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Published in last 50 years
S,S-Dimethyl Dithiocarbonate: A Convenient Reagent for the Synthesis of Symmetrical and Unsymmetrical Ureas.
It is shown that monoalkyl and unsymmetrical dialkyl ureas, and alkyl carbamates, are preparable via a two-step sequence involving tetrahydropyran-2-yl isocyanate, and a primary or secondary amine, or an alcohol, respectively.
A New Synthesis of Ureas. IV. The Preparation of Unsymmetrical Ureas from Carbon Monoxide, Sulfur, and Amines