By considering the concept of the modified Chaplygin gas (MCG) as a single fluid model unifying dark energy and dark matter, we construct a static, spherically charged black hole (BH) solution in the framework of General Relativity. The P–V criticality of the charged anti-de Sitter (AdS) BH with a surrounding MCG is explored in the context of the extended phase space, where the negative cosmological constant operates as a thermodynamical pressure. This critical behavior shows that the small/large BH phase transition is analogous to the van der Waals liquid/gas phase transition. Accordingly, along the P–V phase spaces, we derive the BH equations of state and then numerically evaluate the corresponding critical quantities. Similarly, critical exponents are identified, along with outcomes demonstrating the scaling behavior of thermodynamic quantities near criticality to a universal class. The use of geometrothermodynamic (GT) tools finally offers a new perspective on the discovery of the critical phase transition point. At this stage, we apply a class of GT tools, such as Weinhold, Ruppeiner, HPEM, and Quevedo classes I and II. The findings are therefore non-trivial, as each GT class metric captures at least either the physical limitation point or the phase transition critical point. Overall, this paper provides a detailed study of the critical behavior of the charged AdS BH with surrounding MCG.
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