Preliminary analysis of the oxygen isotopic composition of the solar wind recorded by the Genesis spacecraft suggests that the Sun is 16O-rich compared to most chondrules, fine-grained chondrite matrices, and bulk compositions of chondrites, achondrites, and terrestrial planets (Δ17O = –26.5‰ ± 5.6‰ and –33‰ ± 8‰ (2σ) versus Δ17O ~ ±5‰). The inferred 16O-rich composition of the Sun is similar or slightly lighter than the 16O-rich compositions of amoeboid olivine aggregates and typical calcium-aluminum-rich inclusions (CAIs) from primitive (unmetamorphosed) chondrites (Δ17O = –24‰ ± 2‰), which are believed to have condensed from and been melted in a gas of approximately solar composition (dust/gas ratio ~ 0.01 by weight) within the first 0.1 Myr of the solar system formation. Based on solar system abundances, 26% of the solar system oxygen must be initially contained in dust and 74% in gas. Because solar oxygen is dominated by the gas component, these observations suggest that oxygen isotopic composition of the solar nebula gas was initially 16O-rich. Due to significant thermal processing of the protosolar molecular cloud silicate dust (primordial dust) in the solar nebula and its possible isotope exchange with the isotopically evolved solar nebula gas, the mean oxygen isotopic composition of the primordial dust is not known. In CO self-shielding models, it is assumed that primordial dust and solar nebula gas had initially identical, 16O-rich compositions, similar to that of the Sun (Δ17O ~ –25‰ or –35‰), and solids subsequently evolved toward the terrestrial value (Δ17O = 0). However, there is no clear evidence that the oxygen isotopic compositions of the solar system solids evolved in the direction of increasing Δ17O with time and no 16O-rich primordial dust have yet been discovered. Here we argue that the assumption of the CO self-shielding models that primordial dust and solar nebula gas had initially identical 16O-rich compositions is incorrect. We show that igneous CAIs with highly fractionated oxygen isotopic compositions, fractionation and unidentified nuclear effects (FUN), and fractionation (F) CAIs, have Δ17O ranging from –0.5‰ to –24.8‰. Within an individual FUN or F CAI, oxygen isotopic compositions of spinel, forsterite, and pyroxene define a mass-dependent fractionation trend with a constant Δ17O value. The degree of mass-dependent fractionation of these minerals correlates with the sequence of their crystallization from the host CAI melt. These observations and evaporation experiments on CAI-like melts indicate that FUN and F CAIs formed by melting of solid precursors with diverse Δ17O values in vacuum (total pressure 50☉) ejecta. The 16O-depleted compositions of chondrules, fine-grained matrices, chondrites, and achondrites compared to the Sun's value reflect their formation in the protoplanetary disk regions with enhanced dust/gas ratio (up to 105× solar).
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