The unstable plume mode of hollow cathodes should be avoided in practical applications because it severely degrades the overall cathode lifetime. In this study, we investigate the spot-plume transition and plasma stability characteristics of an unused segmented lanthanum hexaboride emitter. The expansion of the unstable plume mode region is observed during a discharge experiment. Subsequently, the segmented emitter is retrieved, the inner surface of the emitter is observed, and the work function on the surface is measured at room temperature. The emitter surface exhibits color variations with oxygen and carbon detection. The downstream edge shows the original purple color and almost no degradation in the work function. The high temperature in this region promotes the desorption of carbon and oxygen. In the spot mode, this region mainly contributes to thermionic electron emission; therefore, the discharge voltage in the spot mode does not change during the discharge experiment. Carbon or carbide is detected in the middle of the axial direction on the emitter surface, where the surface temperature is not sufficiently high to desorb carbon during discharge. Based on the surface analysis results, the dominant substance in the region where carbon is detected was lanthanum carbide. An increase in the work function is indicated in the region, which appears to increase the plasma instability. According to previous studies, an increase in the work function results in a rise in the potential in the emitter, and an increase in the electron temperature in the outside plume region induces the plasma instability. Further investigation is needed to understand the mechanism connecting the rise in the work function and the rise in the electron temperature in the plume region.
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