Given a “Green function” G on a locally compact space X with countable base, a Borel set A in X is called G-semipolar, if there is no measure ν ≠ 0 supported by A such that $G\nu :=\int G(\cdot ,y)\,d\nu (y)$ is a continuous real function on X. Introducing an intrinsic Hausdorff measuremG using G-balls B(x, ρ) := {y ∈ X : G(x, y) > 1/ρ}, it is shown that every set A in X with $m_{G}(A)<\infty $ is contained in a G-semipolar Borel set. This is of interest, since G-semipolar sets are semipolar in the potential-theoretic sense (countable unions of totally thin sets, hit by a corresponding process at most countably many times), if G is a genuine Green function. The result has immediate consequences for classical potential theory, Riesz potentials and the heat equation (where it solves an open problem). More generally, it is applied to metric measure spaces (X, d, μ), where a continuous heat kernel with upper and lower bounds of the form t−α/βΦj(d(x,y)t− 1/β), j = 1, 2, is given. Then the intrinsic Hausdorff measure on X is equivalent to an ordinary Hausdorff measure mα−β. For the corresponding space-time structure on X × ℝ, the intrinsic Hausdorff measure turns out to be equivalent to an anisotropic Hausdorff measure mα,β.