Ultrahigh Storage Capacity Research Articles

1T′-MoSP monolayer as an anode material for sodium-ion batteries with ultrahigh storage capacity and ultralow diffusion barrier

Sodium-ion batteries (SIBs) have gained significant attention due to the abundant availability and low cost of sodium. However, the search for high-performance anode materials remains a critical challenge in advancing SIB technology. Based on first-principles swarm-intelligence structure calculations, we propose a metallic 1T′-MoSP monolayer as an anode material that offers a remarkably high storage capacity of 1011 mA h g−1, an ultralow barrier energy of 0.04 eV, and an optimal open-circuit voltage of 0.29 V, ensuring high rate performance and safety. Additionally, the monolayer presents favorable wettability with commonly used SIB electrolytes. Even after adsorbing three-layer Na atoms, the 1T′-MoSP monolayer retains its metallic nature, ensuring excellent electrical conductivity during the battery cycle. These desirable properties make the 1T′-MoSP monolayer a promising anode material for SIBs.

High-Density Capacitive Energy Storage in Low-Dielectric-Constant Polymer PMMA/2D Mica Nanofillers Heterostructure Composite

The ubiquitous, rising demand for energy storage devices with ultra-high storage capacity and efficiency has drawn tremendous research interest in developing energy storage devices. Dielectric polymers are one of the most suitable materials used to fabricate electrostatic capacitive energy storage devices with thin-film geometry with high power density. In this work, we studied the dielectric properties, electric polarization, and energy density of PMMA/2D Mica nanocomposite capacitors where stratified 2D nanofillers are interfaced between the multiple layers of PMMA thin films using two heterostructure designs of the capacitors, PMMA/2D Mica/PMMA (PMP) and PMMA/2D Mica/PMMA/2D Mica/PMMA (PMPMP). The incorporation of a 2D Mica nanofiller in the low-dielectric-constant PMMA leads to an enhancement in the dielectric constant, with ∆ε ~ 15% and 53% for PMP and PMPMP heterostructures at room temperature. Additionally, a significant improvement in discharged energy density was measured for the PMPMP capacitor (Ud ~ 38 J/cm3 at 825 MV/m) compared to the pristine PMMA (Ud ~ 9.5 J/cm3 at 522 MV/m) and PMP capacitors (Ud ~ 19 J/cm3 at 740 MV/m). This excellent capacitive and energy storage performance of the PMMA/2D Mica heterostructure nanocomposite may inform the fabrication of thin-film, high-density energy storage capacitor devices for potential applications in various platforms.

Theoretical exploration of AlB2 monolayer with high energy storage properties in the field of ion battery materials

The rapid development of electric vehicles has promoted researchers to explore the field of high-capacity batteries. Two-dimensional (2D) materials have been proven to have ultra-high storage capacity due to their unique structural advantages. A first-principles approach was applied here to verify the feasibility of the novel AlB2 monolayer as an anode material with ultra-high storage capacity for Li/Na-ion batteries. The Li capacity of AlB2 monolayer is up to 3308.6 mAh/g. Meanwhile, the Na capacity up to 1654.3 mAh/g. It is worth noting that the diffusion barrier of the monolayer is extremely low (Li: 0.50 eV; Na 0.26 eV). The results show that AlB2 monolayer is a kind of anode material for high energy storage, which provides a new choice for the development of long-life battery.

TD-graphene: Theoretical prediction of a high-performance anode material for sodium-ion batteries with intrinsic metallicity, high capacity, and fast ion mobility

The utilization of pristine graphene as an anode material in sodium-ion batteries (SIBs) is limited by its inherent chemical inertness toward Na-ions. To address this issue, we propose a two-dimensional carbon allotrope (named as TD-graphene) by assembling tricyclo[4.4.1.11,6]dodecane (C12H20) skeleton. The topological non-hexagonal feature of C12H20 increases the degree of local carbon-ring disorder and introduces additional electron-deficient regions on the surface, thus enhancing the adsorption capability of Na. TD-graphene demonstrates exceptional stability across the energetic, thermodynamic, dynamic, and mechanical aspects. As a promising anode for SIBs, it exhibits an intrinsic metallicity, an ultra-high storage capacity (1487.58 mA h g−1), a low diffusion barrier (0.20 eV), a low average open-circuit voltage (0.33 V), and a small lattice expansion (0.6%). The presence of solvents with high dielectric constants improves the adsorption and migration capability of Na. Furthermore, taking into account the limitation of single-layer materials in practical applications, we employ h-BN as a promising substrate for TD-graphene, which can boost the Na adsorption and diffusion performance. These results render TD-graphene as a promising high-performance anode material for SIBs.

A Novel Two-Dimensional TiClO as a High-Performance Anode Material for Mg-Ion Batteries: A First-Principles Study.

Searching for efficient electrode materials with excellent electrochemical performance is of great significance to the development of magnesium-ion batteries (MIBs). Two-dimensional Ti-based materials are appealing for use in MIBs due to their high cycling capability. On the basis of density functional theory (DFT) calculations, we comprehensively investigate a novel two-dimensional Ti-based material, namely, TiClO monolayer, as a promising anode for MIBs. Monolayer TiClO can be exfoliated from its experimentally known bulk crystal with a moderate cleavage energy of 1.13 J/m2. It exhibits intrinsically metallic properties with good energetical, dynamical, mechanical, and thermal stabilities. Remarkably, TiClO monolayer possesses an ultra-high storage capacity (1079 mA h g-1), a low energy barrier (0.41-0.68 eV), and a suitable average open-circuit voltage (0.96 V). The lattice expansion for the TiClO monolayer is slight (<4.3%) during the Mg-ion intercalation. Moreover, bilayer and trilayer TiClO can considerably enhance the Mg binding strength and maintain the quasi-one-dimensional diffusion feature compared with monolayer TiClO. All these properties indicate that TiClO monolayers can be utilized as high-performance anodes for MIBs.

360-Degree Video Streaming: A Survey of the State of the Art

360-degree video streaming is expected to grow as the next disruptive innovation due to the ultra-high network bandwidth (60–100 Mbps for 6k streaming), ultra-high storage capacity, and ultra-high computation requirements. Video consumers are more interested in the immersive experience instead of conventional broadband televisions. The visible area (known as user’s viewport) of the video is displayed through Head-Mounted Display (HMD) with a very high frame rate and high resolution. Delivering the whole 360-degree frames in ultra-high-resolution to the end-user significantly adds pressure to the service providers’ overall intention. This paper surveys 360-degree video streaming by focusing on different paradigms from capturing to display. It overviews different projections, compression, and streaming techniques that either incorporate the visual features or spherical characteristics of 360-degree video. Next, the latest ongoing standardization efforts for enhanced degree-of-freedom immersive experience are presented. Furthermore, several 360-degree audio technologies and a wide range of immersive applications are consequently deliberated. Finally, some significant research challenges and implications in the immersive multimedia environment are presented and explained in detail.

A record-high ion storage capacity of T-graphene as two-dimensional anode material for Li-ion and Na-ion batteries

Developing applicable two-dimensional (2D) electrode materials with high performance, especially with high ion storage capacity, has become an ever more obsessive quest in recent years. Based on first-principles calculations, we report that T-graphene, a new carbon-based 2D material, has a record-high Li/Na storage capacity. The capacity of T-graphene is as high as 2233.2 mA h g−1 for Li, and can reach 2357.2 mA h g−1 for Na, which are 6 times as much as that of the commercial graphite and are the highest among 2D anode materials identified so far. We demonstrate that the ultrahigh storage capacity of T-graphene mostly benefits from its low atomic mass and special periodic lattice structure. T-graphene has not only the ultrahigh storage capacity but also hosts the stable ion adsorption, good electric conductivity, fast ion diffusion speed, and low open-circuit voltage, which are merits required as a superior anode material for Li-ion and Na-ion batteries with ultrahigh storage capacity.

Graphyne as an anode material for Mg-ion batteries: A computational study

Abstract Although Li-ion batteries have different advantages, they suffer from short lifetime, high cost, and safety problems. The wide availability, multivalent character, and nontoxicity of magnesium suggest Mg-ion batteries (MIBs) as an alternative to Li-ion batteries. Here, we investigated the potential application of graphyne (as an alternative material to graphene) in the anode of MIBs at B3LYP and B3LYP-gCP-D3 levels. The adsorption energies of Mg and Mg2+ on graphyne were observed to be −6.1 and −223.6 kcal/mol, respectively. The dispersion term was predicted to be much more important for the Mg atom adsorption compared to the Mg2+ cation. The maximum energy barrier for the migration of Mg and Mg2+ over the graphyne surface was about 10.6 and 5.2 kcal/mol, respectively. The calculated cell voltage and specific storage capacity for graphyne respectively were 4.69 V and 558 mAh/g. The high cell voltage of MIBs is mostly attributed to the multivalent character of Mg atoms and strong cation–π interactions. Based on the results, the combination of high cell voltage, ultrahigh storage capacity, and good Mg mobility suggests graphyne as a promising anode substance in MIBs.

Investigation of writing error in staggered heated-dot magnetic recording systems

To achieve an ultra-high storage capacity, heated-dot magnetic recording (HDMR) has been proposed, which heats a bit-patterned medium before recording data. Generally, an error during the HDMR writing process comes from several sources; however, we only investigate the effects of staggered island arrangement, island size fluctuation caused by imperfect fabrication, and main pole position fluctuation. Simulation results demonstrate that a writing error can be minimized by using a staggered array (hexagonal lattice) instead of a square array. Under the effect of main pole position fluctuation, the writing error is higher than the system without main pole position fluctuation. Finally, we found that the error percentage can drop below 10% when the island size is 8.5 nm and the standard deviation of the island size is 1 nm in the absence of main pole jitter.

Two-stage optical recording: photoinduced birefringence and surface-mediated bits storage in bisazo-containing copolymers towards ultrahigh data memory.

Ultrahigh density data storage is in high demand in the current age of big data and thus motivates many innovative storage technologies. Femtosecond laser induced multi-dimensional optical data storage is an appealing method to fulfill the demand of ultrahigh storage capacity. Here we report a femtosecond laser induced two-stage optical storage in bisazobenzene copolymer films by manipulating the recording energies. Different mechanisms can be selected for specified memory use: two-photon isomerization (TPI) and laser induced surface deformation. Giant birefringence can be generated by TPI and brings about high signal-to-noise ratio (>20 dB) multi-dimensional reversible storage. Polarization-dependent surface deformation arises when increasing the recording energy, which not only facilitates the multi-level storage by black bits (dots), but also enhances the bits' readout signal and storing stability. This facile bits recording method, which enables completely different recording mechanisms in an identical storage medium, paves the way for sustainable big data storage.

Multihead Multitrack Detection With Reduced-State Sequence Estimation

To achieve ultra-high storage capacity, the data tracks are squeezed more and more on the magnetic recording disks, causing severe intertrack interference (ITI). The multihead multitrack (MHMT) detector is proposed to better combat ITI. Such a detector, however, has prohibitive implementation complexity. In this paper we propose to use the reduced-state sequence estimation (RSSE) algorithm to significantly reduce the complexity, and render MHMT practical. We first consider a commonly used symmetric two-head two-track (2H2T) channel model. The effective distance between two input symbols is redefined. It provides a better distance measure and naturally leads to an unbalanced set partition tree. Different trellis configurations are obtained based on the desired performance/complexity tradeoff. Simulation results show that the reduced MHMT detector can achieve near maximum-likelihood (ML) performance with a small fraction of the original number of trellis states. Error event analysis is given to explain the behavior of RSSE algorithm on 2H2T channel. Search results of dominant RSSE error events for different channel targets are presented. We also study an asymmetric 2H2T system. The simulation results and error event analysis show that RSSE is applicable to the asymmetric channel.

Control Methods in Data-Storage Systems

The recording performance of data-storage devices, in which write/read elements move relative to a storage medium to reliably store and retrieve information, depends on the capability of servo mechanisms to provide the necessary positioning accuracy. The desired characteristics of servo mechanisms for data-storage systems include robustness against variations of environmental parameters, high resolution, accuracy, stability, and fast response. This paper presents a comprehensive overview of advanced servo-control methods for data storage. The applications are to well-established recording technologies, including magnetic tape and magnetic disk systems as well as CD/DVD/Blue-Ray optical data-storage systems. Moreover, newer holographic and near-field optical systems and the emerging probe-storage technology are also addressed. Emphasis is given to the potential exhibited by the technologies considered for achieving ultra-high storage capacity, as required by the exploding demand in data-storage capacity for archival systems and massive multimedia data storage.

High-density magnetoresistive random access memory operating at ultralow voltage at room temperature

The main bottlenecks limiting the practical applications of current magnetoresistive random access memory (MRAM) technology are its low storage density and high writing energy consumption. Although a number of proposals have been reported for voltage-controlled memory device in recent years, none of them simultaneously satisfy the important device attributes: high storage capacity, low power consumption and room temperature operation. Here we present, using phase-field simulations, a simple and new pathway towards high-performance MRAMs that display significant improvements over existing MRAM technologies or proposed concepts. The proposed nanoscale MRAM device simultaneously exhibits ultrahigh storage capacity of up to 88 Gb inch−2, ultralow power dissipation as low as 0.16 fJ per bit and room temperature high-speed operation below 10 ns.