The land surface temperature (LST) changes influence on many factors such as land use and land cover (LULC), vegetation and water resources etc. Now a day’s urban population growth, industrial development and human activity are increased due to human migration and urban expansion. The surface temperature is very harmful to vegetation, groundwater level, and ecosystem health. Urban pollution growth and air pollution factor is also playing important role for increase and decrease the LST with climate change impact. Demand of drinking water are increases particular in the urban city due to the population growth and urban expansion, which all of this direct effect on surface and groundwater sources and resources. Hence we have been chosen the latest technologies such as remote sensing (RS), Geographic information System (GIS) and Google Earth Engine (GEE) are very effective for mapping, monitoring and assessment of spatial maps of LST, LULC, and NDVI (Normalised differential vegetation index) estimation. In this study, main focus on the LULC of 2011 and 2021 were classified using random forest (RF) algorithm, ML and remote sensing datasets. LULC were divided into four categories i. e. agricultural land, built up land, waterbody and waste land. For better understanding about the growth of LST, this study examines the association between LST and NDVI change, what vegetation condition impact on the LST. The main and important results have been found the built-up land and LST positive correlation due to increases both the factors in the urban area. LST increases gradually and its bad effect on the green land, water level and expansion of barren land. The range of LST is 43.60 °C to 45.30 °C. Less vegetation cover showing highest LST and vice versa. All of the LST, NDVI, and LULC direct effect on the groundwater availability in the area. This paper important result found the built-up land and LST both are increased in 2021, NDVI and LST having negative correlation. The results of study can very much useful for understanding the LST, NDVI and LULC, these factors what impact on groundwater availability in the study area.