Type Of Electrolyte Research Articles

Removal of formaldehyde from the air flow in an electrochemical process

This study employed an electrochemical process to eliminate formaldehyde from contaminated air streams. Various factors that influence the process, including electrode material, inter-electrode distance, air injection site, applied voltage, electrical power, current density, pH, reaction time, electrolyte type, concentration, and formaldehyde's initial concentration were investigated. Findings revealed optimal percentage decrease in concentration (χ), reaching 100 %, using aluminum (Al) electrodes with a 1 cm gap between them. Potassium Persulfate (PP) was found to have superior χ compared to sodium thiosulfate (STH). Regarding the air injection site, the higher χ was noted at the cathode (98.9 ± 0.85 %) than at the anode (95.2 ± 0.99 %). Efficiency escalated from 85.1 % at 7.5 volts to 100 % at 15 volts and, for current density, from 89.18 % at 0.042 amps to 100 % at 0.159 amps. Conversely, efficiency for air flow diminished from 100 % at 0.1 l/min to 27.32 ± 2.7 % at 4.4 l/min. Additional factors were also explored, including removing formaldehyde in the reactor's liquid phase and mineralization. Outcomes suggest that formaldehyde reacts with water, eventually transforming into carbon dioxide. Moreover, the reaction kinetics for both electrolytes demonstrated a tendency toward a second-order kinetic model.

Vanadium-doped Li6.7La3Zr1.7V0.3O12 and PVDF-HFP enhanced the ionic conductivity and cycling stability of composite solid electrolytes for All-Solid-State lithium batteries

Solid electrolytes receive widespread attention due to their high safety, high energy density and simplicity of processing. However, the poor interface stability between the solid electrolyte and the electrode leads to a significant increase in interface resistance, greatly reducing the electrochemical performance of lithium-ion batteries (LIBs). Here we designed and prepared a new type of solid composite electrolytes (SCEs), which were composed of poly (ethylene oxide) (PEO) blended with poly (vinylidene fluoride-hexafluoro propylene) (PVDF-HFP) and doped with cubic phase Li6.7La3Zr1.7V0.3O12 (LLZVO) particles. Compared with our previous work, the addition of PVDF-HFP can further reduce the crystallinity of PEO, limit the formation of lithium dendrites, and make the electrolyte/electrode interface more stable. The SCEs had better ionic conductivity of 2.04 × 10-4 S cm−1 and 2.03 × 10-3 S cm−1 at 30 ℃ and 80 ℃, respectively, and the Li/SCEs/Li symmetrical battery cycled for 1800 h without short circuit. Moreover, the coulombic efficiency of LiFePO4/SCEs/Li battery remained at 98 % after 300 cycles. This opens up a new direction for the research of garnet-type composite solid electrolytes with lower interface resistance.

Compressibility, diffusivity, and elasticity in relationship with ionic conduction: An atomic scale description of densified Li2S${\rm Li}_2{\rm S}$–SiS2${\rm SiS}_2$ glasses

AbstractWe examine the dynamic and ionic properties of a typical sulfide glass electrolyte 50–50 using molecular dynamics simulations and a previously parameterized force‐field able to describe both the crystalline phase and the corresponding glass. We especially focus on the effect of moderate pressures on the glassy and supercooled state since the design of all‐solid state batteries use molding conditions at moderate pressures in order to achieve contact between the electrolyte and the electrodes. The behavior of the conductivity with pressure permits to define an activation volume and to infer the role of compressibility and diffusivity, the latter contributing dominantly to ionic conduction, whereas temperature does not seem to impact the structural properties. These features are linked with the underlying dynamics of the Li ions as studied here by computing the longitudinal and transversal atomic species current correlations. The resulting elasticity is found to be close to experimental values.

Effects of Heat Treatment and Electrolyte Type on the Properties of Vanadium Pentoxide

Effects of Heat Treatment and Electrolyte Type on the Properties of Vanadium Pentoxide

E-peroxone with a novel GDE decorated with hydrophobic membrane for the degradation of pyridine: Stability, byproducts and toxicity

E-peroxone process is an emerging electrochemical oxidation process, based on ozone and the in-situ cathodic generation of H2O2, but the stability of cathode is one of the key restraining factors. In this study, we designed a multilayer gas diffusion electrode (GDE) decorated with a commercial hydrophobic membrane for the degradation of pyridine. It was found that a proper control of membrane pore sizes and hot-pressing temperature can significantly promote the GDE stability. Subsequently, key operational parameters of the constructed E-peroxone system were investigated, including the ozone concentration, current density, pH value, electrolyte type and initial concentration of pyridine. The degradation pathways were proposed according to six identified transformation products. The toxicity variation along the degradation progress was evaluated with microbial respiration tests and Toxicity Estimation Software Tool (T.E.S.T.) calculation and an efficient detoxification capacity of E-peroxone was observed. This research provides a theoretical basis and technical support for the development of highly efficient and stable E-peroxone system for the elimination of toxic organic contaminants.

Ultra-trace leakage detection of 1, 2-dimethoxyethane in Lithium-Ion battery electrolyte via lacunary polyoxometalates-driven synthesis of NiO/Si-NiWO4/WO3 heterostructure nanofibers

Early detection of electrolyte leakage is crucial to prevent thermal runaway in lithium-ion batteries (LIBs). Gas sensors offer a potential solution, however, designing sensing materials that can sensitively identify organic molecules from electrolyte leakage remains a great challenge. Herein, the heterostructured NiO/Si-NiWO4/WO3 nanofibers (NFs) were achieved as a sensing material for highly sensitive detection of 1, 2-dimethoxyethane (DME), a typical electrolyte organic molecule. This was accomplished using the highly negatively charged lacunary polyoxometalates (POMs) TBA4H6[SiW9O34]·2 H2O (α-SiW9) and Ni2+ as precursors, resulting in a series of uniform Si-NiWO4/WO3 decorated NiO NFs synthesized through a two-step process involving electrospinning followed by thermal oxidation. By utilizing the synergistic effect of abundant active interfaces, rapid carrier transfer, and a large specific surface area inherent to NFs, the sensor shows high sensitivity (1.87–300 ppb DME), reliable reproducibility and stability, and superior selectivity. Moreover, the sensor is highly responsive to electrolyte leakage simulations, making it a strong candidate for safety systems of LIBs. The study outlines a cost-effective method for preparing NiO/Si-NiWO4/WO3 NFs, setting a foundation for developing various heterostructured nanomaterials with POMs as precursors.

In Situ Polymerized Zwitterionic Copolymer Ionic Gel Electrolytes with High Performance for Lithium-Ion Batteries.

Gel electrolytes are a promising research direction due to their high safety. However, its poor room temperature conductivity along with complex preparation process hinder its practical application. In this article, a type of zwitterionic gel electrolyte is prepared by in situ polymerization. The introduction of charged but nonmigrating zwitterionic copolymer in the polymer chain is beneficial to the dissociation of the lithium salt, improving the ion transport of the electrolyte on this account. At room temperature, the conductivity of lithium ion reaches 9.1 × 10-4 S cm-1, which contributes to achieve excellent electrochemical performance at high rates. The assembled Li|LiFePO4 cell also shows a capacity retention rate of 90.5% after 150 cycles at 0.5 C at room temperature as well as remarkable cycle stability at 1 C. These offer a novel tactic for the efficient and safe commercial application of lithium-ion batteries.

A study on production of hydrogen using Al scrap feedstock.

A sustainable future, concerning the energy transformation of a country, heavily relies on the availability of energy resources, particularly renewables such as solar, wind, hydropower, and clean hydrogen. Among these, hydrogen is the most promising energy source due to its high calorific value, ranging between 120 and 140MJ/kg. It has the potential to lead the market in various industries such as power generation, steel, chemical, petrochemical, and automotive. Significant research has been going on in hydrogen production technologies to reduce costs and improve competitiveness with fossil fuels. One such potential approach includes the use of metal-water reactions, which offer unique opportunities for producing clean hydrogen and other valuable byproducts. However, the quantity of hydrogen produced varies depending on the metal feedstock, type of electrolyte, and the activator or catalyst, used in combination with water. This latest work discusses recent progress on hydrogen production and the effects of variations in different parameters on the process, with a focus on aluminum (Al)-water reactions. Investigations have been conducted and reported on the effect of various activators with different concentrations, the quantity of aluminum scrap feedstock, and the volume of the electrolyte on the kinetics of the metal-water reactions and hydrogen production. Sodium hydroxide (NaOH) was observed to be more effective than potassium hydroxide (KOH) in promoting metal-water reactions. These activator-assisted metal-water reactions help produce clean hydrogen, along with other value-added products such as hydroxides. This work clearly sheds light on the potential utilization of industrial aluminum scrap as feedstock for producing clean hydrogen.

Benchmarking Power Generation From Multiple Wastewater Electrolytes in Microbial Fuel Cells With 3D Printed Disk-Electrodes.

Microbial Fuel Cells (MFCs) have recently gained attention, as they are inexpensive, green in nature, and sustainable. As per the report, by Allied Market Research the global market size of MFCs will increase from $ 264.8 million in 2021 to $ 452.2 million in 2030, growing at a CAGR of 4.5%. The present work is a comparative study of various types of electrolytes that can be used in MFCs. The working electrodes were printed using conducting graphene-based Polylactic Acid (PLA) filaments with the help of a 3D printer under the principle of the fused deposition method. Simulated electrolytes and natural environmental microbial electrolytes were used here. Also, electrolytes of pure E. coli culture were studied. Lake water reported the highest power density of 8.259 mW/cm2 while Stale E. Coli reported the lowest around 0.184 mW/cm2. The study comprehensively lists potential wastewaters that can fuel the MFCs. With the pioneering of various comparative studies of electrolytes, one can insight into the recruitment of electrolytes with high-performance benchmarks for miniaturized energy storage and other microelectronics applications.

Synthesis and characteristics of densified GDC-LSO composite as a new apatite-based electrolyte for intermediate-temperature solid oxide fuel cells (IT-SOFC)

Developing solid-state ionic conductors with desirable charge-transport efficiency and reasonable durability is a fundamental and long-lasting challenge for solid-oxide fuel cells (SOFCs). Ceria-based electrolytes, as one of the most common types of electrolytes for intermediate-temperature solid-oxide fuel cells (IT-SOFCs), offer a high surface-exchange coefficient and faster kinetics in the triple phase boundaries (TPBs); however, they suffer to some extent of electronic conductivity in the reducing atmosphere and gradual phase transitions. Here in this work, we have reported a novel co-doped IT-SOFC electrolyte composite combining the apatite structure of Lanthanum Silicate (LSO) with the fluorite structure of Gadolinium-doped Ceria (GDC), which showed a high ionic conductivity and a minimal electronic leak. The resulting GDC-LSO composite electrolyte also achieved an OCV (open-circuit voltage) of 1 V at 800 °C, implying a significant improvement in the OCV values reported for the typical ceria-based electrolytes (∼0.75 V). The sample was prepared using 40 wt% GDC and 60 wt% LSO (40GDC-60LSO) showed a maximum electrical conductivity of 25 mS cm−1 at 800 °C with good densification properties (>95 % relative density). The cell electrochemical performance measurement was conducted using a 3.0 vol% humified H2 stream at the anode side while the cathode side was exposed to the air at 800 °C. The interdiffusion of cations between La3+ in the LSO phase and Ce4+ and Gd3+ in the GDC phase was detected by XRD and EDX results after sintering samples at 1500 °C for 4 h using 0.5 wt% PVA or 0.5 wt% Ethyl cellulose (EC) as the binder. The proposed GDC-LSO composite could help better understand the influence of compositional constituents and processing variables on the densification and electrical properties of the electrolyte materials for the IT-SOFCs.

Fabrication and Optimisation of Alumina Nanoporous Membranes for Drug Delivery Applications: A Comparative Study.

Neurodegenerative disorders cause most physical and mental disabilities, and therefore require effective treatment. The blood-brain barrier (BBB) prevents drug molecules from crossing from the blood to the brain, making brain drug delivery difficult. Implantable devices could provide sustained and regulated medication to solve this problem. Two electrolytes (0.3 M oxalic acid and 0.3 M sulphuric acid) were used to anodise Al2O3 nanoporous membranes, followed by a third anodisation in concentrated H2SO4 to separate the through-hole membranes from the aluminium substrate. FTIR, AFM, and SEM/EDX were used to characterise the membranes' structure and morphology. The effects of the anodisation time and electrolyte type on the AAO layer pore density, diameter, interpore distance, and thickness were examined. As a model drug for neurodegenerative disorders, donepezil hydrochloride (DHC) was loaded onto thin alumina nanoporous membranes. The DHC release profiles were characterised at two concentrations using a UV-Vis spectrophotometer. Oxalic acid membranes demonstrated an average pore diameter of 39.6-32.5 nm, which was two times larger than sulphuric acid membranes (22.6-19.7 nm). After increasing the anodisation time from 3 to 5 h, all of the membranes showed a reduction in pore diameter that was stable regardless of the electrolyte type or period. Drug release from oxalic acid-fabricated membranes was controlled and sustained for over 2 weeks. Thus, nanoporous membranes as implantable drug delivery systems could improve neurodegenerative disease treatment.

Ligand substitution as a strategy to tailor cationic conductivity in all-solid-state batteries

An increased electrification of society calls for a revolution of battery technologies to further improve energy densities, safety and reduce dependencies on critical raw materials. Here we present a new type of fast magnesium electrolytes for all solid-state batteries created as solid solutions of two other fast Mg2+ ionic conductors, Mg(BH4)2 ∙ NH3 and Mg(BH4)2 ∙ CH3NH2. However, the different ligands introduce stacking faults in the structures of the solid solutions, which are eliminated upon heating to T > 40 °C. The stacking faults appear to influence ionic conductivity, as the samples are less conductive after heating. Interestingly, the ionic conductivity does not correlate directly with the relative ligand content, as the highest conductivity is observed for the 1:1 molar composition (σ(Mg2+) = 7.3 ∙ 10−6 S cm−1 at 40 °C), which also has the lowest melting point of 60 °C. Thus, this work demonstrates a new approach to increase cationic conductivity using mixed ligand systems to alter conduction pathways and introduce microstructural strain.

KF-Containing Interphase Formation Enables Better Potassium Ion Storage Capability.

Rechargeable potassium ion batteries have long been regarded as one alternative to conventional lithium ion batteries because of their resource sustainability and cost advantages. However, the compatibility between anodes and electrolytes remains to be resolved, impeding their commercial adoption. In this work, the K-ion storage properties of Bi nanoparticles encapsulated in N-doped carbon nanocomposites have been examined in two typical electrolyte solutions, which show a significant effect on potassium insertion/removal processes. In a KFSI-based electrolyte, the N-C@Bi nanocomposites exhibit a high specific capacity of 255.2 mAh g-1 at 0.5 A g-1, which remains at 245.6 mAh g-1 after 50 cycles, corresponding to a high capacity retention rate of 96.24%. In a KPF6-based electrolyte, the N-C@Bi nanocomposites show a specific capacity of 209.0 mAh g-1, which remains at 71.5 mAh g-1 after 50 cycles, corresponding to an inferior capacity retention rate of only 34.21%. Post-investigations reveal the formation of a KF interphase derived from salt decomposition and an intact rod-like morphology after cycling in K2 electrolytes, which are responsible for better K-ion storage properties.

Effects of fluid composition and salinity on subcritical crack growth in granite

Using the double-torsion technique, the fracture mechanical response of granite specimens was investigated under the influence of fluid with different electrolyte types and salinities. The fracture toughness (KIC) and critical mechanical energy release rate (G0) of the granite in electrolyte solution are weakened compared to those in distilled water. The KIC in all electrolyte solutions is 2.08–2.28 MPa·m1/2, which is 8.4 % − 16.5 % lower than that in distilled water, and it is insensitive to ion type and salinity. In contrast, the subcritical crack growth index (n) shows different salinity dependence in three salt (AlCl3, CaCl2, and NaCl) solutions. The slight increase in n with rising salinity of the AlCl3 solution is attributed to crack tip blunting caused by over-dissolution of minerals. The n and G0 decrease and then increase with rising salinity of CaCl2 solution, which may be related to the salinity-dependent dissolution rate of quartz and the weakening of repulsive force between crack surfaces. The n and G0 shows a negative correlation with salinity and decrease by 26.4 % and 15.4 %, respectively as the NaCl salinity increases from 0.1 M to 1.0 M. Limitations in the dissolution reactions of the main minerals (albite, biotite and diopside) is accountable for enhancement of n in silica solutions. Experimental results emphasize the critical and subcritical fracture behavior of the granite in response to chemically reactive fluids with implications for both hydraulic fracture stimulations in geothermal fields and caprock integrity for CO2 sequestration. In these applications, the fracture properties of the reservoir rock can be enhanced or weakened by changing the electrolyte type and salinity of the fluid, depending on the actual requirements.

An XPS Study of Electrolytes for Li-Ion Batteries in Full Cell LNMO vs Si/Graphite.

Two different types of electrolytes (co-solvent and multi-salt) are tested for use in high voltage LiNi0.5Mn1.5O4||Si/graphite full cells and compared against a carbonate-based standard LiPF6 containing electrolyte (baseline). Ex situ postmortem XPS analysis on both anodes and cathodes over the life span of the cells reveals a continuously growing SEI and CEI for the baseline electrolyte. The cells cycled in the co-solvent electrolyte exhibited a relatively thick and long-term stable CEI (on LNMO), while a slowly growing SEI was determined to form on the Si/graphite. The multi-salt electrolyte offers more inorganic-rich SEI/CEI while also forming the thinnest SEI/CEI observed in this study. Cross-talk is identified in the baseline electrolyte cell, where Si is detected on the cathode, and Mn is detected on the anode. Both the multi-salt and co-solvent electrolytes are observed to substantially reduce this cross-talk, where the co-solvent is found to be the most effective. In addition, Al corrosion is detected for the multi-salt electrolyte mainly at its end-of-life stage, where Al can be found on both the anode and cathode. Although the co-solvent electrolyte offers superior interface properties in terms of the limitation of cross-talk, the multi-salt electrolyte offers the best overall performance, suggesting that interface thickness plays a superior role compared to cross-talk. Together with their electrochemical cycling performance, the results suggest that multi-salt electrolyte provides a better long-term passivation of the electrodes for high-voltage cells.

A review of electrooxidation systems treatment of poly-fluoroalkyl substances (PFAS): electrooxidation degradation mechanisms and electrode materials.

The prevalence of polyfluoroalkyls and perfluoroalkyls (PFAS) represents a significant challenge, and various treatment techniques have been employed with considerable success to eliminate PFAS from water, with the ultimate goal of ensuring safe disposal of wastewater. This paper first describes the most promising electrochemical oxidation (EO) technology and then analyses its basic principles. In addition, this paper reviews and discusses the current state of research and development in the field of electrode materials and electrochemical reactors. Furthermore, the influence of electrode materials and electrolyte types on the deterioration process is also investigated. The importance of electrode materials in ethylene oxide has been widely recognised, and therefore, the focus of current research is mainly on the development of innovative electrode materials, the design of superior electrode structures, and the improvement of efficient electrode preparation methods. In order to improve the degradation efficiency of PFOS in electrochemical systems, it is essential to study the oxidation mechanism of PFOS in the presence of ethylene oxide. Furthermore, the factors influencing the efficacy of PFAS treatment, including current density, energy consumption, initial concentration, and other parameters, are clearly delineated. In conclusion, this study offers a comprehensive overview of the potential for integrating EO technology with other water treatment technologies. The continuous development of electrode materials and the integration of other water treatment processes present a promising future for the widespread application of ethylene oxide technology.

The Key Role of Grain Boundary Dynamics in Revolutionizing the Potential of Solid Electrolytes

AbstractSolid electrolytes (SEs) have the potential to enhance the safety and performance of Li‐metal batteries. However, the existence of grain boundaries in polycrystalline SEs presents a significant challenge for both ionic and electronic migration, promoting the propagation of detrimental lithium dendrites. This study compares the roles of grain boundaries in electrical properties of three distinct SEs including garnet‐type Li6.5La3Zr1.5Ta0.5O12 (LLZO), argyrodite‐type Li6PS5Cl (LPSC), and NASICON‐type Li1+x+yAlx(Ti,Ge)2‐xSiyP3‐yO12 (LATP). Results demonstrate that the electronic and ionic conductivities of solid‐state electrolytes are affected differently by grain boundaries, depending on the specific type of electrolyte. For instance, LLZO and LATP experience dielectric breakdown at 3.7 and 5.3 V, respectively, while LPSC does not exhibit such behavior. Here, a new chemical modification is proposed that simultaneously alters the composition of both the surface and grain boundaries of SEs, ultimately reducing electronic conductivity for the LLZO SEs. Consequently, the proposed LLZO exhibits unprecedented dendrite‐free cycling stability, achieving a remarkable 12 000‐h lifetime at room temperature, surpassing conventional strategies such as surface coatings in dendrite mitigation. This study highlights the significance of modifying grain boundaries to design safe and durable Li‐metal batteries. It provides new insights for developing SEs that are highly resistant to dendrite formation.

Review of Anodic Tantalum Oxide Nanostructures: From Morphological Design to Emerging Applications.

Anodization of transition metals, particularly the valve metals (V, W, Ti, Ta, Hf, Nb, and Zr) and their alloys, has emerged as a powerful tool for controlling the morphology, purity, and thickness of oxide nanostructures. The present review is focused on the advances in the synthesis of micro/nanostructures of anodic tantalum oxides (ATO) in inorganic, organic, and mixed inorganic-organic type electrolytes with critically highlighting anodization parameters, such as applied voltage, current, time, and electrolyte temperature. Particularly, the growth of ATO nanostructures in fluoride containing electrolytes and their applications are briefly covered. The details of the current- or voltage-time transient and its relation to the growth of the anodic oxide films are presented systematically. The main discussion revolves around the incorporation of various electrolyte species into the surface of ATO structures and its effects on their physicochemical properties. The latest progress in understanding the growth mechanism of nanoporous/nanotubular ATO structures is outlined. Additionally, the impact of annealing temperature (ranging from 400-1000 °C) and atmosphere on the crystalline structure, morphology, impurity content, and physical properties of the ATOs is briefly described. The common modification methods, such as decorating with other transition metal/metal oxide, heteroatom doping, or generating defects in the ATO structures, are discussed. Besides, the review also covers the most promising applications of these materials in the fields of capacitors, supercapacitors, memristive devices, corrosion protection, photocatalysis, photoelectrochemical (PEC) water splitting, and biomaterials. Finally, future research directions for designing ATO-based nanomaterials and their utilities are indicated.

Effect of cation species on pressure-driven electrokinetic energy conversion in charged conical nanochannels

Electrokinetic energy conversion (EEC) offers a promising avenue for transforming elusive natural energy into electric power, showing a wide application spectrum. Unlike prevalent studies that chiefly utilize symmetrical electrolyte solution (e.g., KCl) and uniformly structured negatively charged nanochannels for EEC, this paper delves into a thorough examination of EEC characteristics—streaming current, streaming potential, and output power—in both positively and negatively charged conical nanochannels with symmetrical and asymmetric (CaCl2 and LaCl3) electrolytes solutions. Operating under the assumption that the electrolyte solutions (KCl, CaCl2, and LaCl3) possess equivalent ionic strength and, thereby, a common Debye length, our findings reveal a significant dependency of EEC characteristics and their regulation parameters on the electrolyte type, nanochannel charge polarity, and ionic strength. As the ionic strength increases, both the streaming current and output power initially rise to a peak before subsequently declining, with the ionic strength at the peak being influenced by the cation valence: lower valence leads to lower ionic strength. In asymmetric electrolyte scenarios, optimal EEC characteristic is observed in positively charged conical nanochannels under a reverse pressure difference, attributed to the ion-selective and ionic concentration distribution in the charged conical nanochannels. Moreover, the complex behaviors of the regulation parameters of EEC characteristics are unveiled. Notably, a tri-valent electrolyte's regulation parameters exceed those of a bi-valent electrolyte, indicating that ionic valence asymmetry enhances the regulation effects on EEC in conical nanochannels.

Comparative study of the reduction techniques of Graphene Oxide for Zinc Ion hybrid Storage Application

The increasing demand for low cost and high energy storage devices has given rise to the hybrid supercapacitor device. To overcome the safety issues of the Lithium and Sodium-based devices Zinc ion hybrid supercapacitors (ZIHSCs) are a promising alternative. These devices amalgamate the energy density and power density requirements which makes them suitable for varied applications. The device construction comprises of a zinc anode, zinc-based electrolyte and capacitive type cathode material. Carbon based nanomaterials such as reduced graphene oxide (RGO) are predominantly used as potential cathodes. The strategies involved in obtaining RGO changes the structural characteristic of the samples. This study compares three different strategies such as Chemical reduction (c-RGO), Microwave reduction (m-RGO) and Solar reduction (s-RGO). It was observed that the employment of each these techniques render the change in the physical properties of the materials like number of defect, change in the surface are, porosity and in-situed developed functional group, especially oxygen species. These changes were analyzed thoroughly by various techniques like Raman, Fourier, X-ray diffraction and X-Ray photoelectron spectroscopy. The overall study reveals that solar reduction route shows enhanced surface area and porosity and decrease in defect concentration. Further due to this enhanced property in s-RGO the zinc ion storage capacitance of the fabricated ZIHSC was 200 F/g with a high cyclic stability of 5100 cycles at a current density of 10 A/g. The enhanced energy density thus obtained was 111 Wh/kg corresponding to a power density of 10 KW/kg.