Biomass energy utilization can solve the contradiction between economic development and energy and environment. Biomass pyrolysis technology is not only one of the thermochemical conversion technologies, but also the necessary stage of biomass gasification, which has become a hot academic research topic. Firstly, based on the pyrolysis experimental data of cellulose, hemicellulose and lignin, the analytical expressions of pyrolysis gas mass yields of different biomass components varying with temperature were obtained; then, the prediction of pyrolysis products was obtained by mass component superposition method, and the correction coefficient of biomass pyrolysis gas yield model was obtained based on the comparison between the average yield of biomass pyrolysis gas and the predicted value of pyrolysis products; finally, the gas release mechanism model of biomass pyrolysis was obtained. This study provides theoretical basis and technical support for the development of biomass utilization technology.