Ultraviolet Irradiance Research Articles

Electron Temperature Response to Solar Forcing in the Low‐Latitude Martian Ionosphere

AbstractElectron temperatures are a key parameter for understanding the ionosphere‐thermosphere system. This study uses in situ data from the MAVEN mission to investigate the level of coupling between the Martian ionospheric electrons and the neutral thermosphere below the altitude of 190 km. Such coupling is responsible for significant diurnal variations and dawn/dusk asymmetries in both the neutral and plasma portions of the ionosphere‐thermosphere system. Earlier theoretical studies suggested that neutral species controlled the electron temperature by collisional cooling thus implying a diurnal trend in electron temperatures due to the diurnal variability of the neutrals. This hypothesis is evaluated across the dayside ionosphere in the present work. Observations of neutral densities confirm that neutral‐electron collisions are the primary process controlling the cooling of electrons in the Martian ionosphere below ~190 km. The consequence of this is that electron temperatures can be anticorrelated with the extreme ultraviolet (EUV) irradiance due to enhanced electron cooling brought about by an expansion of neutral densities. The results also indicate that in the afternoon sector, neutral densities are less responsive to changes in EUV. This might be associated with enhanced winds leading to dynamic cooling that mitigates the thermal expansion of the thermosphere in the afternoon region. Subsequently, the electron temperature as a function of EUV is relatively uncorrelated in the afternoon sector.

A Revised Magnesium II Core‐to‐Wing Ratio From SORCE SOLSTICE

The Magnesium II core‐to‐wing ratio (also known as the Mg II index) is a widely used proxy for ultraviolet solar spectral irradiance variability. We have developed a new algorithm for calculating this index from the SOLar‐STellar Irradiance Comparison Experiment (SOLSTICE) on the SOlar Radiation and Climate Experiment (SORCE). The new method uses weighted sums of the core and wing regions of the spectrum calculated from the daily level three high‐resolution spectrum. We also describe a new method of scaling the results in order to compare to other measurements. This new method scales each data set to a standard spectral resolution rather than scaling to other data sets during periods of overlapping measurements. Finally, we quantify the effect of long‐term instrument degradation on the Mg II index. In the case of SORCE SOLSTICE, using uncorrected data would produce an error of less than 0.6% of the solar cycle amplitude over a decade.

Low-Cost and Highly Efficient Carbon-Based Perovskite Solar Cells Exhibiting Excellent Long-Term Operational and UV Stability.

Today's perovskite solar cells (PSCs) mostly use components, such as organic hole conductors or noble metal back contacts, that are very expensive or cause degradation of their photovoltaic performance. For future large-scale deployment of PSCs, these components need to be replaced with cost-effective and robust ones that maintain high efficiency while ascertaining long-term operational stability. Here, a simple and low-cost PSC architecture employing dopant-free TiO2 and CuSCN as the electron and hole conductor, respectively, is introduced while a graphitic carbon layer deposited at room temperature serves as the back electrical contact. The resulting PSCs show efficiencies exceeding 18% under standard AM 1.5 solar illumination and retain ≈95% of their initial efficiencies for >2000 h at the maximum power point under full-sun illumination at 60 °C. In addition, the CuSCN/carbon-based PSCs exhibit remarkable stability under ultraviolet irradiance for >1000 h while under similar conditions, the standard spiro-MeOTAD/Au based devices degrade severely.

Pyrite-induced uv-photocatalytic abiotic nitrogen fixation: implications for early atmospheres and Life

The molecular form of nitrogen, N2, is universally available but is biochemically inaccessible for life due to the strength of its triple bond. Prior to the emergence of life, there must have been an abiotic process that could fix nitrogen in a biochemically usable form. The UV photo-catalytic effects of minerals such as pyrite on nitrogen fixation have to date been overlooked. Here we show experimentally, using X-ray photoemission and infrared spectroscopies that, under a standard earth atmosphere containing nitrogen and water vapour at Earth or Martian pressures, nitrogen is fixed to pyrite as ammonium iron sulfate after merely two hours of exposure to 2,3 W/m 2 of ultraviolet irradiance in the 200–400 nm range. Our experiments show that this process exists also in the absence of UV, although about 50 times slower. The experiments also show that carbonates species are fixed on pyrite surface.

Characterization of chromophoric dissolved organic matter in lakes across the Tibet-Qinghai Plateau using spectroscopic analysis

Fluorescent dissolved organic matter (FDOM) has a significant influence on global inland water carbon cycling and biogeochemical processes. The alpine lakes on Tibet-Qinghai Plateau (TQP) are exposed to high-intensity ultraviolet radiation, long retention time with less anthropogenic influences. Yet, limited studies were conducted on FDOM of lakes on the highest plateau in the world with unique aquatic environments. Spatiotemporal variations of FDOM components from 63 lakes (32 fresh lakes, N = 135; 31 brackish lakes, N = 109) were grouped according to salinity across the TQP collected during 2014–2017. FDOM were examined using excitation-emission matrix spectra (EEM) and fluorescence regional integration (FRI). CDOM absorption and FDOM fluorescence indices, average fluorescence intensities of the five fluorescent components (φi,i = I, II, III, IV, V) and total fluorescence intensities (φT) are significantly different between brackish and freshwater lakes (p < 0.05). High correlations (−0.51** < r < −0.86**, p < 0.01) were revealed between FDOM and dissolved organic carbon (DOC) concentrations with salinity > 10‰. A comparatively prolonged retention time and terrestrial allochthonous inputs caused higher DOC accumulation in brackish water. Strong UV radiation resulted in an important effect on CDOM photo-absorption characteristics, and that contributed to DOC variability and fate. Likewise, average CDOM spectroscopic indices in each basin with different land covers showed a moderate correlation between DOC and normalized humic-like φV for 20 basins (r = −0.46**, p < 0.01). The results suggest that studies on the highest alpine lakes across the TQP should focus on the impact of the evapo-concentration, ultraviolet irradiance and landscape features within different basins on FDOM characteristics. It demonstrated that the FDOM was dominated by the allochthonous sources in brackish lakes from the TQP and had a similarity to those observed in marine environments.

UV‐Inert ZnTiO3 Electron Selective Layer for Photostable Perovskite Solar Cells

AbstractAlthough planar‐structured perovskite solar cells (PSCs) have power conversion efficiencies exceeding 24%, the poor photostability, especially with ultraviolet irradiance (UV) severely limits commercial application. The most commonly‐used TiO2 electron selective layer has a strong photocatalytic effect on perovskite/TiO2 interface when TiO2 is excited by UV light. Here a UV‐inert ZnTiO3 is reported as the electron selective layer in planar PSCs. ZnTiO3 is a perovskite‐structured semiconductor with excellent chemical stability and poor photocatalysis. Solar cells are fabricated with a structure of indium doped tin oxide (ITO)/ZnTiO3/Cs0.05FA0.81MA0.14PbI2.55Br0.45/Sprio‐MeOTAD/Au. The champion device exhibits a stabilized power conversion efficiency of 19.8% with improved photostability. The device holds 90% of its initial efficiency after 100 h of UV soaking (365 nm, 8 mW cm−2), compared with 55% for TiO2‐based devices. This work provides a new class of electron selective materials with excellent UV stability in perovskite solar cell applications.

Compilation and spatio-temporal analysis of publicly available total solar and UV irradiance data in the contiguous United States

Skin cancer is the most common type of cancer in the United States, the majority of which is caused by overexposure to ultraviolet (UV) irradiance, which is one component of sunlight. National Environmental Public Health Tracking Program at CDC has collaborated with partners to develop and disseminate county-level daily UV irradiance (2005–2015) and total solar irradiance (1991–2012) data for the contiguous United States. UV irradiance dataset was derived from the Ozone Monitoring Instrument (OMI), and solar irradiance was extracted from National Solar Radiation Data Base (NSRDB) and SolarAnywhere data. Firstly, we produced daily population-weighted UV and solar irradiance datasets at the county level. Then the spatial distributions and long-term trends of UV irradiance, solar irradiance and the ratio of UV irradiance to solar irradiance were analyzed. The national average values across all years are 4300 Wh/m2, 2700 J/m2 and 130 mW/m2 for global horizontal irradiance (GHI), erythemally weighted daily dose of UV irradiance (EDD) and erythemally weighted UV irradiance at local solar noon time (EDR), respectively. Solar, UV irradiances and the ratio of UV to solar irradiance all increased toward the South and in some areas with high altitude, suggesting that using solar irradiance as indicator of UV irradiance in studies covering large geographic regions may bias the true pattern of UV exposure. National annual average daily solar and UV irradiances increased significantly over the years by about 0.3% and 0.5% per year, respectively. Both datasets are available to the public through CDC's Tracking network. The UV irradiance dataset is currently the only publicly-available, spatially-resolved, and long-term UV irradiance dataset covering the contiguous United States. These datasets help us understand the spatial distributions and temporal trends of solar and UV irradiances, and allow for improved characterization of UV and sunlight exposure in future studies.

The Martian Bow Shock Over Solar Cycle 23–24 as Observed by the Mars Express Mission

AbstractThe Martian bow shock position is known to be correlated with solar extreme ultraviolet irradiance. Since this parameter is also correlated with the evolution of the solar cycle, it is expected that the Martian bow shock position should also vary over such a period. However, previous reports on this topic have often proved contradictory. Using 13 years of observations of the Martian bow shock by the Mars Express mission over the period 2004 to 2017, we report that the Martian bow shock position does vary over the solar cycle. Over this period, our analysis shows the bow shock position to increase on average by 7% between the solar minimum and maximum phases of solar cycle 23–24, which could be even larger for more extreme previous solar cycles. We show that both annual and solar cycle variations play major roles in the location of the bow shock at Mars.

Ultraviolet radiation exposure during daylight Photodynamic Therapy.

Daylight photodynamic therapy (dPDT) is an effective treatment for field-change actinic keratoses (AK), with similar efficacy to conventional PDT but lower patient pain scores. Whilst AK occur consequent to chronic solar ultraviolet (UV) exposure, paradoxically solar visible radiation is used during PDT. To investigate the nature and levels of UV exposure, both erythemal UV and UVA, occurring during dPDT. Four years of solar erythemally effective UV (UVE) irradiance, UVA irradiance and illuminance data were obtained from Pubic Health England for 12 locations. For a standard 2 h treatment period, the data were converted into standard erythemal doses (SEDs), UVA dose and protoporphyrin-IX (PpIX)-weighted dose from UVE irradiance, UVA irradiance and illuminance respectively. These three parameters were compared ascertaining the UV exposure received during dPDT. Analysis of UV exposure during dPDT showed a UK maximum average UVE exposure of 8.2 SED at Camborne (PpIX dose 23.4 J cm-2). Treatment earlier in the day reduces average UV exposure (Camborne 5.2 SED, PpIX dose 18.2 J cm-2), whilst PpIX dose achieves threshold during winter months (Camborne, November, 0.8 SED, PpIX dose 7.1 J cm-2). Cyprus and Gibraltar (with high UV exposure during dPDT) experience a maximum of 14.3 SED and 12.9 SED, with respective PpIX doses of 36.1 J cm-2 and 35.1 J cm-2, in June. UVA exposure is also presented for comparison. Therapeutically effective dPDT doses can be achieved at times of the day and year when UV exposure is minimal.

A Model of Fluxes of Solar Extreme Ultraviolet Irradiance

We develop an approach to create a model of the solar extreme ultraviolet spectrum in the wavelength range responsible for dissociation of molecular oxygen (115−242 nm). The model is based on the concept of the linear dependence of irradiance fluxes in intervals 1 nm in width on the intensity in the Lyman-alpha hydrogen line (this line is supposed to be measured by photometers of the extreme ultraviolet irradiance onboard space probes). The linear dependence coefficients were obtained for each of these intervals. Comparison of the model calculation results with observations showed that the model inaccuracy does not exceed 1−2%, which is sufficient for calculations of the thermospheric state.

Solar Rotation Period Driven Modulations of Plasmaspheric Density and Convective Electric Field in the Inner Magnetosphere

AbstractThis paper presents the first analysis of Van Allen Probes measurements of the cold plasma density and electric field in the inner magnetosphere to show that intervals of strong modulation at the solar rotation period occur in the locations of the outer plasmasphere and plasmapause (~0.7 RE peak‐to‐peak), in the large‐scale electric field (~0.24 mV/m peak‐to‐peak), and in the cold plasma density (~250 to ~70 cm−3 peak‐to‐peak). Solar rotation modulation of the inner magnetosphere is more apparent in the declining phase of the solar cycle than near solar maximum. The periodicities in these parameters are compared to solar extreme ultraviolet irradiance, solar wind dawn‐dusk electric field, and Kp. The variations in the plasmapause location at the solar rotation period anticorrelate with solar wind electric field, magnetospheric electric field, and Kp, but not with extreme ultraviolet irradiance, indicating that convective erosion is the dominant physical process controlling the plasmapause at these timescales.

SmartPatch: A Self-Powered and Patchable Cumulative UV Irradiance Meter

This article pioneers a self-powered, small-form-factor, light-weight, low-cost, and a patch-type ultraviolet (UV) meter for measuring the UV radiation with significant impact on human health and smart sensing.—Paul Bogdan, University of Southern California

One‐ to 10‐Day Forecasts of Ionospheric Total Electron Content Using a Statistical Model

AbstractA new, rapid, nonassimilative technique is demonstrated for forecasting the ionosphere's vertical total electron content (TEC) on time scales longer than 1 day. The approach uses a statistical model constructed by regressing solar extreme ultraviolet irradiance and seasonal, diurnal, and geomagnetic predictors at multiple lags against the 2‐hourly International Global Navigation Satellite Systems Service observations, with a formulation that accounts for solar modulation of the seasonal oscillations and solar and seasonal modulation of the diurnal oscillations. Solar irradiance inputs to the statistical model are forecast at successive 2‐hr intervals from 1999 to 2015 using an autoregressive model of irradiance variations during the prior 100 days. As the forecast time increment increases from 1 to 10 days, the average over the globe of the mean absolute error of TEC observations and the forecasts increases from 2.5 to 3.2 TECU (total electron content unit, 1 TECU = 1016 el/m2); the root‐mean‐square error increases from 3.7 to 4.8 TECU. Averaged over the equatorial ionization anomaly region (30°S–30°N) the mean absolute error of the forecasts increases from 3.2 to 4.3 TECU and the root‐mean‐square error increases from 4.6 to 6.4 TECU. The skill of the TEC forecasts at time increments of 3, 5, and 8 days ahead exceeds persistence by 9%, 13%, and 15% and climatology by 9%, 12%, and 10%, respectively. Forecast skill is higher in April than in July. Long‐range, multiyear forecasts from 2018 to 2030 are demonstrated based on current expectations that solar activity in cycle 25 will be comparable to that in cycle 24.

Characterizing the weathering induced degradation of Poly(ethylene-terephthalate) using PARAFAC modeling of fluorescence spectra

Poly(ethylene-terephthalate) (PET) film is widely used in photovoltaic module backsheets, for its dielectric breakdown strength, and in applications requiring high optical clarity. PET degrades under exposure to ultraviolet (UV) irradiance, heat, and moisture, which leads to loss of optical clarity and performance properties. To study the weathering driven degradation of PET films, three grades of PET, including unstabilized and stabilized grades, were exposed to three types of accelerated weathering exposure. Fluorescence excitation-emission matrix (EEM) spectra were collected after predetermined exposure intervals. Parallel factor analysis (PARAFAC) was applied to the resulting spectra to decompose the fluorescence data into individual fluorophore components and monitor their relative concentrations over time. EEM-PARAFAC was used to identify and distinguish between the formation of monohydroxy-terephthalate and dihydroxy-terephthalate units in PET over time under the UV-light bearing accelerated exposures. The relative concentrations of these fluorophores were found to increase, while the relative concentration of the PARAFAC component assigned to PET was found to generally decrease. ATR-FTIR was used to support findings from EEM-PARAFAC. Results were also used to assess the impact of additives (UV stabilizer and TiO2) on degradation.

The GOES-R EUVS model for EUV irradiance variability

The Geostationary Operational Environmental Satellite R (GOES-R) series of four satellites are the next generation NOAA GOES satellites. Once on orbit and commissioned, they are renamed GOES 16–19, making critical terrestrial and space weather measurements through 2035. GOES 16 and 17 are currently on orbit, having been launched in 2016 and 2018, respectively. The GOES-R satellites include the Extreme Ultraviolet (EUV) and X-ray Irradiance Sensors (EXIS) instrument suite, which measures calibrated solar irradiance in eight lines or bands between 25 nm and 285 nm with the Extreme Ultraviolet Sensors (EUVS) instrument. EXIS also includes the X-Ray Sensor (XRS) instrument, which measures solar soft X-ray irradiance at the legacy GOES bands. The EUVS Measurements are used as inputs to the EUVS Model, a solar spectral irradiance model for space weather operations that predicts irradiance in twenty-two 5 nm wide intervals from 5 nm to 115 nm, and one 10 nm wide interval from 117 to 127 nm at 30 s cadence. Once fully operational, NOAA will distribute the EUVS Model irradiance with 1 min latency as a primary space weather data product, ushering in a new era of rapid dissemination and measurement continuity of EUV irradiance spectra. This paper describes the EUVS Model algorithms, data sources, calibration methods and associated uncertainties. Typical model (relative) uncertainties are less than ~5% for variability at time-scales longer than 6 h, and are ~25% for solar flare induced variability. The absolute uncertainties, originating from the instruments used to calibrate the EUVS Model, are ~10%. Examples of model results are presented at both sub-daily and multi-year timescales to demonstrate the model’s capabilities and limitations. Example solar flare irradiances are also modeled.

A site-specific standard for comparing dynamic solar ultraviolet protection characteristics of established tree canopies

A standardised procedure for making fair and comparable assessments of the ultraviolet protection of an established tree canopy that takes into account canopy movement and the changing position of the sun is presented for use by government, planning, and environmental health authorities. The technique utilises video image capture and replaces the need for measurement by ultraviolet radiometers for surveying shade quality characteristics of trees growing in public parks, playgrounds and urban settings. The technique improves upon tree shade assessments that may be based upon single measurements of the ultraviolet irradiance observed from a fixed point of view. The presented technique demonstrates how intelligent shade audits can be conducted without the need for specialist equipment, enabling the calculation of the Shade Protection Index (SPI) and Ultraviolet Protection Factor (UPF) for any discreet time interval and over a full calendar year.•Tree shade UPF measurements are presented using video capture analysis of moving canopies•A standard method for making accurate assessments of tree shade has been developed•Tree shade comparisons are made without the need for specialist equipment

MS2 coliphage and E. coli UVB inactivation rates in optically clear water: dose, dose rate and temperature dependence.

Natural ultraviolet irradiance disinfection is known to play a significant role in both natural wastewater treatment systems and drinking water disinfection processes, while the influence of ultraviolet B (UVB) delivering method on sunlight disinfection outcome is still unclear. This study aims to determine the effects of environmentally relevant temperatures, UVB doses (J m-2) and dose rates (W m-2) on the inactivation and log reduction values (LRVs) of the F-RNA coliphage MS2 and Escherichia coli in optically clear water. E. coli and MS2 were separately incubated and irradiated at five different doses of UVB light that delivered using six UVB dose rates. The results of the study demonstrate that the UVB dose delivering method (combination of dose rate and exposure time) influences inactivation and LRVs of E. coli and MS2 at all UVB doses investigated (up to seven-fold difference). Two phases were identified within the UVB dose rate, UVB inactivation or LRV curves for both organisms; a UVB dose rate limited inactivation phase and a dose rate saturation inactivation phase. The results contribute to a better understanding of UVB disinfection in the environment and natural wastewater treatment systems, potentially improving the design and operation of high rate algal ponds.

UV measurements at Marambio and Ushuaia during 2000–2010

Abstract. Solar ultraviolet (UV) irradiances were measured with NILU-UV multichannel radiometers at Ushuaia (54∘ S) and Marambio (64∘ S) between 2000 and 2013. The measurements were part of the Antarctic NILU-UV network, which was started in cooperation between Spain, Argentina and Finland. The erythemally weighted UV irradiance time series of both stations were analysed for the first time. The quality assurance procedures included a travelling reference instrument to transfer the irradiance scale to the stations. The time series were homogenized and high quality measurements were available for the period 2000–2010. During this period UV indices of 11 or more were measured on 5 and 35 days at Marambio and Ushuaia, respectively. At Marambio, the peak daily maximum UV index of 12 and daily doses of around 7 kJ m−2 were measured in November 2007. The highest UV daily doses at both stations were typically around 6 kJ m−2 and occurred when the stations were inside the polar vortex, resulting in very low total ozone amount. At both stations, daily doses in late November could even exceed those in the summer. At Marambio, in some years, also daily doses in October can be as high as those during the summer. At Ushuaia, the peak daily maximum UV index of 13 was measured twice: in November 2003 and 2009. Also during those days, the station of Ushuaia was inside the polar vortex.

Statistical Study and Prediction of Variability of Erythemal Ultraviolet Irradiance Solar Values in Valencia, Spain

The goal of this study was to statistically analyse the variability of global irradiance and ultraviolet erythemal (UVER) irradiance and their interrelationships with global and UVER irradiance, global clearness indices and ozone. A prediction of short-term UVER solar irradiance values was also obtained. Extreme values of UVER irradiance were included in the data set, as well as a time series of ultraviolet irradiance variability (UIV). The study period was from 2005 to 2014 and approximately 250,000 readings were taken at 5-min intervals. The effect of the clearness indices on global irradiance variability (GIV) and UIV was also recorded and bi-dimensional distributions were used to gather information on the two measured variables. With regard to daily GIV and UIV, it is also shown that for global clearness index (kt) values lower than 0.6 both global and UVER irradiance had greater variability and that UIV on cloud-free days (kt higher than 0.65) exceeds GIV. To study the dependence between UIV and GIV the χ2 statistical method was used. It can be concluded that there is a 95% probability of a clear dependency between the variabilities. A connection between high kt (corresponding to cloudless days) and low variabilities was found in the analysis of bi-dimensional distributions. Extreme values of UVER irradiance were also analyzed and it was possible to calculate the probable future values of UVER irradiance by extrapolating the values of the adjustment curve obtained from the Gumbel distribution.

Ultraviolet radiation exposure time and intensity modulate tomato resistance to herbivory through activation of jasmonic acid signaling.

Ultraviolet (UV) radiation can modulate plant defenses against herbivorous arthropods. We investigated how different UV exposure times and irradiance intensities affected tomato (Solanum lycopersicum) resistance to thrips (Frankliniella occidentalis) by assessing UV effects on thrips-associated damage and host-selection, selected metabolite and phytohormone contents, expression of defense-related genes, and trichome density and chemistry, the latter having dual roles in defense and UV protection. Short UV daily exposure times increased thrips resistance in the cultivar 'Moneymaker' but this could not be explained by changes in the contents of selected leaf polyphenols or terpenes, nor by trichome-associated defenses. UV irradiance intensity also affected resistance to thrips. Further analyses using the tomato mutants def-1, impaired in jasmonic acid (JA) biosynthesis, od-2, defective in the production of functional type-VI trichomes, and their wild-type, 'Castlemart', showed that UV enhanced thrips resistance in Moneymaker and od-2, but not in def-1 and Castlemart. UV increased salicylic acid (SA) and JA-isoleucine concentrations, and increased expression of SA- and JA-associated genes in Moneymaker, while inducing expression of JA-defensive genes in od-2. Our results demonstrate that UV-mediated enhancement of tomato resistance to thrips is probably associated with the activation of JA-associated signaling, but not with plant secondary metabolism or trichome-related traits.