Types Of Carbon Nanomaterials Research Articles

Carbohydrate-Derived Superhydrophilic Carbon Aerogels and Their Effects on Seedling Growth of Triticum aestivum.

Synthesis methods of carbon nanomaterials have been developed vigorously in recent years, among which a simple, green, and mature approach is of more research significance. Carbon nanomaterials have depicted an impact on the growth and development of plants. In this study, a new type of carbon nanomaterial, superhydrophilic carbon aerogel (CA), was synthesized via a hydrothermal process using carbohydrates and water-soluble polymers as raw materials. Characterized by scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, powder X-ray diffraction, and N2 adsorption analysis, the exemplified CA presented to have porous three-dimensional network structure composed of individual particles with diameters of 25 nm, with reactive surface, single composition, high specific surface area (89.94 m2·g-1), and wide range of density variation. The 9 mg·mL-1 CA suspension had a significant positive effect on the root growth of wheat seedlings, with promoted root elongation (about 67.17% longer) and root diameter (about 28.95% thicker) compared with those of the control group. The cytological results suggested that CA treatment triggered the propagation of meristematic cells, and the increased number of meristematic cells (65.79% more than the control group) led to enhanced root growth by upregulated expression of related phytohormone genes in wheat seedlings.

Investigation of column purified dye derived carbon nanomaterials for security printing and supercapacitor applications

Literature evidence reveals versatile applications of carbon dots (CDs), but generally mixtures of various types of carbon nanomaterials, molecular intermediates as well as side products are obtained upon hydrothermal treatment of the precursor material. This demands isolation of pure components and their complete characterization before these nano carbonaceous materials are chosen for suitable applications. In the present study, perylenetetracarboxylic dianhydride (PTCDA) is subjected to hydrothermal treatment and the mother liquor obtained is separated using column chromatography technique using dichloromethane-methanol solvent system to isolate fractions of various fluorescent carbonaceous nanostructures. The TEM imaging of nano carbonaceous particles of all five fractions indicated that the first and third fractions were composed of nanoribbons, while the latter two fractions largely contained quasi-spherical nanoparticles of both lesser (carbon quantum dots) and greater (carbon nanodots) than 10 nm dimensions. The XPS results of all the fractions suggested separation based on polarity difference. The ID/IG ratios obtained from Raman spectra implied the presence of several defects on the CDs. The time resolved fluorescence spectra of third, fourth and fifth fractions revealed mono-exponential decay of fluorophores with excitation independent average lifetime values. The fifth fraction exhibited good biocompatibility and the highest absolute fluorescence quantum yield of 58.47 % among all the isolated samples. As these CDs displayed a remarkable rise in the quantum yield to 88.60 % when dispersed in water, a water-based flexo-ink was formulated. The photostable pale yellow flexo print proofs obtained on UV dull paper exhibited a green fluorescence under 365 nm illumination, whereas a yellow glow when shined with blue light, which can serve as an authentication feature for security documents and currency notes. Moreover, as the third fraction constitutes mainly of carbon nanoribbons (CNRs), an optimized polymer electrolyte was prepared along with sodium alginate (SA), and MgCl2 to understand their potential use in energy storage application. A supercapacitor was fabricated and tested for its electrochemical performance such as cyclic voltammtery (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge/discharge (GCD). An enhanced current window was observed in the CV of SA/CNRs compared to pure SA and SA/CNRs/Mg films, which indicated a structural interaction of CNRs with SA. The conductivity of SA/CNRs/Mg was lesser than SA/CNRs in EIS studies due to the presence of Mg ions, while pure SA showed lesser conductivity. The dual ionic interaction of Na and Mg along with enhanced structural stability due to doped CNRs favors its convenient supercapacitor application. The fabricated eco-friendly supercapacitor showed a specific capacitance of 84 F/g. The GCD of the device displayed pseudocapacitance behaviour and was quite stable for 2000 cycles with coulombic efficiency of 96 %.

Carbon nanomaterial-based electrochemical sensor in biomedical application, a comprehensive study

Recently, carbon nanocomposites have garnered a lot of curiosity because of their distinctive characteristics and extensive variety of possible possibilities. Among all of these applications, a development of sensors with electrochemical properties based on carbon nanocomposites for use in biomedicine has shown as an area with potential. These sensors are suitable for an assortment of biomedical applications, such as prescribing medications, disease diagnostics, and biomarker detection. They have many benefits, including outstanding sensitivity, selectivity, and low limitations on detection. This comprehensive review aims to provide an in-depth analysis of the recent advancements in carbon nanocomposites-based electrochemical sensors for biomedical applications. The different types of carbon nanomaterials used in sensor fabrication, their synthesis methods, and the functionalization techniques employed to enhance their sensing properties have discussed. Furthermore, we enumerate the numerous biological and biomedical uses of electrochemical sensors based on carbon nanocomposites, among them their employment in illness diagnosis, physiological parameter monitoring, and biomolecule detection. The challenges and prospects of these sensors in biomedical applications are also discussed. Overall, this review highlights the tremendous potential of carbon nanomaterial-based electrochemical sensors in revolutionizing biomedical research and clinical diagnostics.

Multi-Walled Carbon Nanotubes Improve the Development of Chrysanthemum × morifolium (Ramat.) Hemsl. ‘Jinba’ Inflorescences

The application of cut flower preservation technology can significantly enhance both the ornamental and economic value of fresh-cut flowers. Research on vase solutions has become a concentrated area in current studies on cut flower preservation. Multi-walled carbon nanotubes (MWCNTs), as a type of carbon nanomaterial with bactericidal and membrane-penetrating properties, can be used as a component in vase solutions. This supplementation of energy substances aims to improve antioxidant enzyme activity, thereby enhancing the postharvest quality of cut chrysanthemums. In this study, deionized water and a standard preservative solution were employed as control groups to compare the effects of MWCNTs applied at different concentrations, combined with common preservatives such as sugar and 8-hydroxyquinoline, on the postharvest flowering and preservation of Chrysanthemum × morifolium ‘Jinba’. By observing the distribution of MWCNTs in the tissues surrounding the cut and changes in water content, carbon sources, osmoregulatory substance levels, and the expression of relevant key genes, a formulation with excellent postharvest treatment effects was identified. Preliminary investigations into its action and mechanism were also conducted. The results indicated that the combined treatment with 5 mg L−1 MWCNTs, 30 g L−1 sucrose, and 0.2 g L−1 8-hydroxyquinoline effectively promoted water and sugar uptake in chrysanthemum flowers, accelerating bud opening, maintaining larger inflorescence diameter, and extending the vase life. Ultimately, this enhanced the ornamental value of cut chrysanthemums. These research findings provide theoretical and experimental foundations for the application of multi-walled carbon nanotubes as auxiliary additives to improve the ornamental quality of cut flowers.

Well-established carbon nanomaterials: modification, characterization and dispersion in different solvents

Three different types of carbon nanomaterials, SWCNTs, MWCNTs and GNPs were prepared, modified, characterized, and their dispersibility behavior in three different solvents was evaluated. The carbon nanotubes were synthesized by using the well-known chemical vapor deposition method and the graphene nanoplatelets by wet physicochemical treatment techniques. Their characterization was accomplished by using various advanced techniques, such as powder X-ray diffraction and Raman spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy and N2 adsorption at 77 K. Furthermore, the carbon nanostructures were modified via plasma treatment and wet chemical surface modification in order to enhance their dispersion characteristics, for achieving more homogenous suspensions and therefore to be remained dispersed over a reasonable period of time without any sedimentation. The effect of treatment parameters and the use of different solvents were thoroughly studied mainly by optical methods, but also by using the DIN/EN classified ISO method of oil absorption and UV–Vis spectroscopy. The enhanced dispersion rate is observed in both CNTs and GNPs materials following their surface treatment, especially when using the solvent n-methyl-2-pyrrolidone. The aforementioned studied nanomaterials are perfect candidate fillers for preparing polymeric mixed matrix membranes.Graphical abstract

Green synthesis capacitor of carbon quantum dots from Stachys euadenia

AbstractCarbon quantum dots (CQDs) are a new type of carbon nanomaterial that has recently attracted great attention as a potential competitor to standard semiconductor quantum dots. There are various ways to synthesis CQDs, and one of harmless way is undoubtedly green synthesis. In this study, hydrothermal synthesis based on the green way was employed to synthesize CQDs. The CQDs were obtained using the green leaves of the Stachys euadenia plant extract, an endemic species located in Turkey. The CQDs were characterized by fluorescent and UV‐Visible spectroscopy, and results confirmed blue emission (430–480 nm) and absorption around 280 nm. X‐ray photoelectron spectroscopy (XPS) analysis revealed C=C, C–N and C–O interactions. X‐ray diffractometer (XRD) patterns confirmed structure of carbon with a broad peak of (002) plane. High resolution tunneling electron microscopy (HRTEM) and dynamic light scattering (DLS) analysis was used to determine the shape and size of CQDs. The CQDs obtained from Stachys euadenia were employed as electrode materials for capacitor application, and they were tested in Swagelok‐type cell by cyclic voltammetry (CV) measurements. CQD capacitors exhibited 2.12 F/g charge and 1.24 F/g discharge capacitances were obtained with ~58% coulombic efficiency rate for the first cycle. Results highlights that CQDs are synthesized successfully by green synthesis method and can be used for capacitor applications.

Core-shell structured carbon dots with up-conversion fluorescence and photo-triggered nitric oxide-releasing properties.

Cancer-targeted nanotechnology has a new trend in the design and preparation of new materials with functions for imaging and therapeutic applications simultaneously. As a new type of carbon nanomaterial, the inherent core-shell structured carbon dots (CDs) can be designed to provide a modular nanoplatform for integration of bioimaging and therapeutic capabilities. Here, core-shell structured CDs are designed and synthesized from levofloxacin and arginine and named Arg-CDs, in which levofloxacin-derived chromophores with up-conversion fluorescence are densely packed into the carbon core while guanidine groups are located on the shell, providing nitric oxide (NO) for photodynamic therapy of tumors. Moreover, the chromophores in the carbon core irradiated by visible LED light generate large amounts of reactive oxygen species (ROSs) that will oxidize the guanidine groups located on the shell of the Arg-CDs and further increase the NO releasing capacity remarkably. The as-synthesized Arg-CDs show excellent biocompatibility, bright up-conversion fluorescence, and a light-controlled ROS & NO releasing ability, which can be a potential light-modulated nanoplatform to integrate bioimaging and therapeutic functionalities.

Effect of carbon nanomaterials on functional diversity and structure of soil microbial community under single and repeated exposures.

The extensive application of carbon nanomaterials (CNMs) has attracted increasing studies concerned about its environmental impact. These studies focus on single exposure to CNMs, but repeated exposures with relatively low concentration are more likely to occur under actual exposure scenario. In this study, we studied the metabolic functional and structure of soil microorganism community under single and repeated exposures to multiwalled carbon nanotubes (MW), graphene (GR), and fullerene (C60) by Biolog EcoPlates and high-throughput sequencing. Our findings revealed that repeated exposures to CNMs significantly increase the metabolic activity and diversity of the soil microbial community as compared with single exposure. Principal component and similarity analysis not only indicated that GR exerted a stronger effect on soil microbial diversity among three exposures compared to C60 and MW, but also revealed that the metabolic activity of the soil microbial community was more affected by the exposure scenarios of CNMs than the type of CNMs. These findings elucidated the effect of CNMs under different exposure scenarios on soil microorganism community, providing a new perspective on the risk assessment of nanomaterials.

Adsorption properties of hollow carbon spheres to gaseous cyclohexane using DFT simulation and experiments.

The cyclohexane is the common toxic volatiles emitted from the various industry in worldwide leading to environmental degradation and human illnesses. Hence, there is a requirement for an efficient and stable adsorbent for adsorbing these toxic molecules to safeguard human health and the air atmosphere. Hollow carbon spheres (HCS) are a new type of carbon nanomaterial with large specific surface area, low density, and good chemical and thermal stability. In this study, DFT simulations and static-dynamic adsorption studies of cyclohexane were carried out using HCS as the adsorbent material. Among them, static adsorption focuses on adsorption/desorption isotherm, adsorption isotherm model fitting and isosteric heat of adsorption. Dynamic adsorption was mainly studied the effect of initial concentrations, gas flow rate, and ambient temperature on adsorption performance. The results showed that HCS exhibited very good performance in cyclohexane adsorption.

Carbon Nanomaterials (CNMs) in Cancer Therapy: A Database of CNM-Based Nanocarrier Systems.

Carbon nanomaterials (CNMs) are an incredibly versatile class of materials that can be used as scaffolds to construct anticancer nanocarrier systems. The ease of chemical functionalisation, biocompatibility, and intrinsic therapeutic capabilities of many of these nanoparticles can be leveraged to design effective anticancer systems. This article is the first comprehensive review of CNM-based nanocarrier systems that incorporate approved chemotherapy drugs, and many different types of CNMs and chemotherapy agents are discussed. Almost 200 examples of these nanocarrier systems have been analysed and compiled into a database. The entries are organised by anticancer drug type, and the composition, drug loading/release metrics, and experimental results from these systems have been compiled. Our analysis reveals graphene, and particularly graphene oxide (GO), as the most frequently employed CNM, with carbon nanotubes and carbon dots following in popularity. Moreover, the database encompasses various chemotherapeutic agents, with antimicrotubule agents being the most common payload due to their compatibility with CNM surfaces. The benefits of the identified systems are discussed, and the factors affecting their efficacy are detailed.

Study on the performance and mechanism of carbon nanomaterials incorporated SBS composite modified asphalt

Based on the four-component separation technology of asphalt, the influence mechanism of carbon nanotubes (CNTs), graphene microsheets (GNPs) and graphene oxide (GO) in SBS-modified asphalt four-component was systematically analyzed by combining macroscopic properties and microscopic characteristics, as well as exploring the morphological distribution of SBS in asphalt four-component. According to the results of Fourier transform infrared spectroscopy and field emission scanning electron microscopy, the modification mechanism of asphalt by three types of carbon nanomaterials follows two pathways: chemical reaction and physical blending. The addition of CNTs, GNPs, and GO results in the destruction of long carbon chains of the saturated fraction in SBS-modified asphalt, and promotes the aggregation of SBS in the asphaltene, as well as its dense distribution and crosslinking in the oil fractions. The results of the fluorescence microscopy test and phase separation test showed that the dispersing effect of the three carbon nanomaterials could alleviate the aggregation phenomenon of SBS, improve the mutual integration between SBS and matrix asphalt, and promote the storage stability of SBS-modified asphalt. Therefore, based on the excellent mechanical properties of the three carbon nanomaterials and their promotion of filling and crosslinking of SBS in asphaltene, they have made significant contributions to the mechanical properties of carbon nanomaterials-composite SBS modified asphalt. This can also be demonstrated by DSR testing and conventional physical property testing. This study hopes to provide a viable analytical route for the use of nanomaterials in modulating the four-component structure and improving the properties of asphalt.

Electrochemical bottom-up synthesis of biomass-derived carbon dots for promoting Knoevenagel condensation

Natural raw materials such as biomass and plant wastes are the most interesting feedstocks for the synthesis of carbonaceous nanomaterials due to their high availability, environmental compatibility, and affinity with Green Chemistry principles. Carbon dots (CDs), a new type of carbon nanomaterials, perform an important role in this matter by serving in the development of environmentally friendly catalysts. In this study, CDs were synthesized in good yields by using the electrochemical bottom-up synthesis starting from the liquid phase that is separated during the hydrothermal carbonization (HTC) process involving orange peel waste (OPW). The electrochemical setup was also optimized to synthesize CDs based on 5-hydroxymethylfurfural, which represents one of the main components of the liquid phase obtained by HTC. The comprehensive optical and chemo-physical characterization of CDs samples carried out by several techniques such as SEM, TEM, XRD, PL, TGA, and FTIR, highlighted their distinctive morphological and microstructural features. The obtained CDs were successfully employed to catalyse the Knoevenagel condensation, showing excellent results in terms of yield and reproducibility. In addition, the sustainable nature of the CDs was demonstrated by recycling the catalysts up to five cycles without significant activity loss.

Three birds, one stone: Disinfecting and turning waste medical masks into valuable carbon dots for sodium hydrosulfite and Fe3+ detection enabled by a simple hydrothermal treatment

Disposable medical masks are widely used to prevent respiratory infections due to their ability to block virus particles from entering the human body. The coronavirus disease 2019 (COVID-19) pandemic highlighted the importance of medical masks, leading to their widespread use around the world. However, a large number of disposable medical masks have been discarded, some carrying viruses, which have posed a grave threat to the environment and people's health, as well as wasting resources. In this study, a simple hydrothermal method was used for the disinfection of waste medical masks under high-temperature conditions as well as for their transformation into high-value-added carbon dots (CDs, a new type of carbon nanomaterial) with blue-emissive fluorescence, without high energy consumption or environmental pollution. Moreover, the mask-derived CDs (m-CDs) could not only be used as fluorescent probes for sensing sodium hydrosulfite (Na2S2O4), which is widely used in the food and textile industries but is seriously harmful to human health, but also be used for detecting Fe3+ which is harmful to the environment and human health due to its wide use in industries.

Review on Biomedical Advances of Hybrid Nanocomposite Biopolymeric Materials.

Hybrid materials are classified as one of the most highly important topics that have been of great interest to many researchers in recent decades. There are many species that can fall under this category, one of the most important of which contain biopolymeric materials as a matrix and are additionally reinforced by different types of carbon sources. Such materials are characterized by many diverse properties in a variety industrial and applied fields but especially in the field of biomedical applications. The biopolymeric materials that fall under this label are divided into natural biopolymers, which include chitosan, cellulose, and gelatin, and industrial or synthetic polymers, which include polycaprolactone, polyurethane, and conducting polymers of variable chemical structures. Furthermore, there are many types of carbon nanomaterials that are used as enhancers in the chemical synthesis of these materials as reinforcement agents, which include carbon nanotubes, graphene, and fullerene. This research investigates natural biopolymers, which can be composed of carbon materials, and the educational and medical applications that have been developed for them in recent years. These applications include tissue engineering, scaffold bones, and drug delivery systems.

Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine.

Carbon quantum dots as a novel type of carbon nanomaterials have attracted the attention of many researchers because of their unique optical, antibacterial, and anticancer properties as well as their biocompatibility. In this study, for the first time, carbon quantum dots were prepared from o-phenylenediamine dissolved in toluene by a solvothermal route. Subsequently, the prepared carbon quantum dots were encapsulated into polyurethane films by a swelling-encapsulation-shrink method. Analyses of the results obtained by different characterization methods (AFM, TEM, EDS, FTIR, photoluminescence, and EPR) indicate the significant influence of the precursor on structural, chemical, and optical properties. Antibacterial and cytotoxicity tests showed that these dots did not have any antibacterial potential, because of the low extent of reactive oxygen species production, and showed low dark cytotoxicity. By investigating the cellular uptake, it was established that these dots penetrated the HeLa cells and could be used as probes for bioimaging.

Carbon nanomaterials: Types, synthesis strategies and their application as drug delivery system for cancer therapy

Inorganic and organic nanoparticles are used for abundant number of applications due to their novelty, surface charge, alloys, and oxides. Among the different types of nanoparticles, carbon nanomaterials (CNM) are gaining constant attention for biomedical applications. Their unique physical and chemical characteristics, like electrical, thermal, structural, and optical diversity, make them suitable materials. Selecting CNM for the treatment and diagnosis of disease and infection will provide controlled, predictable, low cytotoxic, and target-specific delivery of drugs for biomedical applications. Different types of CNM, like graphene oxide (GO), carbon nanotubes, nanorods, nanowires, and graphene quantum dots (GQDs), need to be investigated for application in Cancer treatment. Therefore, this review focuses on the different types of synthesis, drug loading, surface coating, and application of CNM as a drug delivery agent for cancer diagnosis and treatment.

Role of Defects of Carbon Nanomaterials in the Detection of Ovarian Cancer Cells in Label-Free Electrochemical Immunosensors.

Developing label-free immunosensors to detect ovarian cancer (OC) by cancer antigen (CA125) is essential to improving diagnosis and protecting women from life-threatening diseases. Four types of carbon nanomaterials, such as multi-wall carbon nanotubes (MWCNTs), vapor-grown carbon fiber (VGCFs), graphite KS4, and carbon black super P (SP), have been treated with acids to prepare a carbon nanomaterial/gold (Au) nanocomposite. The AuNPs@carbon nanocomposite was electrochemically deposited on a glassy carbon electrode (GCE) to serve as a substrate to fabricate a label-free immunosensor for the detection of CA125. Among the four AuNPs@carbon composite, the AuNPs@MWCNTs-based sensor exhibited a high sensitivity of 0.001 µg/mL for the biomarker CA125 through the square wave voltammetry (SWV) technique. The high conductivity and surface area of MWCNTs supported the immobilization of AuNPs. Moreover, the carboxylic (COO-) functional groups in MWCNT improved to a higher quantity after the acid treatment, which served as an excellent support for the fabrication of electrochemical biosensors. The present method aims to explore an environmentally friendly synthesis of a layer-by-layer (LBL) assembly of AuNPs@carbon nanomaterials electrochemical immunoassay to CA125 in a clinical diagnosis at a low cost and proved feasible for point-of-care diagnosis.

Carbon nanomaterials for designing next-generation membranes and their emerging applications.

Carbon nanomaterials have enormous applications in various fields, such as adsorption, membrane separation, catalysis, electronics, capacitors, batteries, and medical sciences. Owing to their exceptional properties, such as large specific surface area, carrier mobility, flexibility, electrical conductivity, and optical pellucidity, the family of carbon nanomaterials is considered as one of the most studied group of materials to date. They are abundantly used in membrane science for multiple applications, such as the separation of organics, enantiomeric separation, gas separation, biomolecule separation, heavy metal separation, and wastewater treatment. This study provides an overview of the significant studies on carbon nanomaterial-based membranes and their emerging applications in our membrane research journey. The types of carbon nanomaterials, their utilization in membrane-based separations, and the mechanism involved are summarized in this study. Techniques for the fabrication of different nanocomposite membranes are also highlighted. Lastly, we have provided an overview of the existing issues and future scopes of carbon nanomaterial-based membranes for technological perspectives.

Carbon Dots in Perovskite Solar Cells: Properties, Applications, and Perspectives

Perovskite solar cells (PSCs) have attracted substantial research interest owing to their flexible fabrication, high efficiency, and low cost. Currently, the power conversion efficiency (PCE) of PSCs has reached 25.7%, meeting the requirements for commercialization. In recent years, as a novel type of carbon nanomaterial, carbon dots (CDs) with abundant and tunable surface functional groups have shown great potential in regulating the efficiency and stability of PSCs because of their tunable photovoltaic properties, high photochemical stability, and energy down-shift properties. These CDs not only modify the interface of PSCs to control their energy level structure but also induce the growth of perovskite crystals to improve crystal quality, ultimately improving the efficiency and stability of PSCs. This review systematically summarizes the photoelectric properties of CDs and their application progress in PSCs as an active layer dopant, electron transport layer, hole transport layer, interface modification layer, and energy down-shift material after briefly introducing the structures and types of PSCs. Finally, the existing problems and challenges of CDs applied in PSCs are pointed out; specific solutions are proposed; and the future development prospects are presented.

An overview on atmospheric carbonaceous particulate matter into carbon nanomaterials: A new approach for air pollution mitigation.

Air pollutants consisting of atmospheric particulate matter (PM) poses a major threat to the environment and human health. However, due to their carbonaceous nature, these atmospheric PM can also be used as a precursor for fabrication of high-valued carbon nanomaterials (CNMs) leading to waste to wealth as well as mitigation of air pollution. Over the few years, various results have been reported on different types of physical and chemical methods for the synthesis of CNMs from atmospheric particulate matter with the help of top down and bottom up methods; however, there is a lack of review on these innovative processes and outcome in order to assess their feasibility and suitability for further investigation. This review critically assesses the synthesis, identification, and characterization of different types of CNMs derived from the atmospheric PM. The fascinating fluorescence properties along with the novel multifarious applications of such PM-derived CNMs are also extensively discussed in this review work. This unique review will certainly help to make a new avenue for air pollution mitigation through conversion of PMs in to value added nanomaterials (VNMs) and will boost the research activity in the field of environmental nanotechnology for a cleaner environment.