Unidirectional Processes Research Articles

2D nitrogen-doped porous carbon nanosheets derived from cellulose nanofiber/silk fibroin nanohybrid cellular monoliths with promising capacitive performance

2D nitrogen-doped porous carbon nanosheets are prepared from cellulose nanofiber/silk fibroin nanohybrid cellular monoliths via unidirectional freeze-shaping technique, carbonization, and CO2 activation processes. The micromorphology of the cellulose nanofiber/silk fibroin nanohybrid cellular monoliths can be effectively controlled by simply changing the content of silk fibroin. The 2D nitrogen-doped porous carbon nanosheets (NPCN-X, X represents the content of silk fibroin), inherited from different cellular monolith, show a distinct micromorphology. The NPCN-50 exhibits the best electrochemical performance due to its 2D nanostructure, abundant multi-scale through pores, high specific surface area (about 1882 m2 g−1), and appropriate surface N/O-doping. The largest gravimetric capacitance value is about 329.9 F g−1 at a current density of 0.25 A g−1. The energy density reaches as high as 37.5 Wh kg−1 at a power density of 186.3 W kg−1. The NPCN-50 also exhibits excellent electrochemical cycling stability.

Interplay between the electrostatic membrane potential and conformational changes in membrane proteins.

Transmembrane electrostatic membrane potential is a major energy source of the cell. Importantly, it determines the structure as well as function of charge-carrying membrane proteins. Here, we discuss the relationship between membrane potential and membrane proteins, in particular whether the conformation of these proteins is integrally connected to the membrane potential. Together, these concepts provide a framework for rationalizing the types of conformational changes that have been observed in membrane proteins and for better understanding the electrostatic effects of the membrane potential on both reversible as well as unidirectional dynamic processes of membrane proteins.

Impact of dense bottom water on a continental shelf: An example from the SW Adriatic margin

Dense shelf waters have been recognised as a key factor in transporting sediment and organic matter across continental slopes; however, the effect of their circulation on continental shelves is still overlooked. The Adriatic Sea is one of the areas in the Mediterranean where dense shelf water forms and flows as a bottom-hugging gravity current along the continental margin. A fraction of this dense water passes beyond the shelf break and flows downslope through cascading, while a large (lighter and faster) portion remains on the shelf, with a principal vein flowing between 80 and 120 m water depth.This paper presents the 3D shape, internal architecture and sediment facies of a variety of large-scale sedimentary features detected on the continental shelf and at the shelf edge, between 50 and 300 m water depth. These features include giant comet marks, large flute-shaped scours, muddy sediment waves, very large dunes with superimposed bedforms, active and relict sand ridges and shelf edge contourites. Both erosional and depositional features show an overall internal geometry and orientation consistent with water masses flowing southward, and are located where flows become accelerated by topographic constraints and deviated by the curvature of the shelf edge.In this study, the morphology and seismic stratigraphic structure of large-scale bedforms are investigated in an effort to place constraints on bedform evolution and preservation, especially as predictive tools for sand resource management, and to bring new evidence of the interaction between unidirectional hydrodynamic processes and seafloor dynamics on the shelf.

The Effect of Membrane Structure Prepared from Carboxymethyl Cellulose and Cellulose Nanofibrils for Cationic Dye Removal

Water-stable and eco-friendly membranes were fabricated from carboxymethyl cellulose (CMC) acting as anionic adsorbent and cellulose nanofibrils (CNFs) as strengthening filler by solvent- and unidirectional freeze-casting processes, both supported with simultaneous citric acid (CA) mediated cross-linking. Spectroscopic, thermogravimetric and potentiometric titration techniques were applied to evaluate the efficacy of the cross-linking as well as to quantify the processing-dependant surface charge. In addition, the CMC/CNF assembling and membrane porosity were identified microscopically as the combinatorial effect of components ratio and the applied fabrication technique. Finally, the membrane’s cationic dyes adsorption capacity and kinetic were evaluated depending on the dyes ionization constants, solution pH, and the contact time using batch equilibrium experiment, and further evaluated for filtration performance at optimal pH. The resulting, freeze-casted membranes demonstrate anisotropic to isotropic and highly (> 90%) porous structures with gradient pore sizes (from few nm up to 200 µm range). This provides relatively high and stable flux rates (150–190 kL/m2 h MPa) with ~ 100% cationic dye adsorption, fast dynamic (8.536–5.446 kg/g min) and capacity (1828–1398 g/kg), which highlight their potential in dead-end filtration technologies without need for additional separation step. The similar dye adsorption capacity was assessed for denser and nano-porous (< 50 nm) solvent-casted membranes, however, with much lower and time-declining flux rates (100–10 L/m2 h MPa), demonstrating their potential usage in spiral wound-cross-flow modules. Both types of membranes anyhow showed high dye removal capacity (≥ 90%) even after 4th (solvent-casted) and 50th (freeze-casted) reusing cycle, present a high-value alternative to commercial activated carbons or other bio-nano-absorbents.

Evolutionary Characteristics of Morphogenetic Types of Moss Litter in Swamp Spruce Forests

We identified five types of moss litter in a green moss–hypnum spruce forest during alloevolution (metamorphosis) according to the habitat: peat, peaty, reduced peaty, high-ash peaty, and reduced high-ash peaty litters. During the self-development (autoevolution) of the litter, the transformation of plant matter occurs in four stages: (1) leaf (background) stage, (2) peat- and peaty-fermentative stage (browning, destruction of the litter fall and formation of platy macroaggregates), (3) humified-fermentative stage (formation of colloidal humus plasma and granular organogenic macroaggregates), and (4) the black mold humus stage (formation of colloidal humus plasma and organo-mineral humus nutty and granular macroaggregates). It was found that peat litters undergo only the initial stages of plant substrate transformation (1 and 2). The genetic profile of peaty litter is formed by three unidirectional processes (1, 2, and 3). High-ash peaty litter undergoes all the stages of plant matter transformation. The reduced analogs of peaty and high-ash peaty litter bedding were found to bypass the transitional stage 2.

Linguistic diversification as a long-term effect of asymmetric priming

Abstract This paper tries to narrow the gap between diachronic linguistics and research on population dynamics by presenting a mathematical model corroborating the notion that the cognitive mechanism of asymmetric priming can account for observable tendencies in language change. The asymmetric-priming hypothesis asserts that items with more substance are more likely to prime items with less substance than the reverse. Although these effects operate on a very short time scale (e.g. within an utterance) it has been argued that their long-term effect might be reductionist, unidirectional processes in language change. In this paper, we study a mathematical model of the interaction of linguistic items that differ in their formal substance, showing that, in addition to reductionist effects, asymmetric priming also results in diversification and stable coexistence of two formally related variants. The model will be applied to phenomena in the sublexical as well as the lexical domain.

Entropic Distance for Nonlinear Master Equation

More and more works deal with statistical systems far from equilibrium, dominated by unidirectional stochastic processes, augmented by rare resets. We analyze the construction of the entropic distance measure appropriate for such dynamics. We demonstrate that a power-like nonlinearity in the state probability in the master equation naturally leads to the Tsallis (Havrda–Charvát, Aczél–Daróczy) q-entropy formula in the context of seeking for the maximal entropy state at stationarity. A few possible applications of a certain simple and linear master equation to phenomena studied in statistical physics are listed at the end.

Moderate-to-severe obstructive sleep apnea is associated with telomere lengthening.

Obstructive sleep apnea (OSA) is associated with cardiometabolic diseases. Telomere shortening is linked to hypertension, diabetes mellitus, and cardiovascular diseases. Because these conditions are highly prevalent in OSA, we hypothesized that telomere length (TL) would be reduced in OSA patients. We identified 106 OSA and 104 non-OSA subjects who underwent polysomnography evaluation. Quantitative PCR was used to measure telomere length in genomic DNA isolated from peripheral blood samples. The association between OSA and TL was determined using unadjusted and adjusted linear models. There was no difference in TL between the OSA and non-OSA (control) group. However, we observed a J-shaped relationship between TL and OSA severity: the longest TL in moderate-to-severe OSA [4,918 ± 230 (SD) bp] and the shortest TL in mild OSA (4,735 ± 145 bp). Mean TL in moderate-to-severe OSA was significantly longer than in the control group after adjustment for age, sex, body mass index, hypertension, dyslipidemia, and depression (β = 96.0, 95% confidence interval: 15.4-176.6, P = 0.020). In conclusion, moderate-to-severe OSA is associated with telomere lengthening. Our findings support the idea that changes in TL are not unidirectional processes, such that telomere shortening occurs with age and disease but may be prolonged in moderate-to-severe OSA.NEW & NOTEWORTHY Here, we show that moderate-to-severe obstructive sleep apnea is associated with longer telomeres, independent of age and cardiovascular risk factors, challenging the hypothesis that telomere shortening is a unidirectional process related to age/disease. A better understanding of the mechanisms underlying telomere dynamics may identify targets for therapeutic intervention in cardiovascular aging/other chronic diseases.

Molecular Orientation of Conjugated Polymer Chains in Nanostructures and Thin Films: Review of Processes and Application to Optoelectronics

Semiconducting polymers are composed of elongated conjugated polymer backbones and side chains with high solubility and mechanical properties. The combination of these two features results in a high processability and a potential to orient the conjugated backbones in thin films and nanofibers. The thin films and nanofibers are usually composed of highly crystalline (high charge transport) and amorphous parts. Orientation of conjugated polymer can result in enhanced charge transport or optical properties as it induces increased crystallinity or preferential orientation of the crystallites. After summarizing the potential strategies to exploit molecular order in conjugated polymer based optoelectronic devices, we will review some of the fabrication processes to induce molecular orientation. In particular, we will review the cases involving molecular and interfacial interactions, unidirectional deposition processes, electrospinning, and postdeposition mechanical treatments. The studies presented here clearly demonstrate that process-controlled molecular orientation of the conjugated polymer chains can result in high device performances (mobilities over 40 cm2·V−1·s−1 and solar cells with efficiencies over 10%). Furthermore, the peculiar interactions between molecularly oriented polymers and polarized light have the potential not only to generate low-cost and low energy consumption polarized light sources but also to fabricate innovative devices such as solar cell integrated LCDs or bipolarized LEDs.

The possible source of the causal time arrow in geo-historical explanations

My argument in this article, will be that nature, in general, and human nature in particular, suggests that, in principle, it is possible to derive the causal time arrow from several physical time arrows existing in nature and appearing to be unidirectional and irreversible phenomena. A more concrete argument will be that the assumption of a causal time arrow to which geologists resort in all geo-historical explanations, apparently originates in geo-historical time arrows concealed in unidirectional and irreversible physical-geological processes. I will illustrate this claim with a few examples of geo-historical explanations in the theory of plate tectonics, most of which are based on irreversible geo-physical processes. My final argument is a broader, of an epistemological nature, according to which the causal time arrow assumption used in logical-causative explanations in everyday life and in science, apparently “derives” in a way from the geo-historical time arrow. I will base this argument on the causal relationship and mutual influence that occurs in nature between geo-historical and evolutionary processes in animals, including developmental processes of the human brain and mind. From this reductionist argument, nicely integrated in the framework of evolutionary epistemology (EEM), it is possible to derive a wider naturalistic argument according to which, on principle, the laws of geo-historical physics can be reduced to the laws of logic and causality.

LIN28: A Stem Cell Factor with a Key Role in Pediatric Tumor Formation.

Differentiation and development are normally unidirectional processes in which progenitor/stem cells differentiate into more mature cells. Transformation of adult cells into cancer cells is accompanied in many cases by dedifferentiation of the adult cell, while differentiation failure of progenitor cells can result in the formation of unique type of cancers called pediatric cancer. LIN28A and its paralog LIN28B are pluripotent genes that are expressed mainly in stem/progenitor cells. Since the first identification of LIN28 in mammals, numerous studies demonstrated the general oncogenic features of these genes. In this review, we emphasize the unique role of LIN28 in pediatric tumor formation. We show, based on comprehensive literature screen and analysis of published microarray data, that LIN28 expression in pediatric tumors is even more common than in adult tumors, and discuss the possibility that in the case of pediatric cancers, LIN28 acts by preventing normal development/differentiation rather than by transformation of mature cells into cancer cells. Overall, this review highlights the role of LIN28 as a bridge point between embryonic development, stem cell biology, and cancer.

Modeling of Age-Dependent Epileptogenesis by Differential Homeostatic Synaptic Scaling.

Homeostatic synaptic plasticity (HSP) has been implicated in the development of hyperexcitability and epileptic seizures following traumatic brain injury (TBI). Our in vivo experimental studies in cats revealed that the severity of TBI-mediated epileptogenesis depends on the age of the animal. To characterize mechanisms of these differences, we studied the properties of the TBI-induced epileptogenesis in a biophysically realistic cortical network model with dynamic ion concentrations. After deafferentation, which was induced by dissection of the afferent inputs, there was a reduction of the network activity and upregulation of excitatory connections leading to spontaneous spike-and-wave type seizures. When axonal sprouting was implemented, the seizure threshold increased in the model of young but not the older animals, which had slower or unidirectional homeostatic processes. Our study suggests that age-related changes in the HSP mechanisms are sufficient to explain the difference in the likelihood of seizure onset in young versus older animals. Significance statement: Traumatic brain injury (TBI) is one of the leading causes of intractable epilepsy. Likelihood of developing epilepsy and seizures following severe brain trauma has been shown to increase with age. Specific mechanisms of TBI-related epileptogenesis and how these mechanisms are affected by age remain to be understood. We test a hypothesis that the failure of homeostatic synaptic regulation, a slow negative feedback mechanism that maintains neural activity within a physiological range through activity-dependent modulation of synaptic strength, in older animals may augment TBI-induced epileptogenesis. Our results provide new insight into understanding this debilitating disorder and may lead to novel avenues for the development of effective treatments of TBI-induced epilepsy.

Getting the most out of family data with the R package fSRM.

Family research aims to explore family processes, but is often limited to the examination of unidirectional processes. As the behavior of 1 person has consequences that go beyond that individual, family functioning should be investigated in its full complexity. The social relations model (SRM; Kenny & La Voie, 1984) is a conceptual and analytical model that can disentangle family data from a round-robin design at 3 different levels: the individual level (actor and partner effects), the dyadic level (relationship effects), and the family level (family effect). Its statistical complexity may however be a hurdle for family researchers. The user-friendly R package fSRM performs almost automatically those rather complex SRM analyses and introduces new possibilities for assessing differences between SRM means and between SRM variances, both within and between groups of families. Using family data on negative processes, different type of research questions are formulated and corresponding analyses with fSRM are presented.

Electrostatics, hydration, and proton transfer dynamics in the membrane domain of respiratory complex I.

Complex I serves as the primary electron entry point into the mitochondrial and bacterial respiratory chains. It catalyzes the reduction of quinones by electron transfer from NADH, and couples this exergonic reaction to the translocation of protons against an electrochemical proton gradient. The membrane domain of the enzyme extends ∼180 Å from the site of quinone reduction to the most distant proton pathway. To elucidate possible mechanisms of the long-range proton-coupled electron transfer process, we perform large-scale atomistic molecular dynamics simulations of the membrane domain of complex I from Escherichia coli. We observe spontaneous hydration of a putative proton entry channel at the NuoN/K interface, which is sensitive to the protonation state of buried glutamic acid residues. In hybrid quantum mechanics/classical mechanics simulations, we find that the observed water wires support rapid proton transfer from the protein surface to the center of the membrane domain. To explore the functional relevance of the pseudosymmetric inverted-repeat structures of the antiporter-like subunits NuoL/M/N, we constructed a symmetry-related structure of a possible alternate-access state. In molecular dynamics simulations, we find the resulting structural changes to be metastable and reversible at the protein backbone level. However, the increased hydration induced by the conformational change persists, with water molecules establishing enhanced lateral connectivity and pathways for proton transfer between conserved ionizable residues along the center of the membrane domain. Overall, the observed water-gated transitions establish conduits for the unidirectional proton translocation processes, and provide a possible coupling mechanism for the energy transduction in complex I.

Assessing the biological activity of oil-contaminated soddy-podzolic soils with different textures

The respiratory activity features in oil-contaminated soddy-podzolic soils of different textures have been studied. Unidirectional processes occur in contaminated loamy and loamy sandy soddy-podzolic soils; their intensities depend on the soil parameters. The mineralization rates of the oil products and the activity of the microflora in loamy soils exceed the corresponding parameters for loamy sandy soils. The long-term impact of oil and its transformation products results in more important disturbances of the microbial community in light soils. It has been shown that light soils containing 9% oil require longer time periods or more intensive remediation measures for the restoration of soil microbial cenoses disturbed by the pollutant.

Exclusion of impurity particles in charged colloidal crystals.

Uniformly shaped, charged colloidal particles dispersed in water form ordered "crystal" structures when the interaction between the particles is sufficiently strong. Herein, we report the behavior of "impurity" particles, whose sizes and/or charge numbers are different from those of the bulk, on addition to the charged colloidal crystals. These impurities were excluded from the crystals during the homogeneous crystallization, crystal grain growth, and unidirectional crystallization processes. Such systems will be useful as models for studying the refinement of materials and crystal defects.

Bioinspired solar cell design: Organic thiols as rectifying electron transfer bridges in WS2/TiO2 nano solar cells

► Bioinspired WS 2 /TiO 2 nano solar cells treated with organic thiols are presented. ► An increase of the photocurrent efficiency by a factor of three is observed. ► Organic thiol bridges act as rectifying electronic elements. ► Unidirectional electron transfer is important for innovative solar cell applications. Nano solar cell materials cannot sustain imprinted thermodynamic potentials yielding electrical fields for a charge separation. They have, therefore, to rely on kinetic mechanisms for current rectification and energy conversion. It is shown that treatment of WS 2 nano-sheet sensitized TiO 2 -material with organic thiols increases the photocurrent efficiency at least three fold. They bind to the WS 2 via the thiol sulfur to produce a charged surface state, which converts into an efficient electron transfer bridge in presence of suitable electron donors. These thiol bridges essentially operate in anodic direction. Thus they increase both the photo induced chemical affinity, which is proportional to the photovoltage generated, and the interfacial reaction rate which is proportional to the photocurrent. The results underline the importance of studying unidirectional electron transfer processes for innovative solar cell applications.

Alignment of stone‐pavement clasts by unconcentrated overland flow – implications of numerical and physical modelling

ABSTRACTThe crucial role of stone pavements in arid environments for aeolian or alluvial processes and as numerical dating tools is increasingly acknowledged. This role is based on the assumption that stone pavements are stable landforms, formed gradually over time and predominantly by vertical processes. However, this is challenged by evidence of stone‐pavement clast reworking or burial. Bimodal, mostly slope aspect‐symmetrical clast orientation is a frequent phenomenon in various study areas. It implies that stone pavements may be influenced by unidirectional lateral processes besides vertical ones.Here, the finding of lateral processes contributing to stone‐pavement evolution is supported by numerical modelling and physical experiments. These unequivocally show that unconcentrated overland flow can transport clasts to form a closely packed stone mosaic with characteristics similar to those of natural stone pavements. The commonly observed length‐axes orientation angle of 40 ± 14° for natural stone‐pavement clasts is consistently reproduced by angle‐dependent force equilibrium. Monte Carlo runs confirm the natural scatter and allow characterization of the control parameters of clast orientation. The model explains up to 70% of the natural variance. It is further validated by flume experiments, which confirm model predictions of single object orientation angles. Experiments with multiple objects yield artificial stone pavements with properties similar to those found in the field.The unidirectional lateral process acting on natural stone pavements requires the presence of a vesicular horizon. This underlines the tight genetic coupling of this common epipedon feature and the clast cover. The presented findings highlight the role of stone pavements as process and environment proxies. However, stone pavements represent information since the last surface disturbance only. This has to be considered when using them as age indicators. Copyright © 2013 John Wiley &amp; Sons, Ltd.

Existence results for diffuse interface models describing phase separation and damage

In this paper, we analytically investigate multi-component Cahn–Hilliard and Allen–Cahn systems which are coupled with elasticity and uni-directional damage processes. The free energy of the system is of the form ∫Ω½Γ∇c : ∇c + ½|∇z|2+Wch(c)+Wel(e,c,z)dx with a polynomial or logarithmic chemical energy density Wch, an inhomogeneous elastic energy density Wel and a quadratic structure of the gradient of damage variable z. For the corresponding elastic Cahn–Hilliard and Allen–Cahn systems coupled with uni-directional damage processes, we present an appropriate notion of weak solutions and prove existence results based on certain regularization methods and a higher integrability result for strain e.

The Studies on Numerical Simulation of Unidirectional Solidification Process in 23t Steel Ingot

In this paper, by using the commercial finite-element software of ProCAST, unidirectional solidification processes in 23t steel ingot were simulated. Emphasis is placed on analysis of required time for complete solidification of steel ingot and temperature distribution about ingot and side wall during the solidification process. By comparing simulation values and measured values of side wall during the solidification process, the simulated results conclusively demonstrate that our developed model is feasible and valuable.