Metal halide organic-inorganic hybrid perovskite is a kind of rapid development of semiconductors but its major development has been concentrated in lead-based perovskites. Here we report two zero-dimensional non-lead halide perovskites [3-FPEA]3(SbCl4)Cl2 (1) and [3-FPEA]4(BiI6)I (2) (3-FPEA = 3-fluorophenethylamine) with the reversible phase transitions. The differential scanning calorimetry (DSC) and UV-vis absorption measurements of 1 and 2 revealed that the phase transition temperatures are 350 K (1) and 335 K (2), the bandgaps are 3.53 eV (1) and 2.14 eV (2), respectively. The room temperature X-ray single crystal diffraction showed the cation [3-FPEA]+ in 1 and 2 proceeds a twofold disorder, and the anions in 1 are a dimer [Sb2Cl10] constructed with [SbCl6] octahedra by sharing the Cl···Cl edge, and the anions in 2 are the discrete [BiI6] octahedron. This study can provide an effective molecular design strategy for exploring and investigating non-lead-based halide perovskite semiconductive phase change materials.