Internal buffering paths on temperature-water activity diagrams for the pelitic model system: NaAIO 2 - KAIO 2 - CaAI 2 O 4 - Al 2 SiO 5 - SiO 2 - H 2 O give rise to sequences of assemblages which correspond to those observed in upper amphibolite facies terranes. In particular, the persistence of the assemblage quartz-alkali feldspar-plagioclase-muscovite-sillimanite across a zone and the rapidly changing composition of plagioclase across this zone can be accounted for in a natural way.
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