Upland Catchments Research Articles

Comparison of Sewage and Coal-Mine Wastes on Stream Macroinvertebrates Within an Otherwise Clean Upland Catchment, Southeastern Australia

Macroinvertebrates have been widely used in freshwater ecosystems as surrogates to assess the impacts of waste discharges and water pollution. However, often interpretations have been made on the impact of one pollutant in the presence of others that may provide an unidentified additive effective or otherwise confound the results. There have been few opportunities to study the impact of pollutants without such potentially confounding effects. We studied macroinvertebrates using a replicated kick sampling technique and identified to the family level to assess and compare the effects of zinc-rich coal-mine waste and organic pollution from treated sewage on an otherwise clean upland stream network within a world heritage area. We used multivariate analysis of macroinvertebrate assemblages from polluted and clean sites to measure and compare the effect of each waste impact to community structure. We also calculated three widely used biotic indices (Ephemeroptera, Plecoptera and Trichoptera (EPT) family richness, family richness, and abundance) and found that the EPT index was the only one to respond to both pollution types. Macroinvertebrate abundance was an important attribute of the study, with each source of pollution having a contrasting effect on total abundance. It also helped us to measure the relative response of families to each pollutant. There was an initial significant modification of macroinvertebrate assemblages below the outflow of each of the pollutants, followed by different degrees of recovery downstream.

Recent Low-Flow and Groundwater Storage Changes in Upland Watersheds of the Kanto Region, Japan

Annual trends in baseflow and groundwater storage over the past 40years are deduced from stream flow observations in four upland catchments in the northern parts of the Kanto region. The analysis is based on the assumption that baseflow is an exponential decay function of time, which yields a linear relationship between storage and baseflow. These catchments are part of the water supply system for the Greater Tokyo metropolitan area, and groundwater constitutes an integral component of their storage capacity. Although the data exhibit great variability from year to year, no evidence was found that any persistent or systematic changes in low streamflow regime and in groundwater storage have taken place in this region over the period of record.

An Evaluation of the Introduction of Modified Cropping Practices in Yunnan Province, China, Using Surveys of Farmers' Households

Problems associated with land degradation are serious in China. Sloping land in South China has experienced a decline in crop productivity by 30-60% due to soil erosion and it has been predicted that most topsoil will be lost within the next 100 years if current erosion rates continue. Considering these situations, an agro-environmental research and development project (Sustainable Highland Agriculture in South-East Asia – SHASEA) was conducted in a catchment in Yunnan Province, China, to address the objectives of increasing crop productivity in sustainable and environmentally-friendly ways. A range of cropping practices was developed and implemented in a rural upland catchment (Wang Jia). At the end of the project, farmers were surveyed to evaluate project effectiveness. All farmers from Wang Jia Catchment, who were involved in project implementation, were surveyed. A sample of farmers working in an adjacent catchment (not associated with the project) was surveyed for comparative purposes. Farmers had different perceptions of the cropping practices employed. Contour cultivation was preferred and likely to be adopted. Others practices such as straw mulching and intercropping were seen as less appropriate and unlikely to be adopted. Polythene mulch was recognized as effective, but likely to be adopted only if financial returns were favourable. The availability of relevant information had an important impact on the extent of technology testing by farmers and their willingness to adopt the practices in the future.

A review of the potential impacts of climate change on surface water quality

It is now accepted that some human-induced climate change is unavoidable. Potential impacts on water supply have received much attention, but relatively little is known about the concomitant changes in water quality. Projected changes in air temperature and rainfall could affect river flows and, hence, the mobility and dilution of contaminants. Increased water temperatures will affect chemical reaction kinetics and, combined with deteriorations in quality, freshwater ecological status. With increased flows there will be changes in stream power and, hence, sediment loads with the potential to alter the morphology of rivers and the transfer of sediments to lakes, thereby impacting freshwater habitats in both lake and stream systems. This paper reviews such impacts through the lens of UK surface water quality. Widely accepted climate change scenarios suggest more frequent droughts in summer, as well as flash-flooding, leading to uncontrolled discharges from urban areas to receiving water courses and estuaries. Invasion by alien species is highly likely, as is migration of species within the UK adapting to changing temperatures and flow regimes. Lower flows, reduced velocities and, hence, higher water residence times in rivers and lakes will enhance the potential for toxic algal blooms and reduce dissolved oxygen levels. Upland streams could experience increased dissolved organic carbon and colour levels, requiring action at water treatment plants to prevent toxic by-products entering public water supplies. Storms that terminate drought periods will flush nutrients from urban and rural areas or generate acid pulses in acidified upland catchments. Policy responses to climate change, such as the growth of bio-fuels or emission controls, will further impact freshwater quality.

Post‐flood field investigations in upland catchments after major flash floods: proposal of a methodology and illustrations

AbstractPost‐event survey and investigation is one way to gain experience on natural hazards. The importance of the systematisation and standardisation of such investigations and re‐analysis is progressively recognised in all the geophysical sciences as shown by the growing number of scientific papers and programs on the subject. But how to proceed in the case of a flash floods, what type of data should be collected for what type of analyses and to explore which particular issues? To give a first answer to these questions, a methodology for post‐flash flood field investigations has been developed under the EC FLOODsite project and tested under the EC HYDRATE project. This paper presents shortly the principles of this methodology and illustrates its application for the study of two major flash floods that occurred in November 1999 and September 2002 in the South of France.

Differentiated suspended sediment transport in headwater basins of the Besor catchment, northern Negev

ABSTRACT Alexandrov, Y., Balaban, N., Bergman, N., Chocron, M., Laronne, J.B., Powell, D.M., Reid, I., Tagger, S., and Wener-Frank, I. 2008. Differentiated suspended sediment transport in headwater basins of the Besor catchment, northern Negev. Isr. J. Earth Sci. 57: 177–188. An extensive water and sediment monitoring network has been established during the past two decades in the Nahal Besor catchment of the northern Negev. Its primary purpose is to measure water and sediment fluxes at different hydrological scales and thus assist in understanding the complexity of sedimentary dynamics when these are assessed at the outlet of the trunk stream. Water and suspended sediment monitoring systems have been developed to provide discrete and continuous records, from which material fluxes have been calculated. The network involves 3 upland catchments—Nahal Eshtemoa, Nahal Sekher, and a sub-catchment of Nahal Bikhra—differing in size and/or rainfall regime. Suspended sediment rating curves for the small (0.66 km

Historic and contemporary sediment transfer in an upland Pennine catchment, UK

AbstractA sediment budget for an upland catchment–reservoir system at Burnhope Reservoir, North Pennines, UK has been developed. This provides a framework for quantifying historic and contemporary sediment yields and drainage basin response to disturbance from climate change and human activities in the recent past. Bathymetric survey, core sampling, 137Cs dating and aerial photographs have been used to assess sediment accumulation in the reservoir. The average reservoir sedimentation rate is 1·24 cm yr−1 (annual sediment yield 33·3 t km−2 yr−1 ± 10%, trap efficiency 92%). Mean annual reservoir sedimentation over the 67 year period has been estimated at 592 t ± 10%. Inputs of suspended sediment from direct catchwater streams account for 54% of sediment supply to the budget (best estimate yield of 318 t yr−1 ± 129%), while those from actively eroding reservoir shorelines contribute 328 t yr−1 ± 92%. Sediment yield estimates from stream monitoring and reservoir sedimentation are an order of magnitude lower than those reported from South Pennine reservoirs of comparable drainage basin area. Analysis of historical rainfall series for the catchment shows fluctuations in winter and summer rainfall patterns over the past 62 years. From 1976 to 1998 there has been a diverging trend between winter and summer rainfall, with a large increase in winter and a gradual decrease in summer totals. Periods of maximum variation occur during the summer drought events of the late 1970s, early 1980s and mid‐1990s. Analysis of the particle size of core sediments highlights abrupt increases in sand‐sized particles in the top 20 cm of the core. Based on the 137Cs chronology, these layers were deposited from the late 1970s onwards and relate to these diverging rainfall records and rapidly fluctuating reservoir levels. This provides evidence of potential sediment reworking within the reservoir by rapid water‐level rise after drought. Copyright © 2008 John Wiley & Sons, Ltd.

Characterizing Long‐Term Hydrologic‐Response and Sediment‐Transport for the R‐5 Catchment

Recently there have been several calls to establish long-term data collection networks to monitor near-surface hydrologic response and landscape evolution. The focus of this paper is a long-term dataset from the International Hydrologic Decade (1965-1974). The small upland catchment, known as R-5, located near Chickasha, Olahoma, has been the subject of considerable attention within the event-based hydrologic modeling community for more than 30 yr. Here, for the first time, 8 yr of continuous near-surface hydrologic-response and sediment-transport data are analyzed to show trends in the catchment's long-term behavior. The datasets include precipitation, temperature, solar radiation, soil-water content, infiltration, water discharge, and sediment discharge. Potential and actual evapotranspiration rates were estimated and used to calculate an average annual water balance for the catchment. Findings include, for example, that rainfall intensity rarely exceeds the threshold for Horton-type runoff, soil-water content is both spatially and temporally variable, and the water and sediment discharge rates are positively correlated. The R-5 data provide a unique opportunity to test (and refine) process-based models of continuous hydrologic response and sediment transport at the catchment scale for applications in the emerging fields of hydroecology and hydrogeomorphology.

Holocene sediment budgets for upland catchments: The problem of soilscape model and data availability

Abstract This study presents a Holocene sediment budget for the upland catchment of the Speyerbach in the Palatinate Forest, southwestern Germany. The influences of both, data availability and the choice of an appropriate soilscape model on the sediment budget calculations are investigated. For budget calculations the spatial distribution of soils was derived from the soil map 1:50,000. Thickness values of soil truncation and colluvial burial were extracted from two soil data sets with varying information content. Data processing contained a disaggregation of the soil map with the help of land use data. In order to model the sediment budget a reference soil thickness (a so-called soilscape model), which represents the initial conditions is necessary. As upland soils are developed in periglacial solifluction sheets, the main solifluction sheet (MSS, “Hauptlage”) showing a constant thickness and being affected by soil forming processes was chosen. Determining the initial thickness of the MSS is a crucial point, as a comparison of reference values shows. The literature values are actual thicknesses and differ significantly between 30 and 100 cm among various studies. Therefore a statistical model using the local profile descriptions of the soil database for the Speyerbach catchment was set up. We found that the 95 percentile worked best to extract the depths of pristine soils. Hence, a pristine soil profile depth of 60 or 70 cm could be extracted for the Speyerbach catchment. Calculating the sediment budget for 60 cm returns a sediment delivery rate (SDR) of 64.8%. With a soilscape model of 70 cm a catchment SDR of 83.2% can be derived, which is 18.4% higher than the first one. The computed SDR is twice as high as the SDR determined by Houben et al. [Houben, P., Burggraaf, P., Hoffmann, T., Kleefeld, K., Zimmermann, A., Dikau, R., 2007. Reconstructing Holocene land-use change and sediment budgets in the Rhine system. PAGES News 15 (1), 17–18.] and Rommens et al. [Rommens, T., Verstraeten, G., Poesen, J., Govers, G., Van Rompaey, A.J.J., Peeters, I., Lang, A., 2005. Soil erosion and sediment deposition in the Belgian loess belt during the Holocene: establishing a sediment budget for a small agricultural catchment. The Holocene 15 (7), 1032–1043.]. This may reflect differences in physio-geographical settings and settlement history between a loess covered basin catchment and a deeply furrowed upland catchment. Since no datings or proxy data are available, the classification to individual settlement periods and furthermore an estimation of human impact is not possible yet. Future work will address the estimation of human impact by the analysis of historical data and datings of colluvial layers as well as a field validation of the computed sediment budgets.

Assessing the value of Cl− and δ18O data in modelling the hydrological behaviour of a small upland catchment in northeast Scotland

Model simulation of Cl− and δ18O in stream waters has been investigated as a means of improving interpretation of catchment-scale hydrological processes. The procedure has been evaluated for a small upland catchment which is one of the UK Environmental Change Network sites. Precipitation and stream samples have been analysed for hydrochemical determinands since the mid 1990s and, since November 2004, measurement of δ18O has also been undertaken. A conceptual hydrological model STREAM (STorage REsidence times And Mixing) was applied to the catchment to simulate the hydrology and responses of Cl− and δ18O. Results from model simulations confirmed that the catchment generally behaves as a well-mixed system. The feasibility of flow contributions from a deep groundwater source and infiltration excess runoff was examined, in addition to the apparently dominant shallow groundwater response. The ability to estimate mean residence times and draw strong conclusions about catchment processes was limited by the range of uncertainties in the experimental data and modelling. Integration of the tracer data in the model was found to be of value for probing model sensitivities and developing hypotheses that inform the design of further field experimentation. In this way, the modelling provides key feedback within a catchment learning framework.

Sulphur leaching from headwater catchments in an eroded peatland, South Pennines, U.K

A detailed investigation into sulphur leaching in peatland headwater catchments in the South Pennines, UK shows that, despite significant reductions in sulphur emissions, sulphur remains a key acidifier. This sulphur can be considered as legacy atmospheric pollution, stored within the peat by processes of dissimilatory sulphate reduction and now being leached into the region's surface waters. Persistently lower water tables at gully edge locations define a thick erosional acrotelm that is vulnerable to aeration, oxidation and flushing throughout the year, and not solely confined to periods of drought. Stream discharge behaves as a two-end member system, whereby pre-event water, rich in DOC and sulphate, is diluted by event water as a result of event water flowing through fast flow pathways such as macropores and overland flow. A rapid increase in water table elevation during the storm and a decrease in elevation after the storm indicate that event water has infiltrated the peat and has then been released into the stream. Streamwaters in peat dominated upland catchments with high densities of gullying have high concentrations of sulphate and low concentrations of DOC, whereas the reverse is true for those catchments with low densities of gullying. This is consistent with the concept that high concentrations of sulphate can suppress the solubility of DOC. A significant store of sulphate exists within South Pennine peats, and continued gully erosion will enhance sulphur leaching meaning that the timescale involved for any depletion is uncertain. It is therefore important that models predicting recovery from acidification in these upland systems include an understanding of how this stored sulphur is being leached, especially with respect to gully erosion, climate change and reduced precipitation.

Influence of hydrology and seasonality on DOC exports from three contrasting upland catchments

Variation in dissolved organic carbon (DOC) concentrations of surface waters is a consequence of process changes in the surrounding terrestrial environment, both within annual cycles and over the longer term. Long-term records (1987–2006) of DOC concentrations at six catchments (0.44–10.0 km2) across a climatic transect in Scotland were investigated for intra-annual relationships to evaluate potential long-term seasonal patterns. The intra-annual mode of DOC export contrasted markedly between catchments and appeared dependent on their hydrological characteristics. Catchments in wetter Central Scotland with high rainfall–runoff ratios, short transit times and well-connected responsive soils show a distinct annual periodicity in DOC concentrations throughout the long-term datasets. Increased DOC concentrations occurred between June and November with correspondingly lower DOC concentrations from December to May. This appears unrelated to discharge, and is dependent mainly on higher temperatures driving biological activity, increasing decomposition of available organic matter and solubility of DOC. The drier eastern catchments have lower rainfall–runoff ratios, longer transit times and annual drying–wetting regimes linked to changing connectivity of soils. These are characterised by seasonal DOC concentration–discharge relationships with an autumnal flush of DOC. Temperature influences the availability of organic matter for DOC transport producing a high DOC concentration–discharge relationship in summer/autumn and low DOC concentration–discharge relationship in winter/spring. These two distinct modes of seasonal DOC transport have important implications for understanding changes in DOC concentrations and export brought about by climate change (temperature and precipitation) and modelling of aquatic carbon losses from soil-types under different hydrological regimes.

Runoff and sediment losses from 27 upland catchments in Southeast Asia: Impact of rapid land use changes and conservation practices

Rapid changes in upland farming systems in Southeast Asia generated predominantly by increased population pressure and ‘market forces’ have resulted in widespread land degradation that has been well documented at the plot scale. Yet, the links between agricultural activities in the uplands and downstream off-site effects remain largely unknown because of the difficulties in transferring results from plots to a larger scale. Many authors have thus pointed out the need for long-term catchment studies. The objective of this paper is to summarize the results obtained by the Management of Soil Erosion Consortium (MSEC) over the last 5 years from 27 catchments in five countries (Indonesia, Laos, Philippines, Thailand, and Vietnam). The purpose of the study was to assess the impacts of cultivation practices on annual runoff and erosion rates. Initial surveys in each catchment included topography, soils and land use. Monitoring included climatic, hydrologic and erosion (total sediment yield including bed load and suspended sediment load) data, land use and crop yields, and farmers’ income. In addition, new land management options were introduced through consultations with farmers and evaluated in terms of runoff and erosion. These included tree plantations, fruit trees, improved fallow with legumes, maize intercropped with legumes, planted fodder, native grass strips and agro-ecological practices (direct sowing and mulch-based conservation agriculture). Regressions analyses showed that runoff during the rainy season, and normalized runoff flow coefficient based on erosive rainfall during the rainy season (rainfall with intensity exceeding 25 mm h −1) increase with the percentage of the catchment covered by maize. Both variables decrease with increasing soil depth, standard deviation of catchment slope (that reflects terrain roughness), and the percentages of the catchment covered by fallow (regular and improved), tree plantations and planted fodder. The best predictors of sediment yield were the surface percentages of maize, Job's tears, cassava and footpaths. The main conclusions generated from this study were: (i) soil erosion is predominantly influenced by land use rather than environmental characteristics not only at the plot scale but also at the catchment scale; (ii) slash-and-burn shifting cultivation with sufficiently long rotations (1 year of cultivation, 8 years of fallow) is too often unjustly blamed for degradation; (iii) in its place, continuous cropping of maize and cassava promotes high rates of soil erosion at the catchment scale; (iv) conservation technologies are efficient in reducing runoff and total sediment yield at the catchment scale; (v) the adoption of improved soil management technologies by upland farmers is not a function of the degree of intensification of their farming system and/or of their incomes. The results suggest that if expansion of maize and cassava into already degraded upland systems were to occur due to increased demand for biofuels, there is a risk of higher runoff and sediment generation. A failure to adopt appropriate land use management strategies will result in further rapid resource degradation with negative impacts to downstream communities.

Hydrological modelling using raingauge- and radar-based estimators of areal rainfall

Three types of gridded rainfall estimator, based on raingauge and/or radar observations, are considered and their merits for hydrological modelling explored. Gridded multiquadric surface fitting techniques are developed to form raingauge-only and ‘raingauge-adjusted radar’ rainfall estimators. A third estimator is provided by the unadjusted radar data which comes in raw or Nimrod form. The latter is a post-processed radar product that aims to apply physically based corrections. These estimators are assessed first from a rainfall perspective, and then from a hydrological perspective by using them to provide rainfall inputs to hydrological models and comparing their simulated flows to observations. The PDM, a lumped conceptual rainfall-runoff model, and the Grid-to-Grid Model, a distributed grid-based runoff and routing model, are used for the hydrological assessment over two upland catchments in northwest England. Important insights are gained into the performance of the different rainfall estimators in assessing rainfall over space and their use in lumped and distributed hydrological models. The need for frequent and spatially varying gauge-adjustment of radar is identified as crucial for the weather radar products assessed.

Land use designation and vegetation community structure in the Adirondack uplands (New York, USA)

AbstractQuestion: Does forest vegetation community structure reflect legislative land use designations?Location: Adirondack Park, New York, USA.Methods: The Adirondack Park, located in northern New York State, is a mixture of public and private lands, with state‐owned Forest Preserve lands comprising ca. 42% of the 2.4 million ha, on which timber harvesting and many other forms of anthropogenic disturbance are prohibited. A survey of vegetation communities was conducted in eighteen upland catchments with differing land use history (managed and Forest Preserve), including overstory, understory, and dead wood (snags and downed woody debris) using randomly placed plots.Results: Mean overstory density and basal area were not significantly different between land uses, although mean overstory tree size was greater in Preserve catchments. Sapling densities were greater in managed catchments, while mean herb/shrub coverage was not affected by land use. Densities of 25% of common species were affected by land use, determined by GIS coverages constructed using an Inverse Distance Weighted estimation procedure. Discriminant Analysis of per‐plot plant community data correctly classified 89% of both managed and Preserve plots.Conclusion: The success of the Discriminant Analysis in classifying land uses based on vegetation communities indicates its potential utility of this method in comparing forest vegetation to a reference condition in this and other areas. The analysis suggests that at least 85 years is required for Adirondack up‐land catchments to recover following harvesting. Uncertainty in classification was related to heterogenous management and disturbance patterns within catchments.

Geotechnical properties of a municipal water treatment sludge incorporating a coagulant

The geotechnical properties of a municipal water treatment sludge from an upland catchment are presented. The gelatinous sludge comprised flocs of mainly quartz, manganoan calcite, and clay-sized organic solids, and incorporated an alum coagulant and an anionic polyelectrolyte. Standard Proctor compaction yielded low bulk density values of 0.95–1.10 t/m3and dry density values of 0.12–0.36 t/m3(water content is 160%–780%) in line with the low specific gravity of solids value of 1.86. The undrained shear strength and the water content were inversely related on a semi-log plot. The effective stress shear strength parameter values were c' = 0 and ϕ' = 39°. The consolidation properties were studied using the oedometer, consolidometer, and triaxial apparatus. The material was highly compressible with primary compression index (Cc) values of 2.5–3.7, and primary compression ratio (C*c) values of 0.20–0.28. The majority of the strain response occurred due to primary consolidation although the material had a very low permeability (coefficient of permeability values decreasing from 2 × 10−9to 5 × 10−11m/s for an effective vertical stress of σ'v= 3–800 kPa). Secondary compression was minor, with a mean secondary compression index (Cαe) value of 0.15, and Cαe/Cc= 0.04–0.06.

Sources and management of urban stormwater pollution in rural catchments, Australia

This paper assesses the impact and quantifies the relative contribution of stormwater runoff (diffuse pollution sources) and point pollution sources on the quality of receiving water in the urban catchment of Orange. The study results were employed to develop management strategies to control stormwater pollution at the catchment level. The Orange urban catchment has experienced moderate to high levels of pollution in terms of nutrients (P and N), suspended solids (SS), heavy metals, fecal coliforms, and, to a lesser extent, salinity (TDS). Treated sewage effluent (point source) contributed, on average, 5% SS, 29% total nitrogen (TN) and 41% total phosphorous (TP). The nutrient yield per unit area was 2-31-folds higher than those reported for other Australian urban catchments. The overall contribution of the urban sources accounted for 93% and 94% of the TP and TN mass loads, respectively. In contrast, stormwater pollution in coastal urban catchments, that have similar population and land use, is dominated by rural diffuse sources contributing 81-99% of nutrient mass loads. This striking difference is attributed largely to the position of the catchment with respect to the hydrological system. Orange urban catchment is situated at the headwater of its river system and as such rural runoff into the urban part of the catchment was limited. The coastal catchments, on the other hand, are located at the end of their river systems and thus rural inflow into the urban area is substantially higher than those in upland catchments. This comparative assessment may suggest that the relative impact, per capita, of urban stormwater pollution on the receiving water is more significant in the upland catchments than in the coastal catchments. A stormwater management plan (SMP), consisting of structural and non-structural strategies, was developed to control stormwater pollution and enhance the quality of receiving water.

Sediment budget analysis of slope–channel coupling and in-channel sediment storage in an upland catchment, southeastern Australia

Slope–channel coupling and in-channel sediment storage can be important factors that influence sediment delivery through catchments. Sediment budgets offer an appropriate means to assess the role of these factors by quantifying the various components in the catchment sediment transfer system. In this study a fine (< 63 µm) sediment budget was developed for a 1.64-km 2 gullied upland catchment in southeastern Australia. A process-based approach was adopted that involved detailed monitoring of hillslope and bank erosion, channel change, and suspended sediment output in conjunction with USLE-based hillslope erosion estimation and sediment source tracing using 137Cs and 210Pb ex. The sediment budget developed from these datasets indicated channel banks accounted for an estimated 80% of total sediment inputs. Valley floor and in-channel sediment storage accounted for 53% of inputs, with the remaining 47% being discharged from the catchment outlet. Estimated hillslope sediment input to channels was low (5.7 t) for the study period compared to channel bank input (41.6 t). However an estimated 56% of eroded hillslope sediment reached channels, suggesting a greater level of coupling between the two subsystems than was apparent from comparison of sediment source inputs. Evidently the interpretation of variability in catchment sediment yield is largely dependent on the dynamics of sediment supply and storage in channels in response to patterns of rainfall and discharge. This was reflected in the sediment delivery ratios (SDR) for individual measurement intervals, which ranged from 1 to 153%. Bank sediment supply during low rainfall periods was reduced but ongoing from subaerial processes delivering sediment to channels, resulting in net accumulation on the channel bed with insufficient flow to transport this material to the catchment outlet. Following the higher flow period in spring of the first year of monitoring, the sediment supplied to channels during this interval was removed as well as an estimated 72% of the sediment accumulated on the channel bed since the start of the study period. Given the seasonal and drought-dependent variability in storage and delivery, the period of monitoring may have an important influence on the overall SDR. On the basis of these findings, this study highlights the potential importance of sediment dynamics in channels for determining contemporary sediment yields from small gullied upland catchments in southeastern Australia.

Link between DOC in near surface peat and stream water in an upland catchment

Hydrologic transport of dissolved organic carbon (DOC) from peat soils may differ to organo-mineral soils in how they responded to changes in flow, because of differences in soil profile and hydrology. In well-drained organo-mineral soils, low flow is through the lower mineral layer where DOC is absorbed and high flow is through the upper organic layer where DOC is produced. DOC concentrations in streams draining organo-mineral soils typically increase with flow. In saturated peat soils, both high and low flows are through an organic layer where DOC is produced. Therefore, DOC in stream water draining peat may not increase in response to changes in flow as there is no switch in flow path between a mineral and organic layer. To verify this, we conducted a high-resolution monitoring study of soil and stream water at an upland peat catchment in northern England. Our data showed a strong positive correlation between DOC concentrations at − 1 and − 5 cm depth and stream water, and weaker correlations between concentrations at − 20 to − 50 cm depth and stream water. Although near surface organic material appears to be the key source of stream water DOC in both peat and organo-mineral soils, we observed a negative correlation between stream flow and DOC concentrations instead of a positive correlation as DOC released from organic layers during low and high flow was diluted by rainfall. The differences in DOC transport processes between peat and organo-mineral soils have different implications for our understanding of long-term changes in DOC exports. While increased rainfall may cause an increase in DOC flux from peat due to an increase in water volume, it may cause a decrease in concentrations. This response is contrary to expected changes in DOC exports from organo-mineral soils, where increase rainfall is likely to result in an increase in flux and concentration.

A mass balance approach to quantifying Pb storage and fluxes in an upland catchment of the Peak District, north‐central England

AbstractA mass balance model of the main Pb stores and fluxes for a typical organic‐rich upland catchment in the Peak District, UK, has been produced. The model, based on the Howden reservoir catchment, reveals that the majority of Pb in the catchment is stored within the soil (approximately 8·63 t km−2). Soil Pb levels are extremely high and can only be explained as the result of centuries of atmospheric Pb deposition from surrounding urban–industrial conurbations, and mining and smelting activity within the Peak District National Park. The atmospheric Pb flux onto the Howden catchment is approximately 107 kg a−1. The aquatic Pb flux is estimated at between 29·9 and 71·7 kg a−1; thus, at present, catchment soils are acting as a sink for Pb pollution. The Howden reservoir acts as a secondary store for Pb eroded and leached from catchment soils, with approximately 80% re‐deposited in its sediments. It is estimated that 2·3% of the catchment soil Pb pool has been retained in the reservoir sediments over its 91 year lifespan.Although the catchment is currently acting as a Pb sink, the rate of change in the soil Pb pool is very small. Future change in climate or deposition chemistry could, however, transform catchment soils into a significant source of Pb to the aquatic environment and water supply. Copyright © 2008 John Wiley &amp; Sons, Ltd.