Upward Mass Transport Research Articles

Elimination of V‐Shaped Pits in Thick InGaN Layers via Ammonia‐Assisted Face‐to‐Face Annealing

InGaN, a group‐III nitride semiconductor, is expected to be widely used in the field of optoelectronics, owing to its excellent physical properties. However, InGaN has various limitations. This study reports face‐to‐face annealing (FFA) using vapor‐phase and in‐plane mass transport to improve the surface flatness of an InGaN template. InGaN layers are grown on a GaN template that is grown on a c‐plane sapphire substrate using metal–organic vapor‐phase epitaxy. NH3‐assisted FFA is performed at 1050 °C for 20 min, causing V‐pits to vanish from the InGaN template despite their initial density of 3.3 × 108 cm−2. The surface condition of the lower InGaN layer is worse than that of the upper InGaN layer due to the FFA‐induced upward mass transport from the lower layer, thereby eliminating the V‐pits. Compositional analysis of the upper layer through Auger electron spectroscopy and energy‐dispersive X‐ray spectroscopy reveals In peaks despite high‐temperature annealing, thus confirming the presence of InGaN. The results of this study offer possibilities for future InGaN crystal growth and InGaN‐based device fabrication.

The Influence of the Diurnal Cycle in Wind Shear and Thermodynamics on Squall Lines in the West African Monsoon

Abstract The West African monsoon has a clear diurnal cycle in boundary layer properties, synoptic flow, and moist convection. A nocturnal low-level jet (LLJ) brings cool, moist air into the continent and we hypothesize that it may support storms by providing vertical wind shear and a source of moisture. We use idealized simulations to investigate how the mean diurnal cycle in temperature and humidity compared with that of the wind shear impacts on mature squall lines. Thermodynamic diurnal changes dominate those of the winds, although when isolated the LLJ wind is favorable for more intense systems. Bulk characteristics of the storms, including in-cloud upward mass flux and—if precipitation evaporation is accounted for—total surface rain rates, correlate well with the system-relative inflow of convectively unstable air and moisture into the storms. Mean updraft speeds and mean rainfall rates over the storms do not correlate as well with system-relative inflows due to variations in storm morphology such as cold pool intensity. We note that storms tend to move near the speed of the African easterly jet and so maximize the inflow of convectively unstable air. Our results explain the observed diurnal cycle in organized moist convection, with the hours from 1800 to 0000 UTC being the most favorable. Storms are more likely to die after this, despite the LLJ supporting them, with the environment becoming more favorable again by midday. Significance Statement Large organized storms dominate rainfall in the West African Sahel, but models struggle to predict them at the correct time of day and the underlying mechanisms that control their timings are not well understood. Using idealized simulations, we show that the temperature and humidity of the late evening are favorable for such storms whereas inflow from the low-level jet supports storms overnight. Storm inflows of available energy and moisture predict upward mass transport and total rainfall rates, whereas the strength of the storm’s cold pool is important for storm structure and intensity. Our results demonstrate how the environmental wind profile (which varies throughout the day) interacts with internal storm dynamics, posing a major challenge to parameterized models.

Subsiding shells and the distribution of up- and downdraughts in warm cumulus clouds over land

Abstract. The mass flux of air lifted within the updraughts (updraft in American English) of shallow convection is usually thought to be compensated outside the cloud through either large-scale subsidence or stronger downdraughts in a thin shell surrounding the cloud. Subsiding shells were postulated based on large eddy simulation and are experimentally tested in this study for shallow convection over land. Isolated cumulus clouds were probed with a small research aircraft over flat land and mountainous terrain, in different wind situations and at different levels of the clouds. The average of the 191 cloud transects shows the subsiding shell as a narrow downdraught region outside the cloud boundaries. The ensemble-mean subsiding shell is narrower on the upwind side of the cloud, while it is at least half a cloud diameter wide and more humid on the downwind side. At least half of the upward mass transport in the cloud is compensated within a distance of 20 % of the cloud diameter. However, this shell is not uniform. Distinct regions of downdraughts and updraughts with high variability in the vertical wind are frequent and randomly distributed in the vicinity and also within the cloud. The median diameter of the draughts directly at the cloud boundary is at least 4 times as large as inside the clouds and in the environment. Downdraughts at the cloud boundary are twice as frequent as updraughts. In contrast to the updraughts the major part of the downdraughts is situated outside of the cloud. The subsiding shell results from the distribution of these up- and downdraughts.

Weakening of Upward Mass but Intensification of Upward Energy Transport in a Warming Climate

AbstractHow the atmospheric overturning circulation is projected to change is important for understanding changes in mass and energy budget. This study analyzes the overturning circulation by sorting the upward mass transport in terms of the moist static energy (MSE) of air parcels in an ensemble of coupled climate models. It is found that, in response to greenhouse gas increases, the upward transport of MSE increases in order to balance the increase in radiative cooling of the mass transport. At the same time, the overall mass transport decreases. The increase in energy transport and decrease in mass transport can be explained by the fact that the MSE of rising air parcels increases more rapidly than that of subsiding air, thus allowing for a weaker overturning circulation to transport more energy.

Comments on “A Third-Law Isentropic Analysis of a Simulated Hurricane”

The atmospheric overturning can be estimated by computing an isentropic streamfunction, defined as the net upward mass transport of all air parcels with the potential temperature less than a given threshold. Here, the streamfunctions for the equivalent potential temperature and the entropy potential temperature are compared in a numerical simulation of a hurricane. It is shown that, when condensate is not taken into account, the two streamfunctions are equivalent and can be related to one another by a coordinate transformation. When condensate content is included, the streamfunctions differ substantially in the upper troposphere because of the large amount of ice water found in some updrafts. It is also shown that using an equivalent potential temperature over ice avoids this problem and offers a more robust way to compute the atmospheric overturning when precipitation is included. While it has been recently recommended to limit the isentropic analysis to the entropy potential temperature, it is argued here that more insights can be gained by comparing a circulation averaged in multiple coordinates over limiting oneself to one specific choice.

Temperature-dependent Shape Changes of Ice Nanoclusters on Ag(100).

We investigate the influence of the annealing temperature on the evolution of the ice nanoclusters' geometry by means of low-temperature scanning tunneling microscopy. The clusters, grown at 110 K on Ag(100), gradually increase in height and their shape becomes more compact during annealing at 120 K, 125 K, and 130 K. The increase in height indicates an upward mass transport and reflects a stronger water-water than water-surface bonding. The change in shape, quantitatively expressed as an increase in fractal dimension, is driven by a reduction of the total energy of the step edge. The significant changes in geometry induced by a relatively mild temperature increase underline the importance of temperature for the shape and all properties influenced by this shape of hydrogen-bonded clusters of water ice.

Multiscale Atmospheric Overturning of the Indian Summer Monsoon as Seen through Isentropic Analysis

Abstract This study investigates multiscale atmospheric overturning during the 2009 Indian summer monsoon (ISM) using a cloud-permitting numerical model. The isentropic analysis technique adopted here sorts vertical mass fluxes in terms of the equivalent potential temperature of air parcels, which is capable of delineating the atmospheric overturning between ascending air parcels with high entropy and subsiding air parcels with low entropy. The monsoonal overturning is further decomposed into contributions from three characteristic scales: the basinwide ascent over the Indian monsoon domain, the regional-scale overturning associated with synoptic and mesoscale systems, and the convective-scale overturning. Results show that the convective-scale component dominates the upward mass transport in the lower troposphere while the region-scale component plays an important role by deepening the monsoonal overturning. The spatial variability of the convective-scale overturning is analyzed, showing intense convection over the Western Ghats and the Bay of Bengal while the deepest overturning is localized over northern India and the Himalayan foothills. The equivalent potential temperature in convective updrafts is higher over land than over the ocean or coastal regions. There is also substantial variability in the atmospheric overturning associated with the intraseasonal variability. The upward mass and energy transport increase considerably during the active phases of the ISM. A clear northeastward propagation in the peak isentropic vertical mass and energy transport over different characteristic regions can be found during the ISM, which corresponds to the intraseasonal oscillations of the ISM. Altogether, this study further demonstrates the utility of the isentropic analysis technique to characterize the spatiotemporal variations of convective activities in complex atmospheric flows.

Atmospheric Overturning across Multiple Scales of an MJO Event during the CINDY/DYNAMO Campaign

Abstract This study investigates the atmospheric overturning of the October 2011 MJO event observed during the Cooperative Indian Ocean Experiment on Intraseasonal Variability in the Year 2011 (CINDY)/DYNAMO field experiment using a cloud-permitting numerical model. The isentropic analysis is used to sort the vertical mass transport in terms of the equivalent potential temperature of the air parcels, which naturally decomposes the atmospheric overturning between ascending air with high entropy and subsiding air with low entropy. The circulation is further decomposed into contributions of four main scales: basinwide ascent, meridional overturning, regional overturning, and convection. Results show that the convective scale dominates the upward mass transport while larger scales play an important role both by allowing a deeper overturning and by modulating convective activity. There are substantial changes in the atmospheric overturning during different phases of this MJO event. Increased convective activity at low levels precedes the onset of the MJO by several days. The initiation of the MJO itself is associated with a substantial increase in the atmospheric overturning over the Indian Ocean. The subsequent eastward propagation of the MJO event can be clearly captured by the evolutions of convective-scale vertical mass fluxes at different altitudes. The equivalent potential temperatures of the rising and subsiding air parcels in the convective-scale overturning are also increased in the troposphere during the active phase of the MJO.

Upward mass transport and alloying during the growth of Co on Cu(111)

Co growth on Cu(111) was investigated at several temperatures between 120 K and 300 K by variable-temperature fast-scanning tunneling microscopy at submonolayer coverage. Islands nucleate heterogeneously at step edges and homogeneously on terraces. The height and area distribution difference between these two types of differently nucleated islands is attributed to a step edge alloy. Furthermore, the transformation from one-monolayer high islands to two-monolayer high islands is followed in time-lapsed sequences between 145 and 165 K. A surprising low-energy barrier for upward mass transport of ${E}_{\mathrm{upward}}\ensuremath{\approx}(0.15\ifmmode\pm\else\textpm\fi{}0.04)$ eV is determined for islands on terraces. At 120 and 150 K, the terrace islands are pure Cu; in contrast, at room temperature, terrace islands larger than $\ensuremath{\approx}120$ ${\mathrm{nm}}^{2}$ alloy at their border.

Prospects for simulating macromolecular surfactant chemistry at the ocean–atmosphere boundary

Biogenic lipids and polymers are surveyed for their ability to adsorb at the water–air interfaces associated with bubbles, marine microlayers and particles in the overlying boundary layer. Representative ocean biogeochemical regimes are defined in order to estimate local concentrations for the major macromolecular classes. Surfactant equilibria and maximum excess are then derived based on a network of model compounds. Relative local coverage and upward mass transport follow directly, and specific chemical structures can be placed into regional rank order. Lipids and denatured protein-like polymers dominate at the selected locations. The assigned monolayer phase states are variable, whether assessed along bubbles or at the atmospheric spray droplet perimeter. Since oceanic film compositions prove to be irregular, effects on gas and organic transfer are expected to exhibit geographic dependence as well. Moreover, the core arguments extend across the sea–air interface into aerosol–cloud systems. Fundamental nascent chemical properties including mass to carbon ratio and density depend strongly on the geochemical state of source waters. High surface pressures may suppress the Kelvin effect, and marine organic hygroscopicities are almost entirely unconstrained. While bubble adsorption provides a well-known means for transporting lipidic or proteinaceous material into sea spray, the same cannot be said of polysaccharides. Carbohydrates tend to be strongly hydrophilic so that their excess carbon mass is low despite stacked polymeric geometries. Since sugars are abundant in the marine aerosol, gel-based mechanisms may be required to achieve uplift. Uncertainties distill to a global scale dearth of information regarding two dimensional kinetics and equilibria. Nonetheless simulations are recommended, to initiate the process of systems level quantification.

InGaAs/GaAs (110) quantum dot formation via step meandering

InGaAs (110) semiconductor quantum dots (QDs) offer very promising prospects as a material base for a new generation of high-speed spintronic devices, such as single electron transistors for quantum computing. However, the spontaneous formation of InGaAs QDs is prevented by two-dimensional (2D) layer-by-layer growth on singular GaAs (110) substrates. In this work we have studied, by using atomic force microscopy and photoluminescence spectroscopy (PL), the growth of InGaAs/GaAs QDs on GaAs (110) stepped substrates by molecular beam epitaxy (MBE), and the modification of the adatom incorporation kinetics to surface steps in the presence of chemisorbed atomic hydrogen. The as-grown QDs exhibit lateral dimensions below 100 nm and emission peaks in the 1.35–1.37 eV range. It has been found that a step meandering instability derived from the preferential attachment of In adatoms to [11−0]-step edges relative to [11−n]-type steps plays a key role in the destabilization of 2D growth that leads to 3D mound formation on both conventional and H-terminated vicinal substrates. In the latter case, the driving force for 3D growth via step meandering is enhanced by H-induced upward mass transport in addition to the lower energy cost associated with island formation on H-terminated substrates, which results in a high density array of InGaAs/GaAs dots selectively nucleated on the terrace apices with reduced lateral dimensions and improved PL efficiency relative to those of conventional MBE-grown samples.

Formation and coarsening of Ag(110) bilayer islands on NiAl(110): STM analysis and atomistic lattice-gas modeling

Scanning tunneling microscopy analysis of the initial stages of film growth during deposition of Ag on NiAl(110) reveals facile formation of bilayer Ag(110) islands at temperatures of 130 K and above. Annealing subsequent to deposition at 130 K induces coarsening of the bilayer island distribution. The thermodynamic driving force for bilayer island formation reflects a lower relative surface energy for films of even layer thicknesses. This feature derives from quantum size effects due to electron confinement in the Ag film. The kinetics of island formation and relaxation is controlled by terrace and edge-diffusion barriers, detachment barriers, interlayer diffusion barriers, and layer-dependent adsorption and interaction energies. These key energies are determined from density-functional theory analysis and incorporated into an atomistic lattice-gas model for homogeneous island formation, where specification of the adatom hop rates is consistent with detailed balance. Model analysis via kinetic Monte Carlo simulation elucidates the role of strongly anisotropic interactions in development during deposition of elongated island growth shapes and also in facilitating upward mass transport needed for bilayer island formation. The model succeeds in recovering island densities at lower temperatures but experimental densities exceed model predictions at higher temperatures plausibly due to heterogeneous nucleation at surface defects. The same model successfully describes postdeposition coarsening of small islands grown at 130 K.

Conductive atomic force microscopy study of InAs growth kinetics on vicinal GaAs (110)

Conductive atomic force microscopy has been used to investigate the effect of atomic hydrogen and step orientation on the growth behavior of InAs on GaAs (110) misoriented substrates. Samples grown by conventional molecular beam epitaxy exhibit higher conductivity on [11¯0]-multiatomic step edges, where preferential nucleation of InAs nanowires takes place by step decoration. On H-terminated substrates with triangular terraces bounded by [11¯5]-type steps, three-dimensional InAs clusters grow selectively at the terrace apices as a result of a kinetically driven enhancement in upward mass transport via AsHx intermediate species and a reduction in the surface free energy.

A refined view of vertical mass transport by cumulus convection

The purpose of this letter is to show that the traditional view of transport by shallow cumulus clouds needs important refinement. On the basis of a straightforward geometrical analysis of Large Eddy Simulation results of shallow cumulus clouds, we conclude (1) that the upward mass transport by clouds is strongly dominated by regions close to the edge of clouds rather than by the core region of clouds and (2) that the downward mass transport is dominated by processes just outside the cloud. The latter finding contradicts the accepted view of a uniformly descending dry environment. We therefore advocate a refined view which distinguishes between the near‐cloud environment and the distant environment. The near‐cloud environment is characterized by coherent descending motions, whereas the distant environment is rather quiescent and plays no significant role in vertical transport.

Kinetics of Facile Bilayer Island Formation at Low Temperature:Ag/NiAl(110)

Facile nucleation and growth of bilayer Ag(110) islands on NiAl(110) is observed by STM for Ag deposition at temperatures as low as 127 K. Density functional theory analysis for supported Ag films determines adatom adsorption energies (which favor bilayer islands), interaction energies, and diffusion barriers. Analysis of an atomistic lattice-gas model incorporating these energies elucidates the role of strongly anisotropic interactions in enabling the upward mass transport needed for bilayer island formation.

Upward self-diffusion of adatoms and small clusters on facets of fcc metal (110) surfaces

We study upward self-diffusion of adatoms and small clusters on faceted huts formed in fcc metal (110) homoepitaxy using molecular dynamics simulations with interatomic potentials described by the embedded-atom method. Our results show that both individual adatoms and small clusters on the (111)-sloped and (100)-sloped facets of the huts on Al and Cu(110) can readily diffuse upward and cross the convex edges of the huts, but with different atomistic mechanisms. An adatom crosses the convex edges via a simple concerted exchange or indirect place exchange mechanism. In contrast, the upward diffusion and convex-edge crossing of small clusters is realized by their dissociation at or near the edges of the hut after one or two atoms belonging to the cluster are incorporated into the edges. The present simulation studies reveal that there truly exists efficient upward mass transport on faceted islands in fcc metal (110) homoepitaxy, and such upward diffusion processes are expected to play an important role in defining the kinetic faceting instability in these growth systems.

Pacific and atlantic ‘bomb‐like’ deepenings in mature phase: A comparative study

AbstractThe mesoscale dynamics of a secondary cyclone sampled during the field phase of the Fronts and Atlantic Storm‐Track Experiment (FASTEX) are documented using airborne Doppler radar data. the high quality of the mesoscale airborne Doppler dataset collected within this secondary cyclone is highlighted. This study demonstrates, however, the need to combine in the near future airborne Doppler radar and dropsonde measurements, in order to access multiscale processes involved in the mature stage of this FASTEX cyclone both in clear‐air and in precipitating regions. the studied secondary cyclone developed on the trailing cold front of a parent low situated over Greenland, and underwent the most explosive deepening (roughly −54 mb in 24 hours) sampled in the multiscale sampling area during FASTEX. the main flows responsible for the mesoscale organization of the cyclone are: a warm airflow emerging from the base of the synoptic warm conveyor belt that generates the most active part of the cloud head; a dry intrusion approaching in the dry slot the cyclone centre; a cold conveyor belt that contributes to the upward mass transport towards the upper part of the polar‐front cloud band; and a cold northerly flow in the western part of the cloud head, which tends to wrap around the low centre and is likely to release convective instability through air‐sea interactions. This study also documents a slight shift in position between the high vertical‐vorticity core associated with the active part of the cloud head and the location of the pressure minimum.The detailed three‐dimensional structure of this Atlantic secondary cyclone is also compared with that gathered within another ‘bomb‐like’ deepening (defined as more than a 24 mb surface pressure drop in 24 hours) observed over the Pacific ocean during the Coastal Observation and Simulation with Topography (COAST) experiment. Some similarities are found. the main differences appear to be linked to the warm seclusion that is exclusive to the studied Pacific cyclone. More pronounced ascending motions are found within the cloud head of the Pacific ‘reference’ case, and the deepening results from a more constructive effect of geostrophic and non‐geostrophic processes than for the Atlantic ‘reference’ case.

Secondary Wind Maxima in Hurricanes: Airflow and Relationship to Rainbands

Abstract Aircraft flight-level data from 787 radial legs in 20 hurricanes are analyzed to identify the composite kinematic structure in the hurricane eyewall, and especially with secondary horizontal wind maxima (SHWM) that occur outside the eyewall. Similar to previous studies, analysis of the flight-level wind data in the eyewall reveals radial convergence near the radius of maximum wind (RMW), and the highest frequency of updraft and the largest upward mass transport radially inward of the RMW. More than 20% of the flight legs contain substantial secondary horizontal wind maxima of specified strength and length. The kinematic structure associated with SHWM is similar to that of the hurricane eyewall with radial convergence near the radius of maximum wind and a preferred location for maximum upward motions and upward mass transport just inside the RMW. Statistical analysis confirms the similarity in characteristics between radial and vertical velocities of the eyewall and near the SHWM. In addition, for...

Heating Rates in Tropical Anvils

The interaction of infrared and solar radiation with tropical cirrus anvils is addressed. Optical properties of the anvils are inferred from satellite observations and from high-altitude aircraft measurements. An infrared multiple-scattering model is used to compute heating rates in tropical anvils. Layer-average heating rates in 2 km thick anvils were found to be on the order of 20 to 30 K/day. The difference between heating rates at cloud bottom and cloud top ranges from 30 to 200 K/day, leading to convective instability in the anvil. The calculations are most sensitive to the assumed ice water content, but also are affected by the vertical distribution of ice water content and by the anvil thickness. Solar heating in anvils is shown to be less important than infrared heating but not negligible. The dynamical implications of the computed heating rates are also explored and it is concluded that the heating may have important consequences for upward mass transport in the tropics. The potential impact of tropical cirrus on the tropical energy balance and cloud forcing are discussed.

Vertical Mass Transport in Cumulonimbus Clouds on Day 261 of GATE

Abstract The model of Sikdar, for inferring upward transport of mass in a cumulonimbus cloud from expansion of the anvil in a satellite picture sequence, is refined and tested. In the present mass transport model, the anvil is configured as a stack of slabs, and the thickness of each slab is inferred from cloud radiance, by means of multiple scattering results. In addition, mass transport from the base of the anvil to the base of the cumulonimbus cloud is required to decrease according to the formula of Austin and Houze, in which the entrainment is inversely proportional to total cloud depth. With a sounding of ambient temperature and water vapor mixing ratio, the model yields profiles of upward mass transport and production of condensate. The model is applied to seven cumulonimbus clouds in the eastern Atlantic Occean on 18 member 1974, one of the last days of the GARP Atlantic Tropical Experiment. Transports of the present model at the base of the anvil average 27 &times 1010 g s-1. This is 2.5 times la...