Valorization Technologies Research Articles

CuC(O) Interfaces Deliver Remarkable Selectivity and Stability for CO2 Reduction to C2+ Products at Industrial Current Density of 500mA cm-2.

The electrocatalytic CO2 reduction reaction (CO2 RR) is an attractive technology for CO2 valorization and high-density electrical energy storage. Achieving a high selectivity to C2+ products, especially ethylene, during CO2 RR at high current densities (>500mA cm-2 ) is a prized goal of current research, though remains technically very challenging. Herein, it is demonstrated that the surface and interfacial structures of Cu catalysts, and the solid-gas-liquid interfaces on gas-diffusion electrode (GDE) in CO2 reduction flow cells can be modulated to allow efficient CO2 RR to C2+ products. This approach uses the in situ electrochemical reduction of a CuO nanosheet/graphene oxide dots (CuOC(O)) hybrid. Owing to abundant CuOC interfaces in the CuOC(O) hybrid, the CuO nanosheets are topologically and selectively transformed into metallic Cu nanosheets exposing Cu(100) facets, Cu(110) facets, Cu[n(100) × (110)] step sites, and Cu+ /Cu0 interfaces during the electroreduction step, the faradaic efficiencie (FE) to C2+ hydrocarbonswasreached as high as 77.4% (FEethylene ≈ 60%) at 500mA cm-2 . In situ infrared spectroscopy and DFT simulations demonstrate that abundant Cu+ species and Cu0 /Cu+ interfaces in the reduced CuOC(O) catalyst improve the adsorption and surface coverage of *CO on the Cu catalyst, thus facilitating CC coupling reactions.

A Review of Carbon Capture and Valorization Technologies

Global fossil fuel consumption has induced emissions of anthropogenic carbon dioxide (CO2), which has emanated global warming. Significant levels of CO2 are released continually into the atmosphere from the extraction of fossil fuels to their processing and combustion for heat and power generation including the fugitive emissions from industries and unmanaged waste management practices such as open burning of solid wastes. With an increase in the global population and the subsequent rise in energy demands and waste generation, the rate of CO2 release is at a much faster rate than its recycling through photosynthesis or fixation, which increases its net accumulation in the atmosphere. A large amount of CO2 is emitted into the atmosphere from various sources such as the combustion of fossil fuels in power plants, vehicles and manufacturing industries. Thus, carbon capture plays a key role in the race to achieve net zero emissions, paving a path for a decarbonized economy. To reduce the carbon footprints from industrial practices and vehicular emissions and attempt to mitigate the effects of global warming, several CO2 capturing and valorization technologies have become increasingly important. Hence, this article gives a statistical and geographical overview of CO2 and other greenhouse gas emissions based on source and sector. The review also describes different mechanisms involved in the capture and utilization of CO2 such as pre-combustion, post-combustion, oxy-fuels technologies, direct air capture, chemical looping combustion and gasification, ionic liquids, biological CO2 fixation and geological CO2 capture. The article also discusses the utilization of captured CO2 for value-added products such as clean energy, chemicals and materials (carbonates and polycarbonates and supercritical fluids). This article also highlights certain global industries involved in progressing some promising CO2 capture and utilization techniques.

Application of novel extraction technologies for valorisation of food by‐products and waste for utilising in functional food product development: Editorial

The peer review history for this article is available at https://publons.com/publon/10.1111/ijfs.16355.

Challenges and opportunities for sustainable valorization of rare earth metals from anthropogenic waste.

Progressively and projected integration of rare earth metals (REMs) in modern technologies, especially in the clean energy, consumer electronics, aerospace, automotive, and defense sectors, place REMs as critical raw materials in the supply chain and strategic metal from the fourth industrial revolution perspective. Current REM production from the primary mineral resources in the supply chain versus industrial demand is at a bottleneck. Alternatively, REM-bearing anthropogenic wastes are pertinent and potent to addressing the critical supply chain bottleneck. Although secondary REM resources are prudent to address the critical supply chain bottleneck, the absence of effective and efficient technologies to recover these REMs from anthropogenic waste imposes challenges and provides opportunities. Hence, this review analyses and discusses the significance of anthropogenic wastes for REM recovery, the status of recycling technologies for sustainable valorization of REMs, challenges, and opportunities. The current review covers the potential quantitative REM wealth locked in various anthropogenic waste like (i) spent rare earth permanent magnets, (ii) spent batteries, (iii) spent tri-band REM phosphors, (iv) bauxite industry residue red mud, (v) blast furnace slag and (v) coal mines, and coal byproducts and status of valorization technologies for circularizing the REMs. In industrial waste like red mud, steelmaking slag, blast furnace slag, and coal fly ash typically 109,000, 2000, 39,000, and 354,000 tons of REM get scrapped, respectively, in a conservative estimation. In the years 2020 and 2021, respectively, 240,000 and 280,000 tons of REM were produced by mine production in contrast to 504,000 tons of REM that were scrapped with REM-bearing industrial waste. This review revealed that total REM currently getting scrapped with anthropogenic waste versus projected REM demand for the years 2022, 2023, 2024, and 2025 could be standing at 2.66, 2.51, 2.37, and 2.23, respectively. Our investigation revealed that efficient recovery of REMs from anthropogenic waste is significant and promising but associated with challenges like lack of industrial-scale valorization process, lack of a clear strategy, road map, policy, effort, funding, and diversified research.

Toward sustainable reprocessing and valorization of sulfidic copper tailings: Scenarios and prospective LCA

There has been increasing attention recently to reprocessing of mining waste, which aims to recover potentially valuable materials such as metals and other byproducts from untapped resources. Mining waste valorization may offer environmental advantages over traditional make-waste-dispose approaches. However, a quantitative environmental assessment for large-scale reprocessing, accounting for future trends and a broad set of environmental indicators, is still lacking. This article assesses the life cycle impacts and resource recovery potential associated with alternative waste management through mine tailings reprocessing at a regional scale. Sulfidic copper tailings in the EU were selected as a case study. We perform prospective life cycle assessments of future reprocessing scenarios by considering emerging resource recovery technologies, market supply & demand forecasts, and energy system changes. We find that some reprocessing and valorization technologies in future scenarios may have reduction potentials for multiple impact indicators. However, results for indicators such as climate change and energy-related impacts suggest that specific scenarios perform sub-optimally due to energy/resource-intensive processes. The environmental performance of reprocessing of tailings is influenced by technology routes, secondary material market penetration, and choices of displaced products. The trade-off between climate change and energy related impacts, on the one hand, and toxicity impacts, on the other hand, requires critical appraisal by decision makers when promoting alternative tailings reprocessing. Implementing value recovery strategies for building material production, can save up to 3 Mt. CO2-eq in 2050 compared to business as usual, helping the copper sector mitigate climate impacts. Additional climate mitigation efforts in demand-side management are needed though to achieve the 1.5 °C climate target. This work provides a scientific basis for decision-making toward more sustainable reprocessing and valorization of sulfidic tailings.

Process safety assessment of thermal technologies for biomass valorization by numerical descriptive approach

Process-based safety assessment of biomass thermal valorization technologies including hydrothermal gasification (HTG), pyrolysis, and conventional gasification has been evaluated based on the Numerical Descriptive Logistics Equation (NuD). Process-related data such as temperature, pressure, heat of reaction, and process inventory were collected from the literature for this purpose. The data has been analyzed by using the NuD equations to obtain the process safety total score (PSTS), and then hierarchy of control (HOC) has been applied to propose the strategies for risk mitigation. According to the NuD results, the HTG process has a lower PSTS (210.2) compared with pyrolysis (226.4) and gasification (228.5), and it reveals that HTG is the safest among these three technologies. HTG has the highest score for pressure (60.48) because it has the high pressure (20–25 MPa) process requirement, but the lowest scores for temperature and heat of reaction due to lower temperature operations (374–400 °C) compared with pyrolysis and gasification. The results determined by the NuD have been compared with subjective safety evaluation methods (Process Safety Index Analysis and Inherent Safety Index), and the results of inherent safety index (ISI) are also consistent with that determined by the NuD. Hierarchy of control has been proposed to control and reduce the process risk. As per results, engineering and administrative measures could be drafted for more effective process safety control.

Solvothermal Liquefaction of Blackcurrant Pomace in the Water-Monohydroxy Alcohol Solvent System

Wet organic wastes are especially troublesome in valorization. Therefore, innovative solutions are still in demand to make valorization feasible. In this study, we tested a new transformation route of a blackcurrant pomace as a high-moisture industrial waste through a series of high-temperature and pressure solvothermal liquefaction experiments. The feedstock was directly converted under near-critical conditions of the binary solvent system (water/2-propanol). The goal was to examine the effect of conversion parameters (temperature, biomass-to-solvent ratio) on the change in the yield of resultant bioproducts, as well as the quality thereof. The experiments were conducted in a batch autoclave at a temperature between 250 and 300 °C. The main product of the transformation was liquid biocrude, which was obtained with the highest yield (ca. 52 wt.%) at 275 °C. The quality of biocrude was examined by ATR-FTIR, GC-MS, and elemental analysis. The ultimate biocrude was a viscous heterogeneous mixture containing various groups of components and exhibiting evident energy densification (ca. 145–153%) compared to the value of the feedstock. The proposed processing method is suitable for further development toward efficient valorization technology. More specifically, the co-solvent additive for liquefaction is beneficial not only for the enhancement of the yield of the desired product, i.e., biocrude, but also in terms of technological aspects (reduction of operational pressure and temperature).

A typology of sustainable circular business models with applications in the bioeconomy

As an approach to sustainable development, circular business models are increasingly being developed. However, many circular business models focus on environmental or technological contributions to sustainability rather than considering all dimensions of sustainability simultaneously. Based on existing sustainable business model archetypes, a hierarchical business model typology is developed that allows a stepwise exploration of sustainable business model innovation opportunities incorporating an environmental, social and economic dimension. An analysis of business model components generates a closer look on the six newly defined Sustainable Circular Business Models. Finally, a conceptual application for organic waste valorization technologies, supported by examples from literature, allows a practical view on the implementation of the business models in the bio-economy. The typology offers a guide toward sustainable business model design or innovation opportunities centered around technologies creating value from waste.

Persistence and remote sensing of agri-food wastes in the environment: Current state and perspectives

Food demand is expected to increase globally by 60–110% from 2005 to 2050 due to diet shifts and population growth. This growth in food demand leads to the generation of enormous agri-food wastes (AFWs), which could be classified into pre-consumption and post-consumption. The AFW represents economic losses for all stakeholders along food supply chains, including consumers. It is reported that the direct financial, social, and environmental costs of food waste are 1, 0.9, and 0.7 trillion USD/year, respectively. Diverse conventional AFW management approaches are employed at the different life cycle levels (entre supply chain). The review indicates that inadequate transportation, erroneous packaging, improper storage, losses during processing, contamination, issues with handling, and expiry dates are the main reason for the generation of AFWs in the supply chain. Further, various variables such as cultural, societal, personal, and behavioral factors contribute to the AFW generation. The selection of a specific valorization technology is based on multiple physicochemical and biological parameters. Furthermore, other factors like heterogeneity of the AFWs, preferable energy carriers, by-products management, cost, end-usage applications, and environmental legislative and disposal processes also play a crucial role in adopting suitable technology. Valorization of AFW could significantly impact both economy and the environment. AFWs have been widely investigated for the development of engineered added-value biomaterials and renewable energy production. Considering this, this study has been carried out to highlight the significance of AFW cost, aggregation, quantification, and membrane-based strategies for its management. The study also explored the satellite remote sensing data for Spatio-temporal monitoring, mapping, optimization, and management of AFW management. Along with this, the study also explained the most recent strategies for AFW valorization and outlined the detailed policy recommendation along with opportunities and challenges. The review suggested that AFW should be managed using a triple-bottom-line strategy (economic, social, and environmental sustainability).

Identification of a Phylogenetically Divergent Vanillate O-Demethylase from Rhodococcus ruber R1 Supporting Growth on Meta-Methoxylated Aromatic Acids.

Rieske-type two-component vanillate O-demethylases (VanODs) catalyze conversion of the lignin-derived monomer vanillate into protocatechuate in several bacterial species. Currently, VanODs have received attention because of the demand of effective lignin valorization technologies, since these enzymes own the potential to catalyze methoxy group demethylation of distinct lignin monomers. In this work, we identified a phylogenetically divergent VanOD from Rhodococcus ruber R1, only distantly related to previously described homologues and whose presence, along with a 3-hydroxybenzoate/gentisate pathway, correlated with the ability to grow on other meta-methoxylated aromatics, such as 3-methoxybenzoate and 5-methoxysalicylate. The complementation of catabolic abilities by heterologous expression in a host strain unable to grow on vanillate, and subsequent resting cell assays, suggest that the vanAB genes of R1 strain encode a proficient VanOD acting on different vanillate-like substrates; and also revealed that a methoxy group in the meta position and a carboxylic acid moiety in the aromatic ring are key for substrate recognition. Phylogenetic analysis of the oxygenase subunit of bacterial VanODs revealed three divergent groups constituted by homologues found in Proteobacteria (Type I), Actinobacteria (Type II), or Proteobacteria/Actinobacteria (Type III) in which the R1 VanOD is placed. These results suggest that VanOD from R1 strain, and its type III homologues, expand the range of methoxylated aromatics used as substrates by bacteria.

A review in advancement of valorization and the treatment of bio-waste

The current reality deals with the problem of depleting energy supplies and the age of waste from human activities. While scrap is a gamble, it is also an excellent opportunity to address this dual issue by using trash as a predictable energy source and materials source. A few studies are being sought to allow garbage administration to match the amount of its generation. A fantastic strategy for achieving this goal is the Foundation of the Bioeconomy. The productivity of the cycle, beneficial side-effects, muck, a wide variety of squanders organization, and the financial viability of treatment advancements to raise and industrialize beyond lab setup are, nevertheless, inherent challenges associated with biowaste. To treat the problems as well as to increase the value of waste by using it as a feedstock to produce contemporary synthetics, fillers, and materials, recent advancements have been made in this way with the use of new strategies, synergistic impetuses, combinations of advancements, and newly developed materials. This survey provides information regarding the developments of bio-waste, as well as the fundamental debate, obstacles, and financial viability of waste valorization technology. The novel treatment substances remediate the challenges and maximize the waste value by utilizing it in the feedstock of industrial chemicals, organic materials, and fuels. In the recent Bio-economic strategy, it is essential to include the value of a substitute for the original use of garbage, such as producing hydroelectricity power for the mills. Consequently, different kinds of “waste” can be measured for their value by using the Valorization methodology.

Plastic pyrolysis over HZSM-5 zeolite and fluid catalytic cracking catalyst under ultra-fast heating

Plastic pollution compromises the environment and human well-being, and a global transition to a circular economy of plastics is vital to address this challenge. Pyrolysis is a key technology for the end-of-life recycling of plastics, although high energy consumption limits the economic feasibility of the process. Various research has shown that the application of induction heating in biomass pyrolysis reduces energy consumption when compared to conventional heating. Nevertheless, the potential of induction heating in plastic pyrolysis is rarely explored. This paper presents an exploratory study on the thermal and catalytic pyrolysis of high-density polyethylene, low-density polyethylene, and polypropylene in a fixed bed reactor through induction heating. An MFI-type HZSM-5 zeolite (SiO2/Al2O3 = 23) and an FAU-type spent fluid catalytic cracking (FCC) catalyst with distinctive Brønsted acidity and textural properties were used. A complete conversion of the plastic feedstocks was achieved within 10 min, even without a catalyst. Thermal pyrolysis produced wax (72.4–73.9 wt%) and gas products, indicating a limited degree of polymer cracking. Catalytic pyrolysis over HZSM-5 and FCC catalyst significantly improved polymer cracking, leading to higher gas (up to 75.2 wt%) and liquid product (up to 35.9 wt%) yields at the expense of wax yield (up to 25.4 wt%). In general, the gas products were rich in C3 and C4 compounds. The liquid product composition was highly dependent on the catalyst properties, for example, the HZSM-5 produced high aromatics, while the FCC catalyst produced high alkenes in the liquid products. The catalyst acidity and textural properties played an essential role in plastic pyrolysis within the short reaction time. This study demonstrated the feasibility of a fast, energy-efficient, and versatile plastic valorization technology based on the application of induction heating, where the plastic feed can be converted into wax, gas, and liquid products depending on the end-use applications.

Mechanochemical Synthesis of Bimetallic NiCo Supported on a CeO2 Catalyst with Less Metal Loading for Non-Thermal Plasma Catalytic CO2 Hydrogenation

Non-thermal plasma (NTP) catalysis is a promising technology for CO2 valorization with renewable H2, in which catalyst design is one of the key aspects to progress the hybrid technology. Herein, bimetallic NiCo supported on CeO2 catalysts, that is, NiCo/CeO2, were developed with less metal loading of ∼2 wt % using mechanochemical synthesis for NTP-catalytic CO2 methanation. During the synthesis, different addition orders of Ni and Co precursors were investigated, and the results show that the NiCo1/CeO2-I catalyst (which was prepared by the simultaneous addition of Ni and Co precursors, protocol I) exhibited the highest CO2 conversion (∼60%) and CH4 selectivity/yield (∼80%/∼50%), whereas the NiCo1/CeO2-II and NiCo1/CeO2-III catalysts (prepared by sequential addition protocols of II and III) showed very poor catalytic performance. Characterization results suggested that in protocol I, Ni and Co prefer to alloy, and concentrated oxygen vacancies on the CeO2 surface and high surface basicity are retained as well. Such properties of NiCo1/CeO2-I were responsible for CO2 activation and hydrogenation under NTP conditions, which was explained by the proposed mechanisms.

Development of a system model to predict flows and performance of regional waste management planning: A case study of England

Significant loss of valuable resources and increasing burdens on landfills are often associated with a lack of proper planning in waste management and resource recovery strategy. A sustainable waste management model is thus urgently needed to improve resource efficiency and divert more waste from landfills. This paper proposes a comprehensive system model using stock-and-flow diagram to examine the current waste management performance and project the future waste generation, treatment and disposal scenarios, using England as a case study. The model comprises three integrated modules to represent household waste generation and collection; waste treatment and disposal; and energy recovery. A detailed mass and energy balance has been established and waste management performance has been evaluated using six upstream and downstream indicators. The base case scenario that assumes constant waste composition shows that waste to landfills can be reduced to less than 10% of the total amount, by 2035. However, it entails greater diversion of waste to energy-from-waste facilities, which is not sustainable and would incur higher capital investment and gate fees. Alternative case scenarios that promote recycling instead of energy recovery result in lower capital investment and gate fees. Complete elimination of the food and organic fraction from the residual waste stream will help meet the 65% recycling target by 2035. In light of the need for achieving a more circular economy in England, enhancing material recovery through reuse and recycling, reducing reliance on energy-from-waste and deploying more advanced waste valorisation technologies should be considered in future policy and planning for waste management.

Occurrence of macroplastics and microplastics in biogenic waste digestate: Effects of depackaging at source and dewatering process

Plastic debris, including macroplastics (>5 mm) and microplastics (0.1–5 mm), has proven to be an emerging contaminant. Anaerobic digestion, coupled with energy recovery, can be an effective valorization technology for biogenic waste. But the use of the resulting digestate as a soil conditioner is a source for plastic debris release into the environment. The preprocess and postprocess used could influence the quantity of plastic debris found in the digestate, but the specifics of these effects are relatively unknown. Therefore, we measured the quantity of plastic debris in raw digestate under a variety of preprocessing scenarios. We also investigated the occurrence of plastic debris in solid and liquid digestates resulting from the dewatering of raw digestate. The quantity of plastic debris ranged from 41 to 3298 particles/kg (WW) for raw digestate, 319–3604 particles/kg (WW) for solid digestate and 7–38 particles/kg (WW) for liquid digestate. We observed that depackaging at source by citizens themselves (removing the package of biogenic waste when dropping it into bins), significantly reduced the quantities of plastic debris in raw digestate by an order of magnitude. Furthermore, the number of polymer types in raw digestate, where depackaging occurred at source, were lower than that where this rule was not in place. The average size of plastic debris in solid digestate was significantly smaller than that in raw digestate, which indicated that the process of mechanical dewatering could generate MPs. It is recommended to depackage for biogenic waste at source to reduce the quantities of MPs in digestate.

Sustainable Approaches Using Green Technologies for Apple By-Product Valorisation as A New Perspective into the History of the Apple.

The apple has been recognised as the most culturally important fruit crop in temperate land areas. Centuries of human exploitation and development led to the production of thousands of apple cultivars. Nowadays, the apple represents the third most widely cultivated fruit in the world. About 30% of the total production of apples is processed, being juice and cider the main resulting products. Regarding this procedure, a large quantity of apple by-product is generated, which tends to be undervalued, and commonly remains underutilised, landfilled, or incinerated. However, apple by-product is a proven source of bioactive compounds, namely dietary fibre, fatty acids, triterpenes, or polyphenols. Therefore, the application of green technologies should be considered in order to improve the functionality of apple by-product while promoting its use as the raw material of a novel product line. The present work provides a holistic view of the apple’s historical evolution, characterises apple by-product, and reviews the application of green technologies for improving its functionality. These sustainable procedures can enable the transformation of this perishable material into a novel ingredient opening up new prospects for the apple’s potential use and consumption.

From Lignin to Chemicals: An Expedition from Classical to Modern Catalytic Valorization Technologies

AbstractFor the transition towards greener biorefineries with reduced waste, valorization of lignin to drop‐in chemicals instead of their combustion for energy purposes is a key issue for future processes. In this context, lignin should be extracted from lignocellulosic biomass (LCB) and fragmented into smaller units, followed by catalytic funneling to fine chemicals. In this review, we report on the classical approaches for lignin valorization from LCB: thermal treatments, solvolytic valorization, acid‐catalyzed process, and base‐catalyzed process. We also provide the reader with the modern approach of lignin valorization that led to an integrated LCB biorefinery. The performance of different solid catalysts in lignin‐first approach via reductive or oxidative catalytic fractionation at different conditions is discussed in detail.

Co-Fermenting Pyrolysis Aqueous Condensate and Pyrolysis Syngas with Anaerobic Microbial Communities Enables L-Malate Production in a Secondary Fermentative Stage

The pyrolytic conversion of lignocellulosic biomass into fuels and chemicals is a promising option for the valorization of agricultural and forestry residues. However, technological developments are still needed to maximize product recovery and carbon fixation of the pyrolysis process. The pyrolysis aqueous condensate (PAC), a pyrolysis by-product, has a high water content and is highly toxic, hampering its use. The anaerobic digestion of PAC from different biomasses has been proven a viable technology for PAC valorization and detoxification, but its toxicity limits the methanogenic potential. Alternatively, methanation or VFA production from syngas by anaerobic mixed cultures are technologies of scientific interest. This study investigates the potential of a two-stage process to convert the carbon and energy in syngas and PAC into L-malate. PAC and syngas were co-fermented by two mixed cultures at 37 and 55 °C, identifying kinetic inhibitions and the effects of increasing PAC concentrations on the product pool. The media from selected mixed culture fermentations were then inoculated with Aspergillus oryzae for L-malate production. The results show that mixed cultures can perform simultaneous syngas fermentation and PAC detoxification. While PAC concentrations above 2% completely inhibited methanogenesis, CO consumption was inhibited at PAC concentrations above 5%, regardless of the temperature. In fermentations where PAC inhibited methanation, the mixed cultures channelled the carbon and electrons from syngas and PAC to volatile fatty acids or acetate/H2 production, depending on the incubation temperature. Substantial detoxification of PAC was observed under PAC concentrations up to 10% independently of the rates of syngas metabolism. PAC detoxification enabled the further valorization of the acetate produced via syngas and PAC fermentations into L-malate, achieving yields up to 0.17 mM/mM. These results are promising for the development of an integrated process that simultaneously detoxifies and recovers value from gaseous and aqueous waste streams originating from pyrolysis.

Membrane Technology for Valorization of Mango Peel Extracts

Mango peel is rich in nutritional and functional compounds, such as carbohydrates, dietary fibers, proteins, and phenolic compounds, with high potential to be applied in the food industry. Most of the investigation about recovery of bioactive compounds from fruit bioproducts involves extraction techniques and further separation of target compounds. There is still a lack of information about the potential of membrane processes to recover the nutritive/functional compounds present in aqueous extracts of those bioproducts. This research is addressed to study the performance of ultrafiltration (UF), followed by nanofiltration (NF) of UF permeates, to fractionate the compounds present in aqueous extracts of mango peel. Both UF and NF concentration processes were carried up to a volume concentration factor of 2.0. Membranes with molecular weight cut-offs of 25 kDa and 130 Da were used in the UF and NF steps, respectively. UF and NF concentrates showed antioxidant activity, attributed to the presence of phenolic compounds, with rejections of about 75% and 98.8%, respectively. UF membranes totally rejected the higher molecular weight compounds, and NF membranes almost totally concentrated the fermentable monosaccharides and disaccharides. Therefore, it is envisaged that NF concentrates can be utilized by the food industry or for bioenergy production.

Process simulation and analysis of high‐pressure reverse osmosis (HPRO) in the treatment and utilization of desalination brine (saline wastewater)

Reverse osmosis (RO) is nowadays considered to be the most dominant desalination technology. Nonetheless, due to osmotic pressure constraints, conventional RO cannot desalinate brine effluents (>70 g/L of total dissolved solids [TDS]). Thus, high-pressure RO (HPRO), that is, RO operating at a pressure of more than 82 bar, has recently attracted the interest of the water and wastewater industry. To this aim, a process simulation for the HPRO process was implemented and several sensitivity analyses were conducted for the first time. The results showed that by increasing the recovery rate by 0.05, energy consumption decreased by 3.5%. An increase in the feed brine temperature from 5°C to 30°C increases the permeate flow rate (up to 0.929 m3/h), the permeate concentration (up to 468 mg/L TDS), and the recovery rate (up to 0.435). A 10-bar pressure increases the permeate flow by approximately 9.8% and decreases the permeate concentration by approximately 6 mg/L TDS. Moreover, the use of an energy recovery device significantly reduces energy consumption by 26% (from 4.93-5.10 to 3.65-3.78 kWh/m3). Overall, HPRO is a promising technology for brine treatment and valorization in zero liquid discharge and minimal liquid discharge systems.