Usage Inventories Research Articles

Perceived Benefit and Satisfaction With a Tablet Computer and an Emergency Smartwatch by Older Adults and Their Relatives: Prospective Real-World Pilot Study.

Assistive technologies (ATs) have the potential to promote the quality of life and independent living of older adults and, further, to relieve the burden of formal and informal caregivers and relatives. Technological developments over the last decades have led to a boost of available ATs. However, evidence on the benefits and satisfaction with ATs in real-world applications remains scarce. This prospective, real-world, pilot study tested the perceived benefit and satisfaction with different ATs in the real-world environment. Community-dwelling adults aged ≥65 and their relatives tested a tablet computer with a simplified interface or a smartwatch with programmable emergency contacts for 8 weeks in their everyday life. Perceived benefits and satisfaction with ATs were assessed by all older adults and their relatives using different assessment tools before and after the intervention. Outcome measures included the Technology Usage Inventory, Quebec User Evaluation of Satisfaction with Assistive Technology 2.0, and Canadian Occupational Performance Measure. A total of 17 older adults (tablet computer: n=8, 47% and smartwatch: n=9, 53%) and 16 relatives (tablet computer: n=7, 44% and smartwatch: n=9, 56%) were included in the study. The number of participants that were frail (according to the Clinical Frailty Scale) and received care was higher in the smartwatch group than in the tablet computer group. Older adults of the smartwatch group reported higher technology acceptance (Technology Usage Inventory) and satisfaction (Quebec User Evaluation of Satisfaction with Assistive Technology 2.0) scores than those of the tablet computer group, although the differences were not significant (all P>.05). In the tablet computer group, relatives had significantly higher ratings on the item intention to use than older adults (t12.3=3.3, P=.006). Identified everyday issues with the Canadian Occupational Performance Measure included contact/communication and entertainment/information for the tablet computer, safety and getting help in emergency situations for the smartwatch, and the usability of the AT for both devices. While the performance (t8=3.5, P=.008) and satisfaction (t8=3.2, P=.01) in these domains significantly improved in the smartwatch group, changes in the tablet computer group were inconsistent (all P>.05). This study highlights the remaining obstacles for the widespread and effective application of ATs in the everyday life of older adults and their relatives. While the results do not provide evidence for a positive effect regarding communication deficits, perceived benefits could be shown for the area of safety. Future research and technical developments need to consider not only the preferences, problems, and goals of older adults but also their relatives and caregivers to improve the acceptability and effectiveness of ATs.

Identifying Factors of User Acceptance of a Drone-Based Medication Delivery: User-Centered Design Approach.

The use of drones in the health care sector is increasingly being discussed against the background of the aging population and the growing shortage of skilled workers. In particular, the use of drones to provide medication in rural areas could bring advantages for the care of people with and without a need for care. However, there are hardly any data available that focus on the interaction between humans and drones. This study aims to disclose and analyze factors associated with user acceptance of drone-based medication delivery to derive practice-relevant guidance points for participatory technology development (for apps and drones). A controlled mixed methods study was conducted that supports the technical development process of an app design for drone-assisted drug delivery based on a participatory research design. For the quantitative analysis, established and standardized survey instruments to capture technology acceptance, such as the System Usability Scale; Technology Usage Inventory (TUI); and the Motivation, Engagement, and Thriving in User Experience model, were used. To avoid possible biasing effects from a continuous user development (eg, response shifts and learning effects), an ad hoc group was formed at each of the 3 iterative development steps and was subsequently compared with the consisting core group, which went through all 3 iterations. The study found a positive correlation between the usability of a pharmacy drone app and participants' willingness to use it (r=0.833). Participants' perception of usefulness positively influenced their willingness to use the app (r=0.487; TUI). Skepticism had a negative impact on perceived usability and willingness to use it (r=-0.542; System Usability Scale and r=-0.446; TUI). The study found that usefulness, skepticism, and curiosity explained most of the intention to use the app (F3,17=21.12; P<.001; R2=0.788; adjusted R2=0.751). The core group showed higher ratings on the intention to use the pharmacy drone app than the ad hoc groups. Results of the 2-tailed t tests showed a higher rating on usability for the third iteration of the core group compared with the first iteration. With the help of the participatory design, important aspects of acceptance could be revealed by the people involved in relation to drone-assisted drug delivery. For example, the length of time spent using the technology is an important factor for the intention to use the app. Technology-specific factors such as user-friendliness or curiosity are directly related to the use acceptance of the drone app. Results of this study showed that the more participants perceived their own competence in handling the app, the more they were willing to use the technology and the more they rated the app as usable.

Ultrasound-assisted continence care support in an inpatient care setting - protocol for a pilot implementation study.

This non-randomized exploratory intervention and feasibility study examines how digital assistive technology (DAT), comprising a Dfree ultrasound sensor, affects nursing care for continence support and evaluates nurses' willingness to incorporate DAT into the planning and practical implementation of care processes. The relief provided by DFree in the clinical care setting and the extent it supports nursing care for activities of daily living (ADL) pertaining to "micturition" are unclear. DAT DFree is expected to reduce nurses' workload in clinical continence-care settings and was designed as a human-technology interaction that ensures a high level of usability for the subjects (i.e. the nurses) and increases user acceptance by at least one level (e.g., from average to slightly above average) during the study. Approximately 45 nurses from neurology, neurosurgery, and geriatric medicine clinics and polyclinics at the University Medicine Halle will be included in the 90-day (3-month) intervention onsite in the respective wards. After the wards are equipped with digital technologies, the participating nurses will be trained to use DFree and will be able to select DFree as a possible patient-care resource if the anamnesis includes bladder dysfunction among only patients who are willing to participate. The willingness of nurse participants to use DFree in planning their care process will be assessed using the Technology Usage Inventory (TUI) at three measurement points. The primary target values include the results of the multidimensional TUI assessment that will be processed using descriptive statistics. Ten participating nurses will be invited to conduct extensive guided interviews that are intended to provide information about the usefulness, feasibility in the specific field of continence care, and possible improvements of the device. It is expected that the intention to use will be confirmed by nurses and the number of nursing problems, such as bladder dysfunction-induced bedwetting, will be reduced with a high rating of DAT usability. First, this study aims to produce multilevel innovative impacts, including practical, scientific, and societal effects. The results will provide practical solutions for workload reduction in the field of nursing support for continence care, where digital assistive technologies are becoming increasingly important. The DFree ultrasonic sensor is a new technical tool for the treatment of bladder dysfunction. Generating feedback to improve technical application can increase the user-friendliness and usefulness of the device. This study was approved by the Ethics Committee of the Faculty of Medicine, Martin-Luther-University Halle-Wittenberg (approval no. 2023-031, dated May 9, 2023). The study was registered in the German Register of Clinical Studies (registration no. DRKS00031483), and the protocol has not been published previously.

Evaluation and intention to use the interactive robotic kitchen system AuRorA in older adults.

BackgroundThe number of older adults in need of care and living at home is increasing in Europe. At the same time, the number of professional caregivers is decreasing. This development reinforces the need for assistive technology to support care recipients in their own homes and promote their independence. One of the main challenges of independent living is the preparation of food. Interactive robots could assist older adults with difficulties performing physically demanding tasks. Within the project AuRorA (full German project title: Wiederverwendbare, interaktive Verhalten für proaktive Roboter im Smart Home), an interactive voice-controlled robot arm was developed as an assistance system in the kitchen.ObjectiveThe aim of the study was to assess how older adults evaluate the AuRorA system and to collect data on actual willingness to use the technology. Older adults were asked to evaluate the system in terms of usefulness, usability, accessibility and intention to use.Material and methodsDue to the ongoing coronavirus disease 2019 (COVID-19) pandemic, the older adults evaluated the system via an online survey. The validated questionnaire Technology Usage Inventory (short: TUI) was used in conjunction with self-developed questionnaires to collect data on study population characteristics.ResultsA total of 106 participants were included in the analysis. The acceptance, usability and usefulness of the system were rated as medium, while the intention to use was rated as low. A significant strong correlation was found between the TUI subscales intention to use and usefulness.ConclusionIt can be assumed that the actual need of the individual participant for such a robotic assistive system had an influence on the evaluation of the system. The perceived usefulness may have been a crucial influence on the intention to use and the overall assessment of the system.Supplementary InformationThe online version of this article (10.1007/s00391-022-02105-8) contains supplementary material, which is available to authorized users.

Examining Teachers’ Intention to integrate Robotics-based Storytelling Activities in Primary Schools

&#x0D; Though expanding computational thinking to primary school students has become more prevalent, there is a lack of appropriate didactics. Educational robotics offers a possible approach. However, innovations can only find their way into the classroom if teachers find them feasible and meaningful. Thus, appropriate training and further education of teachers are becoming a necessity. This paper reports on investigating professional development for teachers in programming robots by integrating the method of storytelling in their teaching. It draws on the Technology Usage Inventory (TUI) model to explore how an interdisciplinary intervention with programmable robots, combined with the storytelling method “Tell, Draw &amp; Code” can influence the intention to use them in the classroom. Comparing the pre-and post-test and the qualitative data analysis shows a significant increase in positive attitudes towards the use of robots. The learning scenarios produced by the participants show how successful implementation can succeed. These findings highlight the need for teachers to explore, reflect, and experience the potential of new technologies as part of their teacher development to implement innovations sustainably. The quasi-experimental study shows that this problem-based and interdisciplinary didactic setting is particularly well received by teachers because it promotes computational thinking, narrative, and reading skills in primary school students in equal measure, and it can be easily taught and transferred.&#x0D;

Developing a digital assistive tool for dementia patients and their caregivers: A qualitative study on needs, potential functions, practical requirements, user acceptance, and ethical considerations.

Digital smartphone assistants for the care and support of people with dementia (PwD) have great potential due to the wide availability of smartphones and a growing number of users aged above 65. Research has mainly focused on the development of applications for only one user group (patients, caregivers, or relatives respectively), and with only one or a few functions included (Yousaf et al., 2020). A more integrative, multi-user, and multifunctional application would be beneficial because it could be adapted to the users' needs more flexibly. This qualitative interview study was the first step in a co-creative process with a user-centered approach aimed at developing a multifunctional digital assistant. Qualitative content analysis (Mayring, 2010) combining deductive and inductive techniques was applied to identify burdens, needs, functions, ethical considerations, and acceptance aspects. 14 semi-structured interviews were conducted with three participant groups (relatives of PwD; caregivers and nursing staff; psychologists). Interviews were conducted via video conferences due to Covid-19 restrictions. After the completion of all interviews, participants received several questionnaires on acceptance aspects (Technology Usage Inventory [TUI], acceptance rating of specific functions), and technological affinity (TA-EG questionnaire) via letter. Interviews were transcribed verbatim with the software MAXQDA. Coding was done by two independent researchers. A coding frame was generated using the interview guide as a theoretical basis and the collected data for building inductive categories. The coding frame was pilot-tested before the final analysis and intercoder reliability was sufficient (k=.81). Preliminary results showed that dealing with symptoms of dementia in everyday life was burdening. Emotional needs in patients and needs for additional care resources in relatives and caregivers were the most important unanswered needs. 53 functions were suggested in the areas: digital care, support, training, monitoring, navigation, leisure activities, and social contacts. Participants had ethical requirements (i.e. data protection, privacy, and autonomy) that if met, would enhance acceptance. Results on questionnaires showed positive attitudes towards, curiosity about, and no insecurity with regards to technology. The overall acceptability of suggested functions was high. Participants showed a large interest in the digital assistant. The importance of data protection was underlined.

Does Being Ill Improve Acceptance of Medical Technology?-A Patient Survey with the Technology Usage Inventory.

Acceptance of new medical technology may be influenced by social conditions and an individual’s background and particular situation. We studied this acceptance by hypothesizing that current and former COVID-19 patients would be more likely to accept an electrocardiogram (ECG) “patch” (attached to the chest) that allows continuous monitoring of the heart than individuals who did not have the disease and thus the respective experience. Currently infected COVID-19 patients, individuals who had recovered from COVID-19, and a control group were recruited online through Facebook (and Instagram) and through general practitioners (GPs). Demographic information and questions tailored to the problem were collected via an online questionnaire. An online survey was chosen in part because of the pandemic conditions, and Facebook was chosen because of the widespread discussions of health topics on that platform. The results confirmed the central hypothesis that people who had experienced a disease are more willing to accept new medical technologies and showed that curiosity about new technologies and willingness to use them were significantly higher in the two groups currently or previously affected by COVID-19, whereas fears of being “monitored” (in the sense of surveillance) were significantly higher among people who had not experienced the disease and threat. Experiencing a serious disease (“patient experience”) promotes acceptance of new medical technologies.

Agrochemical Usage Inventory and Measured Residues in Streams Within an Off-Season Durian Production Region of Thailand

Rising demand for off-season durian production in Thailand has led to increased agrichemical use and potential environmental and health concerns. In this study, we surveyed 117 farmers and collected water samples from 11 villages in Krungching Sub-district. Overall, 108 agrochemicals were listed as being used in off-season durian production, but we focused on residual concentrations of the persistent herbicides glyphosate and paraquat in surface water. We applied a pollution release and transfer registry for 2016 to determine an application rate of 288,149 kg/year for these agrichemicals. These were primarily detected during the dry season, and not the wet season. This reporting system can be used to develop seasonal environmental surveillance and monitoring tools for more sustainable use of agrochemical substances in off-season durian production in environmentally sensitive areas such as the Krungching River watershed, especially during the first stage of cultivation (dry season), in order to ensure the use of agricultural chemicals under appropriate circumstances. Further studies are needed to better understand the full diversity of persistent agrochemical substance usage and disposal, in order to reorient agricultural activities to focus on local needs and capabilities as part of efforts to implement more sustainable agriculture in Thailand.

Using a Back Exoskeleton During Industrial and Functional Tasks-Effects on Muscle Activity, Posture, Performance, Usability, and Wearer Discomfort in a Laboratory Trial.

To investigate the effect of using a passive back-support exoskeleton (Laevo V2.56) on muscle activity, posture, heart rate, performance, usability, and wearer comfort during a course of three industrial tasks (COU; exoskeleton worn, turned-on), stair climbing test (SCT; exoskeleton worn, turned-off), timed-up-and-go test (TUG; exoskeleton worn, turned-off) compared to no exoskeleton. Back-support exoskeletons have the potential to reduce work-related physical demands. Thirty-six men participated. Activity of erector spinae (ES), biceps femoris (BF), rectus abdominis (RA), vastus lateralis (VL), gastrocnemius medialis (GM), trapezius descendens (TD) was recorded by electromyography; posture by trunk, hip, knee flexion angles; heart rate by electrocardiography; performance by time-to-task accomplishment (s) and perceived task difficulty (100-mm visual analogue scale; VAS); usability by the System Usability Scale (SUS) and all items belonging to domains skepticism and user-friendliness of the Technology Usage Inventory; wearer comfort by the 100-mm VAS. During parts of COU, using the exoskeleton decreased ES and BF activity and trunk flexion, and increased RA, GM, and TD activity, knee and hip flexion. Wearing the exoskeleton increased time-to-task accomplishment of SCT, TUG, and COU and perceived difficulty of SCT and TUG. Average SUS was 75.4, skepticism 11.5/28.0, user-friendliness 18.0/21.0, wearer comfort 31.1 mm. Using the exoskeleton modified muscle activity and posture depending on the task applied, slightly impaired performance, and was evaluated mildly uncomfortable. These outcomes require investigating the effects of this passive back-supporting exoskeleton in longitudinal studies with longer operating times, providing better insights for guiding their application in real work settings.

How "dirty" is the Dark Triad? Dark character profiles, swearing, and sociosexuality.

Malevolent character traits (i.e., the Dark Triad: Machiavellianism, narcissism, and psychopathy) are associated to emotional frigidity, antagonism, immoral strategic thinking, betrayal, exploitation, and sexual promiscuity. Despite the fact that character is a complex adaptive system, almost every study has solely investigated the linear association between malevolent character and attitudes towards both swearing and sociosexual orientation (i.e., behavior, attitude, and desire regarding promiscuous sexual behavior). In contrast, the aim in this set of studies was to evaluate these associations in relation to specific profiles of malevolent character (i.e., the Dark Cube). In two studies participants responded to the Dark Triad Dirty Dozen, the Taboo Words’ Offensiveness and Usage Inventories (i.e., attitudes towards 30 swear words’ level of offensiveness and usage) (Study 1: N1 = 1,000) and the Sociosexual Orientation Inventory Revised (Study 2: N2 = 309). Participants were clustered according to all eight possible combinations based on their dark trait scores (M/m = high/low Machiavellianism; N/n = high/low narcissism; P/p = high/low psychopathy). The results of this nonlinear approach suggested that the frequent usage, not level of offensiveness, of swear words was associated to Machiavellianism and narcissism. In other words, individuals with high levels in these traits might swear and are verbally offensive often, because they do not see swearing as offensive (cf. with the attitude-behavior-cognition-hypothesis of taboo words; Rosenberg, Sikström & Garcia, 2017). Moreover, promiscuous sociosexual attitude and desire were related to each dark trait only when the other two were low. Additionally, promiscuous sociosexual behavior was not associated to these malevolent character traits. That is, individuals high in the dark traits are willing to and have the desire to engage in sexual relations without closeness, commitment, and other indicators of emotional bonding. However, they do not report high levels of previous sexual experience, relationships, and infidelity. Hence, they approve and desire for it, but they are not actually doing it. The use of person-centered and non-linear methods, such as the Dark Character Cube, seem helpful in the advancement of a coherent theory of a biopsychosocial model of dark character.

Investigation of teacher candidates’ 21st century learner skills via PAMS

In this study we aim to examine the latent profiles of teacher candidates’ 21st century learner skills. In other words, we intend to discover the profiles of participant groups who hang together in terms of 21st century learner skill scores. The data are gathered from students who enrolled in either undergraduate programs in the school of education or pedagogical formation certificate programs. For data collection purposes, we used the 21 st century learner skills usage inventory. In order to achieve our goal, profile analysis via multidimensional scaling approach is employed. Data analysis resulted in two-dimensional solution indicating two major profile patterns. Students whose observed patterns are similar to the first major profile tend to have lower ability in cognitive processing and coding of information and realization of the products. They tend to have higher abilities in self-management, self-control, designing more flexible learning environment, and adaptation of new technology. These students are expected to be better at collaboration-based activities. Students whose observed patterns are similar to the second major profile are expected to be good at self-management, self-control and they are expected to have higher self- and collaborative-learning abilities.

Trends of production, consumption and environmental emissions of Decabromodiphenyl ether in mainland China

Decabromodiphenyl ether (DecaBDE) is a brominated flame retardant belonging to the group of polybrominated diphenyl ethers. DecaBDE has been widely used for various applications, such as plastics, textiles, and building and construction materials. Limited information on DecaBDE production and usage inventory has been elaborated, however. Therefore, this work aimed to produce a preliminary emissions inventory of DecaBDE in mainland China by estimating production and consumption amounts of DecaBDE, and characterizing its emission factors during production and usage, based on industrial investigation and theoretical prediction. It was indicated that the total production of DecaBDE reached 464.68 thousand metric tons (kt), of which 62.72 kt were exported, since the beginning of its production. Shandong and Jiangsu provinces dominate the production, with proportions of 77.95% and 18.45%, respectively. The production stage releases most of the DecaBDE to the atmosphere, with an emissions factor of 23 ± 1.9 kg/t, followed by 20 ± 0.9 kg/t DecaBDE to waste water and 16 ± 1.0 kg/t DecaBDE as solid residue. DecaBDE emissions in the consumption stage—namely the plastic production process—are 0.17 ± 0.06–0.23 ± 0.08 kg DecaBDE to the atmosphere and 1.72 ± 0.58–2.29 ± 0.77 kg DecaBDE to solid residue, for each metric ton of plastic produced. The total annual DecaBDE emissions to waste water are 93.98–1140.9 mg—negligible. The results showed that the sources of DecaBDE environmental pollution are its manufacturing and flame-retardant plastic modification plants, which are easily overlooked by both the government and the public. Yet DecaBDE emissions elimination and the environmentally sound management of the DecaBDE waste generated from these two processes are crucial for environmental protection.

Gridded inventories of historical usage for selected organochlorine pesticides in Gansu Province, China

HCHs and DDTs were banned in 1983 in China; however, they are still remaining in various environmental media. Since endosulfan was introduced in China in 1994, it is widely used in agriculture. In this study, temporal and spatial uses of endosulfan, HCHs, and DDTs in Gansu province of China have been presented. It is estimated that the total usage is 701 tons for endosulfan between 1994 and 2007, 1,712 tons for HCHs between 1952 and 1983, and 462 tons for DDTs between 1951 and 1983, respectively. Endosulfan usage increased dramatically in 1998 due to its application on other crops except on cotton. The HCH and DDT usage displayed a rapid increase after 1972, reaching the peak in 1976 and in 1975, respectively; since then, they declined until being banned in 1983. The gridded usage inventories of these three kinds of organochlorine pesticides in Gansu province, with a 1/4° longitude by 1/6° latitude resolution, have been created by using different crops for endosulfan and the area of dry farmland for HCHs and DDTs as surrogate data. The most intensive use was in northwestern regions for endosulfan and southeastern regions for HCHs and DDTs in Gansu province.

Gridded usage inventories of chlordane in China

Chlordane (1,2,4,5,6,7,8,8-octachloro-3a,4,7, 7a-tetra-hydro-4,7-methanoindane) is one of organochlorine pesticides (OCPs) which has been listed as one of the persistent organic pollutants (POPs) to be reduced and finally eliminated in the Stockholm Convention on Persistent Organic Pollutants, because of its great persistence, toxicity, bio-accumulation and long-range transport potential. It is critical to create a national chlordane usage inventories for China to compile chlordane emission inventories, which is helpful for carrying out risk assessments and other researches related to chlordane in China. The annual data of chlordane usage was calculated and modified in accordance with the reported annual production of chlordane which was caculated on the basis of the termite distribution, the data of chlordane usage rate and the annual new construction area (NCA).With the help of Geographic Information System, the usage data of this NCA were allocated to a grid system then, with a 1/4° longitude by 1/6° latitude resolution and a size for each grid cell of approximately 25 km by 25 km. Between 1988 and 2008, the total usage of chlordane in China was 2745 t, accounting for approximately 80% of the production in the same period. Zhejiang Province was the largest consumer of chlordane in China, whose usage adds up to 980 t, greatly exceeding other provinces/regions, followed by Jiangsu Province (534 t) and Sichuan Province (428 t). The region with the least usage of chlordane was Beijing. Provinces of Guizhou, Henan and Hebei did not use any chlordane, even though termites had occurred in these provinces. Gridded usage inventories showed that the intensive use of chlordane was concentrated in the southeast part of China, Yangtze River Delta and Pearl River Delta in particular. The satisfaction of the inventories was supported by the consistence between the estimated data of annual usage and the reported annual production of chlordane, and by the consistence between distribution pattern of chlordane’s usage and ambient air concentration.

Endosulfan in the Chinese environment: monitoring and modeling

This paper reviews the usage and emissions of endosulfan, the newest member of the persistent organic pollutants (POPs), in China, and its fate and behavior in Chinese environment. Endosulfan usage in China has been estimated to be approximately 25700 t between 1994 and 2004. Concentrations of endosulfan in different environmental compartments in China, such as air, soil, water, and biota, but focusing at air and surface soil, have been summarized. Concentrations of total endosulfan in surface soil across China were ranged from below detection limit (BDL) to 19000 pg·g−1 dry weight (dw), with geometric mean of 120 pg·g−1dw. The results indicated that endosulfan sulfate had highest concentration in Chinese soil, followed by β- and α-endosulfan. Air concentrations of endosulfan in China were ranged 0–340 pg·m−3 for α-endosulfan and 0–121 pg·m−3 for β-endosulfan, with high concentrations occurred in the cotton production areas. Gridded usage inventories of endosulfan on a fine gridded system with a 1/4° longitude by 1/6° latitude resolution were compiled, from which, emission to air and residues in soil of endosulfan were calculated in each grid by using a modified simplified gridded pesticide emission and residue model (SGPERM), an integrated modeling system combining mathematical model, database management system, and geographic information system. Total emissions were around 10800 t from 1994 to 2004. Based on the emission and residue inventories, concentrations of α- and β-endosulfan in Chinese air and agricultural surface soil were also calculated for each grid cell, which are in general consistent with the published monitoring data.

Endosulfan in China 2—emissions and residues

Endosulfan is one of the organochlorine pesticides (OCPs) and also a candidate to be included in a group of new persistent organic pollutants (UNEP 2007). The first national endosulfan usage inventories in China with 1/4 degrees longitude by 1/6 degrees latitude resolution has been reported in an accompanying paper. In the second part of the paper, we compiled the gridded historical emissions and soil residues of endosulfan in China from the usage inventories. Based on the residue/emission data, gridded concentrations of endosulfan in Chinese soil and air have been calculated. These inventories will provide valuable data for the further study of endosulfan. Emission and residue of endosulfan were calculated from endosulfan usage by using a simplified gridded pesticide emission and residue model-SGPERM, which is an integrated modeling system combining mathematical model, database management system, and geographic information system. By using the emission and residue inventories, annual air and soil concentrations of endosulfan in each cell were determined. Historical gridded emission and residue inventories of alpha- and beta-endosulfan in agricultural soil in China with 1/4 degrees longitude by 1/6 degrees latitude resolution have been created. Total emissions were around 10,800 t, with alpha-endosulfan at 7,400 t and beta-endosulfan at 3,400 t from 1994 to 2004. The highest residues were 140 t for alpha-endosulfan and 390 t for beta-endosulfan, and the lowest residues were 0.7 t for alpha-endosulfan and 170 t for beta-endosulfan in 2004 in Chinese agricultural soil where endosulfan was applied. Based on the emission and residue inventories, concentrations of alpha- and beta-endosulfan in Chinese air and agricultural surface soil were also calculated for each grid cell. We have estimated annual averaged air concentrations and the annual minimum and maximum soil concentrations across China. The real concentrations will be different from season to season. Although our model does not consider the transport of the insecticide in the atmosphere, which could be very important in some areas during some special time, the estimated concentrations of endosulfan in Chinese air and soil derived from the endosulfan emission and residue inventories are in general consistent with the published monitoring data. To our knowledge, this work is the first inventory of this kind for endosulfan published on a national scale. Concentrations of the chemical in Chinese air and agricultural surface soil were calculated for each grid cell. Results show that the estimated concentrations of endosulfan in Chinese air and soil agree reasonably well with the monitoring data in general. The gridded endosulfan emission/residue inventories and also the air and soil concentration inventories created in this study will be updated upon availability of new information, including usage and monitoring data. The establishment of these inventories for the OCP is important for both scientific communities and policy makers.

Atmospheric Concentrations of Captan and Folpet in the Lower Fraser Valley Agricultural Region of Canada

Two N-trihalomethylthio fungicides were detected in the atmosphere in the Lower Fraser Valley agricultural region of Canada. Captan was detected in both the particle and gas phase with a dominant particle phase fraction observed in both 2005 and 2006 (only total captan atmospheric concentrations were available for 2004). This provides the first evidence of particle transport as a significant atmospheric transport pathway for captan in an agricultural region in Canada. Weekly captan air concentrations reached maximum levels of 13.2 ng m-3 in June 2006, while for folpet total atmospheric levels were lower with maximum reaching 1.7 ng m-3 in August 2004 and generally &lt;1 ng m3 in 2005 and 2006. Folpet is detected in the atmosphere although not previously reported in usage inventories. In the three years examined (2004-2006) captan concentrations observed a seasonal maximum in atmospheric concentrations during spring to early summer coinciding with expected peak usage period on crops in the Lower Fraser Valley agricultural region located in British Columbia, Canada. No usage data is available in Canada beyond 2003 but these seasonal trends show that captan remains a dominant pesticide used in this agricultural region with no decline in atmospheric concentrations during 2004-2006.

Endosulfan in China 1—gridded usage inventories

Endosulfan, an organochlorine pesticide (OCP), is genotoxic in mammalian cells and generally considered to be toxic and classified by the World Health Organization and the US Environmental Protection Agency as priority pollutants and a nominator for inclusion in a future iteration of the persistent organic pollutants treaty. Endosulfan is a currently used pesticide and still being used worldwide. The general trend of total global endosulfan use has increased continuously since the first year when this pesticide was applied. It is critical to create national endosulfan usage/emission inventories for China to carry out source-receptor relation analysis, risk assessment, and other research related to endosulfan in this country. Chinese inventories have been published for some OCPs, such as technical HCH and lindane, DDT, and chlordane; for endosulfan, however, there has not been any usage inventory available on any scales (national or provincial), although endosulfan has been widely used since 1994 in this country. This is the first part of the work. The goal of this paper is to quantify the historical production and usage of endosulfan in China and to compile gridded historical usage inventories of endosulfan for this country. Based on these usage inventories, emission and residue inventories will be created, which is the goal of the second part of the work. Due to the lack of national production and usage information of endosulfan in China, a method to estimate the use of endosulfan was developed. First, information of crops on which endosulfan is applied and average endosulfan use and annual application frequencies of endosulfan on these crops were collected. Secondly, usage of endosulfan on each crop was estimated using the national cropland area for each province from Chinese government reports. Finally, with the help of GIS (geographic information system), the usage data of this insecticide was allocated to a grid system, with a 1/4 degrees longitude by 1/6 degrees latitude resolution, with a size for each grid cell of approximately 25 km by 25 km. The use of endosulfan in agriculture in China started on cotton in 1994, and on wheat, tea, tobacco, apples, and other fruits in 1998. Endosulfan usage on cotton, wheat, tea, tobacco, and apples in China has been estimated to be approximately 25,700 t between 1994 and 2004. The province with the highest usage of endosulfan is Henan Province, with a total usage reaching 4,000 t, followed by the uses in Xinjiang Autonomous Region (3,200 t), Shandong Province (3,000 t), Hebei Province (2,100 t), and Anhui Province (1,900 t). Gridded usage inventories of endosulfan at a 1/4 degrees longitude by 1/6 degrees latitude resolution have been created, which indicate that the intensive endosulfan use was in the south of Hebei Province, west of Shandong Province, east of Henan Province, north of Anhui Province, east of Jiangsu Province, and some areas in Yunnan Province and Xinjiang Autonomous Region. General agreement has been found between the usage data from our estimation and the small amount of usage data published in China. This is the first national gridded endosulfan usage inventory produced for China. The annual applications of endosulfan from 1994 to 2004 in China were estimated based on the total areas of major crops, on which endosulfan was applied, and spatial distribution of the application was generated at provincial and prefecture levels. With the help of GIS, endosulfan usage based on prefecture was transferred to a 1/4 degrees longitude by 1/6 degrees latitude gridding system. The satisfaction of the inventories was supported by the consistence between the estimation of the annual usage and the reported annual production of endosulfan. This gridded endosulfan usage inventory created in this study will be improved upon availability of new information of endosulfan. The usage inventories can be used to create gridded emission and residue inventories for this insecticide. It is believed that this work will pave the way for further endosulfan studies in China and beyond.

Dichlorodiphenyltrichloroethane usage in the former Soviet Union

DDT (Dichlorodiphenyltrichloroethane), an organochlorine pesticide (OCP), is one of 12 persistent organic pollutants (POPs) that is being proposed for elimination or control under the Stockholm Convention on POPs. This paper presents historical DDT usage in the Former Soviet Union (FSU) from different sources. Although the data from different sources do not agree with each other, the data clearly show that the usage of DDT in the FSU were intensive in the 1950s and 1960s, and the use of DDT continued until early 1990s although DDT was officially banned in 1969/1970 by the FSU government. Two estimations (high and low) are made for the historical annual DDT usage in the FSU. The total DDT usage in the FSU from 1946 and 1990 was 520 kt for the high estimation and 250 kt for the low estimation. Gridded DDT usage inventories in the FSU on a 1° longitude by 1° latitude grid system are created by using the gridded distribution of cropland density for the FSU, and show that DDT usage varied considerably across the FSU. Most DDT was applied in southern regions of the FSU where agricultural activity was greatest, such as in Moldova and Ukraine followed by the Northern Caucasus region of Russia and the Central Asian republics.

Hexachlorocyclohexane Use in the Former Soviet Union

Because of the large size of the former Soviet Union (FSU) and the heavy use of organochlorine pesticides (OCPs) in the FSU, usage information regarding OCPs in the FSU is important in compiling global emission inventories and thus in studying the transport of OCPs among different environmental compartments worldwide. The availability of such information is limited. By analyzing the available 1,2,3,4,5,6-hexachlorocyclohexane (HCH) data in the FSU, this article presents estimates of HCH usage in this region from 1950 to 1990, when HCH was officially banned for agricultural use by the FSU government. The creation of HCH usage inventories for the FSU has paved the way to produce HCH emission inventories for this region. Total HCH usages for agricultural purposes in the FSU from 1950 to 1990 were estimated to be 1,960 kt for technical HCH and 40 kt for lindane. The total usage for the isomers was 270 kt for gamma-HCH, 1,270 kt for alpha-HCH, and 170 kt for beta-HCH. Use of HCH reached a peak in 1965: 130 kt for technical HCH, 2.7 kt for lindane, 18 kt for gamma-HCH, 86 kt for alpha-HCH, and 11 kt for beta-HCH. Gridded usage data sets in the FSU of technical HCH and lindane-and the alpha-HCH, beta-HCH and gamma-HCH isomers-on a 1degree x 1degree longitude and latitude grid system for 1980 are freely available to all users at http://www.msc.ec.gc.ca/data/gloperd/.