Undisturbed Sediment Cores Research Articles

A multi-proxy reconstruction of the late Holocene climate evolution in Lake Bolgoda, Sri Lanka

Palaeoclimate investigations in Sri Lanka have been rarely attempted despite being located directly in the path of the Inter Tropical Convergence Zone. In this study, a 4.1-m undisturbed sediment core was retrieved from the Bolgoda Lake situated in the western coast of Sri Lanka, and influenced by the strong southwest monsoons. Mollusc shells in the core were dated, and the age-depth model indicated a depositional history extending from 2941calyrBP to the present. Grain size, major and trace elements, total organic C and N content and stable C and N isotopes were analysed in freeze-dried sediments to reconstruct the palaeoclimate changes. The multi-proxy records in the core revealed four distinct zones that show distinct variations in physical and chemical conditions in the lake associated with climate change. Zone 1 (2941 to 2390calyrBP; 385–252cm) indicated the climate to be warm and humid with intense precipitation. The resulting high lake level helped in organic matter preservation in bottom sediments. Zone 2 (2390 to 1782calyrBP; 252–140cm) indicated an unstable dry period associated with weak precipitation. Consequently, low lake level and intense degradation of organic matter occurred in this zone. Zone 3 (1782 to 1299calyrBP; 140–60cm) indicated a resurgence of intense monsoon along with warm and humid conditions. Zone 4 (1299calyrBP to present; 60–0cm) indicated dry conditions with less intense monsoon, low lake level and extensive degradation of organic matter. Vascular plants were the predominant organic matter source into the lake during the late Holocene. In contrast, algal input was significant between 2390calyrBP and 2153calyrBP. The palaeoclimate evidences in this study showed an overall weakening trend of SW monsoon during the late Holocene, and this was consistent with changes happening in other locations as in southern and western India.

A push corer developed for retrieving high-resolution sediment cores from shallow waters

Shallow water environments are often difficult ones from which to recover undisturbed sediment cores, lending themselves to neither deep water sampling, nor techniques employed for wetland areas. The most simple and obvious way to obtain a core in water depths of less than 2 m is to drive a core tube directly into the sediments using some form of push rod or a percussion (hammer) device. A core driven by percussive methods, however, may be difficult to recover and sealing the tube may be problematic for retention of the sample. Here we describe a simple coring device designed for shallow water operation. The design contains elements of both deeper water gravity and directly driven push rod coring equipment. The device can recover cores up to about 1 m in length in water depths up to about 3–4 m deep. The sampling device has been tested over a number of years from diverse limnological settings (high and mid-Arctic lakes, temperate lakes) with consistently satisfactory results.

Depositional History of Coastal Plain Sediments, Southern Kerala, South West India

A 15.5 m long undisturbed sediment core were collected from the coastal plain of southern Kerala, India to study the micro-textural analysis of quartz grains to understand the fluvio-marine depositional environment. The down core variation of sediment between 0 m and 7 m shows medium to fine sand, 7 m to 10 m has sand-silt-clay, 10 m to 11 m clay which is hard and desiccated, and 11 m to 15.5 m contains silty clay rich in organic matter. The quartz surface micro-textural features shows conchoidal fractures, fracture plates, abrasion features and pits infers that the sediments undergone short period transportation and rapid deposition through mechanical processes in a fluvial regime under moderate to high-energy condition. Further, down the core the angularity of grains are reduced to become subrounded grains attributing to the recycled process with subaqueous solution activity. These processes can also lead to the development of linear branching-centipede solution features and oriented etch patterns. The sediments 11 m and 15.5 m depth exhibits corroded grain with solution pits and solutions crevasses indicating marine intervention followed by pressure solution, silica pellicle, silica plastering and dissolution etching features revealing prolonged digenesis deciphering the chemical processes under marine condition. Radiocarbon dating reveals that this coastal plain has undergone transgression-regression events during the last 40 kyrs BP depicting distinct textural characteristics of mechanical and chemical features reflecting the fluvio-marine depositional environment.

Oxygen, carbon, and nutrient exchanges at the sediment–water interface in the Mar Piccolo of Taranto (Ionian Sea, southern Italy)

In the shallow environment, the nutrient and carbon exchanges at the sediment-water interface contribute significantly to determine the trophic status of the whole water column. The intensity of the allochthonous input in a coastal environment subjected to strong anthropogenic pressures determines an increase in the benthic oxygen demand leading to depressed oxygen levels in the bottom waters. Anoxic conditions resulting from organic enrichment can enhance the exchange of nutrients between sediments and the overlying water. In the present study, carbon and nutrient fluxes at the sediment-water interface were measured at two experimental sites, one highly and one moderately contaminated, as reference point. In situ benthic flux measurements of dissolved species (O2, DIC, DOC, N-NO3 (-), N-NO2 (-), N-NH4 (+), P-PO4 (3-), Si-Si(OH)4, H2S) were conducted using benthic chambers. Furthermore, undisturbed sediment cores were collected for analyses of total and organic C, total N, and biopolymeric carbon (carbohydrates, proteins, and lipids) as well as of dissolved species in porewaters and supernatant in order to calculate the diffusive fluxes. The sediments were characterized by suboxic to anoxic conditions with redox values more negative in the highly contaminated site, which was also characterized by higher biopolymeric carbon content (most of all lipids), lower C/N ratios and generally higher diffusive fluxes, which could result in a higher release of contaminants. A great difference was observed between diffusive and in situ benthic fluxes suggesting the enhancing of fluxes by bioturbation and the occurrence of biogeochemically important processes at the sediment-water interface. The multi-contamination of both inorganic and organic pollutants, in the sediments of the Mar Piccolo of Taranto (declared SIN in 1998), potentially transferable to the water column and to the aquatic trophic chain, is of serious concern for its ecological relevance, also considering the widespread fishing and mussel farming activities in the area.

Effects of recirculation of seawater enriched in inorganic nitrogen on dissolved organic carbon processing in sandy seepage face sediments

Human activities are now the main source of bioavailable Nitrogen to Earth's ecosystems. Disruption of the N cycle can promote changes to the biogeochemical cycling of other elements in particular to the oxygen and carbon cycles. Nevertheless, information on how increasing Dissolved Inorganic Nitrogen (DIN) availability might affect the benthic processing of organic matter in coastal sandy sediments is currently unavailable. Here, we present a series of flow-through reactor experiments conducted with undisturbed sediment cores collected at an intertidal seepage face (Ria Formosa lagoon, SW Iberian Peninsula) in order to evaluate the effect of increasing DIN availability on benthic dissolved organic C (DOC) reactivity. Our results show that the metabolic activity of the benthic community can be a significant source of DOM to the porewater. Furthermore, in the absence of DIN, increasing porewater flow rates accelerated benthic DOM production and increased the recalcitrant nature of DOC transported across the sediment-water interface. In contrast, the co-occurrence of high DIN concentrations and high seepage velocities increased the microbial breakdown of organic material. Our results suggest that the availability of DIN in permeable seepage faces increases the net production of labile DOC, by enhancing the ability of the benthic microbial community to process refractory organic matter. Hence, we suggest that increasing DIN availability in coastal permeable sediments accelerates benthic organic C processing, promoting the release of more labile DOC to receiving water bodies.

Influence of suspended mussel lines on sediment erosion and resuspension in Lagune de la Grande Entrée, Îles-de-la-Madeleine, Québec, Canada

Downward fluxes of organically rich biodeposits under suspended mussel lines can cause benthic impacts such as changes in benthic community structure or microbial mat production. Quantifying sediment erosion in these coastal ecosystems is important for understanding how fluxes of organic matter and mussel biodeposits contribute to benthic–pelagic coupling. Critical shear velocity (u*crit), erosion rates and particle size distributions of resuspended sediment were measured at four stations distributed along a transect perpendicular to a mussel farm in Lagune de la Grande Entree, Iles-de-la-Madeleine (Quebec, Canada). Stations were selected underneath the outer-most mussel line (0 m) and at distances of 15, 30 m and at a reference station (500 m) further along the transect. Shear velocity was measured using a calibrated portable Particle Erosion Simulator, also referred to as the BEAST (Benthic Environmental Assessment Sediment Tool). Undisturbed sediment cores obtained by divers were exposed to shear stress to compare differences between stations. Erosion sequences indicated no significant differences in u*crit between stations, but there were significant differences in erosion rates beneath mussel lines compared to other stations. Erosion rates were the highest in cores from beneath mussel lines, but paradoxically had the lowest u*crit. Mean erosion rates at u*crit varied between 25 and 47 g m− 2 min− 1 and critical erosion thresholds varied between 1.58 and 1.73 cm s− 1, which compare with intensive mussel culture sites elsewhere in eastern Canada. Significant differences existed in biotic and abiotic properties of sediments which could explain variation in maximum erosion rates within and between stations. Particle sizes measured by videography of resuspended sediment at different shear velocities ranged from 0.2 to 3.0 mm. Quantifying sediment erosion from intact marine sediments helps to improve our mechanistic understanding of these processes, and the BEAST further contributes to predictive capability in benthic–pelagic coupling modeling.

Impacts of Ocean Acidification on Sediment Processes in Shallow Waters of the Arctic Ocean

Despite the important roles of shallow-water sediments in global biogeochemical cycling, the effects of ocean acidification on sedimentary processes have received relatively little attention. As high-latitude cold waters can absorb more CO2 and usually have a lower buffering capacity than warmer waters, acidification rates in these areas are faster than those in sub-tropical regions. The present study investigates the effects of ocean acidification on sediment composition, processes and sediment-water fluxes in an Arctic coastal system. Undisturbed sediment cores, exempt of large dwelling organisms, were collected, incubated for a period of 14 days, and subject to a gradient of pCO2 covering the range of values projected for the end of the century. On five occasions during the experimental period, the sediment cores were isolated for flux measurements (oxygen, alkalinity, dissolved inorganic carbon, ammonium, nitrate, nitrite, phosphate and silicate). At the end of the experimental period, denitrification rates were measured and sediment samples were taken at several depth intervals for solid-phase analyses. Most of the parameters and processes (i.e. mineralization, denitrification) investigated showed no relationship with the overlying seawater pH, suggesting that ocean acidification will have limited impacts on the microbial activity and associated sediment-water fluxes on Arctic shelves, in the absence of active bio-irrigating organisms. Only following a pH decrease of 1 pH unit, not foreseen in the coming 300 years, significant enhancements of calcium carbonate dissolution and anammox rates were observed. Longer-term experiments on different sediment types are still required to confirm the limited impact of ocean acidification on shallow Arctic sediment processes as observed in this study.

Temperature dependent redox zonation and attenuation of wastewater-derived organic micropollutants in the hyporheic zone

The hyporheic zone - a spatially fluctuating ecotone connecting surface water and groundwater - is considered to be highly reactive with regard to the attenuation of organic micropollutants. In the course of the presented study an undisturbed sediment core was taken from the infiltration zone of a bank filtration site in Berlin and operated under controlled laboratory conditions with wastewater-influenced surface water at two different temperatures, simulating winter and summer conditions. The aim was to evaluate the fate of site-relevant micropollutants, namely metoprolol, iopromide, diclofenac, carbamazepine, acesulfame, tolyltriazole, benzotriazole, phenazone and two phenazone type metabolites, within the first meter of infiltration dependent on the prevailing temperature. A change in temperature resulted in a development of significantly distinct redox conditions. Both temperature dependencies and related redox dependencies were identified for all micropollutants except for benzotriazole and carbamazepine, which behaved persistent under all conditions. For the remaining compounds degradation rate constants generally decreased from warm and oxic/penoxic/suboxic over cold and oxic/penoxic to warm and manganese reducing (transition zone). Individual degradation rate constants ranged from 0 (e.g. diclofenac, acesulfame and tolyltriazole in the transition zone) to 1.4×10−4s−1 for metoprolol under warm conditions within the oxic to suboxic zone.

Reconstruction of the Vegetation and Environment during Different Climatic and Sociotechnical Conditions of the Last 3000 Years in Southwestern Hungary

Sedimentary basins such as Lake Baláta in Southwestern Hungary provide information about the development of lake-bog systems, the climate change through time and the environment of the surrounding area. The present study provides combined palynological, anthracological and macrobotanical data regarding climatic, vegetation and hydrological changes of a protected area for the last 3000 years. Lake Baláta is a sedimentary basin developed in a wind-blown yardang system in Southwestern Hungary. Due to its deeper location and the higher groundwater-level, the boggy lake functioned as a sediment catch. Geological drilling with an auger head drill provided an undisturbed sediment core. During the laboratory analysis different methods, such as sedimentological, geochemical, macrofossil, pollen and charcoal analysis were applied. The different stages and the evolution of the lake-bog system and the vegetation around the lake could be reconstructed and human impact was detected for the last 3000 years. Human impact and the transformation of vegetation was detected from the Early Iron Age (900/800 BC). Human impact reached its maximum during the 10th and 12th centuries when extent plant cultivation and grazing field zones were created. Climate change, increasing precipitation and consequently forest regeneration started in the 13th and 14th centuries. Parallel to this human impact decreased in the study area that indicates the reduction of the population and agrarian activity. Later at the beginning of the 15th century human impact increased again and remained significant until to the 16th century.

Response of an Arctic Sediment Nitrogen Cycling Community to Increased CO2

Ocean acidification influences sediment/water nitrogen fluxes, possibly by impacting on the microbial process of ammonia oxidation. To investigate this further, undisturbed sediment cores collected from Ny Alesund harbour (Svalbard) were incubated with seawater adjusted to CO2 concentrations of 380, 540, 760, 1,120 and 3,000 µatm. DNA and RNA were extracted from the sediment surface after 14 days' exposure and the abundance of bacterial and archaeal ammonia oxidising (amoA) genes and transcripts quantified using quantitative polymerase chain reaction. While there was no change to the abundance of bacterial amoA genes, an increase to 760 µatm pCO2 reduced the abundance of bacterial amoA transcripts by 65 %, and this was accompanied by a shift in the composition of the active community. In contrast, archaeal amoA gene and transcript abundance both doubled at 3,000 µatm, with an increase in species richness also apparent. This suggests that ammonia oxidising bacteria and archaea in marine sediments have different pH optima, and the impact of elevated CO2 on N cycling may be dependent on the relative abundances of these two major microbial groups. Further evidence of a shift in the balance of key N cycling groups was also evident: the abundance of nirS-type denitrifier transcripts decreased alongside bacterial amoA transcripts, indicating that NO3− produced by bacterial nitrification fuelled denitrification. An increase in the abundance of Planctomycete-specific 16S rRNA, the vast majority of which grouped with known anammox bacteria, was also apparent at 3,000 µatm pCO2. This could indicate a possible shift from coupled nitrification–denitrification to anammox activity at elevated CO2.

Colloid mobilization in an undisturbed sediment core under semiarid recharge rates

The semiarid US Department of Energy Hanford site has a deep vadose zone with low recharge rates. Contaminants originating from nuclear waste processing are expected to move slowly through the vadose zone. The movement of certain contaminants can be facilitated by colloids. We hypothesized that the low recharge rates and low water contents in semiarid regions, however, tend to inhibit movement of colloidal particles, thereby reducing the risk for colloid‐facilitated contaminant transport. The goal of this study was to investigate whether in situ natural colloids can be mobilized and transported in undisturbed, deep vadose zone sediments at the Hanford site under typical, semiarid recharge rates. We sampled an undisturbed sediment core (i.d. 50 cm, 59.5 cm height) from a depth of 17 m below ground at the Hanford 200 Area. The core was set up as a laboratory lysimeter and exposed to an infiltration rate of 18 mm/yr by applying simulated pore water onto the surface. Particle concentrations were quantified in the column outflow, and selected samples were examined microscopically and for elemental composition (transmission electron microscopy and energy dispersive X‐ray). Measured water contents and potentials were used to calibrate a numerical model (HYDRUS‐1D), which was then applied to simulate colloid mobilization from the sediment core. During 5.3 years of monitoring, natural colloids like silicates, aluminosilicates, and Fe‐oxides were observed in the core outflow, indicating the continuous mobilization of in situ colloids. The total amount of particles mobilized during 5.3 years corresponded to 1.1% of the total dispersible colloids inside the core. Comparison of the amounts of colloids released with weathering rates suggests that mineral weathering can be a major source of the mobilized colloids. The fitted colloid release rate coefficient was 6 to 7 orders of magnitude smaller than coefficients reported from previous studies, where disturbed Hanford sediments and higher flow rates were used. Our findings demonstrate that even under low recharge rates and water contents typical for semiarid, deep vadose zone sediments, particles can continuously be mobilized, although the total mass of particles is low.

Effect of a physical disturbance event on deep-sea nematode community structure and ecosystem function

Numerous studies have been conducted on the effect of physical disturbance on shallow water benthic communities, but there is a paucity of data from deep-sea environments. We conducted a laboratory experiment using undisturbed sediment cores from Chatham Rise (water depth=345m), Southwest Pacific, to investigate the effects of a physical disturbance event (resuspension of surface sediments) on sediment characteristics (sediment grain size, pigment content), nematode community attributes (abundance, diversity, community structure) and ecosystem function (sediment community oxygen consumption (SCOC)) over a period of 9days. Disturbance did not have any noticeable impact on sediment characteristics, SCOC, or nematode species richness, but led to changes in vertical distribution patterns and shifts in nematode community structure. The magnitude of disturbance-related effects was, however, much smaller than the effect of sediment depth (0–1, 1–3, and 3–5cm), and the main impact of disturbance on nematode vertical distribution patterns and community structure appeared to be related to a vertical re-shuffling of nematodes in the sediments rather than mortality. We did not observe substantial increases in the abundance of nematode genera generally regarded as disturbance-tolerant, such as Sabatieria. The worst-affected species belongs to the Stilbonematinae, a group of typically long and slender nematodes that may be easily damaged by physical disturbance. The limited impact of physical disturbance on benthic community structure and function suggests that the Chatham Rise nematode community is relatively resilient to sediment resuspension. This resilience may have arisen from frequent exposure to disturbance in the field (e.g., from strong currents), or may be a more widespread feature of nematode communities.

Measurement of sediment oxygen demand for modeling the dissolved oxygen distribution in a Subalpine lake

Sediment oxygen demand (SOD) is believed to be an important process affecting dissolved oxygen (DO) concentrations and has become an integral part of modeling dissolved oxygen (DO) in surface water bodies. Because no SOD data are measured at specific study sites, it is common for researchers to take SOD values from the literature for use in DO modeling. This paper focuses on an approach for measuring sediment oxygen demand in the laboratory using undisturbed sediment core samples in the Yuan-Yang Lake (YYL) of north-central Taiwan. The measured SOD values among six sampling stations were within the range of 0.06 to 4.50 g/m2/day at a temperature of 20°C. The ordinary kriging method was then applied to map the spatial distribution of the monthly average SOD values, which were incorporated into a three-dimensional water quality model for simulating the dissolved oxygen distribution of the lake. The simulation results accurately reflect the field-measured DO concentrations. Model sensitivity analyses were also conducted with increasing and decreasing 30% SOD values based on the monthly average SOD in the spatial distribution. The simulated results reveal that SOD had a significant impact on the DO concentrations in the lake. The present work, with its field measurements and numerical modeling, will provide assistance in lake water quality management. Key words: Sediment oxygen demand, dissolved oxygen, measurement, water quality model, kriging, Yuan-Yang Lake.

Macrobenthic biodiversity and oxygen uptake in estuarine systems: the example of the Seine estuary

Bioturbation is a major process influencing the functioning of benthic ecosystems. Although controlled experiments with species in monoculture or in artificial combinations have increased the knowledge about the role of biological diversity on geochemical processes, specific interactions have been neglected, making the extrapolation of experimental results to natural systems difficult. In this context, the main objective of this study was to measure the effects of a whole natural macrobenthic community on benthic oxygen uptake. The relationships between macrofauna and oxygen uptakes were investigated in the estuarine system of the Seine, France, during the winter and fall according to the variability of river discharge. Four undisturbed sediment cores with associated macrofauna and overlying water were sampled at nine subtidal stations in order to perform whole core incubations and measure total oxygen uptake (TOU). Moreover, values of diffusive oxygen uptake (DOU) were obtained using microelectrode profiling and fauna-mediated oxygen uptake (FOU) was calculated as the difference between TOU and DOU. FOUs were thus linked to macrofaunal parameters; both traditional (species richness, abundance and biomass) and functional (trophic guilds and bioturbation modes). The average FOU (±SD) ranged from 170 ± 36 to 1,324 ± 701 μmol m−2 h−1, and values represented 33 to 89 % of TOU. Each of the traditional macrofauna parameters had a significant and positive correlation with FOU. In addition, abundance, biomass and species number of some functional groups (e.g. suspension feeders and biodiffusors) were also correlated to FOU, supporting the diversity–stability hypothesis of McArthur (Ecology 36:533–536, 1955). Nevertheless, the relationship between FOU and other functional groups such as conveyors illustrated the idiosyncratic nature of this hypothesis, underlining the difficulty of clearly identifying the role of a macrofaunal community on oxygen exchanges at the sediment–water interface. Our results confirm the importance of functional biodiversity on mineralization processes as well as the need to take into account the whole community. They also suggest that future studies should focus on the functional consequences of species loss and the potential resilience of the communities as a way to maintain ecosystem processes.

210Pb sediment radiochronology: An integrated formulation and classification of dating models

Environmental archives, such as sediments, banded corals and tree rings, are widely used to reconstruct past environmental conditions of ecosystems. In particular, 210Pb has been used during more than 4 decades, through dating of undisturbed sediment cores, to study ecosystem changes during the last 100yr. Since its inception, diverse dating models have been proposed, developed, used and validated in numerous environments, but their nomenclature and formulation is not homogenous. In this work we emphasize that conceptual models used to date undisturbed sediment cores can be deduced from a single fundamental equation, which relates excess 210Pb concentration in sediment, its flux to the sediment surface and mass accumulation rate. From this equation, models were consistently named based on the main hypothesis used and, using a unified and logical nomenclature, dating equations were derived in detail. We applied in detail most of the described models to a sediment core from Mexico and uncertainty expressions were also included. Finally, some recommendations to use the models are proposed. We believe that this work can facilitate the use of 210Pb as a tool to date sediment cores in a more homogeneous way.

An Integrated Approach to the Assessment of Pollutant Delivery Chronologies to Impacted Areas: Hg in the Augusta Bay (Italy)

Assessing pollution levels and trends in heavily impacted environments is important but hardly achievable due to the difficulty of recovering suitable undisturbed sediment records. An integrated approach is here presented to solve this kind of problem. It was adopted in the Augusta Bay (Italy) for the study of Hg historical inputs and present trends. Archive information on dredging and mud disposal, together with bathymetry and high-resolution seismic profiles, were used to identify suitable sampling sites. Undisturbed sediment cores were collected in the port and bay. Sediments were analyzed for depth distributions of radiotracers ((210)Pb and (137)Cs), Hg, and main sediment parameters (magnetic susceptibility, grain size, dry bulk density, mineralogy, and organic carbon and nitrogen contents). Hexachlorobenzene (HCB) was also analyzed as an additional time tracer, since its production history in the area was well-known. Results show that peak Hg contamination (up to 575 mg·kg(-1)) was reached in the 1970s. Technological improvements and waste treatment in the following years determined a consistent decrease, but high concentrations still affect surficial sediments (0.25-92 mg·kg(-1)). Hg-HCB correlation suggests that this situation is likely the effect of resuspension and redistribution of deep sediments by dredging and naval traffic.

Monitoring sediment oxygen demand for assessment of dissolved oxygen distribution in river

Sediment oxygen demand (SOD) has become an integral part of modeling dissolved oxygen (DO) within surface water bodies. Because very few data on SOD are available, it is common for modeler to take SOD values from literature for use within DO models. SOD is such an important parameter in modeling DO that this approach may lead to erroneous results. This paper reported on developing an approach for monitoring sediment oxygen demand conducted with undisturbed sediment core samples, where the measured results were incorporated into a water quality model for simulating and assessing dissolved oxygen distribution in the Xindian River of northern Taiwan. The measured results indicate that a higher freshwater discharge results in a lower SOD. Throughout a 1-year observation in 2004, the measured SOD ranged from 0.367 to 1.246 g/m(2)/day at the temperature of 20°C. The mean values of the measured SOD at each station were adopted in a vertical two-dimensional water quality model to simulate the DO distribution along the Xindian River. The simulating results accurately depict the field-measured DO distribution during the low and high flow conditions. Model sensitivity analyses were also conducted with increasing and decreasing SOD values for the low and high flow conditions and revealed that SOD had a significant impact on the DO distribution along the Xindian River. The present work combined with field measurements and numerical simulation should assist in river water quality management.

Inherent mineralization of 2,6-dichlorobenzamide (BAM) in unsaturated zone and aquifers – Effect of initial concentrations and adaptation

The dichlobenil metabolite BAM (2,6-dichlorobenzamide) is frequently detected in aquifers e.g. in Denmark despite the mother compound dichlobenil was banned here since 1997. BAM mineralization was investigated at environmentally relevant concentrations in sediment samples. Undisturbed sediment cores with known dichlobenil application were collected from topsoil to 8.5 m below surface resulting in 57 samples hereof 4 aquifer samples. Mineralization was only substantial (>10%) in the uppermost meter of the unsaturated zone. Microbial adaptation, observed as faster mineralization in pre-exposed than in pristine sediments from the same location, was only evident in sandy sediment where dichlobenil was still present, but not in clayey sediments. Higher initial concentrations (1–5000 μg/kg) did not stimulate mineralization in pristine clayey or sandy sediments, or in pre-exposed sand. However, in pre-exposed clay mineralization was stimulated at high concentrations. Furthermore BAM was for the first time mineralized in aerobic aquifer sediments from different BAM-contaminated groundwater locations.

Sequestration of metals through association with pyrite in subtidal sediments of the Nanpaishui Estuary on the Western Bank of the Bohai Sea, China

Measurements were made of the degree of trace metal pyritization (DTMP) and ancillary characteristics of four undisturbed sediment cores collected from the subtidal zone of the Nanpaishui Estuary on the Western Bank of the Bohai Sea, a seriously polluted inland sea in northeastern China. The remarkably low concentrations of organic carbon (<0.72%) in these sediments likely constrained sulfate reduction rates, and the low concentrations of acid volatile sulfide (AVS) (<12.5μmolg−1) limited the sequestration of metals through association with pyrite. The most consistent cause of inter-station differences and depth variations in the degree of pyritization was differences in pyrite metal concentrations rather than reactive metal concentrations. Reactive metal concentrations were in several cases negatively correlated with pore water concentrations, consistent with a dissolution/precipitation mechanism. The relationship between pore water metal concentrations and DTMPs was evidenced by a qualitative similarity of the inter-station variability of these same parameters.

An Analysis of Material Circulations in Sediment behind the Drain Gates of Isahaya Reclamation Dike

The environmental characteristics in seabed sediment behind the north and south drain gates of Isahaya Bay were investigated by sampling the undisturbed sediment cores. The vertical distributions of TOC, DO, AVS, NH4-N, NO3-N and PO4-P were obtained. The material circulations in the sediment at two sites were analyzed by using a sediment model. The model parameters were adjusted so that the analytical results agree well with the observed ones. The model analysis revealed that the fluxes of organic material and oxygen consumption to the seabed surface at St.2 were two times larger than those at St.1, respectively. These differences at St.1 and St.2 may be attributed to the current in Isahaya Bay.