Ultrafast Recovery Time Research Articles

Narrow bandgap two-dimensional Nb2SiTe4 as broadband saturable absorber for optical switch

Nb2SiTe4 is a novel narrow-bandgap (∼0.39 eV) two-dimensional material with a high optical absorption coefficient, high carrier mobility, and outstanding air stability, which shows great application potential in broadband optical switches. In this study, high-quality layered Nb2SiTe4 nanosheets were efficiently fabricated by the mechanical exfoliation method, and the basic characterizations were carried out comprehensively. Nondegenerate pump-probe technology was implemented to systematically explore the photocarrier dynamics in the Nb2SiTe4 nanosheets, which exhibit the ultrafast recovery time of Nb2SiTe4 (∼0.3 ps). Furthermore, broadband passively Q-switched lasers operating at 1.0, 2.0, and 2.8 μm with the shortest pulse width of 380, 549, and 218 ns were achieved based on Nb2SiTe4 saturable absorber. This work demonstrates the significant advantages of an optical switch based on Nb2SiTe4 saturable absorber, including a narrow output pulse width, wide working bandwidth, high damage threshold, excellent oxidation resistance, and a straightforward synthesis method, which underscore the immense potential of Nb2SiTe4 broadband optical switches in applications involving mid-infrared lasers.

A humidity-driven film with fast response and continuous rolling locomotion

The widespread availability and easy accessibility of humidity make it essential to explore simple and low-cost methods to prepare structurally and materially efficient humidity-driven actuators with spontaneous and continuous locomotion to facilitate the application of bionic devices, intelligent sensors, and soft robots. Herein, this paper reports a humidity-driven monolayer film actuator. It is self-assembled from agarose (AG) and graphene oxide (GO) modified with polyvinylpyrrolidone (PVP), referred to as PGO, using a simple casting method. The PGO/AG composite film actuator exhibits an ultra-fast humidity response time (124.58° s−1) and recovery time (18.87° s−1), enabling rapid rolling locomotion driven by water evaporation. Notably, the programmable surface patterning of the PGO/AG composite film actuator with graphite results in a shorter single rolling time (0.43 s) and a faster rolling speed (28.73 mm s−1). Based on these advantages, the PGO/AG film actuator can mimic the opening and closing of flowers, mimosas, and fast-crawling robot driven by periodic water vapor (9.9 body length min−1). This finding provides new insights into the design of multifunctional actuators based on humidity-driven films.

A capacitive humidity sensor based on nanodiamond/silver nanoparticles (ND/Ag) nanocomposite with high stability and rapid response for respiratory monitoring

In this work, a high-performance capacitive humidity sensor based on nanodiamond/silver nanoparticles (ND/Ag) nanocomposite is proposed. The influence of silver nanoparticles with different content in nanodiamond is investigated, and the optimum ratio of 5 wt% Ag in the composite shows the maximum humidity sensing performance, which is three times than that of the pure nanodiamond based humidity sensor. Moreover, the proposed sensor exhibits a superior repeatability, ultrafast response time (<2 s) and recovery time (<1 s). More importantly, the sensor can maintain a good repeatability and rapid response speed when exposure to high humidity for a long time, demonstrating the excellent stability of the proposed sensor. Furthermore, complex impedance spectroscopy was applied to account for the underlying sensing mechanisms of the ND/Ag composite film humidity sensor. Finally, we design a circuit to realize non-contact breathing control by using the fabricated humidity sensor, which demonstrate that the fabricated humidity sensor could be applied to some auto-control systems by human-breath. This work demonstrated that ND/Ag composite film is an ideal candidate material for constructing high-performance humidity sensors for respiratory applications.

Q-switched Nd:YVO4 laser operating at 1064 nm with NiPS3 nanoflakes onto a silica metasurface as saturable absorbers.

In this work, we show that a metasurface can be used to improve the performance of the two-dimensional (2D) material saturable absorber in a Nd:YVO4 solid-state laser. To our knowledge, the hybrid saturable absorber was fabricated by spraying the NiPS3 nanoflakes onto a silica metasurface for the first time. It is shown that the optical absorption, modulation depth, saturation intensity, and ultrafast recovery time of the metasurface-NiPS3 saturable absorber exhibit better performance than the 2D material control device. In a proof-of-concept experiment, the Q-switched pulses with a pulse duration of 20.5 ns, repetition rate of 4.35 MHz, output power of 2.3 W, peak power of 30.61 W, and pulse energy of 0.63 μJ were experimentally demonstrated. These findings suggest that a hybrid saturable absorber is a promising candidate for developing pulsed laser and optical modulators.

In-situ growth of vertically stacked 2D SnS2/SnS heterostructure for highly sensitive and rapid room temperature NO2 gas sensor

Construction of 2D heterostructure is a potential strategy to improve the sensing performance of 2D layered materials owing to the high-quality of heterointerfaces. This attributed to the remarkable electronic band alignment between the constituent materials and their distinctive characteristics. Woefully, very limited attempts have been taken to investigate the effect of 2D heterointerface for gas sensing applications. Here, the SnS2/SnS heterostructure is fabricated on a SiO2/Si substrate using a single-step atmospheric chemical vapor deposition technique for room temperature NO2 sensing. The heterostructure has imparted a 1.3 times enhancement in response (S(%)), with ultra-fast response (τres) and recovery time (τrec) of 32 s and 382 s, towards 40 ppm of NO2 at 30 °C. Moreover, the impact of humidity on the sensing performance of SnS2/SnS has also been studied, confirming its negligible effect on relative humidity. Additionally, it also demonstrates a remarkable stability of 93% over a period of 40 days. Besides, due to strong adsorption energy of SnS2 (1914 meV) and SnS (600 meV) towards NO2 endorses the reaction kinetic parameters validated by the gas adsorption/desorption isotherm analysis of heterostructure. The substantial interface contacts between the SnS2/SnS heterostructure facilities the fermi-level mediated charge transfer, contributing significantly towards the improvement in sensing performance. Therefore, the formation of hierarchical 2D heterostructure with electron depletion layer can be considered as a conducive way for the future development low-powered gas sensor.

Metallic layered VSe2 saturable absorber based single- and dual-wavelength ultrafast fiber laser

Vanadium selenide (VSe2) is a special two-dimensional (2D) transition metal dichalcogenide (TMD) material with metallic properties similar to graphene, which has been proved to have saturable absorption properties and used in mode-locked fiber lasers. As an excellent saturable absorber (SA) material, VSe2 has advantage of ultrafast carrier recovery time and broadband optical response range. However, the potential application of VSe2 in the field of ultrafast photonics has not been fully developed so far. In this work, the as-prepared VSe2 nanosheets were deposited on tapered fiber by optical deposition to obtain VSe2 SA. By inserting VSe2 SA into an Er-doped fiber laser, the mode-locked pulses with a central wavelength of 1574.4 nm can be obtained. The pulse width of the laser is measured to be ∼680 fs which is narrowest in the reported VSe2 SA-based lasers. In addition, the unique dual-wavelength mode-locked pulse is also obtained by further adjusting intracavity dispersion and polarization. This kind of dual-wavelength pulse is valuable in high order harmonic generation enhancement, terahertz wave generation, dense wavelength division multiplexing, dual-frequency comb and other applications. Our results show that metallic VSe2 is of great potential value in ultrafast fiber laser.

Multifunctional metasurface for ultrafast all-optical efficient modulation of terahertz wave

Metasurfaces have been widely used to terahertz (THz) modulators due to their unique electromagnetic (EM) modulation properties. However, to realize ultrafast and efficient control of the active metasurfaces remains a critical challenge. Herein, we first demonstrate a multifunctional metasurface modulator based on metal square rings, which have central rotational symmetry with local asymmetry. The former captures more EM energy to achieve strong enhancement of the local EM responses, and the latter generates high quality factor (Q-factor) Fano resonance. By scaling the unit structure, the resonant frequency shifts in an ultra-wideband range of ∼0.29-10 THz, which shows a linear relation between the Q-factor and the scaling factor, and an exponential variation between the full width at half maximum (FWHM) and the scaling factor. The results provide an effective approach to predict the frequency selection characteristics of the modulators in the THz regime. More importantly, by embedding the silicon into the specific position of the metasurface, external optical control results in the unit structure is constructed from meta-atom to molecularization model, the shifting of resonant frequency and the multi-level modulation of amplitude are realized, and the maximum modulation depth (MD) reaches ∼100 %. By systematically studying the dynamics of frequency and amplitude regulation, benefiting from the ultra-short relaxation time of the photo-carriers in silicon bridge, an ultrafast full recovery time of 2000 ps is achieved. Combined with the local field characteristics, the scaled unit structure achieves efficient modulation of the resonant frequency and amplitude under optical pumping, which provides a promising approach for the development of active metasurface modulator suitable for the whole THz band. This work demonstrates the viability of optical control molecularization of specific meta-atoms is applicable to the entire THz band, which has great potential use for future state-of-the-art THz modulators.

Detection of type-Ⅱ diabetes using graphene-based biosensors

Diabetes is a global pandemic that increases the risk of various health complications, including heart attacks, renal failure, blindness, stroke, and peripheral neuropathy. Type-2 diabetes (T2D) results from an imbalance in lipid and glucose metabolism due to hostility to insulin action and insufficient insulin production response. Valine amino acid has been identified as a potential biomarker for T2D, but there have been no rigorous studies on its interaction with branch chain amino acids. In this study, we investigated the potential of graphene/modified graphene as a valine biosensor using density functional theory to examine the electronic properties and adsorption behaviour of graphene, Si-doped graphene (SiG), and P-doped graphene (PG). The adsorption of valine over the substrates was physisorption in nature, and the adsorption energies were in the order of SiG > G > PG. Density of states (DOS) and partial DOS calculations confirmed the molecule’s adsorption over the monolayers and indicated variations in the electronic properties. We also performed recovery time calculations to examine the reusability of the nano-surfaces as potential biosensors. Ultrafast recovery times were predicted for all three systems, with SiG showing the best results. Our study suggests that SiG could be used as a biosensor for valine, providing a real-time and efficient diagnostic tool for T2D.

Water-durability and high-performance all-fiber humidity sensor using methyldiethanolamine-photopolymer-PDMS structure

In the context of optical fiber humidity sensing, the long-term stability of sensors in high humidity and dew environments such as bathrooms or marine climates remains a challenge, especially since many humidity sensitive materials are water soluble. In this study, we use methyldiethanolamine, pentaerythritol triacrylate and Eosin Y to form a liquid-solid structure humidity sensitive component, the outermost layer is coated with PDMS passivating layer to ensure the stability and durability of the humidity sensor under the conditions of dew and high humidity. The liquid microcavity of the sensor consists of methyldiethanolamine-pentaerythritol triacrylate composite solution, and the sensitivity is several times higher than that of the liquid-free cavity sensor. The sensitivity of the sensor to temperature is verified (0.43 nm/°C and 0.30 nm/°C, respectively) and temperature crosstalk is compensated using a matrix. The compact structure allows for ultra-fast response (602 ms) and recovery time (349 ms). Our work provides a promising platform for efficient and practical humidity and other gas monitoring systems.

Bismuth-Based Metal–Organic Framework as a Chemiresistive Sensor for Acetone Gas Detection

Analyzing acetone in the exhaled breath as a biomarker has proved to be a non-invasive method to detect diabetes in humans with good accuracy. In this work, a Bi-gallate MOF doped into a chitosan (CS) matrix containing an ionic liquid (IL) was fabricated to detect acetone gas with a low detection limit of 10 ppm at an operating temperature of 60 °C and 5 V operating bias. The sensor recorded the highest response to acetone in comparison to other test gases, proving its high selectivity along with long-term stability and repeatability. The sensor also exhibited ultra-fast response and recovery times of 15 ± 0.25 s and 3 ± 0.1 s, respectively. Moreover, the sensor membrane also exhibited flexibility and ease of fabrication, making it ideal to be employed as a real-time breath analyzer.

Quantum walk comb in a fast gain laser.

Synthetic lattices in photonics enable the exploration of light states in new dimensions, transcending phenomena common only to physical space. We propose and demonstrate a quantum walk comb in synthetic frequency space formed by externally modulating a ring-shaped semiconductor laser with ultrafast recovery times. The initially ballistic quantum walk does not dissipate into low supermode states of the synthetic lattice; instead, the state stabilizes in a broad frequency comb, unlocking the full potential of the synthetic frequency lattice. Our device produces a low-noise, nearly flat broadband comb (reaching 100 per centimeter bandwidth) and offers a promising platform to generate broadband, tunable, and stable frequency combs.

Passively Q-switched Erbium-Doped Fibre Laser Based on Graphene-Chitin Saturable Absorber

Graphene is a carbon allotrope composed of densely packed sp2-assembled carbon atoms in a honeycomb-like crystal lattice. It is widely used in various fields of materials science to develop sensors, optoelectronic devices, nanocomposites, and others due to its excellent electronic, mechanical, optical, and thermal properties. Graphene offers several advantages, including ease of fabrication, ultrafast recovery times, low fabrication cost, and low saturation intensities. Its unique zero bandgap property makes it the only material with wavelength-independent absorption, which is advantageous in generating pulsed lasers using saturable absorbers. This study investigates the performance of graphene with a chitin bio-host polymer as a saturable absorber in a 1.5 µm erbium-doped fibre laser. Graphene embedded in chitin was fabricated and utilized in a pulsed laser cavity operating in the wavelength region of 1.5 µm to enable Q-switched pulsed laser operation. The study achieved a pulse energy of approximately 19.83 nJ and a peak power of 10.72 mW. Increasing the pump power from 30.67 mW to 174.28 mW resulted in the highest repetition rate of 63.40 kHz, corresponding to the shortest pulse width of 1.74 µs. These findings have significant implications for applications requiring ultrafast precision and accuracy, such as medical laser equipment and flexible sensors.

Passively Q-Switched Thulium-Holmium Doped Fibre Laser with Electrochemical Exfoliation Graphene in Chitin Based Passive Saturable Absorber

Recent years saw low-dimensional carbon nanostructures like graphene as excellent saturable absorber (SA) for its unique electric and optical properties. Graphene exhibits ultrafast recovery times and high damage thresholds and can be manufactured by relatively simple methods. In this work, Graphene was synthesized using the electrochemical exfoliation (ECE) method. Chitin biopolymer was used to develop graphene-based SA as a more environmentally friendly alternative to conventional synthetic polymers. The fabricated passive SA was then integrated into Thulium-Holmium-doped fibre laser (THDFL) in ring cavity for pulsed laser generation via Q-switching. The optical and physical properties of the graphene-based SA were characterized using Raman spectroscopy, field emission scanning electron microscopy (FESEM) and energy-dispersive x-ray spectroscopy (EDS). Q-switched pulse was successfully demonstrated using the fabricated graphene SAs. ECE graphene-chitin SA generated a Q-switched pulse region at 2 micro-metre with the repetition rate and shortest pulse width of 67.78 kHZ and 10.03 micro-second, respectively. The signal-to-noise ratio (SNR) values obtained was 40 dB indicating high stability of the pulse laser-generated. This study demonstrated the potential of graphene embedded in chitin biopolymer as a sustainable and environmentally friendly SA for a wide range of applications, particularly for pulsed fibre lasers.

A stable and highly-sensitive flexible gas sensor based on Ceria (CeO2) nano-cube decorated rGO nanosheets for selective detection of NO2 at room temperature

Sensing and monitoring nitrogen dioxide (NO2) gas is essential, due to its adverse effect on humans and the environment. However, conventional NO2 gas-sensing materials have limitations like elevated temperature operations, lower response, and low selectivity. Herewith, ceria nano-cube decorated reduced graphene oxide nanosheets (CeO2@rGO) were synthesized by a hydrothermal process, and as-synthesized products were characterized by various methods, viz. XRD, FE-SEM, FTIR, Raman spectrometer, BET, and IV characteristics. Afterwards, CeO2@rGO flexible gas sensor was fabricated by drop-cast technique, which is utilized for real-time monitoring of NO2 at room temperature (RT) (24ºC). Notably, the CeO2@rGO-based sensor upholds a significantly high response of 52.84 % towards 70 ppm of NO2, with an ultrafast response and recovery time of 7 s and 58 s respectively, with the LOD of 1 ppm. In addition, the CeO2@rGO flexible gas sensor exhibited long-term stability up to 30 days, solid repeatability, and stability in high relative humidity (RH) conditions. The marvelous sensing characteristics of the CeO2@rGO were attributed to the synergetic effect between CeO2 and rGO. The mechanism of sensing response was exhaustively interpreted by the “surface electron depletion layer mechanism”. Certainly, the scientific investigation conducted in the present study will undeniably advance the possible uses of detecting NO2 at RT.

High-Performance Optoelectronic Gas Sensing Based on All-Inorganic Mixed-Halide Perovskite Nanocrystals with Halide Engineering.

Gas sensors are of great interest to portable and miniaturized sensing technologies with applications ranging from air quality monitoring to explosive detection and medical diagnostics, but the existing chemiresistive NO2 sensors still suffer from issues such as poor sensitivity, high operating temperature, and slow recovery. Herein, a high-performance NO2 sensors based on all-inorganic perovskite nanocrystals (PNCs) is reported, achieving room temperature operation with ultra-fast response and recovery time. After tailoring the halide composition, superior sensitivity of ≈67 at 8ppm NO2 is obtained in CsPbI2 Br PNC sensors with a detection level down to 2 ppb, which outperforms other nanomaterial-based NO2 sensors. Furthermore, the remarkable optoelectronic properties of such PNCs enable dual-mode operation, i.e., chemiresistive and chemioptical sensing, presenting a new and versatile platform for advancing high-performance, point-of-care NO2 detection technologies.

Highly stable femtosecond pulse generation enabled by the indium tin oxide nanocrystals

The ultrafast third-order optical nonlinearity of indium tin oxide nanocrystals (ITO NCs) and their application in femtosecond laser generation have been investigated experimentally. The ITO NCs exhibit a large modulation depth of ∼25%, nonlinear refractive behavior with self-focusing, ultrafast carrier recovery time of ∼300 fs, and high damage threshold of ∼1.16 TW cm−2, and the stable femtosecond Er-doped fiber laser can be delivered with a signal-to-noise ratio over 80 dB modulated by the ITO NCs successfully. The experimental results indicate that the ITO NCs can be excellent ultrafast nonlinear optical materials for developing highly stable photonic and optoelectronic devices.

Hydrogen-Terminated Two-Dimensional Germanane/Silicane Alloys as Self-Powered Photodetectors and Sensors.

2D monoelemental materials, particularly germanene and silicene (the single layer of germanium and silicon), which are the base materials for modern electronic devices demonstrated tremendous attraction for their 2D layer structure along with the tuneable electronics and optical band gap. The major shortcoming of synthesized thermodynamically very unstable layered germanene and silicene with their inclination toward oxidation was overcome by topochemical deintercalation of a Zintl phase (CaGe2, CaGe1.5Si0.5, and CaGeSi) in a protic environment. The exfoliated Ge-H, Ge0.75Si0.25H, and Ge0.5Si0.5H were successfully synthesized and employed as the active layer for photoelectrochemical photodetectors, which showed broad response (420-940 nm), unprecedented responsivity, and detectivity on the order of 168 μA W-1 and 3.45 × 108 cm Hz1/2 W-1, respectively. The sensing capability of exfoliated germanane and silicane composites was explored using electrochemical impedance spectroscopy with ultrafast response and recovery time of less than 1 s. These positive findings serve as the application of exfoliated germanene and silicene composites and can pave a new path to practical applications in efficient future devices.

Development of a Smart and Ultrafast Flexible Humidity Sensor Using the 0D/2D Au/GeS Heterostructure for Human Respiration Rate Monitoring

We have developed a smart, Internet of Things (IoT)-enabled, intelligent, and flexible humidity sensor for human respiration rate monitoring by using a heterostructure of two-dimensional (2D) germanium(II) sulfide (GeS) and zero-dimensional (0D) gold nanoparticles (Au NPs). The 2D GeS was synthesized by a facile liquid-phase exfoliation process, followed by the post-functionalization of Au NPs. Furthermore, the chemical and structural integrities of the heterostructure were corroborated by microscopic and spectroscopic techniques. The as-prepared heterostructure (termed Au-GeS) exhibited a maximum sensor response of 7102% at 90% of relative humidity (RH) level compared to the pristine GeS sensor response of 2700% at the same RH level. Finally, we demonstrate the use of the Au-GeS flexible humidity sensor for human respiration rate monitoring. The sensor showed an ultrafast response and recovery times of 0.69 and 0.73 s, respectively, during exhalation and inhalation. The sensor was further integrated into a portable electronic system to facilitate IoT-enabled real-time wireless sensing at the smartphone application interface. In our study, the excellent sensor performance with a simple fabrication process offers utilization of the flexible sensor in personal health monitoring.

Flexible Paper-Based Room-Temperature Acetone Sensors with Ultrafast Regeneration

Paper-based lightweight, degradable, low-cost, and eco-friendly substrates are extensively used in wearable biosensor applications, albeit to a lesser extent in sensing acetone and other gas-phase analytes. Generally, rigid substrates with heaters have been employed to develop acetone sensors due to the high operating/recovery temperature (typically above 200 °C), limiting the use of papers as substrates in such sensing applications. In this work, we proposed fabricating the paper-based, room-temperature-operatable acetone sensor using ZnO-polyaniline-based acetone-sensing inks by a facile fabrication method. The fabricated paper-based electrodes showed good electrical conductivity (80 S/m) and mechanical stability (∼1000 bending cycles). The acetone sensors showed a sensitivity of 0.02/100 ppm and 0.6/10 μL with an ultrafast response (4 s) and recovery time (15 s) at room temperature. The sensors delivered a broad sensitivity over a physiological range of 260 to >1000 ppm with R2 > 0.98 under atmospheric conditions. Further, the role of the surface, interfacial, microstructure, electrical, and electromechanical properties of the paper-based sensor devices has been correlated with the sensitivity and room-temperature recovery observed in our system. These versatile, green, flexible electronic devices would be ideal for low-cost, highly regenerative, room-/low-temperature-operable wearable sensor applications.

A nanostructured Al-doped ZnO as an ultra-sensitive room-temperature ammonia gas sensor.

Novel chemi-resistive gas sensors with strong detection capabilities operating at room temperature are desirable owing to their extended cycle life, high stability, and low power consumption. The current study focuses on detecting NH3 at room temperature using lower gas concentrations. The co-precipitation technique was employed to produce pure and Al-doped ZnO nanoparticles, which were calcined at 300°Cfor three hours. The effect of aluminium (Al) doping on the structural, morphological, optical, and gas-sensing abilities was investigated and reported. The presence of aluminium was confirmed by XRD, EDX, and FTIR spectroscopy. Additionally, to assess the various characteristics of Al-doped ZnO nanoparticles, scanning electron microscopy (SEM), ultraviolet-visible diffuse reflectance spectroscopy (UV-DRS), atomic force microscopy (AFM), and Brunauer-Emmett-Teller (BET) techniques were used. The crystallite size increased from 14.82 to 17.49nm in the XRD analysis; the SEM pictures showed a flower-like morphology; and the energy gap decreased from 3.240 to 3.210eV when Al doping was raised from 1 wt% to 4 wt%. AFM studies revealed topographical information with significant roughness in the range of 230-43nm. BET analysis showed a mesoporous nature with surface areas varying from 25.274 to 14.755 m2/g and pore diameters ranging from 8.34 to 7.00nm. The sensing capacities of pure and Al-doped ZnO nanoparticles towards methanol (CH3OH), toluene (C7H8), ethanol (C2H5OH), and ammonia (NH3) were investigated at room temperature. The one-wt% Al-doped ZnO sensor demonstrated an ultrafast response and recovery times at one ppm compared to other AZO-based sensors towards NH3.