This study aimed to investigate the potential use of carbon nanotubes (CNTs), which are an innovative construction material preferred by many researchers. Long-term microstructure enhancement and on-site application are major reasons to conduct research on CNT-cement composites; thus, a study on mechanical properties as well as the thermal conductivity of CNT-cement composites was carried out. As the CNT content increased, the thermal conductivity of CNT-cement composites was also enhanced. In addition, a couple of microstructure analyses such as isothermal calorimetry, thermal gravimetric analysis and SEM-EDS (Scanning Electron Microscope-Energy Dispersive X-ray Spectroscopy) for observing hydration reaction rate and types of hydration products were conducted to establish the advantage of CNT use in cement composites. Strength development of CNT-cement composites at early ages was slow, although eventually CNTs containing water developed equivalent level of strengths at last as internal curing effects.