Tuff Layers Research Articles

Central Asian moisture modulated by proto-Paratethys Sea incursions since the early Eocene

The establishment and evolution of the Asian monsoons and arid interior have been linked to uplift of the Tibetan Plateau, retreat of the inland proto-Paratethys Sea and global cooling during the Cenozoic. However, the respective role of these driving mechanisms remains poorly constrained. This is partly due to a lack of continental records covering the key Eocene epoch marked by the onset of Tibetan Plateau uplift, proto-Paratethys Sea incursions and long-term global cooling. In this study, we reconstruct paleoenvironments in the Xining Basin, NE Tibet, to show a long-term drying of the Asian continental interior from the early Eocene to the Oligocene. Superimposed on this trend are three alternations between arid mudflat and wetter saline lake intervals, which are interpreted to reflect atmospheric moisture fluctuations in the basin. We date these fluctuations using magnetostratigraphy and the radiometric age of an intercalated tuff layer. The first saline lake interval is tentatively constrained to the late Paleocene–early Eocene. The other two are firmly dated between ∼46 Ma (top magnetochron C21n) and ∼41 Ma (base C18r) and between ∼40 Ma (base C18n) and ∼37 Ma (top C17n). Remarkably, these phases correlate in time with highstands of the proto-Paratethys Sea. This strongly suggests that these sea incursions enhanced westerly moisture supply as far inland as the Xining Basin. We conclude that the proto-Paratethys Sea constituted a key driver of Asian climate and should be considered in model and proxy interpretations.

First report of coupled Early Permian paleomagnetic and geochronologic data from the Dunhuang block (NW China), and implications for the tectonic evolution of the Paleo-Asian ocean

In order to better understand the tectonic relationship between the Dunhuang block (DHB) and its adjacent blocks, and to constrain the timing of the closure of the Paleo-Asian ocean, a combined geochronologic and paleomagnetic investigation has been undertaken on Early Permian tuff, basalt flows and sandstones from the Shuangbaotang Formation in the northwestern part of the DHB. U-Pb zircon dating indicates that the age of the strata is between 280.6 ± 2.9 Ma and 291.4 ± 2.6 Ma. Thermal demagnetization of a three-component isothermal remanent magnetization (IRM), and Curie point experiment suggest that magnetite dominates in the rock samples analyzed. In addition, there is a minor amount of hematite in some sandstones. Stepwise thermal demagnetization successfully isolated stable characteristic remanent magnetization (ChRM) from 11 tuff layers, two lava flows and nine sandstone beds. Two components were isolated from all samples: a lower temperature component (LTC) and a higher temperature component (HTC). The LTC is near the direction of the present-day geomagnetic field and produced a negative fold test, indicating it is a viscous remanent magnetization in the present-day geomagnetic field. Most of the HTC are reverse polarity (Normal = 4, reverse = 158), which is in accordance with the Kiaman Reversed Superchron that spans the Late Carboniferous-Permian interval. In addition, the HTC of all studied sites passed the fold and reverse tests, suggesting that they likely represent primary remanent magnetization. The tilt-corrected mean direction from all sites (tuff, basalts and sandstones) is Ds = 1.7°, Is = 43.1°, ks = 403, α95 = 1.5°, N = 22. The mean paleopole of the site-mean direction-corresponded VGPs lies at 74.5°N, 268.5°E with A95 = 1.6°. Considering the consistent inclination values recorded among the studied tuff, basalts and sandstones, and the low degrees of anisotropy within all samples, we suggest that there is no significant inclination shallowing caused by depositional compaction in the sedimentary layers of the studied section. Taking into account the results from this study as well as previous Late Paleozoic paleomagentic studies from adjacent tectonic blocks, we conclude that the DHB formed part of the amalgamated Dunhuang-North China-Alxa-Qaidam mega-block during the Early Permian, but was separated from the Tarim block by a small ocean (here named the Qiemo-Xingxingxia paleo-ocean) at this time. A comparison of the Early Permian paleolatitudes of these and other adjacent blocks suggest that the Paleo-Asian ocean (sensu lato) was still open at this time. Combined with other geological evidence, a paleogeographic reconstruction of the Paleo-Asian ocean has been reconstructed for the Early Permian.

A new chronostratigraphy (40Ar-39Ar and U-Pb dating) for the middle section of the Burdur-Fethiye Shear Zone, SW Turkey (eastern Mediterranean)

Southwestern Turkey is a tectonically active region where extensional, strike-slip, and compressional tectonics cooccur. The Burdur-Fethiye Shear Zone is located in the middle of this complex area. Understanding the tectonic evolution of this region is crucial, but the controversial Neogene chronostratigraphy does not allow robust synthesis because of poor age control. The middle section of the Burdur-Fethiye Shear Zone includes three basins: the Acipayam, Cameli, and Golhisar basins. All these basins represent restricted portions of ancient larger carbonate lakes. The lacustrine sediments are locally covered or cut by lamproites with sparse intercalations of tuff levels. New 40 Ar- 39 Ar biotite and U-Pb zircon radiometric ages from volcanics and a tuff layer in this study demonstrate that the previously suggested Pliocene ages for these sediments are incorrect and that these Neogene sediments are middle Miocene in age.

Zircon U-Pb geochronology of crystal tuff on Lingshan Island and its geological implications for magmatism, stratigraphic age and geological events

Due to the unique location in the Ludong region, geochronological study of this area is essential for the understanding of the Cretaceous tectonic evolution of Eastern China. Sedimentary sequences interbedded with tuff layers unconformably overlay metamorphic rocks in the Sulu Orogen. This research presents a more reliable geochronological dataset of a tuff layer on Lingshan Island in Qingdao. A total of 103 valid age values from 216 zircon grains were obtained in three fresh tuff samples. Approximately 87% of these zircon ages are dated as the Early Cretaceous, and their peak ages shift from the Aptian stage to the Albian stage. The spatial-temporal relationship between the tuff and the Mesozoic igneous rocks of Eastern China indicate the impact of the Pacific Plate subduction beneath the Asian continent. Six Albian single detrital zircons have a weighted average age of 103.8 ± 1.4 Ma, with the youngest age (103.4 ± 1.4 Ma) constraining the maximum depositional age of the tuff layer. The age sequence of four sections on Lingshan Island is defined in this study: sections A and B belong to the Laiyang Group, and sections C and D are considered the Qingshan Group and were deposited in the Late Cretaceous. Two pre-Cretaceous zircon age peaks were also observed. These age peaks coincide with the magmatic and metamorphic ages preserved in the Sulu Orogen; thus, the Sulu Orogen is the provenance of the sedimentary rocks on Lingshan Island.

Field Trip D (27 September 2018): characteristics and development of the Mesozoic–Tertiary weathering mantle and Pleistocene periglacial slope deposits in the Hintertaunus mountainous region

Abstract. The Devonian slates and sandstones of the Rhenish Massif were subject to deep and intensive weathering under (sub)tropical climate conditions during the Cretaceous, the Paleogene and the Neogene, which caused the development of a weathering mantle (regolith) >100 m thick, consisting of kaolinitic saprolite and paleosols as well as correlated sediments. Especially the tectonic uplift of the Rhenish Massif and climate change during the Neogene and the Pleistocene led to a vast denudation of the weathering mantle. Only in less uplifted areas of the mountainous region did thick remnants of saprolites remain, and they were covered by Neogene sediments as well as Quaternary periglacial slope deposits. As the kaolinitic weathering products serve as raw materials for the clay industry, unique exposures are available in the Hintertaunus which offer impressive insights into the landscape development of the past ∼80 million years: the excursion proceeds from Giessen to Limburg and further south and southwest to the eastern and western Hintertaunus area. At site 1 near the village of Langhecke, characteristics and properties of the fresh, unweathered slates will be demonstrated. Excursion sites 2 and 3 are situated near the village of Eisenbach. In two open-cast clay mines, both a terrestrial and a semi-terrestrial saprolite from silt slate, covered by periglacial layers, are exposed. Properties and genesis will be discussed on the basis of morphological characteristics and mineralogical and geochemical analyses, as well as isovolumetric elemental mass balances. At site 4 a former basalt quarry near the village of Biebrich exposes a Paleogene Plinthosol above saprolite. The autochthonous paleosol was preserved below Upper Oligocene basalt tuff and periglacial layers. Site 5 is situated within a huge pit for mining of Upper Oligocene to Miocene quartz gravel near the village of Wasenbach. A Miocene Plinthosol developed from alluvial sediments on top of the gravel beds and was covered by periglacial slope deposits. At nearly all sites the basal layers of the periglacial cover beds consist of kaolinitic paleosol/saprolite material, which has an important influence on the site properties of the Holocene soils.

U-Pb geochronology of monazite in Precambrian tuffs reveals depositional and metamorphic histories

Uranium-lead geochronology of zircon in felsic tuffs plays a key role in the development of chronostratigraphic frameworks for sedimentary successions. This is particularly true for Precambrian basins, where biostratigraphy is of limited use for age determination or stratigraphic correlation. Although zircon is widely used to date tuffs, it can yield null results due to the presence of xenocrystic populations or isotopic resetting. Other potential U-Pb chronometers, such as monazite, which also crystallize from felsic magmas, are largely unreported from felsic tuff layers. Consequently, there has been a lack of studies to evaluate the potential of monazite for U-Pb isotope geochronology of tuffs. We present results of in situ U-Pb ion microprobe dating of monazite that co-exists with zircon in felsic tuffs from two Precambrian basins: the Earaheedy Basin (Frere Formation) in Western Australia and the Bushveld Basin (Lephala Formation) in southern Africa. We show that 207Pb/206Pb ages from monazite in felsic tuffs from the Frere Formation (1891 ± 9 Ma) and the Lephala Formation (2307 ± 9 Ma) are identical to zircon ages from the respective tuffs. Also, monazite in the Bushveld tuff preserves additional information, including a chronological fingerprint of the volcanic source (2.4–2.5 Ga xenocrysts) and the timing of low-grade metamorphism (2.16 Ga overgrowths). The ca. 2.16 Ga low-grade metamorphism identified in the Bushveld Basin is reminiscent of that widely recorded in the Pilbara Craton, Western Australian, lending support to arguments for a connection between the Kaapvaal and Pilbara cratons. Igneous and low-grade metamorphic monazites are readily distinguished based on texture and chemistry. Our study demonstrates that monazite can be used to accurately date felsic tuffs, offering a powerful tool for constraining depositional and metamorphic histories of Precambrian sedimentary basins.

Phreatic eruptions and deformation of Ioto Island (Iwo-jima), Japan, triggered by deep magma injection

On Ioto Island (Iwo-jima), 44 phreatic eruptions have been recorded since 1889, when people began to settle there. Four of these eruptions, after the beginning of continuous observation by seismometers in 1976, were accompanied by intense seismic activity and rapid crustal deformation beforehand. Other eruptions on Ioto were without obvious crustal activities. In this paper, we discuss the mechanisms of phreatic eruptions on Ioto. Regular geodetic surveys and continuous GNSS observations show that Ioto intermittently uplifts at an abnormally high rate. All of the four eruptions accompanied by the precursors took place during intermittent uplifts. The crustal deformation before and after one of these eruptions revealed that a sill-like deformation source in the shallow part of Motoyama rapidly inflated before and deflated after the beginning of the eruption. From the results of a seismic array and a borehole survey, it is estimated that there is a layer of lava at a depth of about 100–200 m, and there is a tuff layer about 200–500 m beneath it. The eruptions accompanied by the precursors probably occurred due to abrupt boiling of hot water in hydrothermal reservoirs in the tuff layer, sealed by the lava layer and triggered by intermittent uplift. For the eruptions without precursors, the hydrothermal systems are weakly sealed by clay or probably occurred on the same principle as a geyser because phreatic eruptions had occurred beforehand and hydrostatic pressure is applied to the hydrothermal reservoirs.

Slope stability and rockfall assessment of volcanic tuffs using RPAS with 2-D FEM slope modelling

Abstract. Steep, hardly accessible cliffs of rhyolite tuff in NE Hungary are prone to rockfalls, endangering visitors of a castle. Remote sensing techniques were employed to obtain data on terrain morphology and to provide slope geometry for assessing the stability of these rock walls. A RPAS (Remotely Piloted Aircraft System) was used to collect images which were processed by Pix4D mapper (structure from motion technology) to generate a point cloud and mesh. The georeferencing was made by Global Navigation Satellite System (GNSS) with the use of seven ground control points. The obtained digital surface model (DSM) was processed (vegetation removal) and the derived digital terrain model (DTM) allowed cross sections to be drawn and a joint system to be detected. Joint and discontinuity system was also verified by field measurements. On-site tests as well as laboratory tests provided additional engineering geological data for slope modelling. Stability of cliffs was assessed by 2-D FEM (finite element method). Global analyses of cross sections show that weak intercalating tuff layers may serve as potential slip surfaces. However, at present the greatest hazard is related to planar failure along ENE–WSW joints and to wedge failure. The paper demonstrates that RPAS is a rapid and useful tool for generating a reliable terrain model of hardly accessible cliff faces. It also emphasizes the efficiency of RPAS in rockfall hazard assessment in comparison with other remote sensing techniques such as terrestrial laser scanning (TLS).

Stratiform siderites from the Mesoproterozoic Xiamaling Formation in North China: Genesis and environmental implications

Stratiform or layered siderites are much less common than siderite concretions in the stratigraphic record. In the middle part of the Mesoproterozoic Xiamaling Formation (ca. 1.40–1.35Ga), layered siderites are widespread across the North China Platform. Facies analysis indicates that the Xiamaling siderites were formed in shallow-water environments above the storm wave base. High Fe/Al and V/Al ratios and the lack of pyrites in siderite-bearing strata indicate ferruginous bottom-water conditions during the formation of siderites. The low thermal maturity of organic matter and clay mineral structures suggest that the layered siderites were formed at burial temperatures ≤90°C. The negative δ13C values (−24‰ to −12‰) of siderites and the presence of μm-scale hematite inclusions in siderite grains suggest that dissimilatory iron reduction (DIR) during early diagenesis has played critical roles in siderite formation. The source of Fe-oxyhydroxides required for DIR could be from Fe(II) oxidation in shallow seawater above the redoxcline in response to enhanced hydrothermal activities or, alternatively, directly from continental Fe-oxide input. The positive cerium (Ce) and europium (Eu) anomalies of clay minerals in siderite-bearing strata and their positive correlation with total Fe contents (TFe2O3) seem to favor a hydrothermal origin of iron. Syndepositional hyalophane concretions, intermittent tuff layers, and remarkable enrichment of Cu and Zn in some of the siderite-hosting rocks provide further support to hydrothermally sourced iron. The enhanced hydrothermal activity for the development of stratiform siderites in the Xiamaling Formation probably related to the final breakup of the North China Craton from the Columbia supercontinent, during which active hydrothermal systems provided sufficient Fe(II) for Fe-redox recycling and formation of layered siderites.

Miocene Slănic Tuff, Eastern Carpathians, Romania, in the Context of Badenian Salinity Crisis

New geochronological investigations for the Slănic Formation, correlated with previous bio- and lithostratigaphical information, allow for a better succession of events for the Middle Miocene, including the absolute age of the Badenian salinity crisis in the bend sector of the Eastern Carpathians. Within the green Slănic Tuff, white tuff layers were in evidence. The main element distribution of the white and green tuffs indicates a dacitic composition, with higher SiO2 content for the white tuff. The white tuff has a distinct mineralogical composition with quartz, plagioclase, biotite and clinoptilolite. From such a tuff layer a biotite concentrate gives a 40Ar/39Ar age of 13.7 ± 0.2 Ma. As above these tuff layers discrete levels of gypsum occur, the age documents the beginning of the restrictive circulation and formation of evaporites in this sector of Carpathians during Badenian times.

Magnetostratigraphy of the Fenghuoshan Group in the Hoh Xil Basin and its tectonic implications for India–Eurasia collision and Tibetan Plateau deformation

Early Cenozoic plate collision of India and Eurasia was a significant geological event, which resulted in Tibetan Plateau (TP) uplift and altered regional and global atmospheric circulations. However, the timing of initial collision is debated. It also remains unclear whether the TP was deformed either progressively northward, or synchronously as a whole. As the largest basin in the hinterland of the TP, evolution of the Hoh Xil Basin (HXB) and its structural relationship with development of the Tanggula Thrust System (TTS) have important implications for unraveling the formation mechanism and deformation history of the TP. In this study, we present results from a long sedimentary sequence from the HXB that dates the Fenghuoshan Group to ∼72–51 Ma based on magnetostratigraphy and radiometric ages of a volcanic tuff layer within the group. Three depositional phases reflect different stages of tectonic movement on the TTS, which was initialized at 71.9 Ma prior to the India–Eurasia collision. An abrupt sediment accumulation rate increase from 53.9 Ma is a likely response to tectonic deformation in the plateau hinterland, and indicates that initial India–Eurasia collision occurred at no later than that time. This remote HXB tectonosedimentary response implies that compressional deformation caused by India–Eurasia collision likely propagated to the central TP shortly after the collision, which supports the synchronous deformation model for TP.

Coastal cliffs, rock-slope failures and Late Quaternary transgressions of the Black Sea along southern Crimea

Rock-slope failures represent a significant hazard along global coastlines, but their chronology remains poorly documented. Here, we focus on the geomorphology and chronology of giant rockslides affecting the Crimean Mountains along the Black Sea coast. Geomorphic evidence suggests that high (>100 m) limestone cliffs flanking the southern slopes of the Crimean Mountains are scarps of rockslides nested within larger deep-seated gravitational slope deformations (DSGSDs). Such pervasive slope failures originated due to lateral spreading of intensively faulted Late Jurassic carbonate blocks moving atop weak/plastic Late Triassic flysch and tuff layers. By introducing a dating strategy relying on the combination of the uranium-thorium dating (U-Th) of exposed calcareous speleothems covering the landslide scarps with the 36Cl exposure dating of rock walls, we are able to approximate the time interval between the origin of incipient crevices and the final collapse of limestone blocks that exposed the cliff faces. For the three representative large-scale rockslides between the towns of Foros and Yalta, the initiation of the DSGSDs as evidenced by the widening of crevices and the onset of speleothem accumulation was >300 ka BP, but the recent cliff morphology along the coast is the result of Late Pleistocene/Holocene failures spanning ∼20–0.5 ka BP. The exposures of rockslide scarps occurred mostly at ∼20–15, ∼8, ∼5–4 and ∼2–0.5 ka, which substantially coincide with the last major Black Sea transgressions and/or more humid Holocene intervals. Our study suggests that before ultimate fast and/or catastrophic slope failures, the relaxation of rock massifs correlative with karstification, cracks opening, and incipient sliding lasted on the order of 104–105 years. Rapid Late Glacial/Holocene transgressions of the Black Sea likely represented the last impulse for the collapse of limestone blocks and the origin of giant rockslides, simultaneously affecting the majority of the SW coast of the Crimean Peninsula.

Zircon U-Pb ages and Hf isotope data from the Kukuluma Terrain of the Geita Greenstone Belt, Tanzania Craton: Implications for stratigraphy, crustal growth and timing of gold mineralization

The Geita Greenstone Belt is a late Archean greenstone belt located in the Tanzania Craton, trending approximately E-W and can be subdivided into three NW-SE trending terrains: the Kukuluma Terrain to the east, the Central Terrain in the middle and the Nyamullilima Terrain in the west. The Kukuluma Terrain, forms a NW-SE trending zone of complexly deformed sediments, intruded by the Kukuluma Intrusive Complex which, contains an early-syntectonic diorite-monzonite suite and a late-syntectonic granodiorite suite. Three gold deposits (Matandani, Kukuluma and Area 3W) are found along the contact between the Kukuluma Intrusive Complex and the sediments. A crystal tuff layer from the Kukuluma deposits returned an age of 2717 ± 12 Ma which can be used to constrain maximum sedimentation age in the area. Two granodiorite dykes from the same deposit and a small granodiorite intrusion found along a road cut yielded zircon ages of 2667 ± 17 Ma, 2661 ± 16 Ma and 2663 ± 11 Ma respectively. One mineralized granodiorite dyke from the Matandani deposit has an age of 2651 ± 14 Ma which can be used to constrain the maximum age of the gold mineralization in the area.The 2717 Ma crystal tuff has zircon grains with suprachondritic 176Hf/177Hf ratios (0.28108–0.28111 at 2717 Ma) and positive (+1.6 to +2.6) εHf values indicating derivation from juvenile mafic crust. Two of the granodiorite samples have suprachondritic 176Hf/177Hf ratios (avg. 0.28106 and 0.28107 at 2663 and 2651 Ma respectively) and nearly chondritic εHf values (avg. −0.5 and −0.3 respectively). The other two granodiorite samples have chondritic 176Hf/177Hf ratios (avg. 0.28104 and 0.28103 at 2667 and 2661 Ma respectively) and slightly negative εHf values (avg. −1.1 and −1.5 respectively). The new zircon age and isotope data suggest that the igneous activity in the Kukuluma Terrain involves a significant juvenile component and occurred within the 2720 to 2620 Ma period which, is the main period of crustal growth in the northern half of the Tanzania Craton.

Boundary between the Lower and Middle Carboniferous in the Eastern Urals: New isotope–geochronological data

The U–Pb age of the boundary between the Lower and Middle Carboniferous has been determined on zircons separated from a volcanic tuff layer within a limestone unit near the roof of the Serpukhovian Stage in an occurrence at the right bank of the Iset’ River. The zircons have been dated using SIMS SHRIMP-II at 320 ± 3 Ma. The result agrees well with the accepted age of the boundary between the Serpukhovian and Bashkirian ages (323.2 ± 0.4 Ma, [1]).

Supergene and exotic Cu mineralization occur during periods of landscape stability in the Centinela Mining District, Atacama Desert

AbstractThe Centinela Mining District (CMD), Atacama Desert (northern Chile), includes several mid‐late Eocene porphyry Cu deposits that contains supergene mineralization and provides access to a record of gravel deposits that host syn‐sedimentary exotic Cu mineralized bodies. By studying these gravels, we reconstruct the unroofing history and constrain the geomorphological conditions that produced supergene and exotic Cu mineralization. We present an integrated study based on stratigraphic and sedimentological data, lithology clast counts, 40Ar/39Ar and U/Pb ages from interbedded tuff layers and U/Pb detrital zircon geochronology data. To relate the gravel deposition episodes to the timing of the supergene mineralization, we provide in‐situ and exotic supergene mineral ages (40Ar/39Ar and K‐Ar). Six gravel units were deposited between the mid‐Eocene and the mid‐Miocene. The Esperanza gravels were deposited concurrently with the emplacement of porphyry Cu deposits at depth. The subsequent Tesoro I, II and III and Atravesado gravels register the unroofing of these deposits, from the advanced argillic zone to the sericitic and prophylitic hypogene zones. The Arrieros gravels register landscape pediplanation, that is, denudational removal and wear of the landscape to base level on a relatively stable tectonic regime, occurring roughly contemporaneous with supergene activity. The supergene mineral ages of the CMD define a time span (ca. 25–12 Ma) during which most of the supergene ages cluster in northern Chile. This time span corresponds with a period of warm and humid climate conditions in the southern hemisphere. We conclude that landscape pediplanation favours supergene mineralization and helps preserve the former supergene mineralized zones from significant erosion. Low erosion rates during pediplanation may constitute a necessary condition for the efficiency of the supergene processes in such semi‐arid climate.

Diagenetic model of the Bajo Barreal formation (Cretaceous) in the southwestern flank of the Golfo de San Jorge Basin (Patagonia, Argentina)

This paper analyses the diagenetic evolution of sandstones belonging to the Bajo Barreal Formation (Cretaceous) in the Golfo de San Jorge Basin (Patagonia, Argentina). The Bajo Barreal Formation includes the main reservoirs, which are located along the western area of the basin and is composed of sandstones, conglomerates, mudstones, tuffaceous mudstones and some layers of tuffs. The principal reservoirs comprise medium-to coarse-grained sandstones, which are dominated by feldspathic litharenites and contain minor amounts of litharenites and lithic arkoses. The authigenic minerals include kaolinite, smectite, chlorite, quartz overgrowths, microquartz and calcite, with minor proportions of megaquartz, siderite, analcime, laumontite, feldspar overgrowths and illite/smectite and chlorite/smectite mixed layers. Secondary porosity is much more important than primary porosity and is produced by the dissolution of feldspar, lithic clasts and clay cements. The diagenetic history of the Bajo Barreal sandstones can be divided into seven diagenetic stages, each of which is characterized by a specific assemblage of authigenic minerals and diagenetic processes. Eogenetic conditions occur in stages 1, 2, 3 and 4. Stage 1 corresponds to shallow burial characterized by the physical reduction of primary porosity by compaction; during stage 2, rim clay cements of chlorite, smectite and clinoptilolite, as well as thin quartz overgrowths, were formed. The precipitation of pore-filling cements of kaolinite, chlorite and smectite occurred during stage 3, while stage 4 records the intense dissolution of feldspar, lithic fragments and kaolinite cements. Mesogenesis occurs in diagenetic stages 5 and 6. The former corresponds to a new phase of authigenic kaolinite, while the latter records the significant dissolution of feldspar, lithic clasts and previous cements, which produced the highest values of secondary porosity. Finally, stage 7 corresponds to the highest degree of diagenesis in the Bajo Barreal Formation (mesogenesis), which resulted in the precipitation of cements of zeolites and calcite, as well as quartz and plagioclase overgrowths.

Mineralization age and metallogenic environment of Daotuo manganese deposits in Guizhou: Evidence from Re-Os isotopes

The Neoproterozoic is a critical interval in Earth’s history, having witnessed the breakup of supercontinent Rodinia, global glaciations (or the snowball Earth), and the evolution of multicellular organisms. It is proposed that the breakup of Rodinia might have triggered the snowball Earth, while the termination of the Neoproterozoic global glaciations might have triggered the evolution of life in the Ediacaran Period. Two snowball Earth events, the Sturtian (717–663 Ma) and the Marinoan (654–635 Ma) glaciations, were separated by an interglacial interval of ~10 million years (663–654 Ma). In South China, the Sturtian and Marinoan glacial deposits are represented by the Jiangkou and Nantuo Formations. The interglacial Datangpo Formation is characterized by widespread manganese (Mn) ore deposits, such the Datangpo and Xixibao in Guizhou, Minle in Hunan, and Xiushan in Chongqing, representing the most important metallogenic period of Mn in China. The Daotuo Mn ore, a superlarge-scale deposit (approximately 200 million tons), was first discovered in 2010 in northeastern Guizhou. It is hosted in a fault-bound depression system between the Yangtze block and the Jiangnan orogenic belt. The Mn ores were discovered in black shale of the Member I of the Datangpo Formation, and occur as rhodochrosite (MnCO3). In order to constrain the age of Mn ores, here we report Re-Os isochron age of the ore-bearing black shale from the Member I of the Datangpo Formation. The Re-Os isochron age of the Member I black shale is 660.6±7.5 Ma, consistent with the zircon U-Pb age of the tuff layer from the base of the Datangpo Formation and other Re-Os isochron ages from other localities (such as Canada, Australia, Scotland, and Mongolia). Furthermore, the initial value of 187Os/188Os from the Re-Os isochron age is 0.781, suggesting predominantly terrestrial input. Based on previous research, it is shown that during the Sturtian glaciation, under the influence of sea ice cover barrier and atmospheric material exchange, the hypoxic water led to the formation of iron and sulfide rich environments on the seafloor near hydrothermal vents, giving rise to a large number of rift basins rich in Mn2+. After the glaciation and water and atmospheric exchange of material recovery, the glacier meltwater carries the terrigenous material into the rift basin containing Mn2+, accompanied by the melting of the land glacier and the rapid increase of the atmospheric oxygen content. The surface water body of the rift basin is rapidly oxidized, and the oxidation degree is higher than the ocean area. Mn2+ are also oxidized to MnO2 and precipitate back into the environment, where they buried with organic matter, undergo diagenesis, and eventually form rhodochrosite.

Penyelidikan Zona Longsor dengan Metode Resistivitas dan Analisis Stabilitas Lereng untuk Mitigasi Bencana Tanah Longsor

<p>Research using geoelectric resistivity dipole-dipole configuration and slope stability analysis has been done in the area Jawar, District Dampit to find out the sliding plane landslide, landslide direction and factor of safety. Tracks Retrieval of data by the method of geoelectric resistivity as much as 5 tracks with the direction of the southeast to the northwest three tracks with a length of 100 m - 200 m and southwest to northeast as many as two passes with a length of 200-300 m. While the slope stability analysis performed topographic map data retrieval and data collection sondir and boring. Based on the analysis of the lithology of the study area using resistivity geoelectric method shows three layers of soil is clay (the top layer), tuff (middle layer) and basalt and lava (bottom layer). sliding plane landslide area is in the boundary between the layers of clay and tuff (a depth of 10.5 m). Based on the results of data processing of 3D resistivity geoelectric, landslide direction is southeast. Safety factor value of the security research area based slope stability analysis is 1.015. This value indicates that this area is prone to landslides.</p>

Multimethod Approach to the Study of Recent Volcanic Ashes from Tengger Volcanic Complex, Eastern Java, Indonesia

Volcanic ash is a volcanic product with a wide distribution that can be used as a geological marker. In volcanic regions such as Indonesia, the identification of the sources of volcanic ash and tuff layers from different volcanoes or eruptive events is a challenging task. In this study, samples of volcanic ash from the 2010 eruption of Bromo—a relatively young and active tuff cone volcano within the Sandsea caldera in the Tengger volcanic complex in East Java, Indonesia—along with two older tuff layers from the same caldera (Widodaren tuff: 1.8 kyr and Segarawedi tuff: 33 kyr) were subjected to magnetic measurements, geochemical analyses, and petrographic analyses. The aim is to attempt to use magnetic characters as a fingerprint for volcanic ash and tuff layers. The results show that the samples had variations in grain size and magnetic domain as indicated by the hysteresis parameters. These magnetic characters correlated with the results of geochemical and petrographic analyses, suggesting that magnetic properties may potentially be used as fingerprints to identify volcanic ashes and tuff layers.

Early cretaceous topographic growth of the Lhasaplano, Tibetan plateau: Constraints from the Damxung conglomerate

AbstractConstraining the timing of early topographic growth on the Tibetan plateau is critical for any models of India‐Asia collision, Himalayan orogeny and subsequent plateau development in the Cenozoic. Stratigraphic, sedimentological and provenance analysis of the Lower Cretaceous red‐beds of the Damxung Conglomerate provide new key information to reconstruct the paleogeography and the tectonic evolution of the Lhasa terrane at the time. The over 700‐m‐thick Damxung Conglomerate documents distal alluvial fan to braidplain sedimentation passing upward to proximal alluvial fan sedimentation. Deposition began near sea level, as documented by limestone beds occurring at the base of the unit. Zircon U–Pb dating of interbedded tuff layers constrain deposition age at ca. 111 Ma. Abundance of volcanic clasts, Cretaceous U–Pb ages and Hf isotopes of detrital zircons yielding mainly negative εHf(t) values together with paleocurrent data indicate an active volcanic source located in the North Lhasa subterrane. Pre‐Mesozoic‐aged zircon, recycled quartz and (meta) sedimentary rock fragments increase up‐section, indicating progressive erosional exhumation of the Paleozoic sedimentary/metasedimentary basement. The Damxung Conglomerate thus records a significant uplift and unroofing stage in the source region, implying initial topographic growth on the Lhasa terrane at early Albian time. Early Cretaceous topographic growth on the Lhasa terrane is supported by the stratigraphic record in the Linzhou basin, the Xigaze forearc basin and the southern Nima basin. In contrast, marine strata in the central‐western Lhasa terrane lasted until the early Cenomanian (ca. 96 Ma), indicating diachronous marine regression on the Lhasa terrane from east to west.