Ultrasonic bulk wave inspection of defects in safety–critical components with complex external geometries, such as turbine blades is challenging. While ultrasonic phased array imaging can yield high-resolution subsurface images, a commercial phased array probe can hardly be mounted on irregular external boundaries to perform in-situ imaging. In fact, a component with irregular shapes, as a highly reverberant body, is capable of generating elastic random diffuse or coda wavefields. The diffuse wavefields can be utilized to reconstruct Green’s functions between any two passive receiving points. In this paper, an ultrasonic passive array imaging method using the diffuse reverberation resulting from complex boundaries is implemented to image internal defects. The method involves the utilization of active piezoelectric actuators to excite elastic diffuse waves within the component, which are received by a laser vibrometer scanning at multiple points. A passive full matrix capture (FMC) of array signals is extracted for defect imaging using the total focusing method. The proposed method is evaluated by the numerical simulations, and the effects of centre frequency, bandwidth, and source excitation methods on the imaging performance are investigated. An experiment using a turbine blade-like structure is conducted to further evaluate the imaging method.