Mafic-ultramafic Intrusions Research Articles

Multiple enrichment of subcontinental lithospheric mantle with Archean to Mesozoic components: Evidence from the Chicheng ultramafic complex, North China Craton

Numerous Late Paleozoic to Early Mesozoic mafic-ultramafic intrusions occur along the northern margin of the North China Craton (NCC). The timing, magma source, genetic types and tectonic evolution of these intrusions still remain controversial. Here we conduct a systematic petrological, mineral chemical, whole-rock geochemical, isotopic (zircon Lu–Hf and whole-rock Sr–Nd isotopes) and geochronological study on representative samples from the Chicheng ultramafic complex in the northern NCC, our results provide new insights into multiple melt-fluid interactions in the subcontinental lithospheric mantle through time. Zircon U–Pb data from the ultramafic rocks (pyroxenite and serpentinized dunite) show a wide range of ages (2721–129 Ma), indicating zircon growth within an evolving and metasomatized mantle wedge during multi-stage melt-fluid interactions. The youngest zircon population (145–129 Ma) possibly marks the timing of formation of the Chicheng ultramafic complex at the Early Cretaceous. Moreover, these ultramafic rocks also witnessed tectonic transition from Paleo-Asian Ocean to Paleo-Pacific Plate subduction during the Paleozoic to Early Mesozoic and subsequent progressive lithospheric thinning and craton destruction at the northern margin of the NCC, which is also attested by the newly discovered diorite porphyry dyke from this complex reported in this study with zircon U–Pb ages in the range of 447 to 128 Ma. Zircon Lu–Hf isotopic data show εHf(t) values in the range of −19.9 to +15.4 with TDM of 219–3012 Ma and TDMC of 240–3650 Ma. Whole-rock Sr–Nd isotopic data display εNd(t) values ranging from −12.3 to −1.6, indicating heterogenous sources involving both depleted mantle and reworked ancient crustal components. Whole-rock geochemical data show enrichment in LILEs (Rb, Sr, Ba, Pb) and depletion in HFSEs (Nb, Ta, Ti), with positive anomalies at Ba, K, Pb and Nd and strongly negative Zr and Ti anomalies, suggesting geochemical affinities related to subduction-related island arc setting within an active continental margin. Mineral chemical data on clinopyroxenes do not correspond to “Alaskan-type” affinities. Integrating geochemical, geochronological and isotopic studies from this study and those from previous studies related to the mafic-ultramafic complexes in the northern Hebei Province along the northern margin of the NCC, we propose that these complexes might be composite plutons formed during the Early Cretaceous, which were derived from the interaction of melts and fluids released from subducted slab with metasomatized mantle peridotite, triggering different degree of partial melting of mantle wedge.

Experimental Study of Pt Solubility in the CO-CO2 Fluid at Low fO2 and Subsolidus Conditions of the Ultramafic-Mafic Intrusions

The solubility of Pt in CO-CO2 fluid was studied experimentally at P = 50–200 MPa and T = 950 °C. A mixture of MgC2O4 and MgCO3 was used as a source of the fluid. Upon the reaction of the Pt capsule walls and the fluid, a carbonyl of platinum is formed. The use of the high-temperature quartz ceramics as a fluid trap avoids the effect of mechanical contamination with Pt from the eroded capsule walls. The total content of platinum in the porous fluid traps was measured by the Electrothermal Atomic Absorption (ET-AAS) method. In some experiments, the local analysis of traps was carried out by the Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) method. The composition of fluid in bubbles captured in an albite glass trap was studied by micro-Raman spectroscopy. On the capsule walls and MgO, Pt “whiskers” of submicron diameter were observed, which were formed as a product of carbonyl decomposition during quenching. About 5–15% of carbonyl withstands quenching resulting in 1.5 to 2 ppm Pt soluble in acetone (runs at P = 200 MPa) in a quartz glass trap. The amount of Pt soluble in acetone from the capsule walls corresponds to a concentration of up to 8 ppm in the fluid. A high content of soluble Pt of 2000–3000 ppm was determined in a carbon coated MgO matrix. Our study demonstrated that the solubility of Pt in the CO-CO2 fluid is 15–150 ppm, presumably in the form of Pt3(CO)62− under conditions corresponding to the conditions of the subsolidus stage of layered ultramafic-mafic and ultramafic-alkaline intrusions formation. Our preliminary data showed that this solubility will increase with the addition of water at low fO2.

Petrogenesis and metallogenic potential of the early devonian Yugusayi mafic-ultramafic complex in Qimantagh, East Kunlun orogeic belt

ABSTRACT The Yugusayi mafic-ultramafic complex, located in the Qimantagh area, East Kunlun orogenic belt, consists of harzburgite, olivine orthopyroxenite, hornblende pyroxenite, and hornblende gabbro, which were once considered to be a part of the Early Palaeozoic ophiolite suite. However, the Yugusayi mafic-ultramafic rocks are characterized by thermal emplacement, accompanied by Cu-Ni sulphide mineralization, which is different from typical ophiolite suite. The LA-ICP-MS zircon U-Pb dating yields a 405 ± 2.8 Ma age for the hornblende gabbro, which belongs to the Early Devonian. All rocks are enriched in LREE but depleted in HREE, with a characteristic of ferrous mafic-ultramafic rocks. The εHf(t) values of the zircons from hornblende gabbro are 5.6–14.8, the εNd(t) values of whole rocks are from −4.27 to 0.08, and the δ34S values of sulphide are 1.36–8.72‰, indicating that the magma originated from the depleted mantle and contaminated by continental crust material during the ascending process. Based on the regional geological background, it is reasonable that the rocks formed in the post-collision extension stage after the closure of the Proto-Tethys Ocean and the continental collision, which represents an important metallogenic period for Cu-Ni sulphide deposits in the East Kunlun oregenic belt. Early Devonian magmatic mafic-ultramafic intrusions are developed in the early Palaeozoic ophiolitic tectonic melange belt of Qimantagh area. Combined with good metallogenic conditions and remarkable mineralization characteristics, it is believed that the Qimantagh area is a potential area for the prospecting of magmatic Cu-Ni sulphide deposits.

Late Permian–Early Triassic mafic dikes in the southwestern margin of the South China block: Evidence for Paleo-Pacific subduction

The link of the widespread Late Permian–Triassic magmatism in the southwestern corner of the South China block to a subduction zone or the Emeishan mantle plume is debated. We have carried out an integrated geochronological-petrological-geochemical study of four mafic dikes in the Gulinjing–Nanxi area of this region to shed new light on the issue. Zircon grains from the Gulinjing–Nanxi mafic dikes yield UPb ages from 254 ± 2 to 250 ± 2 Ma, indicating that they are coeval with abundant felsic intrusive-extrusive rocks in the region, but are 6–7 myr younger than the nearby Emeishan flood basalts and associated mafic-ultramafic intrusions. The Gulinjing–Nanxi mafic dikes are characterized by light rare-earth element enrichments and pronounced negative NbTa anomalies, similar to typical arc basalts worldwide, plus enriched Sr-Nd-Hf isotope compositions (initial 87Sr/86Sr from 0.7088 to 0.7103, εNd(t) from −6.6 to −4.6, and zircon εHf(t) from −3.7 to −0.3). The isotopes and incompatible trace element ratios indicate that the parental magmas for the Gulinjing–Nanxi mafic dikes are consistent with contaminated arc mafic magmas, but not contaminated Emeishan flood basalts in the region. This, together with a significant age difference between the mafic dikes and the Emeishan flood basalts and associated mafic-ultramafic intrusions in the nearby areas, support the interpretation that the Gulinjing–Nanxi mafic dikes are unlikely to be parts of the Emeishan mantle plume. Based on regional igneous association and the distribution of known paleo subduction zones in the surrounding regions, we conclude that the Gulinjing–Nanxi mafic dikes are linked to Paleo-Pacific subduction to the south, and not Paleo-Tethys subduction to the west.

Mg–Sr–Nd Isotopic Insights into Petrogenesis of the Xiarihamu Mafic–Ultramafic Intrusion, Northern Tibetan Plateau, China

AbstractTo characterize the integrated magmatic processes for magma plumbing systems from mantle sources to magma chambers, we present Mg–Sr–Nd isotopic data for a representative mafic–ultramafic intrusion in Xiarihamu, northern Tibetan Plateau, China. The intrusion hosts the largest magmatic Ni–Cu sulfide deposit in an orogenic setting in the world and is composed predominantly of harzburgite, orthopyroxenite, websterite, and gabbronorite. The cumulate harzburgites have relatively low δ26Mg of orthopyroxene (–0·49 to –0·34‰) and moderately high (87Sr/86Sr)i and positive εNd(t) values (0·7067–0·7080 and +0·4 to +1·8, respectively). Most of the orthopyroxenites, websterites, and gabbronorites have slightly higher δ26Mg of orthopyroxene (–0·34 to –0·21‰) and higher (87Sr/86Sr)i and lower εNd(t) values (0·7087–0·7118 and –4·0 to –1·4, respectively) than the harzburgites. On the other hand, marginal facies (i.e. a few centimeters to meters from the contact between the intrusion and country rocks of schist, gneiss, and marble) including websterite and gabbronorite are marked by low δ26Mg of orthopyroxene (–0·44 to –0·33‰) and extremely high (87Sr/86Sr)i and negative εNd(t) values (0·7127–0·7172 and –5·4 to –4·8, respectively). The relatively low δ26Mg, moderately high (87Sr/86Sr)i, and positive εNd(t) of the harzburgites are best interpreted by inheritance from the mantle source, which was previously metasomatized by subducted Mg-rich carbonates. Given the fact that the solidus of carbonated mantle is significantly lower than that of volatile-free mantle, mantle metasomatism by carbonates may be critical to generate voluminous mafic magmas and to form the giant Xiarihamu Ni–Cu deposit and other magmatic sulfide deposits in convergent settings worldwide. The relatively high δ26Mg, high (87Sr/86Sr)i, and low εNd(t) of most orthopyroxenites, websterites, and gabbronorites were produced by extensive contamination of isotopically heavy crustal rocks in a deep-seated magma chamber. The slightly low δ26Mg, extremely high (87Sr/86Sr)i and negative εNd(t) of the marginal facies, compared with other websterites and gabbronorites, were governed by assimilation of local low-δ26Mg country rocks (e.g. gneiss and marble) at the Xiarihamu magma chamber during emplacement. These observations indicate that mafic–ultramafic cumulates away from marginal facies can preserve their primitive Mg–Sr–Nd isotope signatures inherited from deep magma chambers, even from mantle sources, with negligible crustal contamination during magma ascent and emplacement. These findings for the first time, to our knowledge, provide observational evidence to characterize the integrated magmatic processes of a single magma plumbing system from deep mantle source to magma chambers, which sheds light on the petrogenesis and mineralization of mafic–ultramafic intrusions.

Early Permian subduction-related Ni-Cu sulfide mineralization in the Central Asian Orogenic Belt: A case of the Halatumiao deposit

The recently discovered Halatumiao magmatic Ni-Cu sulfide deposit is located in the western part of the Baolidao terrane, which represents the middle-eastern segment of the Central Asian Orogenic Belt (CAOB), Inner Mongolia, NE China. This deposit is an important case of a magmatic sulfide deposit related to Early Permian subduction magmatism in an arc setting. In this contribution, we report in-situ zircon U-Pb ages, whole-rock major and trace element and PGE data, and Os and S isotope compositions from the Halatumiao ore-bearing intrusion to constrain its genesis and relationship to the Early Permian subduction-related magmatism. The Halatumiao mafic-ultramafic intrusion is composed of wehrlite, olivine websterite and gabbro. Semi-massive and disseminated sulfide mineralization with a pentlandite + pyrrhotite + chalcopyrite assemblage occurs in both mafic and ultramafic rocks of the intrusion. In-situ dating of magmatic zircon grains separated from an ultramafic rock sample yielded a U-Pb age of 292.3 ± 1.5 Ma. This age is very close to the age of the Erbutu Ni-Cu sulfide deposit (294.2 ± 2.7 Ma) located in the western part of the northern margin of the North China craton. The high Ni/Cu ratios (6.7 in average, except one sample) of ore samples indicate that the parental magma to the Halatumiao deposit was a primitive basalt. The good positive correlation between IPGEs (Ir vs. Os, Ru and Rh) indicates that fractional crystallization of MSS is the key factor for the PGE tenors. The positive γOs(t) values (from +46 to +68) and mantle-like S isotopic compositions (δ34S mostly between −1.5 and 0.5‰), The trace element characteristics show that a minor to moderate degree of crustal contamination (5–10%) has occurred in the magma. Fractional crystallization and crustal contamination were likely the key factors for sulfide saturation in the Halatumiao mafic magma. The relatively high Ni tenors of sulfides (avg. 6.4 wt%) indicate that the Late Paleozoic mafic-ultramafic intrusions abounding in the Xing’an-Inner Mongolia region have a good potential for hosting economic Ni-Cu sulfide mineralization.

Formation of Chromitite Seams and Associated Anorthosites in Layered Intrusion by Reactive Volatile-rich Fluid Infiltration

Abstract Drilling related to development of the platinum-group element deposit of the J-M Reef of the Stillwater Complex returned samples of a rare chromitite seam between anorthosite and norite in a discordant anorthositic body. Plagioclase core An concentrations are marginally higher and modestly reversely zoned on the norite side (average Ancore = 83·8; average Ancore – Anrim = –1·1) as compared with the anorthosite side (average Ancore 82·5; average Ancore – Anrim = +1·0). The anorthosites are also characterized by a slightly smaller average plagioclase grain size than plagioclase in the norite (1·41 mm and 1·54 mm, respectively). The chromite can contain single and polyphase inclusions of orthopyroxene, plagioclase, amphibole, biotite and Cl-rich apatite. These and other compositional and textural features, as well as inference from other discordant anorthositic bodies in the Banded series, are all consistent with a chromatographic model of chromite precipitation at a reaction front as a norite protolith reacts with a Cl-rich aqueous fluid saturated in plagioclase alone. Chromitite seam formation is modeled using an infiltration metasomatic model, in which a fluid becomes progressively undersaturated in pyroxene as it rises into the hotter part of the crystal pile. As this pyroxene-undersaturated fluid moves through a noritic protolith, it dissolves the Cr-bearing orthopyroxene to produce an anorthosite. Chromite precipitates at the reaction front between the anorthosite and the norite owing to liberation of Mg and Cr from pyroxene. Continuous redissolution and reprecipitation of chromite occurs as the pyroxene dissolution front moves in the direction of fluid flow, collecting the Cr lost from the anorthosite. Owing to Cr dissolved mainly as a neutral divalent cation complex, CrCl(OH)0, in the solution, but incorporated as a trivalent cation in chromite, the required redox reaction can involve concurrent precipitation of sulfide with chromite. This mechanism differs from some recent models in that the anorthosites are themselves replacement bodies and are not original precipitates from a magma nor formed by loss of mafic material by partial melting. The results show the need for experimental mineral solubility data at T and P conditions appropriate to upper crustal mafic–ultramafic intrusions.

Mafic-ultramafic intrusions with sulfide Cu-Ni-PGE mineralization: morphology and structural position

Mafic-ultramafic intrusions with sulfide Cu-Ni-PGE mineralization: morphology and structural position

World-Class Fe-Ti-V Oxide Deposits Formed in Feeder Conduits by Removing Cotectic Silicates

AbstractExtremely thick Fe-Ti-V oxide layers are hosted in mafic-ultramafic intrusions of the Emeishan large igneous province (LIP) in the Pan-Xi district of southwest China, accounting for a quarter of the world’s Ti and V resource. It is unclear why these small intrusions contain such huge ore reserves that form world-class Fe-Ti-V oxide deposits. We find that the Hongge intrusion contains 35% Fe-Ti-V oxides, which is twice the typical content in mafic-ultramafic intrusions worldwide and the experimentally determined cotectic proportion in natural ferrobasaltic magma systems. The V content is almost constant in titanomagnetite across the entire Hongge intrusion in the Emeishan LIP, indicating a small (10–20%) proportion of cotectic Fe-Ti-V oxide during fractional crystallization. The bulk composition of the intrusion indicates an open magma system at the time of its formation. Clinopyroxene phenocrysts from overlying basalts contain Fe-Ti-V oxide inclusions, indicating that the phenocrysts crystallized at depth from magma saturated in Fe-Ti-V oxide and were then transported to the surface. We suggest that these intrusions were feeder conduits to the overlying basalts, where the silicates were cotectic with Fe-Ti-V oxides which were then extracted from the underlying intrusion as phenocrysts. Such a fundamental process is key to increase the proportion of oxide minerals in the residual assemblage, thereby upgrading the barren oxide-bearing rocks to world-class Fe-Ti-V oxide deposits in the small intrusions of the Emeishan LIP. A similar process might have occurred in LIPs elsewhere, meaning that intrusions formed as conduit-like open systems to the basalts in LIPs are good exploration targets for giant high-grade Fe-Ti-V oxide deposits.

Tracking a continental deep subduction and exhumation from granulitized kyanite eclogites in the South Altyn Tagh, northern Qinghai-Tibet Plateau, China

Kyanite eclogites can provide insights into global orogenic processes within subduction-collision zones. Here we present an integrated study of the petrography, mineral chemistry, zircon U-Pb geochronology, and whole-rock geochemistry of granulitized kyanite eclogites from South Altyn Tagh, located at the northern margin of the Qinghai-Tibet plateau, China. Our results suggest that the rocks experienced eclogite-facies metamorphism (27–37 kbar, 1030–1068 °C), followed by a high pressure-ultra-high temperature (HP-UHT) stage (17–20 kbar, 945–1033 °C), isothermal decompression, and a medium pressure-(ultra)-high temperature (MP-(U)HT) (10–12 kbar, 810–950 °C) granulite-facies overprint.Zircon U-Pb dating yielded a weighted mean U-Pb age of ca. 500 Ma for the metamorphic domains, which is interpreted as the timing of HP-UHT metamorphism. In contrast, the age of ca. 800 Ma recorded by the inherited cores of zircon grains is considered to represent the protolith formation age. High Al2O3 and CaO and relatively low MgO and FeO contents, LREE enrichment and nearly flat HREE patterns, and enriched Sr-Nd isotopic compositions suggest that the protoliths of the granulitized kyanite eclogites were likely derived from an enriched mantle source affected by crustal contamination. These results, together with previous research on these associations suggested that the protoliths of granulitized kyanite eclogites and associated garnet peridotite in the Bashiwake area are derived from mafic-ultramafic intrusions composed of plagioclase-rich gabbroic rocks and olivine-rich cumulates. These mafic-ultramafic intrusions were possibly generated by plume-induced melting related to the rifting of the Rodinia supercontinent during the Neoproterozoic, and were later subjected to early Paleozoic metamorphism. The geodynamic model proposed envisages continental subduction followed by relamination of felsic and mafic-ultramafic associations at the base of the lower crust, which were subsequently exhumed, forming diapir-like bodies. Our results, combined with those from previous studies, not only provide insights into the processes of continental collision to exhumation, but also provide significant constraints on the geotectonic processes leading to the formation of HP rocks within subduction-collision orogens.

Geology and crystallization conditions of the Särkiniemiintrusion and related nickel-copper ore, central Finland – implications for depth of emplacement of 1.88 Ga nickel-bearing intrusions

Several Ni-Cu deposits occur within the Kotalahti area, central Finland, in proximity to an Archaean gneiss dome surrounded by a Palaeoproterozoic craton-margin supracrustal sequence comprising quartzites, limestones, calc-silicate rocks, black schists and banded diopside amphibolites. The geology of the area and age of the Ni-bearing intrusions (1.88 Ga) are similar to the Thompson Ni belt in the Canadian Trans-Hudson Orogen. The small mafic-ultramafic and Ni-Cu -bearing Särkiniemi intrusion, closely associated with the Archaean basement core of the Kotalahti Dome, is composed of a western peridotite and eastern gabbro body, both of which are mineralized. The eastern gabbro has a contact aureole several meters thick, consisting of orthopyroxene +/- cordierite bearing hornfels between the intrusion and the migmatites. Geochemically, the Särkiniemi intrusion shares many features in common with other Svecofennian mafic-ultramafic intrusions, including crustal contamination and nickel depletion. The related Ni-Cu deposit has a low Ni/Co value (15) and low nickel content in the sulphide fraction (2.8 wt.%), together with a low estimated magma/sulphide ratio of around 170. Svecofennian 1.88 Ga mafic-ultramafic intrusions occur in terrains of variable metamorphic grade (from low-amphibolite to granulite facies) and are likely to represent emplacement at different crustal depths. Multi-equilibrium thermobarometry indicates that the contact aureole at Särkiniemi reached equilibrium at pressures of 4.5–6 kbar (15–20 km depth) and temperatures of 600–670 °C. Combined with the results of earlier research on the Svecofennian intrusions, this study indicates that a depth of 15–20 km crustal level was favourable, along with other critical factors, for nickel sulfide deposition at 1.88 Ga.

Scandium: Ore deposits, the pivotal role of magmatic enrichment and future exploration

Scandium (Sc), known as the 'miracle metal', has unique properties in material sciences, and is a critical resource in the world due to the low supply but wide applications in advanced technology. Despite not extraordinarily sparse in the Earth’s crust, Sc is often dispersed and does not form ore deposits. Nonetheless, Sc can be occasionally concentrated to form magmatic, hydrothermal or supergene deposits. Magmatic deposits are estimated to contribute about 90% of the global Sc resources, in which Sc is primarily hosted in clinopyroxene ± amphibole in mafic–ultramafic intrusions. Hydrothermal enrichment of Sc is often associated with W-Sn mineralization in quartz-vein systems. Supergene deposits mainly include regolith-hosted deposits formed from weathering of mafic–ultramafic protolith and marine sediment-hosted deposits. Magmatic enrichment of Sc is essential to form many of these different types of Sc deposits. Partial melting of anhydrous fertile spinel peridotites could produce Sc-rich primary melts, whereas melts derived from garnet peridotites are generally of low Sc concentrations. Involvement of water during partial melting may not increase Sc concentrations in the primitive melts but, during fractional crystallization, the high water content can sufficiently suppress the crystallization of orthopyroxene and the Sc scavenging by orthopyroxene. Thereby, Sc could be enriched in the melts and subsequently concentrate in clinopyroxene and amphibole. Subduction environment, at where hydrous mafic–ultramafic melts could be generated, is likely favorable locality for exploring Sc deposits, such as the Sc-rich Alaskan-type mafic–ultramafic intrusions. Under favorable supergene conditions such as tropical and sub-tropical climate, regolith-hosted Sc deposits could develop from weathering of these Sc-rich mafic–ultramafic complexes.

Magma oxygen fugacity of mafic-ultramafic intrusions in convergent margin settings: Insights for the role of magma oxidation states on magmatic Ni-Cu sulfide mineralization

AbstractOxygen fugacities (fO2) of mantle-derived mafic magmas have important controls on the sulfur status and solubility of the magmas, which are key factors to the formation of magmatic Ni-Cu sulfide deposits, particularly those in convergent margin settings. To investigate the fO2 of mafic magmas related to Ni-Cu sulfide deposits in convergent margin settings, we obtained the magma fO2 of several Ni-Cu sulfide-bearing mafic-ultramafic intrusions in the Central Asian Orogenic Belt (CAOB), North China, based on the olivine-spinel oxygen barometer and the modeling of V partitioning between olivine and melt. We also calculated the mantle fO2 on the basis of V/Sc ratios of primary magmas of these intrusions.Ni-Cu sulfide-bearing mafic-ultramafic intrusions in the CAOB include arc-related Silurian-Carboniferous ones and post-collisional Permian-Triassic ones. Arc-related intrusions formed before the closure of the paleo-Asian ocean and include the Jinbulake, Heishan, Kuwei, and Erbutu intrusions. Post-collisional intrusions were emplaced in extensional settings after the closure of the paleo-Asian ocean and include the Kalatongke, Baixintan, Huangshandong, Huangshan, Poyi, Poshi, Tulaergen, and Hongqiling No. 7 intrusions. It is clear that the magma fO2 values of all these intrusions in both settings range mostly from FMQ+0.5 (FMQ means fayalite-magnetite-quartz oxygen buffer) to FMQ+3 and are generally elevated with the fractionation of magmas, much higher than that of MORBs (FMQ-1 to FMQ+0.5). However, the mantle fO2 values of these intrusions vary from ~FMQ to ~FMQ+1.0, just slightly higher than that of mid-ocean ridge basalts (MORBs) (≤FMQ). This slight difference is interpreted as the intrusions in the CAOB may have been derived from the metasomatized mantle wedges where only minor slab-derived, oxidized components were involved. Therefore, the high-magma fO2 values of most Ni-Cu sulfide-bearing mafic-ultramafic intrusions in the CAOB were attributed to the fractionation of magmas derived from the slightly oxidized metasomatized mantle. In addition, the intrusions that host economic Ni-Cu sulfide deposits in the CAOB usually have magma fO2 of >FMQ+1.0 and sulfides with mantle-like δ34S values (–1.0 to +1.1‰), indicating that the oxidized mafic magmas may be able to dissolve enough mantle-derived sulfur to form economic Ni-Cu sulfide deposits. Oxidized mafic magmas derived from metasomatized mantle sources may be an important feature of major orogenic belts.

Ultramafic xenoliths from aillikites in the Tarim large igneous province: Implications for Alaskan-type affinity and role of subduction

The Tarim large igneous province (TLIP) located in northwestern China is characterized by a relatively long duration of magmatism and complex lithology as compared to other global LIPs. Previous studies correlated these features to the interaction between mantle plume and subducted slab. However, no direct subduction-related magmatic records were so far recognized to support this interpretation. Here we report the petrological, mineralogical, and geochemical characteristics of a suite of ultramafic xenoliths occurring within aillikites from the northwestern margin of the TLIP. The xenoliths include dunite, wehrlite, olivine clinopyroxenite, clinopyroxenite, amphibole clinopyroxenite, clinopyroxene hornblendite, and hornblendite. These rocks show broadly similar mineralogy and are mainly composed of olivine, clinopyroxene and amphibole with rare phlogopite, chromite, and magnetite, in the absence of orthopyroxene and plagioclase. We evaluate the petrogenesis of these rocks based on whole-rock major and trace element compositions and mineral chemistry. The rocks exhibit enrichment of large ion lithophile elements (LILEs) relative to high field strength elements (HFSE) with negative Nb, Ta, and Ti anomalies, similar to the features of arc-like lavas. Their (87Sr/86Sr)t (0.7035–0.7041) and εNd(t) (1.17–5.67) values are consistent with depleted mantle source. The Mg# [molar Mg/(Mg + Fe2+)] and Fe3+# [molar Fe3+/(Fe3++Al + Cr)] values of spinel in the ultramafic xenoliths are consistent with those of the Alaskan-type mafic-ultramafic intrusions. The Al2O3 contents in clinopyroxene increase with decreasing Mg#, which is comparable with the Al2O3 variation trend of clinopyroxene in Alaskan-type and arc-related magma, in contrast to those of the LIPs. Our data establish that the ultramafic xenoliths in the aillikites are comparable to Alaskan-type ultramafic complexes, and correspond to magmatism associated with the southward subduction of oceanic plate beneath the Tarim craton during Neoproterozoic or Early Paleozoic. Our study provides direct evidence for the interaction between mantle plume and subducted slab in generating the TLIP.

Insights from canonical correlation analysis into sulfide migration during formation of disseminated ores in magmatic Ni–Cu–PGE sulfide deposits

Magmatic Ni–Cu–platinum group element (PGE) sulfide deposits form as the result of segregation of immiscible sulfide liquid from mafic–ultramafic magma. Sulfide ores formed in this process commonly take their places in the lower part of mafic–ultramafic intrusion, and many researchers attribute this phenomenon to gravity settling of dense sulfide droplets within lighter silicate magma. Some laboratory experiments, however, suggest that not all the sulfide droplets can migrate downward through crystal mush, especially those forming disseminated ores. On the basis of geochemical analysis, we employ a multivariate statistical method to investigate whether downward motion of sulfide droplets can happen during formation of disseminated ores. Two typical magmatic Ni–Cu–PGE sulfide deposits, namely the Hongqiling and Kalatongke deposits, were selected, and the relationship between sulfide composition (bulk-rock Cu, Ni, S, and PGE contents) and silicate composition (bulk-rock SiO2, Al2O3, K2O, Na2O, CaO, and MgO contents) was investigated by canonical correlation analysis (CCA). The result shows that there is a strong relationship between the sulfide and silicate compositions in the disseminated ores, which indicates that the sulfide droplets may have formed from the local crystal mushes, and furthermore that they have not migrated away from the crystal mushes. Hence, we conclude that sulfide droplets that form disseminated ores may tend not to migrate downward for long distances after segregating from mafic–ultramafic magma.

PLATINUM-BEARING PLACERS: MINERAL ASSOCIATIONS AND THEIR 190Pt-4He AND Re-Os AGES, AND POTENTIAL LINKS WITH LARGE IGNEOUS PROVINCES IN THE SIBERIAN CRATON

AbstractPlacer deposits in the Siberian platform are closely associated with well-known platiniferous intrusions (Kondyor, Inagli, Noril’sk, Chiney, and Guli) but there are also abundant platinum-group mineral (PGM) placers of large areal extent in the river basins of Siberia (Vilyui, Lena, Aldan, Anabar, and Olenek) for which the primary sources are unknown. The 190Pt-4He dating method is introduced, compared with existing Re-Os isotope dating of PGMs, and applied to Pt-bearing placers of Siberia. Correlations between the 190Pt-4He and Re-Os isotope ages of the PGMs and with ages of major magmatic events in the Siberian craton show that the potential sources for some of the placers are likely buried Precambrian mafic-ultramafic intrusions of Large Igneous Provinces (LIP). The approach of this paper can be applied to other cratonic areas with alluvial PGMs of unknown origin.

Tectonomagmatic Setting and Cu-Ni Mineralization Potential of the Gayahedonggou Complex, Northern Qinghai–Tibetan Plateau, China

The Gayahedonggou magmatic Cu-Ni sulfide deposit was recently discovered in the East Kunlun orogenic belt (Northern Tibetan Plateau, China). The mineralization in this region is associated with mafic–ultramafic intrusions. To date, the formation age and metallogenic model of these ore-bearing intrusions have not been studied systematically. In this paper, the petrology, zircon U-Pb chronology, and geochemistry of ore-bearing wehrlite and quartz diorite are investigated. The results show that the zircon U-Pb isotopic age of wehrlite is 419.9 ± 1.5 Ma with an average εHf(t) value of 3.0, indicating that wehrlite originated from a depleted mantle or the asthenosphere. The (La/Yb)N, (La/Sm)N, (Gd/Yb)N, Nb/U, and Ce/Pb ratios of wehrlite are between 3.01–7.14, 1.69–3.91, 1.36–1.51, 2.07–2.93, and 0.55–1.42, respectively, indicating that the parent magma of the wehrlite had been contaminated by the upper crust. The zircon U-Pb isotopic age of quartz diorite is 410.2 ± 3.5 Ma with an average εHf(t) value of 8.0, and the A/CNK and A/NK ratio of quartz diorites ranges from 1.02 to 1.04 and from 2.13 to 2.23, respectively. These features are similar to those of the type I granite, and the quartz diorite was likely derived from the lower crust. Combined with the regional geological evolution, the Gayahedonggou complex formed in a post-collision extensional environment. The pyroxene in the Gayahedonggou complex is mainly clinopyroxene, which is enriched in the CaO content, indicating that the CaO content of the parent magma of the Gayahedonggou complex is high or that the complex has been contaminated by Ca-rich surrounding rocks, which hinders Cu-Ni mineralization.

Sr-Nd-Hf-O isotope constraints on crustal contamination and mantle source variation of three Fe-Ti-V oxide ore deposits in the Emeishan large igneous province

Magma-carbonate interaction and recycled oceanic crust in the mantle source are thought to have played a critical role in the genesis of magmatic Fe-Ti-V oxide ore deposits in the Emeishan mantle plume-related large igneous province in southwestern China. To test these hypotheses, we have carried out a combined study of zircon Hf-O isotopes and whole-rock Sr-Nd isotopes on three representative magmatic Fe-Ti-V oxide ore deposits associated with different types of wall-rock in the province: the Hongge and Taihe deposits with granitoid wall-rocks in most places, and the Panzhihua deposit with marble wall-rocks. Diopside-garnet marble xenoliths are common in the host gabbros of the Taihe deposit. The zircon separates used in this study are all from the mineralized units of the host layered mafic–ultramafic intrusions. The selected zircon grains yield U-Pb isotopic ages of 258.2 ± 2.8 Ma for Hongge intrusion, 263.3 ± 2.2 Ma for Taihe intrusion, and 257.6 ± 2.1 Ma for Panzhihua intrusion. The Hf-O isotopes of the zircon separates are εHf(t) from 3.1 to 4.7 and δ18O from 5.77 to 6.45‰ for Hongge, εHf(t) from 8.3 to 9.8 and δ18O from 4.12 to 4.56‰ for Taihe, and εHf(t) from 4.6 to 6.3 and δ18O from 5.49 to 6.10‰ for Panzhihua. The zircon δ18O values of the Taihe deposit are significantly lower than the mantle zircon values (5.3 ± 0.3‰), whereas those of the Hongge and Panzhihua deposits are higher than the mantle values. The initial 87Sr/86Sr and εNd(t) of the whole rock samples from the deposits are similar, from 0.7047 to 0.7052 and from 2.3 to 3.1, respectively. The observed decoupling of zircon Hf-O isotopes (low δ18O and high εHf(t) values) in the Taihe deposit is most consistent with a high-temperature altered, low δ18O oceanic gabbroic component in the plume source for this deposit. All of the isotope data together show that the parental magmas for these deposits experienced different types of crustal contamination. Contamination with the Precambrian metamorphic country rocks is much more significant in the parental magma for the Hongge deposit than those for the Panzhihua and Taihe deposits. On the other hand, contamination with marble country rocks is more pronounced in the parental magmas for the Panzhihua and Taihe deposits than in the parental magma for the Hongge deposit. An important new finding from this study is that these deposits are not linked to the same component of the mantle plume nor a single type of crustal contamination.

Early Archean alteration minerals in mafic-ultramafic rocks of the Barberton greenstone belt as petrological analogs for clay mineralogy on Mars

AbstractCharacterization of terrestrial analog sites is critical for detection and determination of clay miner-alogy in remote sensing studies of Mars aimed at geological, hydrological, and potentially biological investigations. In this study, we investigate a suite of hydrothermally altered early Archean rocks from the Barberton greenstone belt (BGB) of South Africa as potential petrological, mineralogical, and spectral analogs to hydrothermally altered metabasalts and mafic-ultramafic intrusions in the martian subsurface and impact craters. We present the first spectral imaging measurements on exceptionally well-preserved early Archean mafic-ultramafic rocks from the BGB, with the aim of studying their clay mineralogy and spectral signatures. Multiple spectral analyses were conducted on different sample textures (rock powders, crushed rocks, and rock slabs) appropriate for Mars rover and remote sensing exploration. Visible/near-infrared (VNIR) and mid-IR reflectance spectra were acquired on particulate samples, while VNIR spectral imaging data were collected on rock slabs. Mid-IR emission spectra were measured for the rock slabs and grains. Spectral features are compared from these different spectral techniques to identify the minerals present in the samples and compare macroscale vs. microscale detections. The measured spectra reveal absorption bands that correspond to clay mineral-ogy of the serpentine and chlorite mineral groups, consistent with petrographic observations, as well as magnetite, olivine, quartz, feldspar, and Al-phyllosilicate. The spectral data acquired in this study expand the reference spectra data set for remote sensing studies. The implications of this study are that rocks from early Archean greenstone belts, such as those of the BGB, serve as potential clay-bearing petrological analogs for hydrothermal environments on Mars.

Emplacement of magmatic Cu-Au-Te(-Ni-PGE) sulfide blebs in alkaline mafic rocks of the Mordor Complex, Northern Territory, Australia

Magmatic Ni-Cu-PGE sulfide mineralisation is mostly confined to tholeiitic to komatiitic mafic-ultramafic intrusions, yet there have been an increasing number of occurrences recorded in alkaline-ultramafic, post-collisional magmatic systems, particularly in the lower and middle crust that generally display a characteristic Cu-Au-Te enrichment over more conventional Ni-Cu(-PGE) mineralisation. The Mordor Alkaline Igneous Complex, Australia, is a mid-crustal, zoned alkaline complex comprised of a syenite body with an alkaline mafic-ultramafic subcomplex containing dunites, wehrlites and shonkinites. Sulfide mineralisation is present either in thin, PGE-enriched stratiform ‘reefs’ within layered ultramafics in the centre of the subcomplex, or in thicker zones of Cu(-Au-PGE-Te) sulfide hosted by phlogopite-rich shonkinites towards the intrusion margins. This latter style comprises blebs of pyrite, chalcopyrite and minor millerite and PGE tellurides formed from the cooling of a Cu-dominant sulfide liquid. Primary igneous calcite is present in intimate association with the sulfide. We note that the circular nature of the complex, with a dunite core and shonkinite rim with chalcophile element mineralisation, is comparable to the pipe-like, intracratonic, alkaline-ultramafic Aldan Shield intrusions in Russia. As such, Mordor may have an intracratonic rather than post-collisional affinity. Nevertheless, sulfide mineralisation is typical of other alkaline-hosted occurrences, with a Cu-Au-Te-rich signature, low Ni contents and textural association with calcite, supporting models of chalcophile metal and S fluxing alongside carbonate in alkaline systems derived from low degrees of partial melting of hydrous and carbonated mantle sources. Mordor illustrates that alkaline igneous rocks are prospective for magmatic Cu-Au-PGE-Ni sulfide mineralisation, and the classic ‘marginal base metal– and sulfide-rich’ and ‘stratiform PGE-rich and sulfide-poor’ mineralisation styles may both be found in such intrusions.