Change detection from multitemporal hyperspectral images has attracted great attention. Most traditional methods using spectral information for change detection treat a hyperspectral image as a two-dimensional matrix and do not take into account inherently structure information of spectrum, which leads to limited detection accuracy. To better approximate both spectral and spatial information, a novel three-order Tucker decomposition and reconstruction detector is proposed for hyperspectral change detection. Initially, Tucker decomposition and reconstruction strategies are used to eliminate the influence of various factors in a multitemporal dataset. Specifically, a singular value accumulation strategy is used to determine principal components in factor matrices. Meanwhile, a spectral angle is used to analyze spectral change after tensor processing in different domains. Finally, a new detector is designed to further improve the detection accuracy. Experiments conducted on five real hyperspectral datasets demonstrate that the proposed detector achieves a better detection performance.