In order to solve the coal spontaneous combustion disaster in the upper layer goaf during the slicing mining process, a slurry that can expand by self-produced gas was developed using phosphogypsum and sodium bicarbonate as raw materials. The effect of different factors on the performance of phosphogypsum based self-produced gas expansion slurry (PSES) was analyzed. The optimal ratio and conditions of PSES were determined through orthogonal experiments. The thermal insulation performance and cooling and fire extinguishing performance of PSES were studied. Finally, it was applied in Luwa coal mine in Shandong province. The research results indicated that the optimal experimental conditions and ratios for PSES were phosphogypsum content of 56 wt%, sodium bicarbonate content of 21 wt%, water temperature of 25 ℃, and mixing time of 65 s. Under these conditions, the expansion performance of the slurry was good, and the setting time and compressive strength can meet the requirements for sealing the coal and rock cracks in the goaf. Under the same heat source, the thicker the slurry, the better its thermal insulation effect. Under the same thickness, the higher the heat source temperature, the shorter the effective insulation time(EIT). After the slurry was injected into the cracks of the broken coal, it wrapped around the broken coal from bottom to top. The temperatures of A-layer, B-layer, and C-layer of the coal pile decreased in sequence. After half an hour of grouting, the temperatures at all points dropped below 50 ℃ without any reignition phenomenon. After injecting PSES into the coal spontaneous combustion dangerous area in the upper layer goaf, the concentrations of CO and O2 in the monitoring borehole decreased to a safe range, and the generated CO2 concentration finally stabilized at around 4.6 %. It showed that PSES can seal the coal and rock cracks in the goaf, suppress the coal spontaneous combustion, and guarantee the lower layer working face can be mined.
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