Turbidity Maximum Zone Research Articles

Transport inventories and exchanges of organic matter throughout the St. Lawrence Estuary continuum (Canada)

Hypoxia (O2 < 2 mg/L) driven by eutrophication in estuaries and shelves is a worldwide expanding problem. The role of organic matter (OM) inputs is emerging as an important contributor to this issue, beside the well-known implication of inorganic nutrients. The St. Lawrence Estuary, one of the largest and deepest estuarine system in the world is facing strong persistent and increasing hypoxia. In this context, transport and exchange of particulate and dissolved organic matter (POM and DOM, respectively) were investigated as a first step to understand their implication in hypoxia. Tributaries and Gulf contributions were compared to St. Lawrence Estuary inventories for the spring freshet (May), the summer low-flow (August), and the fall-mixing (October). Furthermore, changes in OM ratios were examined along the estuarine gradient from the upper St. Lawrence Estuary (USLE), downstream of the maximum turbidity zone, to the lower estuary (LSLE). For the USLE, net transport was always positive and net export/loading ratios suggested that 64–90% of POM and 30–63% of DOM were either retained or transformed during its course from tributaries to LSLE. Net transport from the USLE toward the LSLE was 3–13 fold more important in May than in August or October. For the LSLE, net transport to the Gulf was generally negative meaning that OM production was the dominating proces. The extremely high net export/loading ratios in August indicate that POM production was 28.8 to 41.4 times the combined inputs of tributaries and Gulf. Net export/loading ratios remained superior to one during May and October (1.7–9.4) for the LSLE. Changes along the upstream–downstream continuum were seen for POM, with a steady increase relative to total suspended matter from 7.3% to 50.2%, but they were not observed for DOM, for which no obvious trends were detected. Our results highlight the importance of explicitly considering OM in eutrophication monitoring programs of the St. Lawrence Estuary, as the mineralisation of a portion of the large OM pool size could influence our understanding of hypoxia and acidification of the deep waters of LSLE.

210Po and 210Pb as tracers for particle cycling in a shallow semi-enclosed bay of Taiwan Strait

Naturally-occurring 210Po and 210Pb are good tracers for particle cycling in the estuarine and coastal environment. Activities of 210Po and 210Pb were measured in samples of bulk (wet + dry) atmospheric deposition, river water and surface seawater collected in the Zhangjiang Estuary-Dongshan Bay to investigate the geochemical scavenging rates (or residence times) of these particle-reactive nuclides. The spatial distribution of 210Po and 210Pb were strongly influenced by suspended particulate matter (SPM) concentrations and in almost all stations, 210Po and 210Pb were mainly in particulate form (51.7%–92.2% of the total for 210Po and from 44.3% to 90.3% for 210Pb). Due to the very high SPM concentration, enhanced scavenging of 210Po and 210Pb was observed in the maximum turbidity zone of Zhangjiang River, with a marked decrease of dissolved nuclides’ activities. We built a mass balance model and we found out that atmospheric inputs are the major source of these radionuclides comparing with other sources (e.g., river inputs or ingrowth production) in the study area. Residence times of 210Pb were calculated to be 2.2–9.8 and 0.5–8.9 days for dissolved and particulate 210Pb, respectively. And residence times of dissolved and particulate 210Po were 6.3–31.7 and 2.2–13.9 days, respectively. In the turbidity zone, we found an unexpected result that particulate 210Po and 210Pb had the longest residence times (about two weeks), suggesting that SPMs in the turbidity zone would not be easy to sink to the sea floor. We also found that different SPMs showed significantly different 210Po/210Pb activity ratios, which increased in the following order: atmospheric deposition in dry season < SPMs in river < SPMs in the Zhangjiang Eastuary-Dongshan Bay < biogenic particles (including detritus, fecal pellets, cells of phytoplankton and zooplankton). This phenomenon implied that 210Po/210Pb activity ratio in the particles has the potential application in distinguishing SPM sources in the coastal seas.

Typhoon triggers estuarine heavy metal risk by regulating the multifractal grainsize of resuspended sediment

The turbulent boundary layer generated by wind in the estuarine surface water serves as a main factor affecting the distribution of suspended particulate matter (SPM) and suspended sediment concentration (SSC). In this study, representative typhoon-induced variation of surface fine SPM (<63 μm) was simulated in the Yangtze River Estuary (YRE) under two time scenarios. Each scenario contained four grainsize SPM fractions named Fraction 1 (<8 μm), Fraction 2 (8–16 μm), Fraction 3 (16–32 μm), Fraction 4 (32–63 μm). The typhoon-induced resuspended multifractal SSC quantification (TRMSQ) based on the relationship between SPM grainsize and heavy metal adsorption capacity was proposed to assess the variation in the resuspended threat of heavy metal to 6 key estuarine protected objects (three reservoirs & three national reserves) between Scenarios 1 and 2. The results presented that Fraction 3 exhibited the maximum increment in SSC resuspension mass and longest regression time from typhoon. Combined with TRMSQ, chromium (Cr) was calculated to be the riskiest typhoon-induced factor. The integrated resuspended risk of heavy metals for each protected object tends to increase from the northwest of Chongming Island (1.2) towards the maximum turbidity zone (>9) downstream, with an estuary-wide mean of 3.3.

Departures from the archetypal deltaic ichnofacies

Abstract Recent work has focused on erecting new Seilacherian ichnofacies for depositional environments subject to recurring temporal and spatial variations in physico-chemical stress. In marine deltaic settings, these correspond to the Phycosiphon Ichnofacies for mudstone-dominated prodeltaic deposits and the Rosselia Ichnofacies for sandstone-dominated delta-front successions. The archetypal expressions of these ichnofacies, however, are founded on mixed process (wave- and river-influenced) systems, because the juxtaposition of ambient marine conditions during periods of prolonged wave energy with rapid deposition and physico-chemically stressed conditions during heightened fluvial discharge best expresses the deltaic signal. As deltaic settings shift towards end-member processes (e.g. river domination, wave domination and tide domination), or towards mixed-process conditions other than river and wave influence, the resulting ichnological suites and bioturbation fabrics depart from the recently published archetypes. Using selected studies of marine deltaic deposits, predictable departures from the archetypes can be recognized on the basis of these changing processes and their associated physico-chemical stresses. River-dominated delta deposits and tide-dominated delta successions display the greatest deviation from the published archetypes. River-dominated examples show elevated deposition rates, periods of salinity reduction, slumping and dewatering, elevated water turbidity, flood-induced sediment gravity flows and hypopycnal-generated fluid mud. As a result, river-dominated successions are largely devoid of bioturbation. Evidence of marine conditions is commonly restricted to isolated occurrences of dwelling structures such as Arenicolites , Ophiomorpha or Rosselia in sandstone, and Chondrites , Phycosiphon or Zoophycos in mudstone beds, particularly in prodeltaic intervals. Tide-dominated deltaic successions are markedly heterolithic and typified by highly mobile substrates manifested by incrementally migrating asymmetric bedforms and abundant fluid mud. Such settings are also prone to marked changes in salinity and shifts in the position of the turbidity maximum zone. Successions typically show low intensities of bioturbation and sporadically distributed burrows, as well as deposit-feeding structures, deeply penetrating dwelling structures or fugichnia. Many trace fossil suites consist entirely of facies-crossing elements, making assignment to an ichnofacies impossible. Storm flood-dominated deltaic successions are characterized by tempestites that are typically interstratified with river flood-induced sediment-gravity flow deposits and/or mantled by largely unburrowed mudstone drapes derived from hypopycnal plumes associated with river floods. Where these storm flood cycles are interstratified with ambient fairweather beds, assignment to the archetypal deltaic ichnofacies is straightforward. However, as storm beds become increasingly erosionally amalgamated, the preservation potential of the fairweather beds is reduced and the resulting trace fossil suites are biased towards those recording opportunistic colonization of the event beds. The presence of mudstone layers with low bioturbation intensity (BI) containing small numbers of ichnogenera positively correlated with marine conditions (e.g. Chondrites , Phycosiphon and/or Zoophycos ) may be the only evidence that the suites should be assigned to one of the deltaic ichnofacies. Wave-dominated deltas lacking significant storm influence are typically challenging to differentiate from their archetypal strandplain shoreface counterparts and, correspondingly, the resulting trace fossil suites are broadly comparable to the archetypal Cruziana and Skolithos ichnofacies. Most of the preserved record of wave-dominated delta successions is related to fairweather ambient conditions, and so facies typically show high BI values and uniformly distributed bioturbation. Key to recognizing that the suites should be assigned to one of the deltaic ichnofacies is the presence of rare river-generated mudstone and sandstone beds that display evidence of physico-chemical stress and/or the paucity of domichnia typical of suspension-feeding organisms. In most delta types, the prodeltaic facies are most readily discerned to contain trace fossil suites of the Phycosiphon Ichnofacies, owing to the higher preservation potential of all depositional processes, including marine fairweather beds, river-supplied hyperpycnites and other sediment gravity flow deposits, tempestites and fluid mud derived from river flood-related hypopycnal plumes. Assignment of trace fossil suites to the Rosselia Ichnofacies requires some record of the fairweather conditions, which are generally diminished in river-, tide- and storm-dominated successions. The dominance of structures positively correlated to deposit-feeding ethologies at the expense of those attributed to suspension-feeding strategies may point to elevated water turbidity and assignment of the suite to the Rosselia Ichnofacies. However, in many cases, the ichnological suites of delta fronts are so depauperate that assignment to an ichnofacies is problematic and should be avoided.

Tidal Sediment Supply Maintains Marsh Accretion on the Yangtze Delta despite Rising Sea Levels and Falling Fluvial Sediment Input

Tidal marshes are among the world’s most valuable ecosystems; however, they are increasingly threatened by rising sea levels and a decline in fluvial sediment supply. The survival of a tidal marsh under these twin threats depends upon the net input of tidal sediments, because this will determine the deposition rate. The rate of relative sea level rise currently affecting the Yangtze Delta is rapid (~4 mm/a), and the sediment discharge from the Yangtze River has decreased by &gt;70% over recent decades. In order to improve our understanding of the response of the marshes in the turbid zone of the Yangtze Estuary to these changing environmental conditions, we measured sediment transport in and out of a tidal basin and calculated the deposition rate over eight tidal cycles covering different tidal ranges during the summer and winter seasons. The suspended sediment concentration (SSC) during the flood phase of the tidal cycle (average = 0.395 kg/m3) was markedly higher than that during the ebb (average = 0.164 kg/m3), although water transport during the flood tide was almost equivalent to that during the ebb. As a result, ~40% of the sediment inflow during the flood phase was retained within the marsh. This reason is mainly attributable to the dense marsh vegetation, which attenuates waves and currents and to which the sediments adhere. The annual deposition rate in the marsh was approximately 6.7 mm/a. These findings indicate that under the combined influence of sea level rise and river sediment supply reduction, the sediment transport through the turbidity maximum zone of the Yangtze River estuary could maintain the relative stability of the marsh area to a certain extent.

End-member modeling and sediment trend analysis as tools for sedimentary processes inference in a subtropical estuary

Mathematical models based on grain size data enable identifying sediment transport sources and processes in coastal regions, helping to understand the relationship between hydrodynamic and sedimentary processes. This study applied End-Member Analysis and Grain Size Trend Analysis to a grain size database from the Paranaguá Estuarine Complex (PEC), a subtropical estuary in southern Brazil. The end-member analysis allowed identifying three grain size populations, whose spatial distribution is influenced by the dynamics between river discharge and tidal currents acting in the Paranaguá Estuarine Complex. The end-member 1 — formed by finer sediments — is mainly distributed over Antonina Bay and extends into the maximum turbidity zone. The Grain Sized Trend Analysis revealed that these sediments — derived from the weathering of rocks from the Serra do Mar mountain range system — are transported in the west-east direction by river discharge, mainly from the Cachoeira and Nhundiaquara rivers. Furthermore, our results indicate that sediments from end-members 2 and 3 — which are coarser — are distributed in the Paranaguá and Laranjeiras Bays. The transport of these sediments happens towards the center of the estuary due to wave- and tidal-generated currents.

Luminescence characteristics of muddy sediments in the turbidity maximum zone of the Yangtze River mouth and implications for the depositional mechanisms

Muddy sediments are the most prominent constituents of sedimentary successions in tide-dominated river deltas and have highly complex depositional mechanisms. In this study, we performed fine-grained (4–11 μm) quartz optically stimulated luminescence (OSL) dating on two sediment cores collected at a shipwreck site in the turbidity maximum zone (TMZ) of the modern Yangtze River mouth, China, which were compared with previously published dating results including 45–63 um quartz OSL dating, radionuclide dating, porcelain artifacts recovered from the wreck, macro-plastics, and the morphological history recorded in marine charts. We investigate the luminescence characteristics of muddy sediments trapped in the TMZ and discuss the implications of OSL ages in understanding depositional mechanisms in tide-dominated river mouths. The results indicate that most OSL ages of muddy sediments in the delta front setting are overestimated compared with other dating methods. We suggest that OSL age overestimation reflects the trapping of sediments from offshore in the TMZ imported by saltwater intrusions and storm events. The offshore inputs contain high percentages of residual luminescence and are also subjected to incomplete bleaching due to turbid water conditions and near-bed dispersal in the salt-wedge river mouth. We thus suggest that the reduced bleaching efficiency of muddy sediments in delta front settings needs to be accounted for in understanding sedimentary processes and distinguishing between different sedimentary facies in tide-dominated river mouths. Furthermore, we propose that differences in quartz OSL ages of fine- and medium-grained fractions may arise in response to extreme events.

Transport of trace metals and their bioaccumulation in zooplankton from Changjiang (Yangtze River) to the East China Sea

The present study conducted a comprehensive field investigation on the transport and bioaccumulation of six trace metals (Cr, Cd, Pb, Mn, Ni, Cu) along a transect from Changjiang (Yangtze River) to the East China Sea continental shelf, which exhibited large variations in physiochemical properties (salinity, turbidity, pH, chlorophyll a, total nitrogen, dissolved oxygen, dissolved and particulate organic matter). From riverine sites to marine sites, dissolved Cr and Cd significantly increased, dissolved Pb and Mn showed less variations, while dissolved Cu and Ni showed complex spatial distribution patterns. Particulate trace metals (for Cr, Mn, Ni and Cu) were significantly negatively correlated with salinity. As a result, partition coefficients of trace metals (except Pb) were all significantly negatively correlated with salinity, indicating high salinity facilitated desorption/dissolution of metals from particulate phase. Additionally, the Changjiang derived particulate Pb, Mn, Ni and Cu sharply decreased (particularly for Mn) at the downstream of turbidity maximum zone, suggesting the efficient trapping of metals within this region. We further investigated the site-specific bioaccumulation of trace metals in size-fractionated zooplankton. Metal contents in macro-zooplankton were lower than micro- and meso-zooplankton owing to size-dependent zooplankton communities, while site-specific metal bioaccumulation mainly driven by site-specific zooplankton communities and salinity. The bioaccumulation factors of metals (Cr, Cd, Ni and Cu) were significantly negatively correlated with salinity, indicating high salinity hampered metal uptake which might attribute to competition of cations and formation of less bioavailable inorganic complexes with anions. Overall, high salinity generated two-sided effects (elevated dissolved metal concentrations Vs. reduced metal bioaccumulation) on metal contents in zooplankton (especially for Cr, Cd, Ni, and Cu), resulting in metal- and site-specific metal contents. We noticed relatively higher metal contents in zooplankton at hypoxia sites which could further transfer to predators in the East China Sea, and the underlying mechanisms still require future investigation.

Mapping Dynamic Turbidity Maximum Zone of the Yellow River Estuary from 38 Years of Landsat Imagery

Turbidity maximum zone (TMZ) plays a crucial role in estuarine ecosystems, exerting effects on erosion, environment evolution and socioeconomic activities in the coastal area. However, the long-term understanding of the TMZ in large river estuary such as the Yellow River estuary is still lacking. In this study, we focus on the TMZ distribution, variation and regulation mechanisms in the Yellow River estuary from different time scales. Based on time series Landsat images during the period 1984 to 2021 and Google Earth Engine (GEE), we proposed a TMZ extracting method in the Yellow River estuary to generate 322 TMZ maps. The overall accuracy of our algorithm reached 97.4%. The results show that there are clear decadal and seasonal TMZ variations during the 38-year period in the Yellow River estuary. Morphology, currents and wind speeds combined with seawater stratification have direct effects on TMZ at different time scales, while the direct impacts of tides and fluvial output of the Yellow River on TMZ are limited. In this article, the highly robust method provides a cost-effective alternative to accurately map the TMZ in global large river estuaries and systematically reveals the spatiotemporal evolution of TMZ, shedding light on the response mechanism of coastal geomorphology, marine ecological environment and biogeochemical cycle.

Phytoplankton habitats and size distribution during a neap-spring transition in the highly turbid macrotidal Chikugo River estuary

The effect of neap-spring transition on the spatial and temporal changes in the cell size distribution of different phytoplankton species and their size-based habitats distribution were investigated in the highly turbid macrotidal Chikugo River estuary, Japan in 2021. The estuarine mixing changed from stratified to well-mixed over the transition from neap to spring tides and saltwater (1–5) intruded until 17 km with negligible effect from river discharge. The suspended sediment concentration (SSC) was low (<40 mg L−1) during neap tide and highest (1000 mg L−1) during spring tide associated with strong mixing, which led to the formation of an estuarine turbidity maximum (ETM) zone between 8 and 12 km. A total of 159 phytoplankton species were identified in the estuary and are classified into seven groups. The diatoms (freshwater and marine habitats) were found as significant groups (79–86 %). Principal component analysis (PCA) results showed that salinity (p < 0.05) and mixing (p < 0.05) were the major controlling factors in the phytoplankton habitats distribution. The diatoms abundance started to increase from neap tide and reached the maximum abundance (174.714 cells/mL) two days after neap tide, then decreased towards spring tide (69.257 cells/mL). Additionally, the cell sizes of dominant diatoms species (Skeletonema costatum and Nitzschia acicularis) increased from neap to intermediate tides and continued increasing until the spring tide. Spatially, the abundance of diatoms was lower in the middle estuary (67–86 cells/mL) than in other parts because of ETM formation, although larger size distribution occurred. This study concludes that the abundance and size distribution of phytoplankton are influenced by estuarine mixing, and the neap-spring transition phase is more essential for phytoplankton growth than individual neap and spring tides in tide-dominated estuaries. Furthermore, size-increasing patterns play an important role in sustaining their survival strategy under the strong turbulent conditions in addition to saltwater intrusion and ETM.

Linkages Between Optical and Molecular Signatures of Dissolved Organic Matter Along the Yangtze River Estuary-to-East China Sea Continuum

Changes in the molecular composition of dissolved organic matter (DOM) and its light-absorbing component (CDOM) along the river–coastal ocean continuum are crucial for better understanding the source and fate of DOM in coastal oceans. Both optical (absorbance and fluorescence) techniques and ultrahigh-resolution mass spectrometry have been widely used to trace DOM cycling. However, to the best of our knowledge, the linkage between these two techniques is rarely investigated along the river–coastal ocean continuum. In this regard, bulk characterization, optical techniques, and ultrahigh-resolution mass spectrometry [Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS)] were applied to determine the DOM chemistry along a spatial transect from the Yangtze River Estuary (YRE) to the East China Sea. The results showed that DOM in the YRE was mainly controlled by the mixing of freshwater and seawater. Besides terrestrial input, multiple sources (tributary input from the Huangpu River, wastewater input, and sediment resuspension and subsequent release at the turbidity maximum zone) have been identified. In addition, the linkages between CDOM and thousands of formulas were developed based on Spearman’s rank correlations between optical parameters and FT-ICR MS peaks. The linkages showed that the molecular groups associated with the optical parameters generally agreed with conventional biogeochemical interpretations. Nevertheless, each technique has its unique advantage and weakness in interpreting DOM composition. Therefore, the combination of the untargeted FT-ICR MS approach and optical techniques could be valuable for studying the DOM sources and transformation in large river estuarine systems.

Distribution and spatial-temporal variation of organic matter along the Yangtze River-ocean continuum

River-ocean continuums are rich environments key to the transformations of organic matter and nutrients from many sources. Human impacts on these ecosystems can be local, upstream, or global. Particulate organic matter provides one tool for exploring these processes; inventories and carbon and nitrogen stable isotopes are useful indicators. This study conducted comprehensive field investigations from the upper reaches of the Yangtze River to the coastal waters to explore the distribution and spatial-temporal variation of particulate organic carbon (POC) and nitrogen (PON), and dissolved organic carbon (DOC) in surface waters from April–May (Spring) and October–November (Autumn) 2014. Carbon and nitrogen isotopes (δ13C and δ15 N) were used to assess organic matter sources. Numerous environmental factors were also measured. PON and POC exhibited similar spatial and temporal variations along the river mainstream. POC increased from the upper to lower reaches, similarly in both seasons; POC declined seaward from the river mouth. In contrast, PON showed greater seasonal and spatial variations along the continuum, with greater primary production in offshore areas. DOC along the continuum was higher in autumn, likely related to greater river discharge and warmer waters. The DOC/POC ratios by weight were &amp;gt;1 in most samples except for the ones collected from the turbidity maximum zone, suggesting that DOC contributed to a larger fraction of the total organic matter inventories. End-member mixing models revealed that the proportion of organic matter from upstream (allochthonous) sources was &amp;gt;70% in the mainstream during both seasons. In coastal waters, the proportion of allochthonous sources was only &amp;gt;57%. Compared with other major world rivers, DOC and allochthonous POC are especially high in the Yangtze River-ocean continuum. Human activities causing variations in terrestrial inputs are likely an important driving factor. In addition, the contribution of soil erosion caused by urbanization to riverine organic carbon cannot be ignored.

Lateral Variation of Tidal Mixing Asymmetry and Its Impact on the Longitudinal Sediment Transport in Turbidity Maximum Zone of Salt Wedge Estuary

The lateral bathymetry in the estuary results in different degrees of tidal mixing asymmetry, which has significant impacts on the longitudinal sediment transport by changing the temporal variation of vertical eddy diffusion. This study focus on the lateral variation of tidal mixing asymmetry and longitudinal sediment transport at the landward boundary of turbidity maximum zone in the North Channel of Yangtze estuary, which is a typical time-dependent salt wedge estuary. A transect survey was carried out in December, 2018; five vertical profiles of flow velocity, salinity and suspended sediment concentration were simultaneously measured covering a spring tidal cycle. Analysis of the data revealed that, after the maximum ebb, the stratification in the main and secondary channel was stronger than that on the shoal. In the channel, during ebb tide, the stronger stratification restrained the turbulent mixing induced by vertical shear, vertical mixing during the flood tide was stronger than that during ebb tide and vertical mixing coefficients ranged from 0.06 to 0.12, showing regular tidal mixing asymmetry over a flood–ebb tidal cycle. Therefore, stronger eddy diffusion caused by vertical mixing resulted in higher suspended sediment concentrations during flood tide, the larger landward tidally averaged sediment transport rate was induced by tidal pumping with the transportation of flood tidal current and the net sediment transport over a flood–ebb tidal cycle in the channel was landward. Meanwhile, on the shoal, under the effect of vertical shear, the vertical mixing during flood tide was weaker than that during ebb tide; vertical mixing coefficients ranged from −0.27 to −0.02, showing the reversed tidal mixing asymmetry. Higher suspended sediment concentration was transported seaward by the ebb current, the tidally averaged sediment transport rate by both tidal pumping and advection was seaward and the net sediment transport was seaward. Furthermore, large river discharge increased the seaward advection sediment flux on the surface layer in the main channel, resulting in the seaward tidally averaged sediment flux. Strong resuspension increased the seaward advection sediment flux near the bottom in the main and secondary channel, resulting in the seaward tidally averaged sediment flux.

Rapid and simple determination of iron-porphyrin-like complexes (Fe-Py) in estuarine and marine waters

This work presents a new method for determining iron-porphyrin-like complexes (Fe-Py) based on Continuous Flow Analysis (CFA) with chemiluminescence detection and its application to natural waters in an estuarine environment. The involved reaction is founded on luminol oxidation by hydrogen peroxide in the presence of Fe-Py complexes at pH 13. The detection limit is 7.2 pM hemin equivalent, the linear range extends to 150 nM and precision of the method is 6.4% at 0.25 nM (n = 8). This new method's detection limit is 15 times lower than the previous analytical procedure of Vong et al. (2007), based on Flow Injection Analysis (FIA) and using different chemical conditions. Moreover, the presented method is fast (90s/analysis), involves a low consumption of reagents, a small sample volume, and simplified sample handling. The method was applied to natural samples collected along the temperate macrotidal Aulne estuary (Bay of Brest, France). Here, we report for the first time on the spatial distribution of the Fe-Py complex concentration (dissolved, reactive particulate) over the entire salinity gradient of a macrotidal temperate estuary. The Fe-Py concentrations in the riverine and marine end-members were 0.873 ± 0.007 nM (S = 0.92) and 0.010 ± 0.004 nM (S = 34.86), respectively. Between these two salinities, non-conservative behaviour was observed, with an increase in Fe-Py concentrations to 1.142 ± 0.031 nM at S = 5.2 corresponding to the Maximum Turbidity Zone (MTZ), followed by a strong removal of Fe-Py in the salinity range 5–20. Then, the Fe-Py concentrations decreased linearly during mixing processes, reaching picomolar levels towards the coastal waters. The estimated entering flux from the river equaled 240 ± 2 g.d−1 whereas the net flux to coastal sea waters was 95 ± 10 g.d−1 leading to a loss of ~60%. The estuarine system globally acts as a sink for Fe-Py complexes, probably due to the aggregation of Fe-Py complexes on particles, to flocculation and/or sedimentation.

Human Intervention–Induced Changes in the Characteristics of the Turbidity Maximum Zone and Associated Mouth Bars in the Yangtze Estuary

In the past two decades, the dynamic sedimentation process of the Yangtze Estuary has been seriously disturbed by coupled human interventions from the river basin to the estuary, especially the impoundment of the Three Gorges Dam in 2003 and the large-scale Deep-water Navigational Channel (DNC) regulation project in 1998–2010. This study investigated the changes in sedimentary dynamic and geomorphological processes in the turbidity maximum zone (TMZ) by analyzing the historical and present data for current, salinity, suspended sediment, and bathymetry. The results show that the decreased riverine sediment input caused a lagging decrease in suspended sediment concentration in the TMZ during the flood seasons. The DNC caused changes in the flow structure, sediment transport, and geometry of the TMZ in the North Passage (NP) and the South Passage (SP). In the NP, decreased ebb transport in the upper reaches led to landward migration of the TMZ during low discharges, while increased ebb transport in the middle and lower reaches caused the seaward migration of the TMZ during high discharges. As the associated topography of the TMZ, the mouth bar in the NP was mostly removed by channel dredging. However, rapid deposition at the location of the previous mouth bar indicates the formation of an incipient bar. In the SP, increased ebb transport after the DNC-induced disappearance of the TMZ and the mouth bar in the upper reaches and the seaward migration of the TMZ in the middle and lower reaches. Therefore, we found that the construction of dams and large-scale estuarine projects changed the sediment dynamics and geomorphological processes of the TMZ and even affected the long-term evolution of the estuary. Construction regulation projects in the TMZ, intended to narrow the cross-section and enhance seaward sediment transport, may produce the opposite effect. Before and after engineering projects, their impacts on estuarine processes need to be carefully estimated.

Pulsed distribution of organotins in the turbidity maximum zone of the Yangtze Estuary throughout a tidal cycle

This study investigated the concentration fluctuation of organotin compounds in the Turbidity Maximum Zone (TMZ) of the Yangtze Estuary within a tidal cycle. Organotin concentrations varied greatly during the tidal cycle with dissolved organotins ranged from 39 to 682 ng Sn·L−1 and 40–1588 ng Sn·L−1, and particulate organotins ranged from 59 to 467 ng Sn·g−1 dw and 21–429 ng Sn·g−1 dw in TMZ water close to Hengsha Island and Jiuduansha Island, respectively. Meanwhile, the maximum levels of organotins appeared at each period of tidal transition, suggesting the tidal-driven pulsed exposure of organotins was prevalent in the estuaries. Besides, the organic carbon-normalized partition coefficients (Koc) of tri-organotins between suspended particulate matter (SPM) and aqueous phase were correlated with the phase distribution of natural organic matter (NOM). The dissolved tri-organotins were also associated with the properties of dissolved organic carbon (DOC) including aromaticity, hydrophobicity, and chromophoricity. Hence, pulsed exposure on organotins in the TMZ are highly dictated by the dynamic environmental conditions (i.e., SPM and NOM) with the tidal currents, which could further provide information to assess organotin ecological risks accurately in estuaries.

New Insights Into the Non‐Conservative Behaviors of Nutrients Triggering Phytoplankton Blooms in the Changjiang (Yangtze) River Estuary

AbstractFour research cruises were carried out during March and July in 2015 and 2016 in the Changjiang (Yangtze) River Estuary and the adjacent shelf. Nutrient concentrations (regarded as static parameters) were measured in the surface and bottom waters collected at 86–99 stations over the course of these cruises. In addition, unfiltered seawater samples were incubated onboard for 48 hr to measure the potential change rates of nutrients (regarded as dynamic parameters). These parameters can help directly elucidate non‐conservative behaviors of nutrients in order to determine whether seawater serves as a source or a sink. Large nutrient sinks (with more negative variation rates) were consistently found at the surface during the two July cruises at the stations just along the outside edge of the turbidity maximum zone near the mouth of the river. Negative rates, although with much smaller magnitudes, were also found in most bottom water samples in July and at both the surface and bottom in March. The high net nutrient uptake rates at the surface in the summer triggered bloom events later at the seaward stations, showing that high net nutrient uptake is the cause and high chlorophyll‐a is the consequence of the bloom. Such information about biogeochemical cycling of nutrients and the mechanisms and development of bloom events occurring in large river estuarine and coastal areas could not have been obtained if these static and dynamic parameters had not been studied together.

Spatial and temporal variations of hydrodynamics and sediment dynamics in Indus River Estuary,Pakistan

&lt;p&gt;Field investigations were conducted to study the seasonal variation of hydrodynamics and sediment transport in Indus River Estuary (IRE), Pakistan. The data of water levels, currents, salinity, and suspended sediment concentration (SSC) were collected hourly covering both wet and dry seasons. Tidal amplitudes were higher near the mouth than those at the middle and upper estuary. The ebb phase lasted longer than that of the flood during the wet season. The asymmetric tidal pattern with higher ebb velocity was observed during the wet season. A slight difference in current velocity was found during the dry season. The flood currents were higher at middle estuary than those in wet season. During the wet season, salinity variation within a tidal cycle slightly increased from the upper estuary to the mouth. Salinity was substantially higher during the dry season than the wet season at all three stations, with the absence of the flood-ebb variation, showing a strong saltwater intrusion. The SSC data revealed that the sediments were mainly brought into the estuary by freshwater discharge during the wet season. Sediment re-suspension process persists during the dry season, due to the tidal currents. A stronger saltwater intrusion occurred in the dry season due to weak river discharge. An estuarine turbidity maximum zone was formed near station-2 due to the combined effects of tides, river discharge and saltwater intrusion. Overall, field observations have shown a significant spatial and temporal variation in flood/ebb and wet/dry seasons for hydrodynamics and sediment transport in IRE.&lt;/p&gt;&#x0D;

Turbidity maximum zone index: a novel model for remote extraction of the turbidity maximum zone in different estuaries

Abstract. An efficient recognition and extraction of the estuarine turbidity maximum zone (TMZ) is important for studying terrestrial hydrological processes. Although many studies relevant to the TMZ have been conducted worldwide, the extraction methods and criteria used to describe the TMZ vary significantly both spatially and temporally. To improve the applicability of the methods adopted in previous studies and to develop a novel model to accurately extract the TMZ in multiple estuaries and different seasons from remote-sensing imageries, this study estimated the total suspended solid (TSS) and chlorophyll a (Chl a) concentrations in three estuaries. These were the Pearl River estuary (PRE), the Hanjiang River estuary (HRE), and the Moyangjiang River estuary (MRE) of Guangdong Province, China. The spatial distribution characteristics of the TSS and Chl a concentrations were analyzed. A nearly opposite association was found between the TSS and Chl a concentrations in the three estuaries, particularly in the PRE. The regions with high (low) TSS concentrations had relatively low (high) Chl a concentrations and, therefore, a turbidity maximum zone index (TMZI), defined as the ratio of the difference and sum of the logarithmic transformation of the TSS and Chl a concentrations, was firstly proposed. By calculating the TMZI values in the PRE on 20 November 2004 (low-flow season), it was found that the criterion TMZI&gt;0.2 could be used to identify the TMZs of the PRE effectively. The TMZ extraction results were generally consistent with the visual-interpretation results. The area-based accuracy measures showed that the quality (Q) of the extraction reached 0.8429. The same criterion was applied in the PRE on 18 October 2015 (high-flow season), and high accuracy and consistency across seasons were observed (Q=0.8171). The western shoal of the PRE was the main distribution area of TMZs. Extracting TMZs by the newly proposed index performed well in different estuaries and on different dates (HRE on 13 August 2008 in the high-flow season and MRE on 6 December 2013 in the low-flow season). Compared to the previous fixed threshold of TSS or turbidity methods, extracting the TMZ using the TMZI had higher accuracy and better applicability (Q: 0.1046–0.4770 vs. 0.8171–0.8429). Evidently, this unified TMZI is potentially an optimized method for the global monitoring and extraction of TMZs of estuaries from different satellite remote-sensing imageries. It can be used to help the understanding of the spatial and temporal variation in TMZs and estuarine processes at regional and global scales as well as improve the management and sustainable development of regional society and the natural environment.

Modelling study on estuarine circulation and its effect on the turbidity maximum zone in the Yalu River Estuary, China

The along-channel, lateral estuarine circulation and the related baroclinic effects on the turbidity maximum zone (TMZ) of the Yalu River Estuary (YRE) were explored in our study based on the Finite Volume Coastal Ocean Model (FVCOM). The results show that along-channel estuarine flow in YRE had a two-layer-structure with seaward flow in the surface layer and landward flow in the bottom layer. The along-channel bottom landward flow can transport sediment to the upper estuary and influence the location of the TMZ, which was mainly induced by asymmetric tidal mixing. Then, for the variation in cross-channel circulation (lateral circulation), the TMZ moved westwards after reclamation, due to the decreased eastward residual flow resulting from weakened eastward barotropic and baroclinic pressure gradient forcing. This study qualitatively demonstrated the baroclinic effects and human-induced impacts on estuarine subtidal flow and sedimentation. Although site-specific, these findings have wider implications for sediment transport in other medium-scale estuaries.