Internal combustion engine fuel use is rising, gas prices are fluctuating, we are using less fossil fuels and natural resources, and we need to develop alternative fuels with lower carbon contents. This study compares several gasoline mixtures in a single-cylinder, two-stroke SI engine. The current experimental work provides a thermal barrier for gasoline mixtures containing ethanol, butanol, and propanol by 100-µm piston crown coatings of magnesium partially stabilized zirconium (Mg-PSZ). 20% ethanol and 80% gasoline, 20% butane and 80% gasoline, and 20% propane and 80% gasoline made up the fuel mixture samples. The following engine variables must be assessed in this experiment for coated and uncoated pistons: brake-thermal efficiency (BTH), specific fuel consumption (SFC), and HC and CO emissions. According to the experiment findings, employing E20 resulted in a 4% gain in thermal efficiency, a 1.78% decrease in specific fuel consumption, and a 2.0% and 2.4% decrease in HC and CO exhaust emissions. The results show that heat barrier coatings and gasoline blends (E20) may improve engine performance while lowering exhaust emissions.