properties is an important factor in the application of additive manufacturing processes for products subjected to compressive loads in use. In this study, the compressive strength and compressive modulus of acrylonitrile/butadiene/styrene (ABS) test specimens fabricated using the fused deposition modeling (FDM) process were investigated with the aim of producing products of high-heeled shoes for women. The experimental part of the study includes a central composite experimental design to optimize the main 3D printing parameters (layer thickness, infill density, and extrusion temperature) and the infill geometry (honeycomb and linear at a 45° angle—L45) to achieve maximum printing properties of the 3D-printed products. The results show that the infill density has the greatest influence on the printing properties, followed by the layer thickness and, finally, the extrusion temperature as the least influential factor. The linear infill at a 45° angle resulted in higher compressive strength and lower compressive modulus values compared to the honeycomb infill. By optimizing the results, the maximum compressive strength (that of L45 is 41 N/mm2 and that of honeycomb 35 N/mm2) and modulus (that of L45 is 918 N/mm2 and that of honeycomb is 868 N/mm2) for both types of infill is obtained at a layer thickness of 0.1 mm and infill density of 40%, while the temperature for L45 can be in the range of 209 °C to 254 °C, but for the honeycomb infill, the processing temperature is 255 °C. Additionally, the study highlights the potential for sustainable manufacturing practices and the integration of advanced 3D printing technologies to enhance the efficiency and eco-friendliness of the production process.

Magnetic energy product and hysteresis behavior of antiperovskite Mn3AlN: Monte Carlo Simulation

In this study, we investigated the magnetic properties, magnetocaloric effect, magnetic energy product, and hysteresis behavior of Mn3AlN antiperovskite using Monte Carlo (MC) simulation techniques. We examined the effect of magnetic field on magnetic behavior. As the magnetic field values h increase, the amplitudes of both the specific heat peaks and the susceptibility also increase. For various external magnetic fields and temperatures, we obtained the adiabatic temperature change and the magnetic entropy change. The compound displayed a direct magnetocaloric effect. Furthermore, the relative cooling power (RCP) values for a magnetic field strength of 60 kOe are 117.54 J/kg. The hysteresis loops were used to calculate the energy product BH. These findings suggest that our material is an excellent fit for magnetic refrigeration and information storage applications.

DFT and TD-DFT Investigations for the Limitations of Lengthening the Polyene Bridge between N,N-dimethylanilino Donor and Dicyanovinyl Acceptor Molecules as a D-π-A Dye-Sensitized Solar Cell

One useful technique for increasing the efficiency of organic dye-sensitized solar cells (DSSCs) is to extend the π-conjugated bridges between the donor (D) and the acceptor (A) units. The present study used the DFT and TD–DFT techniques to investigate the effect of lengthening the polyene bridge between the donor N, N-dimethyl-anilino and the acceptor dicyanovinyl. The results of the calculated key properties were not all in line with expectations. Planar structure was associated with increasing the π-conjugation linker, implying efficient electron transfer from the donor to the acceptor. A smaller energy gap, greater oscillator strength values, and red-shifted electronic absorption were also observed when the number of polyene units was increased. However, some results indicated that the potential of the stated dyes to operate as effective dye-sensitized solar cells is limited when the polyene bridge is extended. Increasing the polyene units causes the HOMO level to rise until it exceeds the redox potential of the electrolyte, which delays regeneration and impedes the electron transport cycle from being completed. As the number of conjugated units increases, the terminal lobes of HOMO and LUMO continue to shrink, which affects the ease of intramolecular charge transfer within the dyes. Smaller polyene chain lengths yielded the most favorable results when evaluating the efficiency of electron injection and regeneration. This means that the charge transfer mechanism between the conduction band of the semiconductor and the electrolyte is not improved by extending the polyene bridge. The open circuit voltage (VOC) was reduced from 1.23 to 0.70 V. Similarly, the excited-state duration (τ) decreased from 1.71 to 1.23 ns as the number of polyene units increased from n = 1 to n = 10. These findings are incompatible with the power conversion efficiency requirements of DSSCs. Therefore, the elongation of the polyene bridge in such D-π-A configurations rules out its application in solar cell devices.

Nanocomposites Derived from Construction and Demolition Waste for Cement: X-ray Diffraction, Spectroscopic and Mechanical Investigations

In the production of cement, raw materials can be partially substituted by regenerable waste provided from glasses, construction and demolition waste in order to reduce the environmental problem and burden of landfills. In this study, limestone–silicate composites were synthesized using starting materials such as glass waste and lime, brick, autoclaved aerated concrete (ACC), mortar or plaster waste. The structure and mechanical properties of the nano-composite materials have been studied. The mean CaCO3 crystallite sizes are higher for composites containing ACC and brick than for doping with lime, mortar and plaster. Cement-based materials are formed by replacing 2.5% of the Portland cement with limestone–silicate composites. The results indicate new possibilities for introducing 2.5%of composites in cement paste because they promote the formation of the C-S-H network, which provides strength and long stability for the cement paste. The influence of varied types of mix composites in the expired cement on the initial cracking strain and stress, tensile strength and compressive strength were investigated. The compressive strength values of composite-expired cement specimens are situated between 11.8 and 15.7 MPa, respectively, which reflect an increase from 22.9 up to 63.54% over the compressive strength of expired cement matrix.