This article presents the performance analysis of future Provincial Electricity Authority of Thailand (PEA) distribution networks under high penetration of plug‐in electric vehicle (PEV) home charging using the Monte Carlo method. Network performance indices considered in this study are the voltage profile, power losses, load factor, and voltage unbalance. The voltage profile and power losses are evaluated based on the PEA criteria. In addition, the voltage unbalance factors (%VUF) are evaluated according to the IEC 61000‐2‐4: 2000‐06 standards. A selected PEA distribution network based on the existing data is used for the simulation study with the DIgSILENT PowerFactory. The penetration of PEV home charging at each node and phase is assigned using the Monte Carlo method, which in particular is used to randomly generate patterns of PEV charging behaviors. The simulation study presents five cases; the average points of charge, max‐to‐min charge, min‐to‐max charge, central feeder charge, and random point of charge. All cases are compared with a base case (without PEVs). Charging scenarios at phases ‘a’, ‘b’, and ‘c’ are assumed having overlapped time duration. The PEV charging duration per phase is assumed 6 h. Simulation results indicate that PEV charging time, charging point, and penetration levels at each phase and node are significant factors impacting the network performance. Voltage profiles slightly drop in all cases, meanwhile the average voltage drop increases by 7% compared with the base case; case 3 has the maximum voltage drop, which is deeper than PEA criteria. The power losses increase in all cases. The average power losses have increased by 103.52%. The %VUF increases gradually with the length of the feeder. The maximum %VUF occurs at the end of the feeder for all cases and is higher than 2.0% of the IEC standard. On the other hand, PEV charging improves the load factor. © 2018 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.