Urban Groundwater Quality Research Articles

Integrated Geospatial and Geostatistical Multi-Criteria Evaluation of Urban Groundwater Quality Using Water Quality Indices

Groundwater contamination poses a severe public health risk in Lahore, Pakistan’s second-largest city, where over-exploited aquifers are the primary municipal and domestic water supply source. This study presents the first comprehensive district-wide assessment of groundwater quality across Lahore using an innovative integrated approach combining geographic information systems (GIS), multi-criteria decision analysis (MCDA), and water quality indexing techniques. The core objectives were to map the spatial distributions of critical pollutants like arsenic, model their impacts on overall potability, and evaluate targeted remediation scenarios. The analytic hierarchy process (AHP) methodology was applied to derive weights for the relative importance of diverse water quality parameters based on expert judgments. Arsenic received the highest priority weight (0.28), followed by total dissolved solids (0.22) and hardness (0.15), reflecting their significance as health hazards. Weighted overlay analysis in GIS delineated localized quality hotspots, unveiling severely degraded areas with very poor index values (>150) in urban industrial zones like Lahore Cantt, Model Town, and parts of Lahore City. This corroborates reports of unregulated industrial effluent discharges contributing to aquifer pollution. Prospective improvement scenarios projected that reducing heavy metals like arsenic by 30% could enhance quality indices by up to 20.71% in critically degraded localities like Shalimar. Simulating advanced multi-barrier water treatment processes showcased an over 95% potential reduction in arsenic levels, indicating the requirement for deploying advanced oxidation and filtration infrastructure aligned with local contaminant profiles. The integrated decision support tool enables the visualization of complex contamination patterns, evaluation of remediation options, and prioritizing risk-mitigation investments based on the spatial distribution of hazard exposures. This framework equips urban planners and utilities with critical insights for developing targeted groundwater quality restoration policies through strategic interventions encompassing treatment facilities, drainage infrastructure improvements, and pollutant discharge regulations. Its replicability across other regions allows for tackling widespread groundwater contamination challenges through robust data synthesis and quantitative scenario modeling capabilities.

Exposure to radon gas in groundwater in southwest Angola (Lubango-Huíla): Implications of geology and climate change

In southern African countries most of the population uses groundwater collected in dug wells for domestic consumption instead of water from public distribution systems. To investigate the impact of natural and human factors on urban groundwater quality, 276 samples were collected in the Lubango region (Angola) in water distribution systems and dug wells ranging from a few meters to almost one hundred meters in depth. Radon concentrations (RC) were determined by liquid scintillation counting according to ISO 13164–4:2015.Geology is the main source of the variability of RC, with median values higher than 100 Bq/L in granitoid units and lower values in mafic and sedimentary units (ranging from 5 to 38 Bq/L). On average, RC was higher in dug wells compared to public water distribution systems. The annual effective dose due to ingestion of radon in water is, on average, ten times lower in the later compared to dug wells. Therefore, from a public exposure perspective, water distribution systems are preferred as means for water distribution. A severe multi-year meteorological drought over the past decade affecting 76–94 % of the population in southern Angola has been linked with climate change. Consequently, a regional lowering of the water table was observed, as well as a reduction in the productivity of shallower wells, leading to a search for water at greater depths. This work demonstrates an increase in median RC from 66 Bq/L in wells shallower than 30 m to values over 100 Bq/L with increasing depth of water extraction and for the same geological unit. The highest RC observed were also observed at the deepest wells. The dose ingested is proportional to RC, being also higher at deeper water extraction depths. The increase in public radiation exposure from radon ingestion due to water extraction at greater depths is attributed to the underlying issue of climate change. Monitoring water quality in terms of radionuclide concentration is advised to ensure the exposure to ionizing radiation remains at acceptable levels in the future.

Dye tracing of the Lusaka karstified aquifer system: implications towards urban groundwater quality protection

Management of groundwater resources requires a large amount of data, coupled with an understanding of the aquifer system behavior. In developing countries, the scarcity in groundwater data has led to aquifers being managed according to rule-of-thumb standards or even abandoned as unmanageable at times. Groundwater quality protection thus has been through prescribed separation distances often without due regard for internal and boundary characteristics that affect response rates of groundwater movement, attenuation of pollutants, and recharge. In this study, we examine the boundary characteristics of the highly vulnerable karst aquifer system in the rapidly expanding city of Lusaka using a dye tracer technique. We investigate the flow dynamics (magnitude and direction) of groundwater using dye tracer dyes (fluorescein and rhodamine) spiked in pit latrines and observed at discharge springs. The results provide irrefutable evidence that pit latrines are a source and a pathway to contamination of groundwater. Dye tracer movement in groundwater was rapid, estimated at 340 and 430m/day for fluorescein and rhodamine, respectively, through interconnected conduit density. The vadose zone (epikarst) tends to store diffuse recharge before release to the phreatic zone. These rapid groundwater movements render regulatory separation minimum distances of 30m between abstraction wells and pit latrines/septic tanks in such environments to be an ineffective means of reducing contamination. The policy focus in the protection of groundwater quality should henceforth be on robust sanitation solutions especially for low-income communities that recognize the socio-economic diversity.

Biogeochemical networks in the abandoned historical gold mines affecting mobilization and transport of arsenic in Kolar

Enormous water-logging in ancient abandoned mining shafts of Kolar Gold Fields (KGFs), has largely induced the leaching of sulfide-rich gold minerals contaminating the aquifer system with hazardous elements. Transport of these contaminant has posed threat to the health of the urban population of Kolar township. A detailed survey of borewells, covering radius of 10 km of the KGF was carried out during pre and post-monsoon seasons and various parameters were assessed. Almost 80% of the water samples exceeded the regulatory limits of potable water criteria with excess arsenic (As; 12–127 μg/L), fluoride (F; <0.005 μg/L), dissolved salts (>500 mg/L). Water Quality Index (WQI) was used to understand the overall urban groundwater quality. At the centre of sampling circle core, mineral dissolution was found to be the function of pH, induced by acidophilic sulfur oxidizing bacteria . Modelling of predicted microbial metabolic pathways in metagenomics libraries using PICRUSt, indicated complex functional networks. High expression of siderophore proteins (> 2 cm halo in the chrome azurol test) caused Fe-sequestration, secondary Fe-mineral formation and subsequent release of As. Sulfide bearing Au-rich minerals (Arsenopyrite, Scorodite, Jarosite) were bio-weathered leading to release of H3AsO3+ at low pH, resulted in groundwater composition of Ca–HCO3 type and Ca–Na–HCO3 or Ca–Mg–Cl type.

Retraction Note: Urban groundwater quality monitoring and state-owned assets management optimization based on spatial information processing

Retraction Note: Urban groundwater quality monitoring and state-owned assets management optimization based on spatial information processing

RETRACTED ARTICLE: Urban groundwater quality monitoring and state-owned assets management optimization based on spatial information processing

RETRACTED ARTICLE: Urban groundwater quality monitoring and state-owned assets management optimization based on spatial information processing

Urban groundwater quality assessment using pollution indicators and multivariate statistical tools: a case study in southeast Nigeria

ABSTRACT In recent times, globally, it has been found that several natural and anthropogenic factors are responsible for the degradation and depreciation in quality and quantity of groundwater resources. This problem seems to be more pronounced in urban areas. In this paper, the groundwater quality of Nnewi and Awka urban areas in southeastern Nigeria was assessed using integrated pollution indices and multivariate statistics. pH scores showed that Awka has more of acidic waters than Nnewi. The level of heavy metals in the waters was assessed using heavy metal evaluation index, modified heavy metal index and modified heavy metal pollution index. These indices showed that most of the samples in Awka are polluted with heavy metals (such as Cu, Cd and Pb) whereas they indicated that most samples from Nnewi have low pollution. Similarly, ecological risk assessment was performed to clearly depict the possible impacts of the potentially toxic elements on the water environment. The result revealed that 55% of the total water samples across the two localities recorded low-moderate ecological risk while 45% recorded high-very high ecological risk. The priority pollutants identified by the numerical indicators are Cu, Pb and Cd. Correlation and factor analyses suggested that the associations between the analytes are attributable to both natural and anthropogenic factors. However, human activities seem to have played a higher role. Furthermore, pollution index of groundwater, synthetic pollution index and overall index of pollution were utilised to assess the suitability of the groundwater resources for drinking purpose. Their results appeared to be consistent with other models, indicating that the urban groundwater supply in Awka is posed with higher pollution threat than in Nnewi.

Alternative Sanitation and Strategic Directives for the Well Water Security in Cotonou (Benin) and Lom&amp;#233; (Togo)

In the coastal cities of West Africa, land use change, rapid population growth, bad sanitation systems and poor environmental governance degrade the quality of groundwater. This study aimed to assess alternative, acceptable, affordable sanitation disposal and practices for groundwater quality rehabilitation in the cities of Cotonou and Lome. The study was based on the participatory transdisciplinary approach, field surveys, feedback from interactions with stakeholders, experiences of the practitioners and institutional consultations. This multi-stakeholder approach helped to appreciate ecological aspects of sanitation disposal and its implications on water quality improvement. SWOT model was used to analyze the relevance of assessed ecological system. Well water quality is deteriorated by traditional waste management disposal. Ecological sanitation systems are septic tanks on polyethylene, above-ground latrines and phytoremediation technique in the swamp areas. Collected wastes are used for composting and biogas production. Based on the optimist scenario at 2030 horizon, kind success factors of groundwater security are participation of citizens, existence of sanitation market, valorization of the waste by category, low-cost disposal adaptable to the individual, household and neighborhood’s scales. The strategic directions rely on funding and public policies for WASH, ecological sanitation disposal, cultural environment and good sanitation practices for emergence of new sanitation system to secure and sustain well water quality. But the social acceptability of ecological disposal is limited by the society’s multicultural heritage. These findings could help in decision-making concerning urban groundwater quality protection in the African coastal cities.

Assessment of urban groundwater quality using Piper trilinear and multivariate techniques: a case study in the Abuja, North-central, Nigeria

BackgroundGroundwater pollution ensuing from ion exchange, weathering, agricultural and anthropogenic activities is on the rise in Nigeria. Since groundwater is used for domestic purposes, there is need for routine investigation. Findings on hydrochemistry of the groundwater components is essential for efficient and viable management. As a result, 25 Abuja water samples were collected for microbial and chemical analyses using standard methods. The cations, anions, soluble ions, trace elements, and heavy metal were obtained and compared with WHO standards.ResultsThe Discriminant analysis results shown that the parameters such as hydrogen ion concentration (pH), temperature (T), alkalinity (Alk), dissolve silica (SiO2), and cations such as calcium (Ca2+), potassium (K+), as well as anions such as carbonates ( {{text{CO}}_{3}}^{2 - } ), fluoride (F−), nitrates (NO3−), and heavy metal (Mn) were within the WHO guideline values for drinking water in all the samples for both seasons. Na+, {{text{SO}}_{4}}^{2 - } , EC, Mg2+, TDS, Fe2+, HCO3−, F−, TH and Cl− contents exhibited the most violation of drinking water standards with percent violations of 100, 76, 64, 56, 56, 44, 40, 40, 36 and 24%, respectively. The highest level of significant correlation was found to exist between K+ and EC (r = 0.77, α = 0.05). Four hydro chemical clusters were identified from Hierarchical cluster analysis (HCA) with clearly partitioned water quality. Series and time series plot reveals TDS concentration value between 1200 and 2100 mg/l, has the highest with the mean and SD are 1433.76 and 459.38, respectively. Further analysis revealed that 16, 36 and 48% of the samples were the Ca–Cl, Na–Cl, and Mixed types, respectively.ConclusionGroundwater in the Abuja district is mainly hard to very hard, slightly acidic in nature, polluted by ion exchange, agricultural activities, anthropogenic activities, and weathering. Therefore, there is also need for routine monitoring of groundwater in Abuja.

The combined use of self-organizing map technique and fuzzy c-means clustering to evaluate urban groundwater quality in Seoul metropolitan city, South Korea

To make an overall assessment of the groundwater quality in Seoul city, we used the self-organizing map (SOM) technique in combination with fuzzy c-means (FCM) clustering. SOM visualizes complicate and multidimensional data structures on a 2D surface while the FCM algorithm creates overlapping cluster boundaries among samples that are continuously distributed over a data space. The combination of SOM and FCM clustering was expected to help characterize highly complicated urban groundwater quality. As a result, the SOM characterized 343 groundwater samples using 91 neurons, which were further classified by FCM clustering into three water groups. Group 1 addressed the least polluted groundwater (17% of the samples (n = 58), average TDS = 194.5 mg/L and NO3 = 6.9 mg/L) and occurred in the peripheral areas whose land cover is mainly occupied by forests. Increasing pH with increasing sodium and bicarbonate concentrations indicated that the hydrogeochemistry of Group 1 was largely controlled by water-rock interactions. Group 2 included the highly polluted groundwater (24% of the samples (n = 82), average TDS = 326.2 mg/L and NO3 = 42.6 mg/L), and sporadically occurred in Seoul, with no distinct spatial control. This group seemed to be affected by sewage from broken sewer pipes, which are a primary pollution source of Seoul groundwater and are ubiquitously distributed beneath the city. Group 3 water also represented the highly contaminated groundwater (30% of the samples (n = 103), average TDS = 527.1 mg/L), but contained low nitrate concentrations (average NO3 = 13.1 mg/L). Based on their spatial locations, intensive groundwater pumping from subway tunnels and other underground spaces at the city center seemed to drive the induced flow of organic contaminants, resulting in local reducing conditions sufficient for denitrification. The remaining 100 samples (29% of the samples) shared the hydrogeochemical properties of two or three groups. This study successfully characterized the spatial pattern of urban groundwater quality that is complicated by various contamination sources and hydrogeochemical processes. The combined use of SOM and FCM clustering was proven as a powerful tool to interpret nonlinear and highly heterogeneous environmental data for which it is difficult to define cluster boundaries. Taken together, our results contribute to a better management of urban groundwater in metropolitan cities under high risks of anthropogenic contamination.

Integrated evaluation of urban groundwater hydrogeochemistry in context of fractal behaviour of groundwater level fluctuations

ABSTRACTThe present study was carried out as part of a complex survey of urban groundwater quality and quantity in Szeged, southeast Hungary. The concentrations of 12 inorganic contaminants in 28 shallow groundwater monitoring wells were determined over a 2-year period (2010–2012). The evaluation of concentrations indicates remarkable contamination all over the city. Discriminant analysis (DA) was used to evaluate the spatial changes of groundwater quality. The groundwater levels were measured over a 14-year period (2000–2013). The fractal properties of water level fluctuations time series characterizing the groundwater system and Tisza River were investigated using rescaled range (R/S) analysis. The resulting Hurst exponents clearly showed the persistency and thus long memory effects of both the groundwater and the river flow. Comparison of the results of DA with the results of R/S analysis thus implies that the geological conditions and the changing groundwater quantities are not related to groundwater quality.EDITOR A. CastellarinASSOCIATE EDITOR A. Fiori

Urban groundwater quality in sub-Saharan Africa: current status and implications for water security and public health

Groundwater resources are important sources of drinking water in Africa, and they are hugely important in sustaining urban livelihoods and supporting a diverse range of commercial and agricultural activities. Groundwater has an important role in improving health in sub-Saharan Africa (SSA). An estimated 250 million people (40% of the total) live in urban centres across SSA. SSA has experienced a rapid expansion in urban populations since the 1950s, with increased population densities as well as expanding geographical coverage. Estimates suggest that the urban population in SSA will double between 2000 and 2030. The quality status of shallow urban groundwater resources is often very poor due to inadequate waste management and source protection, and poses a significant health risk to users, while deeper borehole sources often provide an important source of good quality drinking water. Given the growth in future demand from this finite resource, as well as potential changes in future climate in this region, a detailed understanding of both water quantity and quality is required to use this resource sustainably. This paper provides a comprehensive assessment of the water quality status, both microbial and chemical, of urban groundwater in SSA across a range of hydrogeological terrains and different groundwater point types. Lower storage basement terrains, which underlie a significant proportion of urban centres in SSA, are particularly vulnerable to contamination. The relationship between mean nitrate concentration and intrinsic aquifer pollution risk is assessed for urban centres across SSA. Current knowledge gaps are identified and future research needs highlighted.

Applying spatial regression to evaluate risk factors for microbiological contamination of urban groundwater sources in Juba, South Sudan

This study developed methodology for statistically assessing groundwater contamination mechanisms. It focused on microbial water pollution in low-income regions. Risk factors for faecal contamination of groundwater-fed drinking-water sources were evaluated in a case study in Juba, South Sudan. The study was based on counts of thermotolerant coliforms in water samples from 129 sources, collected by the humanitarian aid organisation Médecins Sans Frontières in 2010. The factors included hydrogeological settings, land use and socio-economic characteristics. The results showed that the residuals of a conventional probit regression model had a significant positive spatial autocorrelation (Moran’s I = 3.05, I-stat = 9.28); therefore, a spatial model was developed that had better goodness-of-fit to the observations. The most significant factor in this model (p-value 0.005) was the distance from a water source to the nearest Tukul area, an area with informal settlements that lack sanitation services. It is thus recommended that future remediation and monitoring efforts in the city be concentrated in such low-income regions. The spatial model differed from the conventional approach: in contrast with the latter case, lowland topography was not significant at the 5% level, as the p-value was 0.074 in the spatial model and 0.040 in the traditional model. This study showed that statistical risk-factor assessments of groundwater contamination need to consider spatial interactions when the water sources are located close to each other. Future studies might further investigate the cut-off distance that reflects spatial autocorrelation. Particularly, these results advise research on urban groundwater quality.

Urban Groundwater Quality in India

The electrical conductivity, alkalinity, salinity, hardness and chemical load of the groundwater in urban area of the country are increased enormously due to excessive urban stresses by making water unsafe for drinking purposes. Therefore, the groundwater quality of Raipur city, capital of Chhattisgarh state, India has been investigated. The physico-chemical characteristic of the groundwater along with the chemical loading variations is described. Various indices were used for rating of groundwater quality for drinking and irrigation purposes. The cluster and factor analysis models were used for source apportion of the contaminants.

The impacts of groundwater heat pumps on urban shallow groundwater quality in Shenyang China

In order to assess the impacts of groundwater heat pumps on urban shallow groundwater quality in Shenyang China, the urban groundwater samples from pumping and recharging wells of groundwater heat pumps were collected during heating season in the months of November, September, January, February and March in 2007 and 2008. 17 groundwater quality parameters were analyzed using Chinese state or professional standard laboratory methods and procedures. The results show that temperature, pH and the concentrations of total dissolved solid (TDS), total mineralization of groundwater (TMG), chloride (Cl), total hardness (TH), zinc (Zn), petroleum-related pollutants (PRP) and ferrum (Fe) in pumping water were lower than that in recharging water, while the turbidity, SO4 and fluoride showed crosscurrent. There were no changes in Mn, Cu, nitrite nitrogen and total coliforms. The total bacterial count was 1/ml average in pumping water and 0/ml average in recharging water. The sampling of urban groundwater quality is higher than Chinese groundwater quality standard grade III. The groundwater heat pumps showed little impacts on urban shallow water quality during the heating season. Key words: Urban shallow ground water quality, ground source heat pump, groundwater heat pumps, pumping wells, recharging wells, Shenyang.

The effectiveness of selected microbial and chemical indicators to detect sewer leakage impacts on urban groundwater quality

Sewer and stormwater pipe leakage can lead to the degradation of urban groundwater quality. This groundwater may be subsequently used for public water supply and so the resulting water treatment and public health consequences can be serious. To understand the impact of sewer exfiltration on groundwater quality, suitable indicators need to be sampled and analysed for. This study examined potential sewer-derived inorganic and microbial parameters in the U.K. city of Doncaster. Sulphite reducing clostridia, faecal streptococci and boron were all detected in groundwater with reductions compared with sewer values ranging from 1 to 6 orders of magnitude for the former two, to 1 to 2 orders of magnitude decrease for boron. The correlation between these two different indicator types suggests that groundwater quality is being adversely affected by sewer leakage in the study area. The employment of several and varied indicators can better demonstrate the effect than use of single parameters.

Effects of land use on the spatial distribution of trace metals and volatile organic compounds in urban groundwater, Seoul, Korea

To investigate the urban groundwater contamination by eight trace metals and 69 volatile organic compounds (VOCs) in relation to land use in Seoul, a total of 57 groundwater samples collected from wells were examined using a non-parametric statistical analysis. Land use was classified into five categories: less-developed, residential, agricultural, traffic, and industrial. A comparison of analyzed data with US EPA and Korean standards for drinking water showed that some metals and VOCs exceeded the standards in a few localities, such as Fe (N=5), Mn (N=6), Cu (N=1), TCE (N=6), PCE (N=8), 1,2-DCA (N=1), and 1,2-dichloropropane (N=1). Among the 69 investigated VOCs, 19 compounds such as some gasoline-related compounds (e.g., toluene) and chlorinated compounds (e.g., chloroform, PCE, TCE) were detected in groundwater. Non-parametric statistical analysis showed that the concentrations of most trace metals (Fe, Mn, As, Cr, Pb, Cd) and some VOCs (especially, TCE, PCE, chloroform; toluene, carbon tetrachloride, bromodichloromethane, CFC113) are significantly higher in the industrial, residential, and traffic areas (P<0.05), indicating that anthropogenic contamination of urban groundwater by those chemicals is growing. Those chemicals can be used as effective indicators of anthropogenic contamination of groundwater in urban areas and therefore a special attention is warranted for a safe water supply in those areas. The results of this study suggest that urban groundwater quality in urban areas is closely related with land use.

The comparison of rapid bioassays for the assessment of urban groundwater quality

Groundwater is a complex mixture of chemicals that is naturally variable. Current legislation in the UK requires that groundwater quality and the degree of contamination are assessed using chemical methods. Such methods do not consider the synergistic or antagonistic interactions that may affect the bioavailability and toxicity of pollutants in the environment. Bioassays are a method for assessing the toxic impact of whole groundwater samples on the environment. Three rapid bioassays, Eclox TM, Microtox TM and ToxAlert TM, and a Daphnia magna 48-h immobilisation test were used to assess groundwater quality from sites with a wide range of historical uses. Eclox TM responses indicated that the test was very sensitive to changes in groundwater chemistry; 77% of the results had a percentage inhibition greater than 90%. ToxAlert TM, although suitable for monitoring changes in water quality under laboratory conditions, produced highly variable results due to fluctuations in temperature and the chemical composition of the samples. Microtox TM produced replicable results that correlated with those from D. magna tests.