Type Zeolite Research Articles

Antimicrobial zeolites and metal-organic frameworks.

The current surge in antibiotic resistance and the emergence of pandemics have created an urgent need for novel antimicrobial strategies. The controlled release of antimicrobial active principles remains the most viable strategy to date, and transition metal ions currently represent the main alternative to antibiotics. In this review, we explore the potential of two types of materials, zeolites and metal-organic frameworks (MOFs), for the controlled release of antimicrobial active principles, notably transition metal ions. These materials have unique crystalline microporous structures that act as reservoirs, enabling sustained bactericidal effects in various applications such as coatings, packaging, and medical devices. However, there are currently no convenient and standardised methods for evaluating their metal ion release and antimicrobial efficacy. This work discusses analytical techniques and the proposed mechanisms of action while highlighting recent advances in film, membrane, and coating technologies. By addressing the current limitations, microporous materials can revolutionise antimicrobial approaches, offering enhanced effectiveness and long-term sustainability.

An investigation of a hybrid solar-mineral disinfection technique using Zeolite and Dead Sea clay

Effluents from water treatment plants (WTP) can often contain a complex mixture of residual micro-contaminants and organisms, not removed during wastewater treatment. A combined trickling filter, activated sludge treatment, ozonation, membrane filtration, and suspended biofilm reactors have been shown to reduce these contaminants in waste effluent but at high capita cost. This study examined an inexpensive method of purifying water, which combines solar water disinfection with natural mineral clays (SOMIN-DIS). The study involved the addition of two types of mineral clays, Zeolite and Dead Sea minerals, to containers of polluted wastewater, at varying concentrations. The containers were then subjected to different durations of sunlight exposure. Then, samples were taken from all of the containers to quantify the overall numbers of Total Coliform, Pseudomonas aeruginosa (P.aeruginosa), and Escherichia coli (E.coli), utilizing the IDEXX system. The findings indicated that incorporating Dead Sea clay and Zeolite into SODIS-treated wastewater decreased the overall number of harmful microorganisms and shortened the disinfection duration, as compared to using natural minerals and solar water disinfection (SODIS) independently. Additionally, the study determined that the most effective concentration of Dead Sea minerals, resulting in the least amounts of harmful microorganisms and shortest purification duration, was 0.001 g/ml. In contrast, the optimum concentration of Zeolite was 0.002 g/ml. In general, the addition of Dead Sea and Zeolite minerals to the wastewater increased the inactivation of bacteria under SODIS from 40% to 65%.

Comparison of zeolite adsorbent with N-permutite adsorbent

Zeolite is an aluminosilicate mineral with a three-dimensional framework structure with interconnected cavities and channels, which makes its surface area very large and effective as an adsorbent. There are currently natural and artificial types of zeolites. The high adsorption efficiency of zeolite is used as an adsorbent in all areas of the chemical industry. This scientific work obtained an alternative version of zeolite by synthesizing H-permutite based on natural raw materials. To study the characteristics of the structure of the molecular compounds of the studied samples, the Nicolet iS50 (Thermo Fisher Scientific, USA) IR-Fourier spectrometer was used. Measurements were made in the 4000-400 cm-1 spectral range, with spectral resolution not exceeding 0.1 cm. The test specimen was pressed against the mounting surface with a flat-tip probe. near, mid, and far IR attenuated total internal reflection (ATR) I S50 Analytical indicators were determined using a hole and a diamond crystal for measurement.

Characterization of Zeolite Types Contained in Sangaredi Bauxite in the Republic of Guinea

Characterization of Zeolite Types Contained in Sangaredi Bauxite in the Republic of Guinea

A Study on the Mechanical Properties of Alkali Activated Concrete Using Various Types of Synthetic Zeolites

Abstract -The world's most common man-made material is concrete. Portland cement is a key component of a typical concrete mix. However, about 5% of the world's carbon dioxide emissions are brought on by the manufacture of cement. Engineers and scientists need to invent and use a green building material to make the world more sustainable. Due to its corrosion resistance, geopolymer concrete is also significantly more durable than regular concrete. It is also significantly stronger than regular concrete. The development of green construction will be facilitated by the innovative sustainable building material known as geopolymer concrete. Alkali- activated materials also known as geopolymers, are made from a variety of materials (usually industrial byproducts) known as precursors. These are combined with an alkaline medium to create a cementitious material that can be used in place of Portland cement in the production of concrete. Mineral admixtures (such as fly ash and GGBS) are typically added in larger amounts in concrete to improve its workability, resistance to thermal cracking, alkali-aggregate expansion, and sulphate attack, and to allow for a reduction in cement content. In the current study, sodium hydroxide and sodium silicate were used as alkaline activators with a Molarity of 12M, and fly ash, GGBS, and types of synthetic zeolites as binder ingredients. 40% of GGBS is kept constant and fly ash is replaced with zeolite in various percentages. In this paper, zeolite is replaced with 5%, 7.5%, and 10% of fly ash to create geopolymer concretes. Zeolite powder obtained by the calcination process with the aid of sodium hydroxide and fly ash, industrial wastages. The performance of the created concrete is then evaluated using mechanical behavior on developed mix. Key Words: Alkali activator, fly ash, Ground granulated blast- frunace slag, synthetic zeolites, strength properties.

One-pot template-free synthesis of metal-doped ETS-10 zeolites for Knoevenagel condensation of benzaldehyde with ethyl cyanoacetate

Three types of metal-doped ETS-10 zeolites including Ni-ETS-10, Al-ETS-10, and Ga-ETS-10 were successfully synthesized by one-pot template-free hydrothermal treatments. The effect of doping metals on the crystallinity, morphology, textural property, and basicity of the produced zeolites was systematically studied. It was found that doping with an appropriate amount of Ni could enhance the crystallinity and basicity of ETS-10 zeolites in comparison with Al and Ga, and the Ni species mainly existed in two forms of framework coordination and exchange site connection within Ni-ETS-10. The catalytic evaluation by the liquid Knoevenagel condensation reaction of benzaldehyde with ethyl cyanoacetate confirmed the superiority of ETS-10 and metal-doped ETS-10 in comparison with the contrast base zeolites of NaY and KY. And the 0.4Ni-ETS-10 catalyst exihibted the best performance with 75.6 % yield of ethyl ɑ-cyanocinnamate (ECC) among all the synthesized (metal-doped) ETS-10 zeolites. It is reasonable to expect that the demonstrated work has important implications for the design and facile synthesis of new-type high-performance base zeolite catalysts.

Metal Ions Removal from Aqueous Media Using an Electrokinetic Cell

Electro-kinetic (EK) remediation is a technique used for the treatment of contaminated soil and groundwater [1-2]. It involves the application of a low voltage-electrical current through the soil, which causes the movement of charged contaminants towards electrodes, where they can be extracted or immobilized. In EK remediation, electrodes are placed in the soil or contaminated water and connected to a power supply. In case of soil, soil need to be wetted with an electrolyte solution to facilitate the movement of charged particles. When a low voltage-electrical current is applied, it creates an electric field that drives the migration of charged contaminants, such as heavy metals ions and or charged organic pollutants, towards the opposite charge electrodes. The anode is typically made of a reactive metal, such as iron, while the cathode can be made of stainless steel or graphite. The electrodes are connected to a power supply that applies a low-voltage electrical current to the system. The contaminants can then be collected or treated using various methods, such as adsorption, precipitation, or electrochemical reactions [3-10]. EK remediation has several advantages over traditional remediation methods, such as in situ chemical oxidation and pump-and-treat systems. It can be applied to a wide range of contaminants and soil types, and is generally more effective at removing contaminants that are difficult to treat using other methods. Additionally, EK remediation can be a cost-effective and environmentally friendly option for the treatment of contaminated sites. This study explores the removal of cobalt (II) ions from aqueous solution combining the use of adsorbents such as zeolite placed in an electrokinetic cell. The most effective removing is almost 93% of cobalt (II) ions from aqueous solution after 300 minutes at 15 V in the presence of Faujasite type zeolites. Therefore, EK remediation technique has shown promise as an innovative approach to environmental remediation. References Omar H. Elsayed-Ali, Hani E. Elsayed-Ali and Tarek M. Abdel-Fattah, Journal of Hazardous Materials, 185 (2-3), 1550-1557 (2011)Alya Elsayed-Ali, Tarek Abdel-Fattah, Hani Elsayled-Ali, Hani, Journal of Chemical Education, 88(8), 1126-1129 (2011).TM Abdel-Fattah, ME Mahmoud, Chemical engineering journal 172 (1), 177-183 (2011)TM Abdel-Fattah, ME Mahmoud, MM Osmam, SB Ahmed, Journal of Environmental Science and health, part A 49 (9), 1064-1076 (2014)ME Mahmoud, TM Abdel-Fattah, MM Osman, SB Ahmed, Journal of Environmental Science and Health, Part A 47 (1), 130-141 (2012)TM Abdel-Fattah, B Bishop, Journal of Environmental Science and Health, Part A 39 (11-12), 2855-2866 (2004)ME Mahmoud, MM Osman, SB Ahmed, TM Abdel-Fattah, The Scientific World Journal 2012 (2012)ME Mahmoud, SS Haggag, TM Abdel-Fattah, Polyhedron 26 (14), 3956-3962 (2007)ME Mahmoud, AA Yakout, MT Abed El Aziz, MM Osman, TM Abdel-Fattah, Journal of Environmental Science and Health, Part A 50 (10), 1072-1081 (2015)H Namkoong, E Biehler, G Namkoong, TM Abdel-Fattah, ACS omega 7 (44), 39931-39937 (2022)

Kinetic and Isotherm Studies for Cu2+ and Cs+ Uptake with Mono- and Bimetallic FeO(OH)-MnOx-Clinoptilolite

This study investigates the adsorption of selected water pollutants, namely caesium and copper, by using natural zeolite of the clinoptilolite type, as well as clinoptilolites coated with MnOx, FeO(OH)-MnOx and FeO(OH). A comprehensive evaluation of these processes was conducted. The kinetics of Cs and Cu adsorption on all examined samples smoothly followed the pseudo-second-order kinetic model, with the liquid film step regarded as the slower step in both cases. The Langmuir isotherm model provided the most accurate description of Cs and Cu adsorption for all examined samples. However, when considering natural clinoptilolite and FeO(OH)-clinoptilolite systems in relation to Cu(II), the Redlich–Peterson model slightly outperformed the Langmuir model. The modification of clinoptilolite with Mn and Fe oxyhydroxides did not significantly enhance the removal efficiency of Cs compared to the unmodified sample. In contrast, the adsorption capacity, especially for MnOx-clinoptilolite, increased fourfold for Cu and other tested cations such as Pb and Zn, indicating improved efficiency in these cases.

Effect of Zeolite 3.7 ̊ A coated monoliths on improvement of aviation fuel thermal oxidative stability

The effect of zeolite 3.7̊ A acidity on the reduction of surface deposition propensity of a Jet A-1 fuel, with marginal thermal oxidative stability was studied. This was achieved through treatment of the fuel in a packed bed reactor, using three types of monolithic zeolite with different Si/Al ratios. It was found that the increase of acidity is directly proportional to the surface deposition reduction such that the treatment with the highest ratio (Si/Al = 25) resulted in the most significant surface propensity reduction. However, a combination of zeolite with the lowest acidity (Si/Al = 17) and the activated carbon exhibited the greatest improvement of thermal oxidative stability. As a general trend, for all three Si/Al ratios in the monolithic zeolites used in this work, surface deposition propensity of the Jet A-1 fuel decreased markedly with the increase of monolithic size. Nevertheless, it is anticipated that efficacy will reach an steady state after a certain point. Quantum chemistry calculations demonstrate that polar species can interact with the CHA and 2Al doped chabazite in a number of ways, from dispersion interactions to forming covalent and hydrogen bonds. Furthermore, our calculations suggest that the doping CHA with Al enhanced the adsorption of polar species, which agree with a lab-scale experiment with the model fuel.

Waste to health: Green synthesis of Zn loaded LTA zeolite prepared from waste glass and aluminum scrap with high antioxidant and antimicrobial activities

The aim of this study is to evaluate the in vitro antibacterial and the antioxidant activities of low cost ZnO@Zn-ZF2 zeolite. The carrier was Na-LTA type zeolite prepared from waste glass and aluminum scraps by alkaline fusion at 550 °C using NaOH as mineralizer followed by hydrothermal crystallization at 60 °C for 6 days. Three samples of ZnO@Zn-ZF2 were prepared with different amount of zinc (2, 4 and 6 wt%). The antioxidant activities of ZnO@Zn-ZF2 zeolite were evaluated by different methods, including 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical method, reducing power and β-carotene bleaching assay. All particles showed interesting antioxidant activities. Further, the prepared samples exhibited considerable antibacterial activity against Gram- and Gram + bacteria. The obtained results showed that 6ZnO@Zn-ZF2 zeolite had the highest antioxidant and antibacterial activities against Klebsiella pneumoniae and Micrococcus luteus, which can be attributed to the good dispersion of ZnO particles on the zeolite surface.

The Effect of Adsorbent-Material Properties on PSA Based Oxygen Concentrators

An oxygen concentrator is a technology for producing pure oxygen. By using the Pressure Swing Adsorption method, zeolite as an oxygen concentrator will absorb nitrogen in the free air and release oxygen as an output from the oxygen concentrator. This final project aims to determine the effect of the size, mass, and type of zeolite used in oxygen concentrators on the purity of the oxygen produced. Zeolite will be stored in a closed tube in this study. Experiments will be carried out with the resulting oxygen concentration parameters. The zeolite used is 13X, and Li-X. This research was conducted with mass variations of 200gr, 400gr, 600gr, and 800gr with sizes of 0.4mm and 1.7mm. The results obtained can show a comparison graph of the zeolite to the resulting oxygen concentration. The test results from the mass variation obtained that the mass variation of 800gr had higher purity in all types and sizes of zeolite. Zeolite Li-X has the highest purity value compared to 13X and the size of 0.4mm has a higher purity value compared to the size of 1.7mm.

The effect of the active site and substrate structure in preparation of substituted tetrahydropyrans via intramolecular cyclization

Substituted tetrahydropyrans (THPs) are important biologically active compounds and synthetic intermediates. Their prevalence and diverse applications make them desirable targets in synthetic organic chemistry. Current synthetic routes for THP synthesis involve homogeneous catalysts and usually multiple steps and the use of expensive heavy metal catalysts, which pose environmental concerns. Therefore, there is a need for alternative approaches that can enhance efficiency, eco-friendliness, and cost-effectiveness This study focuses on the acid-catalyzed synthesis of THPs through the intramolecular cyclization of substituted (E)− 5-phenylpent-4-en-1-ols over zeolites as heterogeneous catalysts. The study particularly focused on investigating the influence of functional groups, as well as substrate size, on the reaction outcome. The results demonstrated that electron-donating groups enhance the conversion of the reactants and increase selectivity towards THPs, while electron-withdrawing groups have the opposite effect. Furthermore, the cyclization reaction also occurred on substrates containing different aromatic cycles. However, the conversion of a bulky substrate containing naphthyl group decreased due to mass transfer limitations. The catalytic performance of different types of zeolites with diverse acid sites was also examined. Brønsted acidic zeolites such as Al-BEA and Ga-BEA exhibited promising catalytic performance and 94 % and 83 % selectivity towards THPs, respectively. In contrast, Lewis acidic zeolites such as Sn-BEA, Ti-BEA, and Zr-BEA showed conversions below 6.5 % and poor selectivity, showing that Brønsted acidic zeolites are more suitable for the cyclization reaction than Lewis acidic zeolites.

Understanding the performance of RHO type zeolite membrane for CH4/N2 separation based on molecular dynamics and deep neural network methods

This study shows a molecular dynamics (MD) simulation study on the performance of the RHO zeolite membrane for separating nitrogen from methane/nitrogen gas mixtures. The contamination of natural gas, predominantly composed of methane, with nitrogen diminishes its value. Zeolite membranes offer promising prospects for gas separation due to their stability, rigid pore structure, and molecular sieving properties. The study investigates the impact of pressure difference (up to 30 MPa), feed composition, and membrane thickness on the separation rate at a system temperature of 298 K. Results demonstrate that the RHO zeolite membrane exhibits high permeability and selectivity for N2 separation, surpassing the upper limit defined by Robson with a maximum permeability of 2.14 × 105 GPU (Gas Permeation Units). Exceptional selectivity of N2 over CH4 molecules is observed. Additionally, altering the feed composition and membrane thickness positively influences the membrane's separation performance, thereby enhancing its efficiency. The findings contribute to the advancement of separation technologies, providing valuable insights into the potential application of zeolite membranes for efficient N2 separation from CH4/N2 gas mixtures in natural gas processing. Furthermore, the study explores the use of Deep Neural Network (DNN) models to predict the membrane's performance under diverse operating conditions. The DNN models, trained using simulation data from MD simulations, exhibit high accuracy with a coefficient of determination (R2) exceeding 0.9, ensuring reliable predictions. The integration of DNN models facilitates the optimization of zeolite membrane-based gas separation systems, improving their design and operation.

Fabrication of LD-slag derived zeolite Y coated polysulfone (PSf) membrane for decontamination of groundwater

Faujesite type zeolite Y was prepared via ultrasonic energy facilitated hydrothermal technique using Linz-Donawitz (LD) process slag as a precursor material. The surface modification of the polysulfone membrane was conducted with the as-synthesized zeolite powder in the presence of N-methyl pyrrolidone (NMP) solvent. The synthetic zeolite nanoparticles (ZNPs) were sonicated by mixing them in NMP solvent before spreading over the membrane surface. The ZNPs layered flat sheet membrane was fabricated via dry-cast technique followed by phase inversion. The optimization of drying temperature and time was studied along with the variation of ZNPs wt.% to obtain defect-free membranes. The developed ZNPs layered membranes were characterized for membrane morphology, surface roughness, mechanical strength, thermal stability, functional group analysis, and surface hydrophilicity. The chemical characterization of all fabricated membranes was examined by X-ray photoelectron spectroscopy (XPS). An increased water flux of 28.83 L/m2h was obtained whereas the fluoride concentration was reduced to 1.47 mg/L (∼50.33 % reduction) for the optimized PSf/Zeolite-1 wt% membrane. Moreover, other contaminants namely chromium (Cr6+) and manganese (Mn2+) were removed very significantly by utilizing the modified PSf/Zeolite-1 wt% membrane. The regeneration experiment was conducted utilizing an HCl solution through dead-end filtration. The flux recovery of membrane PSf/Zeolite-1 wt% was found to be 85.43 % with an antifouling improvement of 42.70 %.

Treatment of radium-bearing brine using various zeolites: NaP1, NaX, clinoptilolite, 3A, 5A, 13X, ZSM-5, SAPO-11, SAPO-34

This paper investigates the possibility of radium removal from brines using zeolites. Radium concentration in collected from hard coal mine water was as follows: 226Ra 3.3 ± 0.2 Bq/L, 228Ra 5.5 ± 0.5 Bq/L. Ten types of zeolites were selected for treatment: clinoptilolite, NaP1, NaX, 3A, 5A, 13X, Y, ZSM-5, SAPO-11, and SAPO-34. Sequential batch purification tests were performed. High efficiencies of radium removal from mine brine achieved with NaP1 and NaX, synthesized from fly ahes, are promising for the further application of obtained zeolitic materials, especially for water treatment. Furthermore, the use of zeolites derived from waste fly ash is an ecological and sustainable solution for environmental protection and remediation.

Production of higher hydrocarbon-pool from bio-ethanol for fuel applications

In a way to explore the inherent acidity and porosity properties of zeolites for the conversion of renewable biomass-derived ethanol into various fuel stocks, three types of zeolites; HZ, HY, and HB have been studied in their proton form. The studies indicated the formation of catalyst-dependent hydrocarbon composition of the product falling in gasoline and jet fuel for the specific end-use applications. The flexibility in product choice facilitated by changing the catalyst makes the present process suitable for industrial applications based on the nature of product in demand. At optimized temperature and pressure reaction conditions, HB zeolite produced >40 wt% jet fuel hydrocarbons (T = 400 °C and P = 50 bar), HZ produced 53 wt% octane gasoline (RON >100) and HY zeolite produced 25 wt% of olefins in liquid product. The novelty of the present process lies in its simple, single-step, continuous-flow vapour-phase single catalytic process operating on zeolites bearing no metal function but possessing variable pore size and other catalytic properties required for producing higher range hydrocarbons from ethanol.

Reduction of Heavy Metal (Pb) ions in industrial waste using activated carbon based on used catalysts

Used catalyst-based activated carbon is activated carbon made from used catalysts from the crude oil cracking process. The used catalyst used is a type of crystalline Zeolite with a regular structure, which contains elements of Silica Oxide, Alumina Oxide, and Calcium Oxide. The use of organic activated carbon to treat waste has been widely used, the use of used catalyst waste as activated carbon is very potential because the catalyst used for oil company cracking is no longer used. Tofu industry is one of Indonesia's industries dominated by small-scale businesses with limited capital, so most tofu industries do not have waste treatment units, where liquid waste is directly discharged into sewers or water bodies without treatment first. Tofu industrial waste contains pollutants both organic and inorganic. Initial analysis of tofu industry liquid waste containing Pb metal. This study aims to determine the effect of mass variation and stirring time of used catalyst-based activated carbon adsorbent on reducing Heavy Metal Ions (Pb) in tofu industry liquid waste. The adsorption process is carried out with mass variations of activated carbon of 5, 10, 15, 20, and 25 grams. Stirring time variations are 30, 60, 90, 120, and 150 minutes. From the results of the study, it is known that the best condition for reducing Pb content was obtained at a stirring time of 60 minutes and a large catalyst-based activated carbon mass of 66.33%

Low-temperature catalytic dechlorination of model plastic pyrolytic oil over zeolite catalysts

Catalytic dechlorination of model plastic pyrolytic oil was investigated over different types of zeolites and ion-exchanged 13X zeolites at the low temperatures of 20–120 °C. Among different types of parent zeolites (13X, β, MCM-41), 13X had the highest catalytic dechlorination performance. After ion exchange of 13X with Ag+, its catalytic dechlorination performance was significantly enhanced, and the chlorine removal over Ag-13X reached 97.2 % after reaction for 5 h at 120 °C. The characterization results indicated that the acidity of the zeolite governed its catalytic dechlorination performance, and higher acid amount and stronger acid strength are preferred. Different types of chlorinated compounds followed different dechlorination mechanisms. The primary chlorinated alkanes (e.g., 1-chlorooctane) underwent nucleophilic substitution by the surface –OH groups or H2O to form alcohols and HCl, or dehydrochlorination reaction to produce olefins and HCl, while higher chlorinated alkanes with adjacent hydrogen (e.g., chlorocyclohexane) mainly underwent dehydrochlorination reaction to produce olefins and HCl. Chlorinated aromatics (e.g., chlorobenzene) was removed mainly by physical adsorption. Ag-13X showed good stability, and the chlorine removal still retained 72.1 % after 102 h on stream. After four dechlorination-regeneration cycles, the chlorine removal had only a slight decrease due to the partial collapse of its structure and slight loss of its acid amount.

Recent Advances in the Catalytic Conversion of Methane to Methanol: From the Challenges of Traditional Catalysts to the Use of Nanomaterials and Metal-Organic Frameworks.

Methane and carbon dioxide are the main contributors to global warming, with the methane effect being 25 times more powerful than carbon dioxide. Although the sources of methane are diverse, it is a very volatile and explosive gas. One way to store the energy content of methane is through its conversion to methanol. Methanol is a liquid under ambient conditions, easy to transport, and, apart from its use as an energy source, it is a chemical platform that can serve as a starting material for the production of various higher-value products. Accordingly, the transformation of methane to methanol has been extensively studied in the literature, using traditional catalysts as different types of zeolites. However, in the last few years, a new generation of catalysts has emerged to carry out this transformation with higher conversion and selectivity, and more importantly, under mild temperature and pressure conditions. These new catalysts typically involve the use of a highly porous supporting material such as zeolite, or more recently, metal-organic frameworks (MOFs) and graphene, and metallic nanoparticles or a combination of different types of nanoparticles that are the core of the catalytic process. In this review, recent advances in the porous supports for nanoparticles used for methane oxidation to methanol under mild conditions are discussed.

Continuous adsorption process of [formula omitted]/[formula omitted]/[formula omitted] from [formula omitted] flow using type A zeolite adsorbents in the presence of ultrasonic waves

In this study, the adsorption capacity of different types of zeolite (3A, 4A, and 5A) for adsorbing CO2 from a mixture of CH4, N2, and water vapor was investigated with and without the use of ultrasonic waves. In this study, functional groups of O–H, Si–O–Al and Si–O–Si bands were identified in Fourier transform infrared (FTIR) spectroscopy of these adsorbents. X-ray diffraction patterns (XRD) for zeolite 3A and 5A showed the structure of chabazite and for zeolite 4A the structure of sodalite. In the Brunauer-Emmett-Teller (BET) test, the specific surface area of zeolites was measured as 16, 11.96 and 437 m2g−1, respectively. Ultrasonic waves increased the adsorption capacity of zeolites to adsorb CO2 at lower temperatures 80.64 to 175.44 mgg−1. Zeolite 5A has a higher affinity for CO2 than CH4 or N2, the selectivity of CO2/ N2 and CO2/ CH4 were 19.55 and 24.17, respectively. Data from adsorption experiments were used to learn an artificial neural network (ANN), and the ANN provided acceptable results for predicting the adsorption process.