Silver ink demonstrates significant potential in the field of printed electronics due to its excellent electrical conductivity and stability. However, traditional silver electrodes still face issues such as microscopic fractures under mechanical stresses like bending, twisting, and stretching, which are common in conformal circuits and flexible electronic devices. This study introduces a cost-effective, one-step method for synthesizing high stability carbon nanotube (CNT)-doped Ag2O ink. The feasibility of using CNTs as a scaffold with silver as the conductive network is validated. The study investigated the microscopic structural characteristics and composition of the printed films. It also analyzed their electrical conductivity and mechanical properties before and after annealing. A special surfactant ratio was employed to ensure the ink remains stable for an extended period of time. In testing, CNT-doped silver films exhibit exceptional electrical conductivity, and the printed lines achieve extremely low resistance after low-temperature (200 °C) annealing. The ink with a 5.45% mass fraction of CNTs achieved a minimum resistivity of approximately 1.4×10−7Ωm. Under external twisting forces, CNTs enhance the yield strength of the conductors by transferring and absorbing stress, refining the grain structure within the conductive network, and increasing the dislocation density. The printed circuits maintained nearly the initial resistivity even after multiple twists. The CNT-doped Ag2O ink demonstrates outstanding mechanical strength and flexibility, showcasing its potential for practical applications.
Read full abstract