The study of the processes of unsteady heat conduction, the calculation of the parameters of media under conditions of unsteady heat conduction of the latter is an important direction, which is used in applied problems of heat and mass transfer. When solving a mathematical model under various boundary conditions, there is a problem of the reliability of numerical calculations, therefore there is a need to solve the mathematical model by an analytical method. For example, a mathematical model of heat and mass transfer processes in a heat accumulator during its charging and discharging is solved analytically by the Green's function method, similarly, a mathematical model of heat carrier heating processes in solar collectors is solved. The specific definition of the Green's function corresponds to a specific problem in mathematical physics. Green's function contains complete information about the studied equation, and with its help one can construct a solution for any inhomogeneity. The development of the method of Green's functions for solving boundary value problems of unsteady heat conduction of generalized type on the basis of the Maxwell-Cattaneo-Lykov law is proposed. On the basis of the introduced Green's function of the differential equation, the Green's function of the boundary value problem is determined. Green's function of a boundary value problem is considered as an element of the set of Green's functions of an equation or a system of equations. Boundary conditions are formulated in accordance with the specified law. When considering specific problems, in a number of cases, it is expedient to transfer the integral form of writing boundary conditions of the second or third kind into a differential form equivalent to the integral one. The proposed integral relations for analytical solutions of boundary value problems of unsteady heat conduction for equations of hyperbolic type. Necessary and sufficient conditions for the existence and uniqueness of the Green's function of the boundary value problem are given and its analytical representation is given in terms of the fundamental system of solutions and boundary conditions. Boundary conditions are formulated for hyperbolic models of heat conduction in integral and differential forms. Boundary value problems for a semi-infinite region are considered, analytical solutions are obtained, their analysis is carried out, and temperature jumps at the heat wave front are calculated. Illustrative problems for a semi-infinite region are considered, and the heat wake region and the unperturbed region are described.