Blind passive signal detection is a challenging endeavor since typically there is no prior knowledge of the transmitted signal. This becomes further complicated in time-spreading distortion (TSD) underwater channels [R. Rashid, E. Zhang, A. Abdi, and Z. H. Michalopoulou, “Theoretical and experimental multi-sensor signal detection in time spreading distortion underwater channels,” Proc. Oceans (2022)], where due to the presence of multiple propagation paths, the unknown signal is convolved with an unknown channel impulse response. In this paper, we introduce and develop a blind passive signal detection method, using dictionary learning [M. Sadeghi, M. Babaie-Zadeh, and C. Jutten, “Dictionary learning for sparse representation: A novel approach,” IEEE Signal Process. Lett. (2013)]. In our blind passive signal detection method, we use the received data to estimate the unknown signal, and also to separate it from the unknown channel impulse response. We have conducted simulations and underwater experiments, to generate receiver operating characteristic curves, to study the performance of the proposed method. The high detection probabilities of the blind method, compared to the replica correlation integration method—that needs to know the transmitted signal for matched filtering—demonstrate the usefulness of the method for passive detection of unknown signals in unknown TSD channels.