The properties and appearance of ancient architectural red sandstone will be damaged after being eroded by the natural environment for a long time. In order to investigate the weathering and erosion characteristics of the red sandstone structure of an existing ancient building, ultrasonic testing techniques, combined with scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray computed tomography (X-CT), were used to analyze a building in Ganzhou. The variation in chemical substances contained in the red sandstone specimens according to phenology was analyzed by X-ray diffraction (XRD). The characteristic parameters of the CT grayscale images of the red sandstone were extracted and combined with the ultrasonic wave velocity values to comprehensively analyze the degradation characteristics of the red sandstone specimens, and a method to characterize the degradation degree of the red sandstone as a whole plane is proposed. We use the gray model (GM (1, 1)) to predict the surface degradation degree of red sandstone specimens, and gray relation analysis (GRA) to further analyze the correlation between the characteristic parameters of CT grayscale images of red sandstone and its degradation degree. The results show that in the natural erosion environment, dolomite and chlorite are generated on the exposed surface of the red sandstone, which can protect the internal sandstone to a certain extent. The degradation degree of the red sandstone specimens in the horizontal X and Y directions varies, and the proposed method of calculating the overall plane degradation degree of the red sandstone is feasible. The minimum average relative error of the surface degradation degree obtained from the gray prediction GM (1, 1) model is 1.4591%. There is a good correlation between the characteristic parameters of the red sandstone CT grayscale images and the degradation degree.
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