There has been rising demand in recent years for environment friendly technologies which has spurred interest in sustainable energy solutions. The use of solar radiation in place of fossil fuel-derived thermal energy to extract essential oils in decentralized manner is one such potentially attractive proposition. The present work reports such a study for hydrodistillation of essential oil from fresh orange peels. The distillation was carried out in the absorber tube of a square parabolic trough concentrator of 1.3 m2 collector aperture area. 400–500 g of fresh peels was processed per batch and the limonene content in the crude oil was in the range of 86% to 90% while the yield of the oil varied from 0.49% to 2.16% (w/w). The volume of distillate was found to correlate nicely with the average absorber tube temperature over the duration of the experiment and the maximum hydrodistillation efficiency was computed to be 8.37%. The yield of oil also showed a good correlation with the absorber tube temperature. The tube temperature, in turn, was controlled by the beam radiation, ambient temperature and wind speed.