Ultra-low Temperature Research Articles

Compressive stress-strain relationship of steam free reactive powder concrete at ultra-low temperatures

To explore the applicability of reactive powder concrete (RPC) as a material for LNG storage tanks, the mechanical properties of RPC at ultra-low temperatures were investigate in this paper. Forty-two axial compressive strength tests were conducted on RPC prisms at 20 °C ∼ −165 °C. The influence of temperature and steel fiber on the compressive stress-strain relationship of RPC at ultra-low temperatures was evaluated. The results showed that the axial compressive strength of RPC increases at low temperatures, with a compressive strength increase of over 70 % at −165 °C compared to room temperature. The increase in compressive strength of RPC at ultra-low temperatures is significantly greater than that of ordinary concrete. A relation for predicting the axial compressive strength development of RPC at ultra-low temperatures was also proposed. Steel fibers can increase the toughness of RPC at ultra-low temperatures to a certain extent, and effectively improve the failure mode of RPC, allowing the damaged RPC to maintain its integrity. This work provides a basis for RPC applicability as LNG storage tanks.

Ultralow‐Temperature (≤ −80 °C) Proton Pseudocapacitor with High Power‐Energy Density Enabled by Tailored Proton‐Rich Electrolyte and Electrode

AbstractProton‐based energy storage systems provide a more sustainable alternative for large‐scale energy storage applications. However, conventional proton batteries/pseudocapacitors suffer from severe capacity loss because of reduced ionic conductivity and water‐to‐ice conversion at ultralow temperatures. Here, anti‐freezing proton‐rich electrolytes with ultralow freezing point (below −80 °C) and high conductivity (7.89 mS cm−1 at −80 °C) are developed, combined with open framework‐structured Prussian blue analogous (VHCF) electrodes with proton‐rich binding sites, to construct a promising proton pseudocapacitor at ultralow temperatures. Hydrogen bond‐induced solvated structures and physicochemical properties are clarified by comprehensive characterization techniques and computational simulations. Temperature‐dependent structure and valence changes for VHCF electrodes at low temperatures are revealed, where the multi‐electron transfer reaction is affected by temperature to limit the capacity output. The proton pseudocapacitor (VHCF//6 m H2SO4//MoO3‐x) achieves excellent electrochemical performance in the temperature range from −80 to 25 °C, and delivers a voltage window of 0 to 2.8 V and a high energy density of 74.9 Wh kg−1 at −80 °C. This proton‐rich electrolyte‐electrode design principle suggests an effective strategy enabling next‐generation energy technology under extreme conditions.

Magnetic anisotropy and GGG substrate stray field in YIG films down to millikelvin temperatures

Quantum magnonics investigates the quantum-mechanical properties of magnons, such as quantum coherence or entanglement for solid-state quantum information technologies at the nanoscale. The most promising material for quantum magnonics is the ferrimagnetic yttrium iron garnet (YIG), which hosts magnons with the longest lifetimes. YIG films of the highest quality are grown on a paramagnetic gadolinium gallium garnet (GGG) substrate. The literature has reported that ferromagnetic resonance (FMR) frequencies of YIG/GGG decrease at temperatures below 50 K despite the increase in YIG magnetization. We investigated a 97 nm-thick YIG film grown on 500 μm-thick GGG substrate through a series of experiments conducted at temperatures as low as 30 mK, and using both analytical and numerical methods. Our findings suggest that the primary factor contributing to the FMR frequency shift is the stray magnetic field created by the partially magnetized GGG substrate. This stray field is antiparallel to the applied external field and is highly inhomogeneous, reaching up to 40 mT in the center of the sample. At temperatures below 500 mK, the GGG field exhibits a saturation that cannot be described by the standard Brillouin function for a paramagnet. Including the calculated GGG field in the analysis of the FMR frequency versus temperature dependence allowed the determination of the cubic and uniaxial anisotropies. We find that the total crystallographic anisotropy increases more than three times with the decrease in temperature down to 2 K. Our findings enable accurate predictions of the YIG/GGG magnetic systems behavior at low and ultralow millikelvin temperatures, crucial for developing quantum magnonic devices.

Electrically tunable giant Nernst effect in two-dimensional van der Waals heterostructures

The Nernst effect, a transverse thermoelectric phenomenon, has attracted significant attention for its potential in energy conversion, thermoelectrics and spintronics. However, achieving high performance and versatility at low temperatures remains elusive. Here we demonstrate a large and electrically tunable Nernst effect by combining the electrical properties of graphene with the semiconducting characteristics of indium selenide in a field-effect geometry. Our results establish a new platform for exploring and manipulating this thermoelectric effect, showcasing the first electrical tunability with an on/off ratio of 103. Moreover, photovoltage measurements reveal a stronger photo-Nernst signal in the graphene/indium selenide heterostructure compared with individual components. Remarkably, we observe a record-high Nernst coefficient of 66.4 μV K−1 T−1 at ultralow temperatures and low magnetic fields, an important step towards applications in quantum information and low-temperature emergent phenomena.

Research on temperature distribution in container ship with Type-B LNG fuel tank based on CFD and analytical method

The liquefied natural gas (LNG) fuel tank in a large container ship is loaded with liquid LNG at an ultra-low temperature (-163°C), there is a significant temperature difference in the cargo hold area where the entire fuel tank is located, which will have an important impact on the steel grade design and structural safety of the cargo tank in container ship. This paper develops two heat transfer models using Computational Fluid Dynamics method (CFD method) and an analytical method to analyze the temperature distribution in a large container ship equipped with Type-B LNG fuel tank. These models incorporate the arrangement and heat transfer characteristics of LNG fuel tanks. The temperature field analysis is conducted under typical the environmental conditions specified in the Code for the Construction and Equipment of Ships Transporting Liquefied Gas in Bulk (IGC Code) and the United States Coast Guard Code (USCG Code), based on the CFD method and the analytical method, and the results of temperature field distribution are compared. Additionally, a parametric analysis of the hull temperature field is further carried out, the results show that the thermal conductivity of the insulation layer in LNG storage tanks and the types of the loaded liquid cargo have a limited impact on the final temperature field distribution in hull structure. However, the selection of steel grade in the local structure of the cargo hold, especially in the inner hull part, may lead to significant changes.

Negligible normal fluid in superconducting state of heavily overdoped Bi2Sr2CaCu2O8+δ detected by ultra-low temperature angle-resolved photoemission spectroscopy

Negligible normal fluid in superconducting state of heavily overdoped Bi2Sr2CaCu2O8+δ detected by ultra-low temperature angle-resolved photoemission spectroscopy

The extremotolerant desert moss Syntrichia caninervis is a promising pioneer plant for colonizing extraterrestrial environments

Many plans to establish human settlements on other planets focus on adapting crops to growth in controlled environments. However, these settlements will also require pioneer plants that can grow in the soils and harsh conditions found in extraterrestrial environments, such as those on Mars. Here, we report the extraordinary environmental resilience of Syntrichia caninervis, a desert moss that thrives in various extreme environments. S.caninervis has remarkable desiccation tolerance; even after losing >98% of its cellular water content, it can recover photosynthetic and physiological activities within seconds after rehydration. Intact plants can tolerate ultra-low temperatures and regenerate even after being stored in a freezer at -80°C for 5 years or in liquid nitrogen for 1month. S.caninervis also has super-resistance to gamma irradiation and can survive and maintain vitality in simulated Mars conditions; i.e., when simultaneously exposed to an anoxic atmosphere, extreme desiccation, low temperatures, and intense UV radiation. Our study shows that S.caninervis is among the most stress tolerant organisms. This work provides fundamental insights into the multi-stress tolerance of the desert moss S.caninervis, a promising candidate pioneer plant for colonizing extraterrestrial environments, laying the foundation for building biologically sustainable human habitats beyond Earth.

A Review of the Analysis of Austenitic Stainless Steel, Welding Methods, and Ultra-Low Temperature Characteristics for the Manufacture of Liquefied Hydrogen Tanks

Paris agreement’s goal was to the increase in the global average temperature to well below 2℃ above pre-industrial levels and limit global temperature increase to 1.5℃ above pre-industrial levels. The International Maritime Organization (IMO) has reinforced regulations regarding sulfur content, aiming to limit the sulfur content of ship fuel oil from 3.5% to 0.5% from 2020. LNG fuel contains a small amount of sulfur, enabling compliance with IMO’s sulfur content regulations and effectively reducing carbon emissions. However, the main component of LNG is liquefied methane, which has limitations due to methane emissions generated during LNG production, transportation, and distribution. Hydrogen energy is in the spotlight as an alternative fuel to significantly reduce greenhouse gases such as carbon monoxide, carbon dioxide, and methane. In the case of liquid hydrogen, rather than gaseous hydrogen, the volume is reduced to 1/800, increasing the storage and transport efficiency of hydrogen by about seven times. Additionally, there is an advantage that a separate dehydrogenation process is not required. The most promising material for liquefied hydrogen tanks is austenitic stainless steel (ASS), although there are various materials that can be considered. It is expected that the use of ASS will be actively pursued in the future, especially for applying storage tanks to maritime transportation, where welding is essential. Evaluation methods of the physical properties of the weld in a cryogenic atmosphere for the stability of the liquefied hydrogen storage tank were also discussed.

An efficient numerical method for modeling silver powder heat exchanger in dilution refrigerator

Dilution refrigerator provides continuous ultralow temperature environments as low as 10 mK. It has been widely used in a variety of important applications such as quantum computations. The silver powder heat exchanger in a dilution refrigerator plays a crucial role in realizing ultralow temperatures on the order of 10 mK by precooling the circulation of helium mixtures. To study the silver powder heat exchanger quantitatively, we have proposed an efficient numerical solution method for its thermodynamic model. This method utilizes constraint conditions cleverly to convert the initial value problem of differential equations into a boundary value problem, allowing us to solve the control equations using the existing ODE function quickly. Furthermore, we demonstrate the application of this method in the evaluation and design of silver powder heat exchanger. The research results of this paper have certain significance for the development of dilution refrigerator.

Atomic Level-Macroscopic Structure-Activity of Inhomogeneous Localized Aggregates Enabled Ultra-Low Temperature Hybrid Aqueous Batteries.

The utilization of hybrid aqueous electrolytes has significantly broadened the electrochemical and temperature ranges of aqueous batteries, such as aqueous zinc and lithium-ion batteries, but the design principles for extreme operating conditions remain poorly understood. Here, we systematically unveil the ternary interaction involving salt-water-organic co-solvents and its intricate impacts on both the atomic-level and macroscopic structural features of the hybrid electrolytes. This highlights a distinct category of micelle-like structure electrolytes featuring organic-enriched phases and nanosized aqueous electrolyte aggregates, enabled by appropriate low donor number co-solvents and amphiphilic anions. Remarkably, the electrolyte enables exceptional high solubility, accommodating up to 29.8 m zinc triflate within aqueous micelles. This configuration maintains an intra-micellar salt-in-water setup, allowing for a broad electrochemical window (up to 3.86 V), low viscosity, and state-of-the-art ultralow-temperature zinc ion conductivity (1.58 mS cm-1 at -80 °C). Building upon the unique nature of the inhomogeneous localized aggregates, this micelle-like electrolyte facilitates dendrite-free Zn plating/stripping, even at -80 °C. The assembled Zn||PANI battery showcases an impressive capacity of 71.8 mAh g-1 and an extended lifespan of over 3000 cycles at -80 °C. This study opens up a promising approach in electrolyte design that transcends conventional local atomic solvation structures, broadening the water-in-salt electrolyte concept.

Mechanical properties of base metal and heat-affected zone in friction-stir-welded AA6061-T6 at ultra-low temperature of 20 K

This study investigates the mechanical properties of a friction-stir-welded (FSW) AA6061-T6 aluminum alloy at ultra-low temperature (ULT) of 20 K. In-situ neutron diffraction and orientation imaging microscopy were employed to compare the tensile deformation behavior of the base metal (BM) and heat-affected zone (HAZ) in the FSW aluminum plate. The results demonstrate that compared to room-temperature (RT), ULT induces a significant improvement in tensile strength and ductility in both the BM and HAZ. The enhanced mechanical properties in BM at ULT result from a more homogeneous deformation than occurs at RT. On the other hand, HAZ at ULT exhibits an even lower yield strength than at RT, but the strain hardening rate (SHR) is the most significant among the alloys, leading to a tensile strength of 346 MPa and the highest ductility of 46.8%. The lowest yield strength corresponds to the lowest-hardness zones in HAZ, caused by dissolved/coarsened precipitates during the FSW process. The highest SHR in HAZ at ULT is attributed to the hardening of the {111} grain families and finer dislocation cell structures. The dislocation densities of both the BM and HAZ increased considerably during tensile deformation at ULT, which accounts for the improvement in tensile strength. Revealing the mechanism behind the remarkable improvement in the mechanical properties of FSW AA6061-T6 at ULT suggests its applicability for cryogenic applications.

Mechanical properties of Q235 and 20# steel after CO2 fire extinguishing treatment

The carbon dioxide fire extinguishing process can produce temperatures as low as −80 °C. However, the effect of rapid cooling and ultralow temperatures on the properties of steel is not yet clear. To accurately evaluate the effect of CO2 fire extinguishing on the mechanical properties of crude oil tank walls (Q235-B) and accessory and pipe materials (20#), this study employs tensile, Charpy impact, and bending tests to analyze the changes in the primary mechanical properties of Q235-B and 20# steels after three pretreatments: high-temperature burning, CO2 spraying, and CO2 fire extinguishing. The results of the study show that 1) the high-temperature burning process and short-term spraying of CO2 after fire may damage the mechanical properties of steel; 2) the rapid use of CO2 spraying after fire does not damage the mechanical properties of Q235-B or 20#; and 3) the three pretreatments investigated have little effect on the bending properties of all the specimens.

Study on the Influencing Factors on the Effectiveness of Liquid Nitrogen Fracturing Technology

Liquid nitrogen fracturing technology is a new fracturing and permeability enhancement technology for reservoirs unsuitable for hydraulic fracturing, and its ultralow temperature, high compression ratio, high freezing and expansion force, and low viscosity characteristics are expected to provide a program for fracturing and permeability enhancement in low-permeability reservoirs. The paper systematically analyzes the influencing factors restricting the effect of liquid nitrogen fracturing, aiming to provide theoretical basis and technical support for the efficient and environmentally friendly exploitation of low-permeability oil and gas fields.

A solvent-free processed low-temperature tolerant adhesive

Ultra-low temperature resistant adhesive is highly desired yet scarce for material adhesion for the potential usage in Arctic/Antarctic or outer space exploration. Here we develop a solvent-free processed low-temperature tolerant adhesive with excellent adhesion strength and organic solvent stability, wide tolerable temperature range (i.e. −196 to 55 °C), long-lasting adhesion effect ( > 60 days, −196 °C) that exceeds the classic commercial hot melt adhesives. Furthermore, combine experimental results with theoretical calculations, the strong interaction energy between polyoxometalate and polymer is the main factor for the low-temperature tolerant adhesive, possessing enhanced cohesion strength, suppressed polymer crystallization and volumetric contraction. Notably, manufacturing at scale can be easily achieved by the facile scale-up solvent-free processing, showing much potential towards practical application in Arctic/Antarctic or planetary exploration.

Quality analysis of dough and steamed bread under various freezing conditions.

Freezing is a crucial step in the process of frozen foods. In this study, the effects of different freezing methods, including liquid nitrogen immersion freezing (LF), quick-freezing machine freezing (QF), packaging immersion freezing (PF), and ultralow temperature refrigerator freezing (UF), and freezing time (0, 15, 30, and 60 days) on the textural properties, dynamic rheological properties, water distribution, and structure of dough and the quality of end steamed bread were evaluated. Freezing resulted in a decline in the physicochemical properties of dough. UF- and QF-doughs had higher storage modulus and loss modulus, compared with PF- and LF-doughs. LF enhanced the textural attributes of the dough, resulting in reduced hardness and increased springiness. At 15 days of freezing, QF- and LF-doughs exhibited a compact and continuous structure with a smooth surface. Additionally, the correlation analysis elucidated that the weight loss rate and the bound water content of the dough had discernible impacts on the texture of both the dough and the resulting steamed bread. Overall, LF demonstrated a relatively high freezing efficiency and effectively maintained the quality of the dough for up to 15 days of freezing. These results offer valuable insights for the applications of freezing methods and time in frozen foods.

Density profile of 3He in a nanoscale 3He-4He superfluid film determined by neutron scattering

For decades, superfluid helium has attracted the interest of the scientific community as an extremely pure realisation of a quantum liquid, only accessible at temperatures close to absolute zero. Previously, helium films have only been observed directly using X-rays. However, this method is limited to temperatures above 1 K due to the high levels of energy deposition, and it also suffers from an inability to distinguish between helium isotopes. Here we show that a 3He layer on top of a phase separated mixture film at 170 mK gradually dissolves into the 4He with increasing temperature. We also observe an anomaly in film behaviour near 300 mK and unexpected restoration of the layered structure at 1.5 K which is consistent with a re-entrant phase transition leading to the suppression of superfluidity in the film near 300 mK. Our successful application of neutron scattering to study helium films at ultra-low temperatures opens up new possibilities for future research.

Relay Adsorption in Metal-Organic Frameworks for One-Step Helium Purification at Ambient Temperature.

One-step He purification from natural gas represents a crucial solution for addressing the global He shortages. The prevailing method to produce high-grade He involves cryogenic distillation and ultralow temperature adsorption processes, which is highly cost- and energy-intensive. Separating and purifying He at ambient temperature is a great challenge because the fundamental limitation lies in the boiling point, polarizability, and kinetic diameters of CH4/N2/He gases. In this study, we seek to implement a relay adsorption strategy using Ni(ina)2 and MIL-100(Cr) metal-organic frameworks (MOFs) to produce high-purity He from ternary mixtures (CH4, N2, and He) at ambient temperature. The CH4/He selectivity in Ni(ina)2 and N2/He selectivity in MIL-100(Cr) both reach record 15.39 and 128.49, respectively, making the relay adsorption for helium purification highly efficient. The breakthrough experiments show that the two MOFs can sequentially adsorb CH4 and N2 in ternary mixtures, producing He with a purity of up to 99.99% in one step. The remarkable separation performance and stability of these MOFs underscore the industrial potential in purifying He at ambient temperature.

Anti-crosstalk fiber-optic directional torsion sensor via intensity-modulated Lyot filter

In this paper, a fiber-optic directional torsion sensor based on the intensity modulated Lyot filter is completed to alleviate the crosstalk from ambient temperature and axial strain. The transmission is analyzed and compared with the varied twisted length. The experimental results show that the torsion response of 1.18 dB/° can be achieved by the 45° incident angle and 10-cm twisted length, with tiny wavelength shift (∼0.012 nm/°) and minimum range of π-phase jumping. Meanwhile, the crosstalk is well compressed within 0.006°/με and 0.23°/°C owing to ultralow axial-strain and temperature responses. In addition, an in-field test is performed electrically and the detection limit of 0.08° is witnessed experimentally.

A New Family of SO42–‐Templated 3d‐4f High‐Nuclearity Clusters: Syntheses, Structures, and Magnetic Properties†

Comprehensive SummaryThe precise syntheses of transition–rare‐earth metal clusters with desired structures remain a great challenge. Herein, by utilizing SO42– anion released by in‐situ decomposition of sodium dodecyl sulfate (SDS) as a template, a series of novel high‐nuclearity 3d‐4f clusters, formulated as [Ni24Pr22(μ3‐OH)31(pida)24(SO4)4(NO3)9(CH3COO)3]·Br4·(NO3)11·16H2O·25CH3OH (1, H2pida = N‐phenyliminodiacetic acid), [Ni24Nd22(μ3‐OH)31(pida)24(SO4)4(NO3)9(CH3COO)3]·Br4·(NO3)11·14H2O·24CH3OH (2) and [Ni24Gd22(μ3‐OH)36(bida)24(SO4)7(NO3)3(CH3COO)3]·(SO4)·Br4·(NO3)4·31H2O·32CH3OH (3, H2bida = N‐benzyliminodiacetic acid), have been successfully isolated. X‐ray crystal structure analyses reveal that all the cationic {Ni24RE22} cores in 1—3 possess a ball‐like structure with C3v symmetry, and can be viewed as consisting of an inner {RE22} core and an outer {Ni24} shell. From 1 and 2 to 3, due to the lanthanide contraction effect, the coordination numbers for rare‐earth metal centers in {RE22} are different, resulting in different number of SO42– and NO3– anions to support and stabilize the skeleton structures. Meanwhile, the magnetic properties of complexes 1—3 were also studied. The result revealed that complexes 1—3 show antiferromagnetic/ferrimagnetic interactions, and 3 exhibits magneto‐caloric effect at ultralow temperatures with a maximum –ΔSm (magnetic entropy change) value of 33.03 J·kg−1·K−1 at 3.0 K and 7 T.

Ultralow-freezing-point (−70 °C), organic solvent-free aqueous electrolyte with superior ionic conductivity and thermodynamics stability

Water-in-salt and organic solvent-additive strategies have significantly improved the electrochemical stability window of aqueous electrolyte, while it still faces poor low-temperature thermodynamics stability and unsatisfied transport kinetics, as well as flammability risks caused by organic solvent. Herein we report a novel “cation-water-urea ternary interaction strategy” via environmental-friendly and non-flammable urea (CO(NH2)2) to solve the above dilemma. The cation-water-urea ternary interaction strategy preferentially develops CO(NH2)2-cation solvation structures for weakened cation-anion associations, improved anti-salt-precipitation capability, and thus enhanced ionic conductivity, meanwhile it improves the low-temperature thermodynamics stability via the stronger CO(NH2)2-water hydrogen-bond interactions to suppress the freezing and electrolysis of water. The optimum ternary aqueous electrolyte exhibits an ultralow freezing point (−70 °C), wide electrochemical stability window (2.9 V) and outstanding ionic conductivity (135 mS cm−1@25 °C and 5.3 mS cm−1@−50 °C), demonstrating superior performance compared to traditional organic solvent-additive and water-in-salt electrolytes. Finally, to demonstrate its potential for practical applications, ternary aqueous electrolyte-based supercapacitors are fabricated using commercial activated carbon electrodes, which exhibit outstanding capacitance retention (71.4 %) and much lower ion transport resistance even at ultralow temperature of −40 °C. This work proposes a novel ternary aqueous electrolyte with improved thermodynamics stability and kinetics for safe, low-temperature energy storage applications.