Unusual Abundances Research Articles

Multiple methods of diet assessment reveal differences in Atlantic puffin diet between ages, breeding stages, and years

IntroductionAtlantic puffin (Fratercula arctica, hereafter “puffin”) reproductive success in the Gulf of Maine (GoM) has declined following a recent oceanographic regime shift that has led to rapid warming and increasingly frequent marine heatwaves. Concurrent changes in both the regional forage fish community and puffin chick diets and provisioning rates suggest that inadequate prey resources may be driving this decline. Traditional, noninvasive methods of diet assessment, however, are unable to determine seabird diet at many age classes and breeding stages.MethodsTo determine what prey GoM puffins were feeding on during two years of marine heatwave conditions, we assessed puffin diet using two complementary methods: traditional, observational methods that utilize bill-load photography and emerging methods employing fecal DNA metabarcoding. We then examined the effect of methodology, age, breeding stage, and year on puffin diet composition. ResultsWe identified a strong correlation between the composition of chick diet as estimated through traditional and emerging methods, supporting the interpretation of DNA relative read abundance as a quantitative metric of diet composition. Both methods identified the same dominant prey groups yet metabarcoding identified a greater number of species and offered higher taxonomic resolution. Additionally, metabarcoding revealed adult puffin diet during the incubation period for the first time. Although puffin adults and chicks fed on many of the same prey types, adults consumed a greater variety of taxa and consumed more low quality prey types than they provisioned chicks.DiscussionFor both age classes, diet varied both between and within years, likely reflecting changes in the local forage fish community in response to environmental variability. Puffins exploited unusual abundances of typically-uncommon prey during these two years of marine heatwave conditions, yet low puffin productivity suggests the observed dietary plasticity was not fully able to compensate for apparent prey shortages. Continued refinement of molecular methods and the interpretation of the data they provide will enable better assessments of how seabirds of diverse ages and breeding stages are adapting to changing prey communities.

Spectroscopic Determination of C, N, and O Abundances of Solar-analog Stars Based on the Lines of Hydride Molecules

Photospheric C, N, and O abundances of 118 solar-analog stars were determined by applying the synthetic-fitting analysis to their spectra in the blue or near-UV region comprising lines of CH, NH, and OH molecules, with an aim of clarifying the behaviors of these abundances in comparison with [Fe/H]. It turned out that, in the range of −0.6 ≲ [Fe/H] ≲ +0.3, [C/Fe] shows a marginally increasing tendency with decreasing [Fe/H] with a slight upturn around [Fe/H] ∼ 0, [N/Fe] tends to somewhat decrease toward lower [Fe/H], and [O/Fe] systematically increases (and thus [C/O] decreases) with a decrease in [Fe/H]. While these results are qualitatively consistent with previous determinations mostly based on atomic lines, the distribution centers of these [C/Fe], [N/Fe], and [O/Fe] at the near-solar metallicity are slightly negative by several hundredths of dex, which is interpreted as due to unusual solar abundances possibly related to the planetary formation of our solar system. However, clear anomalies are not observed in the [C, N, O/Fe] ratios of planet-host stars. Three out of four very Be-deficient stars were found to show anomalous [C/Fe] or [N/Fe] which may be due to mass transfer from the evolved companion, though its relation to the Be depletion mechanism is still unclear.

Unusual Abundances from Planetary System Material Polluting the White Dwarf G238-44

Ultraviolet and optical spectra of the hydrogen-dominated atmosphere white dwarf star G238-44 obtained with FUSE, Keck/HIRES, HST/COS, and HST/STIS reveal 10 elements heavier than helium: C, N, O, Mg, Al, Si, P, S, Ca, and Fe. G238-44 is only the third white dwarf with nitrogen detected in its atmosphere from polluting planetary system material. Keck/HIRES data taken on 11 nights over 24 yr show no evidence for variation in the equivalent width of measured absorption lines, suggesting stable and continuous accretion from a circumstellar reservoir. From measured abundances and limits on other elements, we find an anomalous abundance pattern and evidence for the presence of metallic iron. If the pollution is from a single parent body, then it would have no known counterpart within the solar system. If we allow for two distinct parent bodies, then we can reproduce the observed abundances with a mix of iron-rich Mercury-like material and an analog of an icy Kuiper Belt object with a respective mass ratio of 1.7:1. Such compositionally disparate objects would provide chemical evidence for both rocky and icy bodies in an exoplanetary system and would be indicative of a planetary system so strongly perturbed that G238-44 is able to capture both asteroid and Kuiper Belt–analog bodies near-simultaneously within its <100 Myr cooling age.

LAMOST J045019.27 + 394758.7, with peculiar abundances of N, Na, V, Zn, is possibly a Sculptor dwarf galaxy escapee

ABSTRACT We present the results of the high-resolution (R ∼ 60 000) spectroscopic analysis of the star LAMOSTJ045019.27 + 394758.7 (hereafter J045) from the list of carbon stars of LAMOST DR2. From our analysis, we find that J045 does not exhibit the spectral characteristics of carbon stars. It is found to be a metal-poor ([Fe/H] = −1.05) giant that shows very unusual elemental abundances, particularly for N, Na, V, and Zn. J045 shows α-elements (Mg, Si, Ca) with near-solar values (&amp;lt;[α/Fe]&amp;gt; = 0.09) in contrast to Galactic stars that show [α/Fe] in the range 0.2–0.3 dex. In J045, Sc and Ti are under abundant with [X/Fe] ≤ −0.25. Vanadium gives [V/Fe] = 0.51 and zinc is under-abundant with [Zn/Fe] = −0.62. The object exhibits near-solar abundances for Sr, Y, Ba, Pr, and Sm. The La is marginally enhanced, and Ce and Nd are marginally under-abundant in J045. With [Ba/Eu] = −0.38, the object falls into the category of neutron-capture rich r-I stars. The estimated abundances of various elements show that the observed abundance pattern is not compatible with the abundances characteristic of Galactic metal-poor stars but matches quite closely with the abundance pattern of Sculptor Dwarf galaxy stars of similar metallicity. Based on the above observational evidences, we suggest that the object is a possible Sculptor Dwarf Galaxy escapee.

A SUBLIME 3D Model for Cometary Coma Emission: The Hypervolatile-rich Comet C/2016 R2 (PanSTARRS)

Abstract The coma of comet C/2016 R2 (PanSTARRS) is one of the most chemically peculiar ever observed, in particular due to its extremely high CO/H2O and N 2 + /H2O ratios, and unusual trace volatile abundances. However, the complex shape of its CO emission lines, as well as uncertainties in the coma structure and excitation, has lead to ambiguities in the total CO production rate. We performed high-resolution, spatially, spectrally, and temporally resolved CO observations using the James Clerk Maxwell Telescope and Submillimeter Array to elucidate the outgassing behavior of C/2016 R2. Results are analyzed using a new, time-dependent, three-dimensional radiative transfer code (SUBlimating gases in LIME; SUBLIME, based on the open-source version of the LIne Modeling Engine), incorporating for the first time, accurate state-to-state collisional rate coefficients for the CO–CO system. The total CO production rate was found to be in the range of (3.8 − 7.6) × 1028 s−1 between 2018 January 13 and February 1 (at r H = 2.8–2.9 au), with a mean value of (5.3 ± 0.6) × 1028 s−1. The emission is concentrated in a near-sunward jet, with a half-opening angle of ∼62° and an outflow velocity of 0.51 ± 0.01 km s−1, compared to 0.25 ± 0.01 km s−1 in the ambient (and nightside) coma. Evidence was also found for an extended source of CO emission, possibly due to icy grain sublimation around 1.2 × 105 km from the nucleus. Based on the coma molecular abundances, we propose that the nucleus ices of C/2016 R2 can be divided into a rapidly sublimating apolar phase, rich in CO, CO2, N2, and CH3OH, and a predominantly frozen (or less abundant), polar phase containing more H2O, CH4, H2CO, and HCN.

Spectral analysis of cool white dwarfs accreting from planetary systems: from the ultraviolet to the optical

ABSTRACT The accretion of planetary debris into the atmospheres of white dwarfs leads to the presence of metal lines in their spectra. Cool metal-rich white dwarfs, which left the main sequence many Gyr ago, allow the study of the remnants of the oldest planetary systems. Despite their low effective temperatures (Teff), a non-negligible amount of their flux is emitted in the near-ultraviolet (NUV), where many overlapping metal lines can potentially be detected. We have observed three metal-rich cool white dwarfs with the Space Telescope Imaging Spectrograph (STIS) onboard the Hubble Space Telescope, and compare the results determined from the NUV data with those previously derived from the analysis of optical spectroscopy. For two of the white dwarfs, SDSS J1038−0036 and SDSS J1535+1247, we find reasonable agreement with our previous analysis and the new combined fit of optical and NUV data. For the third object, SDSS J0956+5912, including the STIS data leads to a 10 per cent lower Teff, though we do not identify a convincing explanation for this discrepancy. The unusual abundances found for SDSS J0956+5912 suggest that the accreted parent body was composed largely of water ice and magnesium silicates, and with a mass of up to ≃ 2 × 1025 g. Furthermore, SDSS J0956+5912 shows likely traces of atomic carbon in the NUV. While molecular carbon is not observed in the optical, we demonstrate that the large quantity of metals accreted by SDSS J0956+5912 can suppress the C2 molecular bands, indicating that planetary accretion can convert DQ stars into DZs (and not DQZs/DZQs).

APOGEE-2 Discovery of a Large Population of Relatively High-metallicity Globular Cluster Debris

Abstract We report the discovery of a new, chemically distinct population of relatively high-metallicity ([Fe/H] &gt; −0.7) red giant stars with super-solar [N/Fe] (≳+0.75) identified within the bulge, disk, and halo of the Milky Way. This sample of stars was observed during the second phase of the Apache Point Observatory Galactic Evolution Experiment (APOGEE-2); the spectra of these stars are part of the seventeenth Data Release (DR 17) of the Sloan Digital Sky Survey. We hypothesize that this newly identified population was formed in a variety of progenitors, and is likely made up of either fully or partially destroyed metal-rich globular clusters, which we refer to as globular cluster debris (GCD), identified by their unusual photospheric nitrogen abundances. It is likely that some of the GCD stars were probable members of the Gaia–Enceladus–Sausage accretion event, along with clusters formed in situ.

The ASAS-SN catalogue of variable stars IX: The spectroscopic properties of Galactic variable stars

ABSTRACT The All-Sky Automated Survey for Supernovae provides long baseline (∼4 yr) V-band light curves for sources brighter than V≲ 17 mag across the whole sky. We produced V-band light curves for a total of ∼61.5 million sources and systematically searched these sources for variability. We identified ∼426 000 variables, including ∼219 000 new discoveries. Most (${\sim }74{ per\ cent}$) of our discoveries are in the Southern hemisphere. Here, we use spectroscopic information from LAMOST, GALAH, RAVE, and APOGEE to study the physical and chemical properties of these variables. We find that metal-poor eclipsing binaries have orbital periods that are shorter than metal-rich systems at fixed temperature. We identified rotational variables on the main-sequence, red giant branch, and the red clump. A substantial fraction (${\gtrsim }80{ per\ cent}$) of the rotating giants have large $v$rot or large near-ultraviolet excesses also indicative of fast rotation. The rotational variables have unusual abundances suggestive of analysis problems. Semiregular variables tend to be lower metallicity ($\rm [Fe/H]{\sim }-0.5$) than most giant stars. We find that the APOGEE DR16 temperatures of oxygen-rich semiregular variables are strongly correlated with the WRP − WJK colour index for $\rm T_{eff}\lesssim 3800$ K. Using abundance measurements from APOGEE DR16, we find evidence for Mg and N enrichment in the semiregular variables. We find that the Aluminum abundances of the semiregular variables are strongly correlated with the pulsation period, where the variables with $\rm P\gtrsim 60$ d are significantly depleted in Al.

Phosphorus-rich stars with unusual abundances are challenging theoretical predictions

Almost all chemical elements have been made by nucleosynthetic reactions in various kind of stars and have been accumulated along our cosmic history. Among those elements, the origin of phosphorus is of extreme interest because it is known to be essential for life such as we know on Earth. However, current models of (Galactic) chemical evolution under-predict the phosphorus we observe in our Solar System. Here we report the discovery of 15 phosphorus-rich stars with unusual overabundances of O, Mg, Si, Al, and Ce. Phosphorus-rich stars likely inherit their peculiar chemistry from another nearby stellar source but their intriguing chemical abundance pattern challenge the present stellar nucleosynthesis theoretical predictions. Specific effects such as rotation or advanced nucleosynthesis in convective-reactive regions in massive stars represent the most promising alternatives to explain the existence of phosphorus-rich stars. The phosphorus-rich stars progenitors may significantly contribute to the phosphorus present on Earth today.

Atomic Data Needs in Astrophysics: The Galactic Center “Scandium Mystery”

Investigating the Galactic center offers unique insights into the buildup and history of our Galaxy and is a stepping stone to understand galaxies in a larger context. It is reasonable to expect that the stars found in the Galactic center might have a different composition compared to stars found in the local neighborhood around the Sun. It is therefore quite exciting when recently there were reports of unusual neutral scandium, yttrium, and vanadium abundances found in the Galactic center stars, compared to local neighborhood stars. To explain the scandium abundances in the Galactic center, we turn to recent laboratory measurements and theoretical calculations done on the atomic oscillator strengths of neutral scandium lines in the near infrared. We combine these with measurements of the hyper fine splitting of neutral scandium. We show how these results can be used to explain the reported unusual scandium abundances and conclude that in this respect, the environment of the Galactic center is not that different from the environment in the local neighborhood around the sun.

Discovery of a nitrogen-enhanced mildly metal-poor binary system: Possible evidence for pollution from an extinct AGB star

We report the serendipitous discovery of a nitrogen-rich, mildly metal-poor ([Fe/H] = −1.08) giant star in a single-lined spectroscopic binary system found in the SDSS-IV Apache Point Observatory Galactic Evolution Experiment (APOGEE-2) survey, Data Release 14 (DR14). Previous work has assumed that two percent of halo giants with unusual elemental abundances have been evaporated from globular clusters, but other origins for their abundance signatures, including binary mass transfer, must also be explored. We present the results of an abundance reanalysis of the APOGEE-2 high-resolution near-infrared spectrum of 2M12451043+1217401 with the Brussels Automatic Stellar Parameter (BACCHUS) automated spectral analysis code. We manually re-derive the main element families, namely light elements (C, N), elements (O, Mg, Si), the iron-peak element (Fe), s-process element (Ce), and light odd-Z element (Al). Our analysis confirms the N-rich nature of 2M12451043+1217401, which has a [N/Fe] ratio of +0.69, and shows that the abundances of C and Al are slightly discrepant from those of a typical mildly metal-poor red giant branch star, but exhibit Mg, Si, O and s-process abundances (Ce) of typical field stars. We also detect a particularly large variability in the radial velocity of this star over the period of the APOGEE-2 observations; the most likely orbit fit to the radial velocity data has a period of 730.89 ± 106.86 days, a velocity semi-amplitude of 9.92 ± 0.14 km s−1, and an eccentricity of ∼0.1276 ± 0.1174. These data support the hypothesis of a binary companion, which has probably been polluted by a now-extinct asymptotic giant branch star.

Interpretation and diversity of exoplanetary material orbiting white dwarfs

ABSTRACT Nine metal-polluted white dwarfs are observed with medium-resolution optical spectroscopy, where photospheric abundances are determined and interpreted by comparison with Solar system objects. An improved method for making such comparisons is presented, which overcomes potential weaknesses of prior analyses, with numerous sources of error considered to highlight the limitations on interpretation. The stars are inferred to be accreting rocky, volatile-poor asteroidal materials with origins in differentiated bodies, in line with the consensus model. The most heavily polluted star in the sample has 14 metals detected, and appears to be accreting material from a rocky planetesimal, whose composition is mantle-like with a small Fe–Ni core component. Some unusual abundances are present. One star is strongly depleted in Ca, while two others show Na abundances elevated above bulk-Earth abundances; it is speculated that either the latter reflect diversity in the formation conditions of the source material, or they are traces of past accretion events. Another star shows clear signs that accretion ceased around 5 Myr ago, causing Mg to dominate the photospheric abundances, as it has the longest diffusion time of the observed elements. Observing such post-accretion systems allows constraints to be placed on models of the accretion process.

A Sub-damped Lyα Absorber with Unusual Abundances: Evidence of Gas Recycling in a Low-redshift Galaxy Group

Abstract Using Hubble Space Telescope/Space Telescope Imaging Spectrograph G140M spectroscopy, we investigate an absorption-line system at z = 0.07489 in the spectrum of the quasi-stellar object PG 1543+489 (z QSO = 0.401). The sightline passes within ρ = 66 kpc of an edge-on disk galaxy at a similar redshift, but the galaxy belongs to a group with four other galaxies within ρ = 160 kpc. We detect H i [log N(H i/cm−2) = 19.12 ± 0.04] as well as N i, Mg ii, Si ii, and Si iii, from which we measure a gas-phase abundance of [N/H] = −1.0 ± 0.1. Photoionization models indicate that the nitrogen-to-silicon relative abundance is solar, yet magnesium is underabundant by a factor of ≈2. We also report spatially resolved emission-line spectroscopy of the nearby galaxy, and we extract its rotation curve. The galaxy’s metallicity is ≈8× higher than [N/H] in the absorber, and interestingly, the absorber velocities suggest that the gas at ρ = 66 kpc is corotating with the galaxy’s stellar disk, possibly with an inflow component. These characteristics could indicate that this sub-damped Lyα absorber system arises in a “cold-accretion” flow. However, the absorber abundance patterns are peculiar. We hypothesize that the gas was ejected from its galaxy of origin (or perhaps is a result of tidal debris from interactions between the group galaxies) with a solar nitrogen abundance, but that subsequently mixed with (and was diluted by) gas in the circumgalactic medium or group. If the gas is bound to the nearby galaxy, this system may be an example of the gas “recycling” predicted by theoretical galaxy simulations. Our hypothesis is testable with future observations.

Long-term X-ray variation of the colliding-wind Wolf–Rayet binary WR 125

WR 125 is considered as a Colliding Wind Wolf-rayet Binary (CWWB), from which the most recent infrared flux increase was reported between 1990 and 1993. We observed the object four times from November 2016 to May 2017 with Swift and XMM-Newton, and carried out a precise X-ray spectral study for the first time. There were hardly any changes of the fluxes and spectral shapes for half a year, and the absorption-corrected luminosity was 3.0e+33 erg/s in the 0.5 - 10.0 keV range at a distance of 4.1 kpc. The hydrogen column density was higher than that expected from the interstellar absorption, thus the X-ray spectra were probably absorbed by the WR wind. The energy spectrum was successfully modeled by a collisional equilibrium plasma emission, where both the plasma and the absorbing wind have unusual elemental abundances particular to the WR stars. In 1981, the Einstein satellite clearly detected X-rays from WR 125, whereas the ROSAT satellite hardly detected X-rays in 1991, when the binary was probably around the periastron passage. We discuss possible causes for the unexpectedly low soft X-ray flux near the periastron.

Unusual Isotopic Abundances in a Fully Convective Stellar Binary

Abstract Low-mass M dwarfs represent the most common outcome of star formation, but their complex emergent spectra hinder detailed studies of their composition and initial formation. The measurement of isotopic ratios is a key tool that has been used to unlock the formation of our solar system, the Sun, and the nuclear processes within more massive stars. We observed GJ 745AB, two M dwarfs orbiting in a wide binary, with the NASA Infrared Telescope Facility/iSHELL spectrograph. Our spectroscopy of CO in these stars at the 4.7 μm fundamental and 2.3 μm first-overtone rovibrational bandheads reveals , , and in their photospheres. Because the stars are fully convective, the atomic constituents of these isotopologues should be uniformly mixed throughout the stars’ interiors. We find that in these M dwarfs, both / and / greatly exceed the Solar values. These measurements cannot be explained solely by models of Galactic chemical evolution, but require that the stars formed from an interstellar medium significantly enriched by material ejected from an exploding core-collapse supernova. These isotopic measurements complement the elemental abundances provided by large-scale spectroscopic surveys, and open a new window onto studies of Galactic evolution, stellar populations, and individual systems.

On the discovery of K-enhanced and possibly Mg-depleted stars throughout the Milky Way

Stars with unusual elemental abundances offer clues about rare astrophysical events or nucleosynthetic pathways. Stars with significantly depleted magnesium and enhanced potassium ([Mg/Fe] < -0.5; [K/Fe] > 1) have to date only been found in the massive globular cluster NGC 2419 and, to a lesser extent, NGC 2808. The origin of this abundance signature remains unknown, as does the reason for its apparent exclusivity to these two globular clusters. Here we present 112 field stars, identified from 454,180 LAMOST giants, that show significantly enhanced [K/Fe] and possibly depleted [Mg/Fe] abundance ratios. Our sample spans a wide range of metallicities (-1.5 < [Fe/H] < 0.3), yet none show abundance ratios of [K/Fe] or [Mg/Fe] that are as extreme as those observed in NGC 2419. If confirmed, the identified sample of stars represents evidence that the nucleosynthetic process producing the anomalous abundances ratios of [K/Fe] and [Mg/Fe] probably occurs at a wide range of metallicities. This would suggest that pollution scenarios that are limited to early epochs (such as Population III supernovae) are an unlikely explanation, although they cannot be ruled out entirely. This sample is expected to help guide modelling attempts to explain the origin of the Mg-K abundance signature.

Massive shelf dense water flow influences plankton community structure and particle transport over long distance

Dense waters (DW) formation in shelf areas and their cascading off the shelf break play a major role in ventilating deep waters, thus potentially affecting ecosystem functioning and biogeochemical cycles. However, whether DW flow across shelves may affect the composition and structure of plankton communities down to the seafloor and the particles transport over long distances has not been fully investigated. Following the 2012 north Adriatic Sea cold outbreak, DW masses were intercepted at ca. 460 km south the area of origin and compared to resident ones in term of plankton biomass partitioning (pico to micro size) and phytoplankton species composition. Results indicated a relatively higher contribution of heterotrophs in DW than in deep resident water masses, probably as result of DW-mediated advection of fresh organic matter available to consumers. DWs showed unusual high abundances of Skeletonema sp., a diatom that bloomed in the north Adriatic during DW formation. The Lagrangian numerical model set up on this diatom confirmed that DW flow could be an important mechanism for plankton/particles export to deep waters. We conclude that the predicted climate-induced variability in DW formation events could have the potential to affect the ecosystem functioning of the deeper part of the Mediterranean basin, even at significant distance from generation sites.

Super-solar Metallicity Stars in the Galactic Center Nuclear Star Cluster: Unusual Sc, V, and Y Abundances

Abstract We present adaptive-optics assisted near-infrared high-spectral-resolution observations of late-type giants in the nuclear star cluster of the Milky Way. The metallicity and elemental abundance measurements of these stars offer us an opportunity to understand the formation and evolution of the nuclear star cluster. In addition, their proximity to the supermassive black hole (∼0.5 pc) offers a unique probe of the star formation and chemical enrichment in this extreme environment. We observed two stars identified by medium spectral-resolution observations as potentially having very high metallicities. We use spectral-template fitting with the PHOENIX grid and Bayesian inference to simultaneously constrain the overall metallicity, [M/H], alpha-element abundance [α/Fe], effective temperature, and surface gravity of these stars. We find that one of the stars has very high metallicity ([M/H] &gt; 0.6) and the other is slightly above solar metallicity. Both Galactic center stars have lines from scandium (Sc), vanadium (V), and yttrium (Y) that are much stronger than allowed by the PHOENIX grid. We find, using the spectral synthesis code Spectroscopy Made Easy, that [Sc/Fe] may be an order of magnitude above solar. For comparison, we also observed an empirical calibrator in NGC 6791, the highest metallicity cluster known ([M/H] ∼ 0.4). Most lines are well matched between the calibrator and the Galactic center stars, except for Sc, V, and Y, which confirms that their abundances must be anomalously high in these stars. These unusual abundances, which may be a unique signature of nuclear star clusters, offer an opportunity to test models of chemical enrichment in this region.

ABUNDANCE DERIVATIONS FOR THE SECONDARY STARS IN CATACLYSMIC VARIABLES FROM NEAR-INFRARED SPECTROSCOPY

ABSTRACT We derive metallicities for 41 cataclysmic variables (CVs) from near-infrared spectroscopy. We use synthetic spectra that cover the 0.8 μm ≤ λ ≤ 2.5 μm bandpass to ascertain the value of [Fe/H] for CVs with K-type donors, while also deriving abundances for other elements. Using calibrations for determining [Fe/H] from the K-band spectra of M-dwarfs, we derive more precise values for for the secondaries in the shortest period CVs, and examine whether they have carbon deficits. In general, the donor stars in CVs have subsolar metallicities. We confirm carbon deficits for a large number of systems. CVs with orbital periods &gt;5 hr are most likely to have unusual abundances. We identify four CVs with CO emission. We use phase-resolved spectra to ascertain the mass and radius of the donor in U Gem. The secondary star in U Gem appears to have a lower apparent gravity than a main sequence star of its spectral type. Applying this result to other CVs, we find that the later-than-expected spectral types observed for many CV donors are mostly an effect of inclination. All of the magnetic CVs, except the low accretion rate polar MQ Dra, have donors with subsolar metallicities. We find that two systems with unusual spectra, EI Psc and QZ Ser, have large excesses of sodium and extreme deficits of carbon. Synthetic spectra that have a reduced abundance of hydrogen are best able to explain the spectra of these two objects.

IR excesses around nearby Lambda Boo stars are caused by debris discs rather than ISM bow waves

Lambda Boo stars are predominately A-type stars with solar abundant C, N, O, and S, but up to 2 dex underabundances of refractory elements. The stars' unusual surface abundances could be due to a selective accretion of volatile gas over dust. It has been proposed that there is a correlation between the Lambda Boo phenomenon and IR-excesses which are the result of a debris disk or interstellar medium (ISM) interaction providing the accreting material. We observe 70 or 100 and 160 $\mu$m excess emission around 9 confirmed Lambda Boo stars with the Herschel Space Observatory, to differentiate whether the dust emission is from a debris disk or an ISM bow wave. We find that 3/9 stars observed host well resolved debris disks. While the remaining 6/9 are not resolved, they are inconsistent with an ISM bow wave based on the dust emission being more compact for its temperature and predicted bow wave models produce hotter emission than what is observed. We find the incidence of bright IR-excesses around Lambda Boo stars is higher than normal A-stars. To explain this given our observations, we explore Poynting-Robertson (PR) drag as a mechanism of accretion from a debris disk but find it insufficient. As an alternative, we propose the correlation is due to higher dynamical activity in the disks currently underway. Large impacts of planetesimals or a higher influx of comets could provide enough volatile gas for accretion. Further study on the transport of circumstellar material in relation to the abundance anomalies are required to explain the phenomenon through external accretion.