Tunable Flux Research Articles

A non-equilibrium dissipation system with tunable molecular fuel flux.

Cells convert macromolecule fuel into small molecule fuel through energy pathways, including glycolysis, the citric acid cycle, and oxidative phosphorylation. These processes drive vital dissipative networks or structures. Distinct from direct fuel (DF) utilization (directly acquire and utilize small molecule fuel), this macromolecule fuel mechanism is referred to as indirect fuel (IF) utilization, wherein the generation rate of small molecule fuel (fuel flux) can be effectively regulated. Here, we reported a bionic dissipation system with tunable fuel flux based on dynamic DNA nanotechnology. By regulating the rates of strand displacement and enzymatic reactions, we controlled the fuel flux and further tuned the strength of non-equilibrium transient states. Interestingly, we found that within a certain range, the fuel flux was positively correlated with the strength of the transient state. Once saturation was reached, it became negatively correlated. An appropriate fuel flux supports the maintenance of high-intensity non-equilibrium transients. Furthermore, we harnessed the dissipation system with tunable molecular fuel flux to regulate the dynamic assembly and disassembly of AuNPs. Different fuel fluxes resulted in varying assembly and disassembly rates and strengths for AuNPs, accomplishing a biomimetic process of regulating microtubule assembly through the control of fuel flux within living organisms. This work demonstrated a dissipation system with tunable molecular fuel flux, and we envision that this system holds significant potential for development in various fields such as biomimetics, synthetic biology, smart materials, biosensing, and artificial cells.

Applications of synchrotron-based X-ray diffraction in investigating thermal barrier coatings

Thermal barrier coatings play crucial roles in protecting the hot end components of aero-engines against high-temperature erosion. They must suffer extremely harsh environments including high temperatures, heavy loads, and large internal temperature gradients, which would result in various complex failures. Therefore, it is important to unveil these failure mechanisms to minimize and even prevent them for obvious reasons. Strain/stress evolution between different layers and foreign material erosion are the main failure mechanisms of thermal barrier coatings, which are well suited to be investigated using synchrotron X-ray diffraction. With its tunable energy, high flux, and many other advantages, synchrotron-based X-ray diffraction has become an advanced non-destructive characterization technique for engineering materials yielding important information including their compositions and residual stress which also provides spatial and temporal resolution that is vital for understanding their service performance. This paper presents a concise review of the applications of synchrotron-based X-ray diffraction in investigating thermal barrier coatings to explore their failure mechanisms.

Tunable flux pinning in granular superconducting Pb films

In granular superconductors, the macroscopic superconducting properties and vortex dynamics are closely linked with the granularity. This research focuses on preparing Pb films with different grain sizes by simply varying the evaporation rate. A progressively emergence of second magnetization peak is observed with increasing the grain size, which finally evolves into flux avalanche. The underlying vortex pinning mechanism evolution has also been analyzed. The results provide an efficient way to tune the vortex-pin interactions as well as the related macro properties in superconductors.

Tunable Superconducting Flux Qubits with Long Coherence Times

In this work, we study a series of tunable flux qubits inductively coupled to a coplanar waveguide resonator fabricated on a sapphire substrate. Each qubit includes an asymmetric superconducting quantum interference device which is controlled by the application of an external magnetic field and acts as a tunable Josephson junction. The tunability of the qubits is typically $\pm 3.5$ GHz around their central gap frequency. The measured relaxation times are limited by dielectric losses in the substrate and can attain $T_{1}\sim 8 \mu s$. The echo dephasing times are limited by flux noise even at optimal points and reach $T_{2E}\sim 4 \mu s$, almost an order of magnitude longer than state of the art for tunable flux qubits.

Tunable Ion Transport in Two-Dimensional Nanofluidic Channels

Layered two-dimensional (2D) materials with interlayer channels at the nanometer scale offer an ideal platform to control ion transport behaviors, including high-precision separation, ultrafast diffusion, and tunable permeation flux, which show great potential for energy conversion and storage, water treatment, catalysis, biosynthesis, and sensing. Recent advances in controlling the structure and functionality of 2D nanofluidic channels sustainably open doors for more revolutionary applications. In this Perspective, we first present a brief introduction to the fundamental mechanisms for ion transport in 2D nanofluidic channels and an overview of state-of-the-art assembly technologies of nanochannel membranes. We then point out new avenues for developing advanced nanofluidics, combining molecular-level cross-linking, and surface modification in nanoconfinement. Finally, we outline the potential applications of these 2D nanofluidic channel membranes and their technical challenges that need to be addressed to afford for practical applications.

Continuously tunable high photon flux high harmonic source.

In this work, a continuously tunable extreme ultraviolet source delivering a state-of-the-art photon flux of >1011 ph/s/eV spanning from 50 eV to 70 eV is presented. The setup consists of a high-power fiber laser with a subsequent multipass cell followed by a waveguide-based high harmonic generation setup. Spectral tuning over the full line spacing is achieved by slightly adjusting the lasers driving pulse energy, utilizing nonlinear propagation effects and pulse chirping. The presented method enables a high tuning speed while delivering reproducible and reliable results due to a simple experimental realization. For possible future experiments, a method for continuous, on-demand pulse-to-pulse switching of the generated XUV radiation with full spectral coverage is conceived.

Selective Swelling of Polystyrene (PS)/Poly(dimethylsiloxane) (PDMS) Block Copolymers in Alkanes

Block copolymers (BCPs) containing poly(dimethylsiloxane) (PDMS) blocks have been extensively used as precursors to prepare nanoporous materials with a diversity of compositions and morphologies. However, it remains desirable to facilely and efficiently transform the precursors into porous structures under mild conditions. Herein, we investigate the swelling behaviors of thin films of polystyrene-block-poly(dimethylsiloxane)-block-polystyrene (PS-b-PDMS-b-PS, SDS) in linear alkanes and produce well-defined nanoporosities in the SDS films following the mechanism of selective swelling-induced pore generation. Alkanes strongly swell PDMS blocks while slightly swell PS blocks, triggering the cavitation of the PDMS minority phases. The pore sizes as well as the porosities are determined by the interaction between the alkanes and the constituent blocks. Alkanes with lower carbon numbers exhibit a stronger affinity to the copolymer, leading to larger pores. Interestingly, we find that n-hexane is able to produce a porosity >30% at room temperature within a duration as short as 1 min. We demonstrate that PDMS, which has a lower surface energy, is enriched on the film surface, thus rendering a strong hydrophobicity to the produced porous SDS films. Ethanol permeation tests demonstrate the interconnected and accessible porosities and tunable flux as well as excellent pressure resistance of the porous SDS films, implying their potential applications as selective membranes in the filtration of organic solvents and oil/water separation.

Tunable Noninteger Flux Quantum of Vortices in Superconducting Strips.

Flux quantization has been widely regarded as the hallmark of the macroscopic quantum state of superconductivity. However, practical design of superconductor devices exploiting finite size confinement effects may induce exotic phenomena, including nonquantized vortices. In our research, the magnetic flux of vortices has been studied in a series of superconducting strips as a function of the strip width and the penetration depth. In both circumstances, the observation using scanning Hall probe microscope (SHPM) displays a controlled evolution from singly quantized vortices to nonquantized ones. It is also found that the magnetic flux is immune to the flowing supercurrent. The simulations based on Ginzburg-Landau theory agree well with experimental results. The observed behavior of the vortex flux may open new perspectives for fundamental research and applications based on vortex matter, such as vortex-memory devices and magnetic field traps for ultracold atoms.

Tunable magnetic flux avalanches triggered by a focalized laser spot

Magnetic flux avalanches caused by thermomagnetic instabilities are a common phenomenon occurring in type II superconducting films. The unpredictability of these catastrophic events threaten the application of superconducting thin film equipment, such as high-temperature superconducting magnets. In the present work, through the fast Fourier transform method, we numerically investigate artificially triggered flux avalanches in superconducting films by a focalized laser, unveiling new features beyond those associated to naturally occurring avalanches. The numerical modeling is validated by reproducing previous experimental results. We investigate the effects of laser irradiation on the nucleation and evolution of flux avalanches for different cases, namely varying the laser irradiation position, laser power, laser-spot size, ramping rate of applied magnetic field and working temperature. We find that the laser irradiation can control and guide the position of flux avalanches at applied magnetic fields with small ramping rate, while similar guidance effect cannot be observed at high ramping rates. We demonstrate that such phenomenon can be tuned by the environmental temperature, and the underlying physical mechanism can be ascribed to current crowding and local heating around the laser spot. Furthermore, by considering a pair of laser spots, we observe two possible scenarios depending on the laser power, (i) single flux avalanche triggered at one of the laser spots and (ii) double flux avalanches triggered at both laser spots.

Quantum transport through a quantum dot side-coupled to a Majorana bound state pair in the presence of electron-phonon interaction

We theoretically study quantum transport through a quantum dot coupled to Majorana bound states confined at the ends of a topological superconducting nanowire. The topological superconductor forms a loop and is threaded by a tunable magnetic flux, which allows one to control the electron transport in the system. In particular, we investigate phonon-assisted transport properties in the device when the central quantum dot interacts with a single long-wave optical phonon mode. We find that when the two Majorana bound states are unhybridized, the zero-temperature linear conductance has a $2\pi$ periodicity as a function of magnetic flux phase, independent of the electron-phonon interaction, the quantum dot energy, or the finite values of dot-Majorana couplings. For a finite overlap between the Majorana bound states, the linear conductance periodicity generally changes to $4\pi$ either due to a finite electron-phonon coupling strength, or a dot energy level that is tuned away from the Fermi level. Additionally, the differential conductance periodicity changes from $2\pi$ to $4\pi$ when the Majorana bound states hybridize and the electron-phonon coupling is finite. Our results provide insight into transport signatures expected in topological quantum computational platforms that integrate quantum dots as a means for Majorana qubit readout. The energy exchange with an environmental bath, here a single phonon mode, significantly alters the current signatures expected from Majorana modes.

Synthetic Hall ladder with tunable magnetic flux

We describe a synthetic three-leg Hall ladder system with a tunable magnetic flux for neutral $^{173}\mathrm{Yb}$ atoms in a one-dimensional optical lattice. The ladder legs are formed by three hyperfine ground spin states of the atoms, and the complex interleg links are generated through Raman couplings between the spin states using multiple laser beams. The effective magnetic flux through a ladder plaquette $\ensuremath{\phi}$ is controlled by the angles of the Raman laser beams with the lattice axis. We investigate the quench dynamics of the Hall ladder system for $\ensuremath{\phi}\ensuremath{\approx}\frac{\ensuremath{\pi}}{3},\frac{\ensuremath{\pi}}{2},$ and $\frac{2\ensuremath{\pi}}{3}$ after a sudden application of the Raman coupling in various interleg link configurations. The semiclassical trajectory of the atoms in the plane of the spin composition and lattice position exhibits the characteristic motion of the effective magnetic field. In a tube configuration with the three legs cyclically linked, the quench evolution was observed to be substantially damped, which is attributed to the random flux threading the Hall tube.

Exploration of Defect Dynamics and Color Center Qubit Synthesis with Pulsed Ion Beams

Short-pulse ion beams have been developed in recent years and now enable applications in materials science. A tunable flux of selected ions delivered in pulses of a few nanoseconds can affect the balance of defect formation and dynamic annealing in materials. We report results from color center formation in silicon with pulses of 900 keV protons. G-centers in silicon are near-infrared photon emitters with emerging applications as single-photon sources and for spin-photon qubit integration. G-centers consist of a pair of substitutional carbon atoms and one silicon interstitial atom and are often formed by carbon ion implantation and thermal annealing. Here, we report on G-center formation with proton pulses in silicon samples that already contained carbon, without carbon ion implantation or thermal annealing. The number of G-centers formed per proton increased when we increased the pulse intensity from 6.9 × 109 to 7.9 × 1010 protons/cm2/pulse, demonstrating a flux effect on G-center formation efficiency. We observe a G-center ensemble linewidth of 0.1 nm (full width half maximum), narrower than previously reported. Pulsed ion beams can extend the parameter range available for fundamental studies of radiation-induced defects and the formation of color centers for spin-photon qubit applications.

Tunable Near-Field Radiative Effect in a Td – WTe2 Single Layer

In contrast to artificial metamaterials, natural two-dimensional (2D) hyperbolic materials are able to support higher electromagnetic confinement and stronger photonic density of states. This means natural 2D hyperbolic materials have fascinating potential for applications in thermal photonics. In this work, we investigate mechanisms of near-field thermal radiation (NFTR) in a ${\mathrm{T}}_{d}$--${\mathrm{WTe}}_{2}$ single layer at the nanoscale using the fluctuation-dissipation theorem and density-functional theory. The results show that NFTR of ${\mathrm{T}}_{d}$--${\mathrm{WTe}}_{2}$ can be 3 orders of magnitude larger than the blackbody limit. By using the photonic tunneling coefficient and the plasmon dispersion, we present a comprehensive study of plasmonic properties of ${\mathrm{T}}_{d}$--${\mathrm{WTe}}_{2}$. Moreover, our first-principles calculations predict that application of a certain amount of mechanical stress can trigger topological transition between the elliptic and the hyperbolic surface states by regulating the Fermi surface and interband excitation threshold. Lastly, we systematically exhibit the evolution of surface plasmon polaritons in ${\mathrm{T}}_{d}$--${\mathrm{WTe}}_{2}$ under mechanical stress and analyze the performance of using mechanical stress to modulate the corresponding NFTR. Our work explores the great potential of tunable radiative heat flux in ${\mathrm{T}}_{d}$--${\mathrm{WTe}}_{2}$, which is explained here through the peculiar nature of hyperbolic surface plasmons.

Surface-Catalyzed Nitric Oxide Release via a Metal Organic Framework Enhances Antibacterial Surface Effects.

It has been previously demonstrated that metal nanoparticles embedded into polymeric materials doped with nitric oxide (NO) donor compounds can accelerate the release rate of NO for therapeutic applications. Despite the advantages of elevated NO surface flux for eradicating opportunistic bacteria in the initial hours of application, metal nanoparticles can often trigger a secondary biocidal effect through leaching that can lead to unfavorable cytotoxic responses from host cells. Alternatively, copper-based metal organic frameworks (MOFs) have been shown to stabilize Cu2+/1+ via coordination while demonstrating longer-term catalytic performance compared to their salt counterparts. Herein, the practical application of MOFs in NO-releasing polymeric substrates with an embedded NO donor compound was investigated for the first time. By developing composite thermoplastic silicon polycarbonate polyurethane (TSPCU) scaffolds, the catalytic effects achievable via intrapolymeric interactions between an MOF and NO donor compound were investigated using the water-stable copper-based MOF H3[(Cu4Cl)3(BTTri)8-(H2O)12]·72H2O (CuBTTri) and the NO donor S-nitroso-N-acetyl-penicillamine (SNAP). By creating a multifunctional triple-layered composite scaffold with CuBTTri and SNAP, the surface flux of NO from catalyzed SNAP decomposition was found tunable based on the variable weight percent CuBTTri incorporation. The tunable NO surface fluxes were found to elicit different cytotoxic responses in human cell lines, enabling application-specific tailoring. Challenging the TSPCU-NO-MOF composites against 24 h bacterial growth models, the enhanced NO release was found to elicit over 99% reduction in adhered and over 95% reduction in planktonic methicillin-resistant Staphylococcus aureus, with similar results observed for Escherichia coli. These results indicate that the combination of embedded MOFs and NO donors can be used as a highly efficacious tool for the early prevention of biofilm formation on medical devices.

Calibration of Flux Crosstalk in Large-Scale Flux-Tunable Superconducting Quantum Circuits

Magnetic flux tunability is an essential feature in most approaches to quantum computing based on superconducting qubits. Independent control of the fluxes in multiple loops is hampered by crosstalk. Calibrating flux crosstalk becomes a challenging task when the circuit elements interact strongly. We present a novel approach to flux crosstalk calibration, which is circuit model independent and relies on an iterative process to gradually improve calibration accuracy. This method allows us to reduce errors due to the inductive coupling between loops. The calibration procedure is automated and implemented on devices consisting of tunable flux qubits and couplers with up to 27 control loops. We devise a method to characterize the calibration error, which is used to show that the errors of the measured crosstalk coefficients are all below 0.17%.

Agile spectral tuning of high order harmonics by interference of two driving pulses.

In this work, the experimental realization of a tunable high photon flux extreme ultraviolet light source is presented. This is enabled by high harmonic generation of two temporally delayed driving pulses with a wavelength of 1030 nm, resulting in a tuning range of 0.8 eV at the 19th harmonic at 22.8 eV. The implemented approach allows for fast tuning of the spectrum, is highly flexible and is scalable towards full spectral coverage at higher photon energies.

Tunable flux through a synthetic Hall tube of neutral fermions

Hall tube with a tunable flux is an important geometry for studying quantum Hall physics, but its experimental realization in real space is still challenging. Here, we propose to realize a synthetic Hall tube with tunable flux in a one-dimensional optical lattice with the synthetic ring dimension defined by atomic hyperfine states. We investigate the effects of the flux on the system topology and study its quench dynamics. Utilizing the tunable flux, we show how to realize topological charge pumping, where interesting charge flow and transport are observed in rotated spin basis. Finally, we show that the recently observed quench dynamics in a synthetic Hall tube can be explained by the random flux existing in the experiment.

Robust cellulose-based composite adsorption membrane for heavy metal removal

Adsorptive membranes offer an effective mode to remove heavy metal ions from contaminated water, due to the synergies made possible by low-cost, high-affinity adsorbents and highly scalable filtration in one system. However, the development of adsorptive membranes is hampered by their instability in the aqueous phase and low binding affinity with a broad spectrum of heavy metals in a reasonable flux. Herein, a regenerated cellulose support membrane is strongly grafted with stable and covalent-bonded polyelectrolyte active layers synthesized by a reactive layer-by-layer (LBL) assembly method. The LBL assembled layers have been successfully tested by scanning electron microscopy, Fourier-transform infrared spectroscopy and X-ray photo-electron spectroscopy. The covalent bonding provides the membrane with long-term stability and a tunable water flux compared to a membrane assembled by electrostatic bonding. The maximum adsorption capacity of the membrane active layers can reach up to 194 mg/g, showing more efficient adsorption at lower heavy metal concentration and higher pH value of feed solution. The membrane can remove multiple ions, such as Cu, Pb, and Cd, by adsorption and is easy to be regenerated and recovered. The strong covalent bonding can extend the membrane lifetime in water purification to remove multiple heavy metals at high efficiency.

Design and Analysis of a Linear Memory Machine for Ocean Wave Power Generation

In this paper, a permanent magnet (PM) linear memory machine is proposed for ocean wave power generation. A notable feature of this machine is its online tunable mnemonic flux. This enables it to operate efficiently in a wide speed range and makes it suitable for the variable-speed wave-power generation. Moreover, this machine has both the PMs and the windings arranged in its stator so that it does not need slip rings or brushes. The proposed machine is also robust and cost-effective because it has a simple translator of slotted steel. In this paper, the configuration and working principle of the linear memory machine are firstly introduced. The results of a parametric analysis are presented to investigate the effects of the proposed machine’s geometric parameters. The performance of the proposed machine is then analyzed using time-stepping finite element method (TS-FEM).

Superlyophilic Shape Memory Porous Sponge for Smart Liquid Permeation.

Recently, smart liquid permeation has aroused much attention. However, existing strategies to achieve such a goal are often based on reversibly controlling hydrophobicity/hydrophilicity on static porous structures, which are unsuitable for oils with low surface tension, and meanwhile they cannot realize tunable permeation flux since the pore sizes are constant. Herein, we report a superlyophilic shape memory porous sponge (SSMS) that can demonstrate tunable pore size from about 28 nm to 900 μm as the material's shape is changed. Based on the controllability in pore size, not only ON/OFF penetration but also precisely tunable permeation flux can be obtained for both water and oil. Furthermore, by using the SSMS, an application in accurate release of small-molecule rhodamine B was also demonstrated. This work reports a material with tunable pore size for controllable liquid permeation, which provides some ideas for designing smart superwetting permeation materials.