In this study, the PLA plied yarn was fabricated by twisting four of PLA yarns together, then PLA plied yarn was used a 16-spindle braid machine to produce the PLA braids. PLA braids were immersed in the suspension of β-tricalcium phosphate (β-TCP), and heat treatment to improve the adhesion of β-TCP particles. PLA/β-TCP composite braids were immersed in simulated body fluid (SBF) to promote bonelike apatite production. The morphology of PLA braids were investigated by scanning electron microscopy (SEM), and the results shown that when twist coefficient was 3 of PLA plied yarn, the concentration of β-TCP suspension was 0.15 wt % and heat treatment at 175 °C for 9 min, we can obtain the optimal conditions of β-TCP particles adhesion.