This paper consists of two parts: 1.(1) We consider the two-phase (fusion) Stefan problem for a semi-infinite material with one unknown thermal coefficient. We have an overspecified condition of type k2∂T2∂x(0, t) = −ho/√t with ho > 0 on the fixed face x = 0 of the phase-change material. We obtain: (i) if ρ is unknown, then the corresponding free boundary problem always has a unique solution of the Neumann type; (ii) if one of the remaining five coefficients is unknown, then the corresponding free boundary problem has a unique solution of the Neumann type iff a complementary condition is verified.2.(2) We consider the inverse two-phase (fusion) Stefan problem for a semi-infinite material with an overspecified condition k2∂T2∂x(0, t) = −ho/√t with ho > 0 on the fixed face and with two unknown thermal coefficients.We obtain: (i) if (p, k2) are unknown, the corresponding moving boundary problem always has a unique solution of the Neumann type; (ii) if (l, k1), (l, c1) or (, k1, c1) are unknown, the corresponding moving boundary problem has infinite solutions whenever the complementary conditions are verified; (iii) in the remaining eleven cases, the corresponding moving boundary problem has a unique solution of the Neumann type iff complementary conditions are verified. (1) We consider the two-phase (fusion) Stefan problem for a semi-infinite material with one unknown thermal coefficient. We have an overspecified condition of type k2∂T2∂x(0, t) = −ho/√t with ho > 0 on the fixed face x = 0 of the phase-change material. We obtain: (i) if ρ is unknown, then the corresponding free boundary problem always has a unique solution of the Neumann type; (ii) if one of the remaining five coefficients is unknown, then the corresponding free boundary problem has a unique solution of the Neumann type iff a complementary condition is verified. (2) We consider the inverse two-phase (fusion) Stefan problem for a semi-infinite material with an overspecified condition k2∂T2∂x(0, t) = −ho/√t with ho > 0 on the fixed face and with two unknown thermal coefficients. We obtain: (i) if (p, k2) are unknown, the corresponding moving boundary problem always has a unique solution of the Neumann type; (ii) if (l, k1), (l, c1) or (, k1, c1) are unknown, the corresponding moving boundary problem has infinite solutions whenever the complementary conditions are verified; (iii) in the remaining eleven cases, the corresponding moving boundary problem has a unique solution of the Neumann type iff complementary conditions are verified. Moreover, in both parts, we obtain formulas for the unknown thermal coefficients.
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